Chapter 15: Organic Compounds and the Atomic Properties of Carbon
Chapter 15: Organic Compounds and the Atomic Properties
of Carbon 1. Select the correct name for the following compound. A) 1,1,!trieth"l!#!meth"lbutane $) !eth"l!%,5!dimeth"lheptane &) 1,1!dieth"l!#,!dimeth"lpentane ') none of the abo(e C) #,%!dieth"l!!meth"lhe)ane Ans: $ $ifficult": ' #. Select the correct name for the following compound. A) #!isoprop"l!#,,%!trimeth"lbutane $) 1,1,#,#,!pentameth"lpentane &) #!isoprop"l!#,!dimeth"lpentane ') none of the abo(e C) #,,,%!tetrameth"lhe)ane Ans: C $ifficult": ' Page ##* Chapter 15: Organic Compounds and the Atomic Properties of Carbon . Select the correct name for the following compound. A) 1,#!dieth"l!1!meth"l!!prop"l!%!isobut"lhe)ane &) 1,+,+!trimeth"l!1,#,%!trieth"l!!prop"lhe)ane C) 1,1,+!trimeth"l!,5,+!trieth"l!%!prop"lhe)ane $) %,+!dieth"l!#,,!dimeth"l!5!prop"lnonane ') ,5!dieth"l!1,1,+!trimeth"l!%!prop"loctane Ans: $ $ifficult": ' %. Select the correct name for the following compound. A) #,%,5!triprop"lheptane $) 5!eth"l!#,%!diprop"loctane &) +!meth"l!,%!diprop"lnonane ') %!eth"l!,!meth"l!5!prop"ldecane C) %!eth"l!5,,!diprop"loctane Ans: ' $ifficult": ' 5. Select the correct name for the following compound. A) ortho!diprop"lc"clopent"lhe)ane $) 1!he)"l!#,!diprop"lc"clopentane Page ##1 Chapter 15: Organic Compounds and the Atomic Properties of Carbon &) #,!diprop"lc"clopent"lhe)ane ') 1,#!diprop"l!!he)"lc"clopentane C) #!he)"l!1,5!diprop"lc"clopentane Ans: $ $ifficult": - +. Select the correct name for the following compound. A) ortho!eth"lhept"lc"clopentane $) eth"lc"clopent"lheptane &) meta!eth"lhept"lc"clopentane ') ortho!eth"lhept"lben.ene C) 1!eth"l!#!hept"lc"clopentane Ans: C $ifficult": ' ,. Select the correct name for the following compound. A) 1!eth"l!!meth"lc"clohe)ane $) meta!eth"lmeth"lben.ene &) 1!meth"l!5!eth"lc"clohe)ane ') !eth"ltoluene C) meta!eth"lmeth"lc"clohe)ane Ans: A $ifficult": ' /. Select the correct name for the following compound. A) cis!#!meth"l!%!heptene $) trans!+!meth"l!!heptene Page ### Chapter 15: Organic Compounds and the Atomic Properties of Carbon &) trans!#!meth"l!%!heptene ') cis!#!meth"l!!heptene C) cis!+!meth"l!!heptene Ans: C $ifficult": ' 0. Select the correct name for the following compound. A) cis!!eth"l!#,+1dimeth"l!+!prop"l!%!nonene &) trans!!eth"l!#,+!dimeth"l!+!prop"l!%!nonene C) cis-,!eth"l!%,/!dimeth"l!%!prop"l!5!nonene $) trans!,!eth"l!%,/!dimeth"l!%!prop"l!5!nonene ') none of the abo(e Ans: & $ifficult": - 1*. Select the correct name for the following compound. A) cis!#!meth"l!#,!diprop"l!%!octene &) cis!,!meth"l!+,,!diprop"l!%!octene Page ## Chapter 15: Organic Compounds and the Atomic Properties of Carbon C) cis-%,%!dimeth"l!5!prop"l!+!decene $) trans!,,,!dimeth"l!+!prop"l!%!decene ') cis!,,,!dimeth"l!+!prop"l!%!decene Ans: ' $ifficult": - 11. Select the correct name for the following compound. A) cis!#,!dimeth"l!%!he)ene $) trans-%,5!dimeth"l!#!he)ene &) trans!#,!dimeth"l!%!he)ene ') trans-%,5!dimeth"l!#!heptene C) cis-%,5!dimeth"l!#!he)ene Ans: $ $ifficult": - 1#. Select the correct name for the following compound. A) cis!#,5!dieth"l!+!meth"l!!nonene $) %,+!dieth"l!!meth"l!+!nonene &) #,5!dieth"l!+!meth"l!!nonene ') trans!#,5!dieth"l!+!meth"l!!nonene C) cis!%,+!dieth"l!!meth"l!+!nonene Ans: & $ifficult": - Page ##% Chapter 15: Organic Compounds and the Atomic Properties of Carbon 1. Select the correct name for the following compound. A) #!eth"l!!pentene $) %!meth"l!#!he)ene &) %!eth"l!#!pentene ') none of the abo(e C) !meth"l!%!he)ene Ans: $ $ifficult": ' 1%. Select the correct name for the following compound. A) 1,1!dieth"l!!but"l!!he)ene $) !eth"l!5!prop"l!5!nonene &) 5!but"l!!eth"l!5!octene ') %!but"l!+!eth"l!,%!octene C) %!but"l!+!eth"l!!octene Ans: C $ifficult": - 15. Select the correct name for the following compound. A) 1!but"l!%!pent"l!!prop"lc"clohe)ene &) 1!but"l!%!pent"l!5!prop"lc"clohe)ene Page ##5 Chapter 15: Organic Compounds and the Atomic Properties of Carbon C) #!but"l!5!pent"l!+!prop"lc"clohe)ene $) %!but"l!1!pent"l!#!prop"lc"clohe)ene ') 1!but"l!%!pent"l!!prop"lben.ene Ans: A $ifficult": - 1+. Select the correct name for the following compound. A) 1,1!dimeth"l!1!c"lcopent"l!#!pentane &) 1,1!dimeth"l!#!he)ene!c"clopentane C) #!c"clopent"l!#!meth"l!!he)ene $) 5,5!dimeth"l!5!c"clopent"l!!pentane ') 5,5!dimeth"l!5!c"clopent"l!!pentene Ans: C $ifficult": - 1,. Select the correct name for the following compound. A) #!eth"l!%!prop"lc"cloheptene $) ,!eth"l!5!prop"lc"cloheptene &) !eth"l!5!prop"lc"cloheptene ') !eth"l!5!prop"lc"clohe)ene C) +!eth"l!%!prop"lc"cloheptene Ans: & $ifficult": - Page ##+ Chapter 15: Organic Compounds and the Atomic Properties of Carbon 1/. Select the correct name for the following compound. A) %!eth"l!1,1,5!trimeth"l!#!hept"ne $) !eth"l!,,!dimeth"l!5!oct"ne &) %,5!dieth"l!1,1!dimeth"l!#!hept"ne ') 5!eth"l!#,+!dimeth"l!!oct"ne C) 5!eth"l!#,+!dimeth"l!!octene Ans: ' $ifficult": ' 10. Select the correct name for the following compound. A) 5!but"l!%,%!dimeth"l!!prop"l!1!heptene &) 5!eth"l!%!%!dimeth"l!!prop"l!1!non"ne C) 5!eth"l!+!+!dimeth"l!,!prop"l!/!non"ne $) %,+!dieth"l!5!5!dimeth"l!%!dec"ne ') 5!eth"l!%!%!dimeth"l!!prop"l!1!nonene Ans: & $ifficult": ' Page ##, Chapter 15: Organic Compounds and the Atomic Properties of Carbon #*. Select the correct name for the following compound. A) %!%!dieth"l!#!pent"ne $) %!eth"l!%!meth"l!#!he)"ne &) #,#!dieth"l!!pent"ne ') #!eth"l!#!meth"l!%!he)ene C) #!eth"l!#!meth"l!%!he)"ne Ans: $ $ifficult": ' #1. Select the correct name for the following compound. A) #,5!dimeth"l!!oct"ne!+!c"clobutane &) %!c"clobut"l!1!isoprop"l!!meth"l!1!he)"ne C) !c"clobut"l!%,,!dimeth"l!5!oct"ne $) +!c"clobut"l!#,5!dimeth"l!!oct"ne ') !c"clobut"l!%,,!dimeth"l!5!octene Ans: $ $ifficult": - ##. Select the correct name for the following compound. A) meta!chloroeth"lc"clohe)ene $) 1!chloro!5!eth"lben.ene Page ##/ Chapter 15: Organic Compounds and the Atomic Properties of Carbon &) 1!chloro!5!eth"lc"clohe)ene ') 1!chloro!!eth"lc"clohe)ane C) meta!chloroeth"lben.ene Ans: C $ifficult": ' #. Select the correct name for the following compound. A) 1!chloro!#!eth"l!!prop"lc"clohe)ane &) 1!chloro!#!eth"l!!prop"lc"clohe)ene C) 1!chloro!ortho!eth"lprop"lben.ene $) 1!chloro!meta!eth"lprop"lben.ene ') 1!chloro!#!eth"l!!prop"lben.ene Ans: ' $ifficult": - #%. Select the correct name for the following compound. A) ortho!but"leth"lben.ene $) 1!but"l!#!eth"lc"clohe)ene &) meta!but"leth"lben.ene ') 1!but"l!#!eth"lc"clohe)ane C) para!but"leth"lben.ene Ans: A $ifficult": ' Page ##0 Chapter 15: Organic Compounds and the Atomic Properties of Carbon #5. Select the correct name for the following compound. A) ortho!dibromoben.ene $) 1,%!dibromoc"clohe)ene &) meta!dibromoben.ene ') 1,%!dibromoc"clohe)ane C) para!dibromoben.ene Ans: C $ifficult": ' #+. Select the correct name for the following compound. A) para!bromochloro!#!eth"lben.ene &) %!bromo!1!chloro!#!eth"lben.ene C) 5!bromo!#!chloro!1!eth"lben.ene $) 1!bromo!%!chloro!!eth"lc"clohe)ene ') %!bromo!1!chloro!#!eth"lc"clohe)ane Ans: & $ifficult": - #,. Select the correct name for the following compound. A) ,%!dieth"l!%!meth"l!#!butanol $) !eth"l!%!meth"l!#!he)anol &) #,!dieth"l!%!pentanol ') !eth"l!%!meth"l!#!he)anal Page #* Chapter 15: Organic Compounds and the Atomic Properties of Carbon C) ,%!dieth"l!#!pentanol Ans: $ $ifficult": - #/. 2hat is the molecular formula of the compound #,!dimeth"l!%!c"clopent"l!5! eth"ldecane3 A) C1+4% &) C1,4% C) C1/4+ $) C104/ ') C#*4%* Ans: $ $ifficult": - #0. 2hat is the difference between 1!but"ne and 1!butene3 A) 1 carbon atom $) % h"drogen atoms &) 1 carbon atom and # h"drogen atoms ') 1 carbon atom and % h"drogen atoms C) # h"drogen atoms Ans: C $ifficult": - *. Select the correct name for the following compound. A) !eth"l!#,!dimeth"l!1!propanol $) ,%!dimeth"l!5!pentanol &) #,,%!trimeth"l!1!butanol ') #,!dimeth"l!1!pentanal C) #,!dimeth"l!1!pentanol Ans: C $ifficult": - Page #1 Chapter 15: Organic Compounds and the Atomic Properties of Carbon 1. 2hich compound, if an", will be opticall" acti(e3 A) A &) & C) C $) $ ') 5one of the abo(e is opticall" acti(e. Ans: & $ifficult": ' Page ## Chapter 15: Organic Compounds and the Atomic Properties of Carbon #. 2hich compound, if an", will not be opticall" acti(e3 A) A &) & C) C $) $ ') 6he" are all opticall" acti(e. Ans: $ $ifficult": ' . ')cluding c"clic compounds, how man" possible isomers e)ist for C%4/3 A) # &) % C) 5 $) + ') , Ans: & $ifficult": - %. 7ncluding c"clic compounds, how man" possible isomers e)ist for C%4/3 A) # &) % C) 5 $) + ') , Ans: $ $ifficult": ' 5. 2hich of the following features do c"clohe)ene and !meth"l!1!pent"ne ha(e in common3 A) same ph"sical properties $) same molecular weight &) same chemical properties ') same number of double bonds C) same boiling point Ans: $ $ifficult": ' Page # Chapter 15: Organic Compounds and the Atomic Properties of Carbon +. Select the correct t"pe for the following reaction. C4C4#C4#C4#O4 8 4&r C4C4#C4#C4#&r 8 4#O A) deh"dration $) elimination &) deh"dro)"lation ') substitution C) addition Ans: ' $ifficult": ' ,. Alcohols undergo a (ariet" of reactions. 2hich one of the following reactions is not undergone b" the alcohol functional group3 A) substitution &) addition C) deh"dration $) o)idation to form a 9etone ') o)idation to form an aldeh"de or a carbo)"lic acid Ans: & $ifficult": ' /. &en.ene will react with chloromethane in the presence of a catal"st to produce toluene and h"drogen chloride. Select the correct reaction t"pe for the process. A) addition &) elimination C) substitution $) o)idation ') reduction Ans: C $ifficult": ' 0. Select the correct reaction t"pe for the following process. A) addition &) elimination C) substitution $) o)idation ') reduction Ans: A $ifficult": ' Page #% Chapter 15: Organic Compounds and the Atomic Properties of Carbon %*. 6he reaction of bromine with an al9ene such as c"clopentene is a good laborator" test for the presence of a double bond in a compound. 2hat t"pe of reaction is it3 A) addition &) elimination C) substitution $) displacement ') reduction Ans: A $ifficult": ' %1. #!chloro!#,!dimeth"lbutane will react with potassium h"dro)ide dissol(ed in alcohol to produce #,!dimeth"l!#!butene. 2hat t"pe of reaction is this3 A) addition &) elimination C) substitution $) o)idation ') displacement Ans: & $ifficult": ' %#. Select the correct t"pe for the following reaction. A) addition &) elimination C) substitution $) o)idation ') deh"drogenation Ans: & $ifficult": ' %. Select the correct t"pe for the following reaction. A) addition &) elimination C) carbon"lation $) deh"dration ') o)idation Ans: ' $ifficult": - Page #5 Chapter 15: Organic Compounds and the Atomic Properties of Carbon %%. Select the correct t"pe for the following reaction. A) addition &) elimination C) substitution $) o)idation ') reduction Ans: $ $ifficult": - %5. 7dentif" the functional group circled. A) aldeh"de &) 9etone C) alcohol $) ester ') carbo)"lic acid Ans: ' $ifficult": ' %+. :anillin is a fla(oring agent which occurs naturall" in the (anilla bean, the seed of an orchid. 7dentif" the functional group circled. A) aldeh"de &) 9etone C) alcohol $) carbo)"lic acid ') carbon"l Ans: $ $ifficult": ' %,. One source of a mus9" odor in perfumes is ci(etone, a compound e)tracted from the scent gland of the ci(et cat. 7dentif" the functional group circled. A) aldeh"de &) 9etone C) alcohol $) carbo)"lic acid ') o)ide Ans: & $ifficult": ' Page #+ Chapter 15: Organic Compounds and the Atomic Properties of Carbon %/. Aspirin is an effecti(e and widel" used pain relie(er. 7dentif" the functional group circled. A) aldeh"de &) 9etone C) ester $) carbo)"lic acid ') carbon"l Ans: C $ifficult": - %0. 'nflurane is an effecti(e gaseous anesthetic with relati(el" low flammabilit". 7dentif" the functional group circled. A) aldeh"de &) 9etone C) ester $) ether ') alcohol Ans: $ $ifficult": ' 5*. Anethole, a deri(ati(e of anise, is used in fla(oring and as perfume in soap and toothpaste. 7dentif" the functional group circled. A) aldeh"de &) 9etone C) alcohol $) ester ') ether Ans: ' $ifficult": ' 51. ;l"cerin is used in cosmetics as a moisturi.er. 7dentif" the functional group circled. A) carbo)"lic acid &) alcohol C) ester $) ether ') aldeh"de Ans: & $ifficult": ' Page #, Chapter 15: Organic Compounds and the Atomic Properties of Carbon 5#. ;lucose is an important sugar in a person<s metabolic c"cle. 7dentif" the functional group circled. A) aldeh"de &) 9etone C) alcohol $) ester ') carbo)"lic acid Ans: A $ifficult": ' 5. 6estosterone is a male hormone. 7dentif" the functional group circled. A) aldeh"de &) 9etone C) alcohol $) ester ') carbo)"l Ans: & $ifficult": ' 5%. 6he compound shown below is responsible for the odor in rancid butter. 7dentif" the functional group circled. A) aldeh"de &) 9etone C) alcohol $) carbo)"lic acid ') carbon"l Ans: $ $ifficult": ' 55. &en.ocaine is from a famil" of chemicals that are good local anesthetics. 7dentif" the functional group circled. A) aldeh"de &) 9etone C) ester $) carbo)"lic acid ') carbon"l Ans: C $ifficult": - Page #/ Chapter 15: Organic Compounds and the Atomic Properties of Carbon 5+. Putrescine is produced during the deca" and protein brea9down of meats and is responsible for some of the odor found in them. 7dentif" the functional group circled. A) aldeh"de &) 9etone C) amide $) nitrile ') amine Ans: ' $ifficult": ' 5,. Serotonin transmits ner(e impulses through the bod". 7dentif" the functional group circled. A) aldeh"de &) alcohol C) amide $) amine ') nitride Ans: $ $ifficult": ' 5/. Acetaminophen is a widel" used and an effecti(e pain relie(er. 7dentif" the functional group circled. A) aldeh"de &) alcohol C) amide $) amine ') carbon"l Ans: C $ifficult": - 50. =rea carries waste nitrogen from the bod" in urine. 7dentif" the functional group circled. A) aldeh"de &) alcohol C) carbo)"l $) amine ') amide Ans: ' $ifficult": - Page #0 Chapter 15: Organic Compounds and the Atomic Properties of Carbon +*. 6he millipede e>ects the compound shown below to protect itself from its enemies. 7dentif" the functional group circled. A) nitrile &) alcohol C) amide $) amine ') nitro Ans: A $ifficult": - +1. Am"gdalin ?@aetrile) was once touted for its potential anticancer acti(it". 4owe(er, the claims were ne(er scientificall" (erified. 7dentif" the functional group circled. A) carbonite &) ether C) amide $) amine ') nitrile Ans: ' $ifficult": - +#. 2hich one of the following classes of organic compound does not contain the carbon"l ?CAO) group3 A) aldeh"des &) carbo)"lic acids C) 9etones $) alcohols ') esters Ans: $ $ifficult": ' +. 7dentif" the principal organic product of the reaction between butane and chlorine. A) C4Cl &) C4C4#Cl C) C4C4ClC4 $) C4C4#C4ClC4 ') 5one of the abo(e is a ma>or product of the reaction. Ans: $ $ifficult": - Page #%* Chapter 15: Organic Compounds and the Atomic Properties of Carbon +%. 7dentif" the principal organic product when ben."l chloride reacts with aBueous sodium h"dro)ide. A) A &) & C) C $) $ ') none of the abo(e Ans: A $ifficult": - +5. 7dentif" the two principal products of the reaction between ammonia and eth"l propionate. A) A &) & C) C $) $ Page #%1 Chapter 15: Organic Compounds and the Atomic Properties of Carbon ') 5one of the abo(e is a ma>or product of the reaction. Ans: & $ifficult": 4 ++. 7dentif" the products of the following reaction. A) A &) & C) C $) $ ') 5one of the abo(e pairs of compounds are formed in the reaction. Ans: & $ifficult": 4 Page #%# Chapter 15: Organic Compounds and the Atomic Properties of Carbon +,. 7dentif" the products for the reaction between c"cloheptene and bromine. A) A &) & C) C $) $ ') 5one of the abo(e are the ma>or products of the reaction. Ans: & $ifficult": - +/. 7dentif" the products of the reaction of !octene with chlorine.
CH 3 CH 2 CH 2 CH 2 CH CHCH 2 CH 3 Cl 2 8 A) CH 3 CH 2 CH 2 CH 2 CH CHCH 2 CH 3 Cl Cl &) CH 3 CH 2 CH 2 CH 2 CH CHCH 2 CH 3 Cl Cl Cl Cl C) CH 3 CH 2 CH 2 CH 2 CH CHCH 2 CH 3 Cl H $) CH 3 CH 2 CH 2 CH 2 CH CHCH 2 CH 3 Cl Cl ') CH 3 CH 2 CH 2 CH 2 CH 2 Cl CH 3 CH 2 CH 2 Cl 8 Page #% Chapter 15: Organic Compounds and the Atomic Properties of Carbon Ans: A $ifficult": - +0. 7dentif" the products of the reaction between #!bromopentane and potassium etho)ide. A) A &) & C) C $) $ ') 5one of the abo(e are the ma>or products of the reaction. Ans: C $ifficult": 4 Page #%% Chapter 15: Organic Compounds and the Atomic Properties of Carbon ,*. 7dentif" the principal organic products for the following reaction. A) A &) & C) C $) $ ') 5one of the abo(e are the ma>or products of the reaction. Ans: & $ifficult": 4 Page #%5 Chapter 15: Organic Compounds and the Atomic Properties of Carbon ,1. 7dentif" the organic product when c"clohe)anol reacts with e)cess potassium dichromate in the presence of sulfuric acid. A) A &) & C) C $) $ ') 5one of the abo(e is a ma>or product of the reaction. Ans: & $ifficult": - Page #%+ Chapter 15: Organic Compounds and the Atomic Properties of Carbon ,#. 7dentif" the organic product when !c"lcobut"l!1!propanol reacts with e)cess potassium dichromate in sulfuric acid. A) A &) & C) C $) $ ') 5one of the abo(e is a ma>or product of the reaction. Ans: C $ifficult": 4 Page #%, Chapter 15: Organic Compounds and the Atomic Properties of Carbon ,. 7dentif" the organic product for the reaction of #!pentanol with sulfuric acid. A) A &) & C) C $) $ ') 5one of the abo(e is a ma>or product of the reaction. Ans: $ $ifficult": - ,%. 7dentif" the organic product when c"clopentanol reacts with sulfuric acid. A) A &) & C) C Page #%/ Chapter 15: Organic Compounds and the Atomic Properties of Carbon $) $ ') 5one of the abo(e is a ma>or product of the reaction. Ans: & $ifficult": - ,5. One characteristic of the monomers that form condensation pol"mers that is not common in monomers which form addition pol"mers is A) the presence of pi bonds. &) the presence of two functional groups. C) the presence of al9"l side chains. $) the abilit" to form free radicals. ') the presence of sulfur atoms. Ans: & $ifficult": - ,+. 2hich of the following pol"mers is a condensation pol"mer3 A) pol"st"rene $) pol"prop"lene &) 6eflon C ') $acron C C) pol"(in"lchloride Ans: ' $ifficult": 4 ,,. 5"lon!t"pe compounds are prepared b" the reaction of A) a diol with a diacid. $) an amine with a diacid. &) an alcohol with a diacid. ') a diamine with an acid. C) a diamine with a diacid. Ans: C $ifficult": - ,/. $acron is a DDDDDDDDDDD compound and is produced b" a DDDDDDDDDD reaction. A) pol"amideE addition $) pol"esterE condensation &) pol"amideE condensation ') pol"eneE addition C) pol"esterE addition Ans: $ $ifficult": 4 ,0. 6he most abundant organic chemical on earth is A) gl"cogen. &) starch. C) cellulose. $) glucose. ') carbonate. Ans: C $ifficult": - Page #%0 Chapter 15: Organic Compounds and the Atomic Properties of Carbon /*. 'ach amino acid has two functional groups in common and one of #* other groups attached to the !carbon. 6he two functional groups are A) carbo)"l and amine. $) alcohol and amine. &) ester and amine. ') carbo)"l and peptide. C) carbo)"l and amide. Ans: A $ifficult": ' /1. 4elical and sheet!li9e segments in proteins arise from A) disulfide bridges. &) salt bridges. C) crosslin9ing (ia co(alent bonds. $) dispersion forces within the protein<s interior. ') h"drogen bonding. Ans: ' $ifficult": - /#. 6he protein amino acid seBuence, the F5A base seBuence, and the $5A base seBuence are interrelated. 2hich of the following descriptions is correct3 A) 6he F5A base seBuence determines the $5A base seBuence which, in turn, determines the protein amino acid seBuence. &) 6he $5A base seBuence determines the F5A base seBuence which, in turn, determines the protein amino acid seBuence. C) 6he $5A base seBuence determines the protein amino acid seBuence which, in turn, determines the F5A base seBuence. $) 6he F5A base seBuence determines the protein amino acid seBuence which, in turn, determines the $5A base seBuence. ') 5one of the abo(e statements is correct. Ans: & $ifficult": - /. $raw and name two non!al9enes with the formula C%4/. Ans: $ifficult": ' /%. $raw and name all stable molecules with the formula C541#. Ans: Page #5* Chapter 15: Organic Compounds and the Atomic Properties of Carbon $ifficult": - /5. $raw and name four al9enes with the formula C%4/. Ans: $ifficult": - /+. 5ame the compound with the molecular structure shown. Ans: #!meth"l!#!pentene $ifficult": - /,. $raw the structure of trans!5!meth"l!!heptene. Ans: $ifficult": - //. 5ame the compounds: Ans: a. c"clobutane Page #51 Chapter 15: Organic Compounds and the Atomic Properties of Carbon b. c"clooctene c. toluene ?meth"lben.ene) $ifficult": ' /0. 2hat is the simplest molecular formula for a. an al9ane capable of ha(ing structural isomers3 b. an al9ane capable of ha(ing optical isomers3 c. an al9ene capable of ha(ing geometrical isomers3 Ans: a. C%41* b. C,41+ c. C%4/ $ifficult": 4 0*. 7n one sentence, what is the general reBuirement for a molecule to be opticall" acti(e3 Ans: 7n order to be opticall" acti(e, the compound must ha(e a non!superimposable mirror image. $ifficult": - 01. a. $raw two different structures with the molecular formula C#4+O. b. 5ame the functional group in each structure. c. 2hich one will ha(e the higher boiling point, and wh"3 Ans: a. 4CG C4#GO4 4CGOG C4 b. alcohol and ether c. 6he alcohol will ha(e the higher boiling pointE it will ha(e h"drogen bonding while the ether does not. $ifficult": - 0#. 5ame each of the following functional groups: Ans: a. alcohol b. ether c. 9etone d. aldeh"de e. carbo)"lic acid f. amide $ifficult": ' Page #5# Chapter 15: Organic Compounds and the Atomic Properties of Carbon 0. 2rite down the structure of the missing organic reactant or product?s) in the following reactions, and name the t"pe of reaction in(ol(ed ?inorganic products ma" also be formed): Ans: Page #5 Chapter 15: Organic Compounds and the Atomic Properties of Carbon $ifficult": - 0%. $escribe and contrast fibrous and globular proteins in terms of their amino acid composition, their structure, and their function. Ans: Hibrous proteins are composed of relati(el" few amino acids in a repeating pattern. 6heir structures are helices or sheets, and the" are found in hair, s9in and muscle. ;lobular proteins use more amino acids in their structures, and the" ha(e (arious of irregular shapes. 6heir functions are (arious: messenger molecules, en."mes ?catal"sts), etc. $ifficult": - 05. ')plain how a disulfide bridge can arise a protein molecule. Ans: $isulfide bridges arise when two c"steine 1S14 side chains react to form a co(alent 1S1S1 lin9 between the two regions of the protein bac9bone. 6he two regions of the protein bac9bone are thus held together. Page #5% Chapter 15: Organic Compounds and the Atomic Properties of Carbon $ifficult": 4 0+. ')plain how a salt bridge can arise a protein molecule. Ans: A salt bridge is the result of ionic attraction between a side chain with a carbo)"late ?1COO 1 ) group and one with a protonated amine group ?154 8 ). 6hese regions of the molecule are then held together b" this ionic attraction. $ifficult": 4 0,. 5ame the three component parts of a nucleotide. Ans: phosphate, base, sugar $ifficult": ' 0/. ')plain what is meant b" Icomplementar"J in the conte)t of $5A strands. Ans: 'ach nucleotide along a single strand of $5A has one of four possible bases, namel" guanine ?;), c"tosine ?C), adenine ?A), and th"mine ?6). 6he double heli) of $5A is held in place b" h"drogen bonds between pairs of bases, one base being on each of the two strands. ; alwa"s pairs with C and A alwa"s pairs with 6. 6hus, the base seBuence on one strand determines the base seBuence on the other strand, and the strands are Icomplementar"J to each other. $ifficult": - 00. ;i(en that each !base seBuence in $5A is a Icode wordJ for a particular amino acid, how man" different code words are possible using a !base seBuence and the bases a(ailable in $5A3 Ans: % % % A +% $ifficult": - 1**. &ecause organic compounds are associated with li(ing organisms, their properties are go(erned b" fundamentall" different chemical principles from those of inorganic compounds. Ans: Halse $ifficult": ' 1*1. 'thane ?C#4+) is much more reacti(e than disilane ?Si#4+). Ans: Halse $ifficult": ' 1*#. 6he carbon atoms in a molecule of c"clohe)ane lie in the same plane. Ans: Halse $ifficult": - 1*. All the atoms in a molecule of ben.ene lie in the same plane. Ans: 6rue $ifficult": - 1*%. &oth al9enes and al9"nes e)hibit geometric ?cisKtrans) isomerism. Ans: Halse $ifficult": ' Page #55 Chapter 15: Organic Compounds and the Atomic Properties of Carbon 1*5. &ecause of delocali.ation, all the carbon!carbon bond lengths in 1,!c"clopentadiene are identical. Ans: Halse $ifficult": ' 1*+. As a result of delocali.ation of the pi!electrons, all the carbon!carbon bonds in ben.ene are identical. Ans: 6rue $ifficult": ' 1*,. A characteristic reaction of al9anes is addition. Ans: Halse $ifficult": ' 1*/. A characteristic reaction of al9enes is addition. Ans: 6rue $ifficult": ' 1*0. A characteristic reaction of haloal9anes is substitution. Ans: 6rue $ifficult": ' 11*. All alcohols are capable of h"drogen bonding. Ans: 6rue $ifficult": - 111. All 9etone molecules are capable of h"drogen bonding to other 9etone molecules. Ans: Halse $ifficult": - 11#. Carbo)"lic acids are wea9 acids. Ans: 6rue $ifficult": - 11. Secondar" amines ha(e the general formula F54#. Ans: Halse $ifficult": ' 11%. 'sters can be formed b" the deh"dration!condensation of a carbo)"lic acid and an alcohol. Ans: 6rue $ifficult": - 115. Addition pol"mers are mostl" made from monomers with carbon!carbon double bonds. Ans: 6rue $ifficult": - 11+. Condensation pol"mers are formed b" free radical addition reactions. Ans: Halse $ifficult": - 11,. &oth n"lons and proteins are pol"amides. Ans: 6rue $ifficult": - 11/. Amino acids in solution can undergo an internal acid!base reaction. Ans: 6rue $ifficult": - Page #5+ Chapter 15: Organic Compounds and the Atomic Properties of Carbon 110. 6he bac9bone of protein molecules consists of repeating 51C1C1O units. Ans: Halse $ifficult": - Page #5,