Sunteți pe pagina 1din 38

Chapter 15: Organic Compounds and the Atomic Properties of Carbon

Chapter 15: Organic Compounds and the Atomic Properties


of Carbon
1. Select the correct name for the following compound.
A) 1,1,!trieth"l!#!meth"lbutane $) !eth"l!%,5!dimeth"lheptane
&) 1,1!dieth"l!#,!dimeth"lpentane ') none of the abo(e
C) #,%!dieth"l!!meth"lhe)ane
Ans: $ $ifficult": '
#. Select the correct name for the following compound.
A) #!isoprop"l!#,,%!trimeth"lbutane $) 1,1,#,#,!pentameth"lpentane
&) #!isoprop"l!#,!dimeth"lpentane ') none of the abo(e
C) #,,,%!tetrameth"lhe)ane
Ans: C $ifficult": '
Page ##*
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
. Select the correct name for the following compound.
A) 1,#!dieth"l!1!meth"l!!prop"l!%!isobut"lhe)ane
&) 1,+,+!trimeth"l!1,#,%!trieth"l!!prop"lhe)ane
C) 1,1,+!trimeth"l!,5,+!trieth"l!%!prop"lhe)ane
$) %,+!dieth"l!#,,!dimeth"l!5!prop"lnonane
') ,5!dieth"l!1,1,+!trimeth"l!%!prop"loctane
Ans: $ $ifficult": '
%. Select the correct name for the following compound.
A) #,%,5!triprop"lheptane $) 5!eth"l!#,%!diprop"loctane
&) +!meth"l!,%!diprop"lnonane ') %!eth"l!,!meth"l!5!prop"ldecane
C) %!eth"l!5,,!diprop"loctane
Ans: ' $ifficult": '
5. Select the correct name for the following compound.
A) ortho!diprop"lc"clopent"lhe)ane $) 1!he)"l!#,!diprop"lc"clopentane
Page ##1
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
&) #,!diprop"lc"clopent"lhe)ane ') 1,#!diprop"l!!he)"lc"clopentane
C) #!he)"l!1,5!diprop"lc"clopentane
Ans: $ $ifficult": -
+. Select the correct name for the following compound.
A) ortho!eth"lhept"lc"clopentane $) eth"lc"clopent"lheptane
&) meta!eth"lhept"lc"clopentane ') ortho!eth"lhept"lben.ene
C) 1!eth"l!#!hept"lc"clopentane
Ans: C $ifficult": '
,. Select the correct name for the following compound.
A) 1!eth"l!!meth"lc"clohe)ane $) meta!eth"lmeth"lben.ene
&) 1!meth"l!5!eth"lc"clohe)ane ') !eth"ltoluene
C) meta!eth"lmeth"lc"clohe)ane
Ans: A $ifficult": '
/. Select the correct name for the following compound.
A) cis!#!meth"l!%!heptene $) trans!+!meth"l!!heptene
Page ###
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
&) trans!#!meth"l!%!heptene ') cis!#!meth"l!!heptene
C) cis!+!meth"l!!heptene
Ans: C $ifficult": '
0. Select the correct name for the following compound.
A) cis!!eth"l!#,+1dimeth"l!+!prop"l!%!nonene
&) trans!!eth"l!#,+!dimeth"l!+!prop"l!%!nonene
C) cis-,!eth"l!%,/!dimeth"l!%!prop"l!5!nonene
$) trans!,!eth"l!%,/!dimeth"l!%!prop"l!5!nonene
') none of the abo(e
Ans: & $ifficult": -
1*. Select the correct name for the following compound.
A) cis!#!meth"l!#,!diprop"l!%!octene
&) cis!,!meth"l!+,,!diprop"l!%!octene
Page ##
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
C) cis-%,%!dimeth"l!5!prop"l!+!decene
$) trans!,,,!dimeth"l!+!prop"l!%!decene
') cis!,,,!dimeth"l!+!prop"l!%!decene
Ans: ' $ifficult": -
11. Select the correct name for the following compound.
A) cis!#,!dimeth"l!%!he)ene $) trans-%,5!dimeth"l!#!he)ene
&) trans!#,!dimeth"l!%!he)ene ') trans-%,5!dimeth"l!#!heptene
C) cis-%,5!dimeth"l!#!he)ene
Ans: $ $ifficult": -
1#. Select the correct name for the following compound.
A) cis!#,5!dieth"l!+!meth"l!!nonene $) %,+!dieth"l!!meth"l!+!nonene
&) #,5!dieth"l!+!meth"l!!nonene ') trans!#,5!dieth"l!+!meth"l!!nonene
C) cis!%,+!dieth"l!!meth"l!+!nonene
Ans: & $ifficult": -
Page ##%
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
1. Select the correct name for the following compound.
A) #!eth"l!!pentene $) %!meth"l!#!he)ene
&) %!eth"l!#!pentene ') none of the abo(e
C) !meth"l!%!he)ene
Ans: $ $ifficult": '
1%. Select the correct name for the following compound.
A) 1,1!dieth"l!!but"l!!he)ene $) !eth"l!5!prop"l!5!nonene
&) 5!but"l!!eth"l!5!octene ') %!but"l!+!eth"l!,%!octene
C) %!but"l!+!eth"l!!octene
Ans: C $ifficult": -
15. Select the correct name for the following compound.
A) 1!but"l!%!pent"l!!prop"lc"clohe)ene
&) 1!but"l!%!pent"l!5!prop"lc"clohe)ene
Page ##5
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
C) #!but"l!5!pent"l!+!prop"lc"clohe)ene
$) %!but"l!1!pent"l!#!prop"lc"clohe)ene
') 1!but"l!%!pent"l!!prop"lben.ene
Ans: A $ifficult": -
1+. Select the correct name for the following compound.
A) 1,1!dimeth"l!1!c"lcopent"l!#!pentane
&) 1,1!dimeth"l!#!he)ene!c"clopentane
C) #!c"clopent"l!#!meth"l!!he)ene
$) 5,5!dimeth"l!5!c"clopent"l!!pentane
') 5,5!dimeth"l!5!c"clopent"l!!pentene
Ans: C $ifficult": -
1,. Select the correct name for the following compound.
A) #!eth"l!%!prop"lc"cloheptene $) ,!eth"l!5!prop"lc"cloheptene
&) !eth"l!5!prop"lc"cloheptene ') !eth"l!5!prop"lc"clohe)ene
C) +!eth"l!%!prop"lc"cloheptene
Ans: & $ifficult": -
Page ##+
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
1/. Select the correct name for the following compound.
A) %!eth"l!1,1,5!trimeth"l!#!hept"ne $) !eth"l!,,!dimeth"l!5!oct"ne
&) %,5!dieth"l!1,1!dimeth"l!#!hept"ne ') 5!eth"l!#,+!dimeth"l!!oct"ne
C) 5!eth"l!#,+!dimeth"l!!octene
Ans: ' $ifficult": '
10. Select the correct name for the following compound.
A) 5!but"l!%,%!dimeth"l!!prop"l!1!heptene
&) 5!eth"l!%!%!dimeth"l!!prop"l!1!non"ne
C) 5!eth"l!+!+!dimeth"l!,!prop"l!/!non"ne
$) %,+!dieth"l!5!5!dimeth"l!%!dec"ne
') 5!eth"l!%!%!dimeth"l!!prop"l!1!nonene
Ans: & $ifficult": '
Page ##,
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
#*. Select the correct name for the following compound.
A) %!%!dieth"l!#!pent"ne $) %!eth"l!%!meth"l!#!he)"ne
&) #,#!dieth"l!!pent"ne ') #!eth"l!#!meth"l!%!he)ene
C) #!eth"l!#!meth"l!%!he)"ne
Ans: $ $ifficult": '
#1. Select the correct name for the following compound.
A) #,5!dimeth"l!!oct"ne!+!c"clobutane
&) %!c"clobut"l!1!isoprop"l!!meth"l!1!he)"ne
C) !c"clobut"l!%,,!dimeth"l!5!oct"ne
$) +!c"clobut"l!#,5!dimeth"l!!oct"ne
') !c"clobut"l!%,,!dimeth"l!5!octene
Ans: $ $ifficult": -
##. Select the correct name for the following compound.
A) meta!chloroeth"lc"clohe)ene $) 1!chloro!5!eth"lben.ene
Page ##/
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
&) 1!chloro!5!eth"lc"clohe)ene ') 1!chloro!!eth"lc"clohe)ane
C) meta!chloroeth"lben.ene
Ans: C $ifficult": '
#. Select the correct name for the following compound.
A) 1!chloro!#!eth"l!!prop"lc"clohe)ane
&) 1!chloro!#!eth"l!!prop"lc"clohe)ene
C) 1!chloro!ortho!eth"lprop"lben.ene
$) 1!chloro!meta!eth"lprop"lben.ene
') 1!chloro!#!eth"l!!prop"lben.ene
Ans: ' $ifficult": -
#%. Select the correct name for the following compound.
A) ortho!but"leth"lben.ene $) 1!but"l!#!eth"lc"clohe)ene
&) meta!but"leth"lben.ene ') 1!but"l!#!eth"lc"clohe)ane
C) para!but"leth"lben.ene
Ans: A $ifficult": '
Page ##0
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
#5. Select the correct name for the following compound.
A) ortho!dibromoben.ene $) 1,%!dibromoc"clohe)ene
&) meta!dibromoben.ene ') 1,%!dibromoc"clohe)ane
C) para!dibromoben.ene
Ans: C $ifficult": '
#+. Select the correct name for the following compound.
A) para!bromochloro!#!eth"lben.ene
&) %!bromo!1!chloro!#!eth"lben.ene
C) 5!bromo!#!chloro!1!eth"lben.ene
$) 1!bromo!%!chloro!!eth"lc"clohe)ene
') %!bromo!1!chloro!#!eth"lc"clohe)ane
Ans: & $ifficult": -
#,. Select the correct name for the following compound.
A) ,%!dieth"l!%!meth"l!#!butanol $) !eth"l!%!meth"l!#!he)anol
&) #,!dieth"l!%!pentanol ') !eth"l!%!meth"l!#!he)anal
Page #*
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
C) ,%!dieth"l!#!pentanol
Ans: $ $ifficult": -
#/. 2hat is the molecular formula of the compound #,!dimeth"l!%!c"clopent"l!5!
eth"ldecane3
A) C1+4% &) C1,4% C) C1/4+ $) C104/ ') C#*4%*
Ans: $ $ifficult": -
#0. 2hat is the difference between 1!but"ne and 1!butene3
A) 1 carbon atom $) % h"drogen atoms
&) 1 carbon atom and # h"drogen atoms ') 1 carbon atom and % h"drogen atoms
C) # h"drogen atoms
Ans: C $ifficult": -
*. Select the correct name for the following compound.
A) !eth"l!#,!dimeth"l!1!propanol $) ,%!dimeth"l!5!pentanol
&) #,,%!trimeth"l!1!butanol ') #,!dimeth"l!1!pentanal
C) #,!dimeth"l!1!pentanol
Ans: C $ifficult": -
Page #1
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
1. 2hich compound, if an", will be opticall" acti(e3
A) A &) & C) C $) $ ') 5one of the abo(e is opticall" acti(e.
Ans: & $ifficult": '
Page ##
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
#. 2hich compound, if an", will not be opticall" acti(e3
A) A &) & C) C $) $ ') 6he" are all opticall" acti(e.
Ans: $ $ifficult": '
. ')cluding c"clic compounds, how man" possible isomers e)ist for C%4/3
A) # &) % C) 5 $) + ') ,
Ans: & $ifficult": -
%. 7ncluding c"clic compounds, how man" possible isomers e)ist for C%4/3
A) # &) % C) 5 $) + ') ,
Ans: $ $ifficult": '
5. 2hich of the following features do c"clohe)ene and !meth"l!1!pent"ne ha(e in
common3
A) same ph"sical properties $) same molecular weight
&) same chemical properties ') same number of double bonds
C) same boiling point
Ans: $ $ifficult": '
Page #
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
+. Select the correct t"pe for the following reaction.
C4C4#C4#C4#O4 8 4&r C4C4#C4#C4#&r 8 4#O
A) deh"dration $) elimination
&) deh"dro)"lation ') substitution
C) addition
Ans: ' $ifficult": '
,. Alcohols undergo a (ariet" of reactions. 2hich one of the following reactions is not
undergone b" the alcohol functional group3
A) substitution
&) addition
C) deh"dration
$) o)idation to form a 9etone
') o)idation to form an aldeh"de or a carbo)"lic acid
Ans: & $ifficult": '
/. &en.ene will react with chloromethane in the presence of a catal"st to produce toluene
and h"drogen chloride. Select the correct reaction t"pe for the process.
A) addition &) elimination C) substitution $) o)idation ') reduction
Ans: C $ifficult": '
0. Select the correct reaction t"pe for the following process.
A) addition &) elimination C) substitution $) o)idation ') reduction
Ans: A $ifficult": '
Page #%
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
%*. 6he reaction of bromine with an al9ene such as c"clopentene is a good laborator" test
for the presence of a double bond in a compound. 2hat t"pe of reaction is it3
A) addition &) elimination C) substitution $) displacement ') reduction
Ans: A $ifficult": '
%1. #!chloro!#,!dimeth"lbutane will react with potassium h"dro)ide dissol(ed in alcohol to
produce #,!dimeth"l!#!butene. 2hat t"pe of reaction is this3
A) addition &) elimination C) substitution $) o)idation ') displacement
Ans: & $ifficult": '
%#. Select the correct t"pe for the following reaction.
A) addition &) elimination C) substitution $) o)idation ') deh"drogenation
Ans: & $ifficult": '
%. Select the correct t"pe for the following reaction.
A) addition &) elimination C) carbon"lation $) deh"dration ') o)idation
Ans: ' $ifficult": -
Page #5
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
%%. Select the correct t"pe for the following reaction.
A) addition &) elimination C) substitution $) o)idation ') reduction
Ans: $ $ifficult": -
%5. 7dentif" the functional group circled.
A) aldeh"de &) 9etone C) alcohol $) ester ') carbo)"lic acid
Ans: ' $ifficult": '
%+. :anillin is a fla(oring agent which occurs naturall" in the (anilla bean, the seed of an
orchid. 7dentif" the functional group circled.
A) aldeh"de &) 9etone C) alcohol $) carbo)"lic acid ') carbon"l
Ans: $ $ifficult": '
%,. One source of a mus9" odor in perfumes is ci(etone, a compound e)tracted from the
scent gland of the ci(et cat. 7dentif" the functional group circled.
A) aldeh"de &) 9etone C) alcohol $) carbo)"lic acid ') o)ide
Ans: & $ifficult": '
Page #+
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
%/. Aspirin is an effecti(e and widel" used pain relie(er. 7dentif" the functional group
circled.
A) aldeh"de &) 9etone C) ester $) carbo)"lic acid ') carbon"l
Ans: C $ifficult": -
%0. 'nflurane is an effecti(e gaseous anesthetic with relati(el" low flammabilit". 7dentif"
the functional group circled.
A) aldeh"de &) 9etone C) ester $) ether ') alcohol
Ans: $ $ifficult": '
5*. Anethole, a deri(ati(e of anise, is used in fla(oring and as perfume in soap and
toothpaste. 7dentif" the functional group circled.
A) aldeh"de &) 9etone C) alcohol $) ester ') ether
Ans: ' $ifficult": '
51. ;l"cerin is used in cosmetics as a moisturi.er. 7dentif" the functional group circled.
A) carbo)"lic acid &) alcohol C) ester $) ether ') aldeh"de
Ans: & $ifficult": '
Page #,
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
5#. ;lucose is an important sugar in a person<s metabolic c"cle. 7dentif" the functional
group circled.
A) aldeh"de &) 9etone C) alcohol $) ester ') carbo)"lic acid
Ans: A $ifficult": '
5. 6estosterone is a male hormone. 7dentif" the functional group circled.
A) aldeh"de &) 9etone C) alcohol $) ester ') carbo)"l
Ans: & $ifficult": '
5%. 6he compound shown below is responsible for the odor in rancid butter. 7dentif" the
functional group circled.
A) aldeh"de &) 9etone C) alcohol $) carbo)"lic acid ') carbon"l
Ans: $ $ifficult": '
55. &en.ocaine is from a famil" of chemicals that are good local anesthetics. 7dentif" the
functional group circled.
A) aldeh"de &) 9etone C) ester $) carbo)"lic acid ') carbon"l
Ans: C $ifficult": -
Page #/
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
5+. Putrescine is produced during the deca" and protein brea9down of meats and is
responsible for some of the odor found in them. 7dentif" the functional group circled.
A) aldeh"de &) 9etone C) amide $) nitrile ') amine
Ans: ' $ifficult": '
5,. Serotonin transmits ner(e impulses through the bod". 7dentif" the functional group
circled.
A) aldeh"de &) alcohol C) amide $) amine ') nitride
Ans: $ $ifficult": '
5/. Acetaminophen is a widel" used and an effecti(e pain relie(er. 7dentif" the functional
group circled.
A) aldeh"de &) alcohol C) amide $) amine ') carbon"l
Ans: C $ifficult": -
50. =rea carries waste nitrogen from the bod" in urine. 7dentif" the functional group circled.
A) aldeh"de &) alcohol C) carbo)"l $) amine ') amide
Ans: ' $ifficult": -
Page #0
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
+*. 6he millipede e>ects the compound shown below to protect itself from its enemies.
7dentif" the functional group circled.
A) nitrile &) alcohol C) amide $) amine ') nitro
Ans: A $ifficult": -
+1. Am"gdalin ?@aetrile) was once touted for its potential anticancer acti(it". 4owe(er, the
claims were ne(er scientificall" (erified. 7dentif" the functional group circled.
A) carbonite &) ether C) amide $) amine ') nitrile
Ans: ' $ifficult": -
+#. 2hich one of the following classes of organic compound does not contain the carbon"l
?CAO) group3
A) aldeh"des &) carbo)"lic acids C) 9etones $) alcohols ') esters
Ans: $ $ifficult": '
+. 7dentif" the principal organic product of the reaction between butane and chlorine.
A) C4Cl
&) C4C4#Cl
C) C4C4ClC4
$) C4C4#C4ClC4
') 5one of the abo(e is a ma>or product of the reaction.
Ans: $ $ifficult": -
Page #%*
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
+%. 7dentif" the principal organic product when ben."l chloride reacts with aBueous sodium
h"dro)ide.
A) A &) & C) C $) $ ') none of the abo(e
Ans: A $ifficult": -
+5. 7dentif" the two principal products of the reaction between ammonia and eth"l
propionate.
A) A
&) &
C) C
$) $
Page #%1
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
') 5one of the abo(e is a ma>or product of the reaction.
Ans: & $ifficult": 4
++. 7dentif" the products of the following reaction.
A) A
&) &
C) C
$) $
') 5one of the abo(e pairs of compounds are formed in the reaction.
Ans: & $ifficult": 4
Page #%#
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
+,. 7dentif" the products for the reaction between c"cloheptene and bromine.
A) A
&) &
C) C
$) $
') 5one of the abo(e are the ma>or products of the reaction.
Ans: & $ifficult": -
+/. 7dentif" the products of the reaction of !octene with chlorine.

CH
3
CH
2
CH
2
CH
2
CH CHCH
2
CH
3
Cl
2
8
A)
CH
3
CH
2
CH
2
CH
2
CH CHCH
2
CH
3
Cl Cl
&)
CH
3
CH
2
CH
2
CH
2
CH CHCH
2
CH
3
Cl Cl
Cl Cl
C)
CH
3
CH
2
CH
2
CH
2
CH CHCH
2
CH
3
Cl H
$)
CH
3
CH
2
CH
2
CH
2
CH CHCH
2
CH
3
Cl Cl
')
CH
3
CH
2
CH
2
CH
2
CH
2
Cl CH
3
CH
2
CH
2
Cl 8
Page #%
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
Ans: A $ifficult": -
+0. 7dentif" the products of the reaction between #!bromopentane and potassium etho)ide.
A) A
&) &
C) C
$) $
') 5one of the abo(e are the ma>or products of the reaction.
Ans: C $ifficult": 4
Page #%%
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
,*. 7dentif" the principal organic products for the following reaction.
A) A
&) &
C) C
$) $
') 5one of the abo(e are the ma>or products of the reaction.
Ans: & $ifficult": 4
Page #%5
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
,1. 7dentif" the organic product when c"clohe)anol reacts with e)cess potassium
dichromate in the presence of sulfuric acid.
A) A
&) &
C) C
$) $
') 5one of the abo(e is a ma>or product of the reaction.
Ans: & $ifficult": -
Page #%+
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
,#. 7dentif" the organic product when !c"lcobut"l!1!propanol reacts with e)cess potassium
dichromate in sulfuric acid.
A) A
&) &
C) C
$) $
') 5one of the abo(e is a ma>or product of the reaction.
Ans: C $ifficult": 4
Page #%,
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
,. 7dentif" the organic product for the reaction of #!pentanol with sulfuric acid.
A) A
&) &
C) C
$) $
') 5one of the abo(e is a ma>or product of the reaction.
Ans: $ $ifficult": -
,%. 7dentif" the organic product when c"clopentanol reacts with sulfuric acid.
A) A
&) &
C) C
Page #%/
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
$) $
') 5one of the abo(e is a ma>or product of the reaction.
Ans: & $ifficult": -
,5. One characteristic of the monomers that form condensation pol"mers that is not
common in monomers which form addition pol"mers is
A) the presence of pi bonds.
&) the presence of two functional groups.
C) the presence of al9"l side chains.
$) the abilit" to form free radicals.
') the presence of sulfur atoms.
Ans: & $ifficult": -
,+. 2hich of the following pol"mers is a condensation pol"mer3
A) pol"st"rene $) pol"prop"lene
&) 6eflon
C
') $acron
C
C) pol"(in"lchloride
Ans: ' $ifficult": 4
,,. 5"lon!t"pe compounds are prepared b" the reaction of
A) a diol with a diacid. $) an amine with a diacid.
&) an alcohol with a diacid. ') a diamine with an acid.
C) a diamine with a diacid.
Ans: C $ifficult": -
,/. $acron is a DDDDDDDDDDD compound and is produced b" a DDDDDDDDDD reaction.
A) pol"amideE addition $) pol"esterE condensation
&) pol"amideE condensation ') pol"eneE addition
C) pol"esterE addition
Ans: $ $ifficult": 4
,0. 6he most abundant organic chemical on earth is
A) gl"cogen. &) starch. C) cellulose. $) glucose. ') carbonate.
Ans: C $ifficult": -
Page #%0
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
/*. 'ach amino acid has two functional groups in common and one of #* other groups
attached to the !carbon. 6he two functional groups are
A) carbo)"l and amine. $) alcohol and amine.
&) ester and amine. ') carbo)"l and peptide.
C) carbo)"l and amide.
Ans: A $ifficult": '
/1. 4elical and sheet!li9e segments in proteins arise from
A) disulfide bridges.
&) salt bridges.
C) crosslin9ing (ia co(alent bonds.
$) dispersion forces within the protein<s interior.
') h"drogen bonding.
Ans: ' $ifficult": -
/#. 6he protein amino acid seBuence, the F5A base seBuence, and the $5A base seBuence
are interrelated. 2hich of the following descriptions is correct3
A) 6he F5A base seBuence determines the $5A base seBuence which, in turn,
determines the protein amino acid seBuence.
&) 6he $5A base seBuence determines the F5A base seBuence which, in turn,
determines the protein amino acid seBuence.
C) 6he $5A base seBuence determines the protein amino acid seBuence which, in
turn, determines the F5A base seBuence.
$) 6he F5A base seBuence determines the protein amino acid seBuence which, in
turn, determines the $5A base seBuence.
') 5one of the abo(e statements is correct.
Ans: & $ifficult": -
/. $raw and name two non!al9enes with the formula C%4/.
Ans:
$ifficult": '
/%. $raw and name all stable molecules with the formula C541#.
Ans:
Page #5*
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
$ifficult": -
/5. $raw and name four al9enes with the formula C%4/.
Ans:
$ifficult": -
/+. 5ame the compound with the molecular structure shown.
Ans: #!meth"l!#!pentene
$ifficult": -
/,. $raw the structure of trans!5!meth"l!!heptene.
Ans:
$ifficult": -
//. 5ame the compounds:
Ans: a. c"clobutane
Page #51
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
b. c"clooctene
c. toluene ?meth"lben.ene)
$ifficult": '
/0. 2hat is the simplest molecular formula for
a. an al9ane capable of ha(ing structural isomers3
b. an al9ane capable of ha(ing optical isomers3
c. an al9ene capable of ha(ing geometrical isomers3
Ans: a. C%41*
b. C,41+
c. C%4/
$ifficult": 4
0*. 7n one sentence, what is the general reBuirement for a molecule to be opticall" acti(e3
Ans: 7n order to be opticall" acti(e, the compound must ha(e a non!superimposable
mirror image.
$ifficult": -
01. a. $raw two different structures with the molecular formula C#4+O.
b. 5ame the functional group in each structure.
c. 2hich one will ha(e the higher boiling point, and wh"3
Ans: a. 4CG C4#GO4 4CGOG C4
b. alcohol and ether
c. 6he alcohol will ha(e the higher boiling pointE it will ha(e h"drogen bonding
while the ether does not.
$ifficult": -
0#. 5ame each of the following functional groups:
Ans: a. alcohol
b. ether
c. 9etone
d. aldeh"de
e. carbo)"lic acid
f. amide
$ifficult": '
Page #5#
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
0. 2rite down the structure of the missing organic reactant or product?s) in the following
reactions, and name the t"pe of reaction in(ol(ed ?inorganic products ma" also be
formed):
Ans:
Page #5
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
$ifficult": -
0%. $escribe and contrast fibrous and globular proteins in terms of their amino acid
composition, their structure, and their function.
Ans: Hibrous proteins are composed of relati(el" few amino acids in a repeating
pattern. 6heir structures are helices or sheets, and the" are found in hair, s9in and
muscle. ;lobular proteins use more amino acids in their structures, and the" ha(e
(arious of irregular shapes. 6heir functions are (arious: messenger molecules,
en."mes ?catal"sts), etc.
$ifficult": -
05. ')plain how a disulfide bridge can arise a protein molecule.
Ans: $isulfide bridges arise when two c"steine 1S14 side chains react to form a
co(alent 1S1S1 lin9 between the two regions of the protein bac9bone. 6he two
regions of the protein bac9bone are thus held together.
Page #5%
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
$ifficult": 4
0+. ')plain how a salt bridge can arise a protein molecule.
Ans: A salt bridge is the result of ionic attraction between a side chain with a
carbo)"late ?1COO
1
) group and one with a protonated amine group ?154
8
).
6hese regions of the molecule are then held together b" this ionic attraction.
$ifficult": 4
0,. 5ame the three component parts of a nucleotide.
Ans: phosphate, base, sugar
$ifficult": '
0/. ')plain what is meant b" Icomplementar"J in the conte)t of $5A strands.
Ans: 'ach nucleotide along a single strand of $5A has one of four possible bases,
namel" guanine ?;), c"tosine ?C), adenine ?A), and th"mine ?6). 6he double heli)
of $5A is held in place b" h"drogen bonds between pairs of bases, one base
being on each of the two strands. ; alwa"s pairs with C and A alwa"s pairs with
6. 6hus, the base seBuence on one strand determines the base seBuence on the
other strand, and the strands are Icomplementar"J to each other.
$ifficult": -
00. ;i(en that each !base seBuence in $5A is a Icode wordJ for a particular amino acid,
how man" different code words are possible using a !base seBuence and the bases
a(ailable in $5A3
Ans: % % % A +%
$ifficult": -
1**. &ecause organic compounds are associated with li(ing organisms, their properties are
go(erned b" fundamentall" different chemical principles from those of inorganic
compounds.
Ans: Halse $ifficult": '
1*1. 'thane ?C#4+) is much more reacti(e than disilane ?Si#4+).
Ans: Halse $ifficult": '
1*#. 6he carbon atoms in a molecule of c"clohe)ane lie in the same plane.
Ans: Halse $ifficult": -
1*. All the atoms in a molecule of ben.ene lie in the same plane.
Ans: 6rue $ifficult": -
1*%. &oth al9enes and al9"nes e)hibit geometric ?cisKtrans) isomerism.
Ans: Halse $ifficult": '
Page #55
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
1*5. &ecause of delocali.ation, all the carbon!carbon bond lengths in 1,!c"clopentadiene are
identical.
Ans: Halse $ifficult": '
1*+. As a result of delocali.ation of the pi!electrons, all the carbon!carbon bonds in ben.ene
are identical.
Ans: 6rue $ifficult": '
1*,. A characteristic reaction of al9anes is addition.
Ans: Halse $ifficult": '
1*/. A characteristic reaction of al9enes is addition.
Ans: 6rue $ifficult": '
1*0. A characteristic reaction of haloal9anes is substitution.
Ans: 6rue $ifficult": '
11*. All alcohols are capable of h"drogen bonding.
Ans: 6rue $ifficult": -
111. All 9etone molecules are capable of h"drogen bonding to other 9etone molecules.
Ans: Halse $ifficult": -
11#. Carbo)"lic acids are wea9 acids.
Ans: 6rue $ifficult": -
11. Secondar" amines ha(e the general formula F54#.
Ans: Halse $ifficult": '
11%. 'sters can be formed b" the deh"dration!condensation of a carbo)"lic acid and an
alcohol.
Ans: 6rue $ifficult": -
115. Addition pol"mers are mostl" made from monomers with carbon!carbon double bonds.
Ans: 6rue $ifficult": -
11+. Condensation pol"mers are formed b" free radical addition reactions.
Ans: Halse $ifficult": -
11,. &oth n"lons and proteins are pol"amides.
Ans: 6rue $ifficult": -
11/. Amino acids in solution can undergo an internal acid!base reaction.
Ans: 6rue $ifficult": -
Page #5+
Chapter 15: Organic Compounds and the Atomic Properties of Carbon
110. 6he bac9bone of protein molecules consists of repeating 51C1C1O units.
Ans: Halse $ifficult": -
Page #5,

S-ar putea să vă placă și