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| :- l- z|| +| /;|- = <+ + ~|+| 5 ln- lz| | : = := +|n + ln, l t +
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
A. =|n|-; :
1. t l-+| ~|+| z-= t+ :=+i n t - -+ -
-| -+ l-i-|+ + }|| :=+| l- z| - l|
|+
2. z-= +| +| (CODE) := a + -i | +|-
| t +
3. +-- +| + ln, [||ni a ~| [||ni ||- := l-+|
n ti t+ +-- +| + ln, +| : ~l-l+- +| -ti l|
||+
4. +| +|] l+n | ] n| -|ln+|] n|: :n] + -+ n ]
+ n|] = n+| -] ~| l+=i +| + :n + |l-+ -+|
i-|| +-| n ~-nl- -ti t +
5. := l-+| + ln a l, , ||- n ~-| -|n
~| +|n -- lnl|(+
6. --| =] ,+ ; =&|i +| ;| ; = (ORS) t | l+ ~n
= l | +
7. ~| ~|(=(ORS) ;| := l-+| n t + !ll- -
+ +
8. := l-+| +i n t -| - + z-|- + | | - n l+ :=n
36 a t ~| + l|; + =|i 20 z- ~| --+ --|
l+- ai+ = <+ | =+- t+ =|i [| | +i z| ~|- n
l t , l-z|| +| /;|- = <+ +
B. ~| ~|(= (ORS) +| || :
9. i-|||i +| tn l+ z- +| --| ORS --| l-+|
n =ti ||- +|n | n |:- +nn = -l-- |n +|
t| ++ -| t +
10. ORS + ( a = [;| 1) n| i : =n- |-+|i /;|-
+ ~z; | ~| ~- t-|-| + +
C. z-= +| | :
:= z-= + -i- || (l|-] ||l-+ la|- ~|
=|- la|-) t+ t || + -i- [| t+
INSTRUCTIONS / = --|(
SCORE-I : JEE (Advanced) # 01
PATTERN : JEE (Advanced) LEADER & ENTHUSIAST COURSE
SCORE-I
PAPER CODE
01CT313071 KOTA - 1/36
TM
Path to success
KOTA(RAJASTHAN)
Your Target is to secure Good Rank in JEE 2014
A. General :
1. The booklet is your Question Paper. Do not break
the seal of this booklet before being instructed to
do so by the invigilator.
2. The question paper CODE is printed on the left hand
top corner of this sheet.
3. Blank spaces and blank pages are provided in the
question paper for your rough work. No additional
sheets will be provided for rough work.
4. Blank papers, clipboards, log tables, slide rules,
calculators, cameras, cellular phones, pagers and
electronic gadgets are NOT allowed inside the
examination hall.
5. Write your name and Form number in the space
provided on the back cover of this booklet.
6. The answer sheet, a machine-readable Optical
Response Sheet (ORS), is provided separately.
7. DO NOT TAMPER WITH/MUTILATE THE ORS OR THE
BOOKLET.
8. On breaking the seal of the booklet check that it
contains 36 pages and all the 20 questions in each
subj ect and corresponding answer choices are
legible. Read carefully the instructions printed at the
beginning of each section.
B. Filling the ORS :
9. A candidate has to write his / her answers in the ORS
sheet by darkening the appropriate bubble with the
help of Black ball point pen as the correct answer(s)
of the question attempted.
10. Write all information and sign in the box provied on
part of the ORS (Page No. 1).
C. Question Paper Formate :
The question paper consists of 3 parts (Mathematics,
Physics and Chemistry). Each part consists of three
sections.
| z| | l- z|| + ln := l-+| + ~l--n a +| <+ +
Please read the last page of this booklet for read the instructions
0 1 C T 3 1 3 0 7 1
Date : 08 - 03 - 2014 TARGET : JEE (Main + Advanced) 2014
TEST # 03
=n; : 3 | nt-|n ~ + : 225
Time : 3 Hours Maximum Marks : 225
01CT313071 KOTA - 2/36
l|; | a = [;|
Subject Section Page No.
||-1 l|- I(i) + n ,+ =ti l+- +| 03 - 04
Part-1 Mathematics Only One Option Correct Type
I(ii) (+ ;| ~l|+ =ti l+- +| 05 - 05
One or More Options Correct Type
I(iii) ~- - +| 06 - 06
Paragraph Type
II nl +=nn +| 07 - 07
Matrix Match Type
IV || + n|- =ti +| 08 - 10
Integer Value Correct Type
||-2 || l-+ la|- I(i) + n ,+ =ti l+- +| 11 - 15
Part-2 Physics Only One Option Correct Type
I(ii) (+ ;| ~l|+ =ti l+- +| 16 - 19
I(iii) ~- - +| 20 - 21
Paragraph Type
II nl +=nn +| 22 - 23
Matrix Match Type
IV || + n|- =ti +| 24 - 26
||-3 =|- la|- I(i) + n ,+ =ti l+- +| 27 - 28
Part-3 Chemistry Only One Option Correct Type
I(ii) (+ ;| ~l|+ =ti l+- +| 29 - 30
I(iii) ~- - +| 31 - 31
Paragraph Type
II nl +=nn +| 32 - 32
Matrix Match Type
IV || + n|- =ti +| 33 - 34
SOME USEFUL CONSTANTS
Atomic No. H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16, Cl = 17,
Br = 35, Xe = 54, Ce = 58,
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
Boltzmann constant k = 1.38 10
23
JK
1
Coulomb's law constant
pe
9
0
1
= 910
4
Universal gravitational constant G = 6.67259 10
11
Nm
2
kg
2
Speed of light in vacuum c = 3 10
8
ms
1
StefanBoltzmann constant s = 5.67 10
8
Wm
2
K
4
Wien's displacement law constant b = 2.89 10
3
mK
Permeability of vacuum
0
= 4p 10
7
NA
2
Permittivity of vacuum
0
= 2
0
1
c m
Planck constant h = 6.63 10
34
Js
TARGET : JEE (Main + Advanced) 2014
08-03-2014
TM
Path to success
KOTA(RAJASTHAN)
LEADER & ENTHUSIAST COURSE
(DATE : 08-03-2014)
MATHEMATICS
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KOTA(RAJASTHAN)
01CT313071 KOTA - 3/36
PART-1 : MATHEMATICS
||-1 : l|-
SECTIONI : (i) Only One option correct Type
[|-I : (i) + n ,+ =ti l+- +|
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct.
:= [| n 6 t l+- z- t + + z- n -| l+- (A), (B), (C) ~| (D) t l-n = + n ,+
=ti t+
1. If
[ ]
n
2 n
x dx
n x f(x) C
x x
1 x ...
2 n
= - +
+ + + +
, where f(0) = 0.
then
n
l i m ( f (1) )

is equal to
(A) 1 (B) 2 (C) 3 (D) does not exist
l
[ ]
n
2 n
x dx
n x f(x) C
x x
1 x ...
2 n
= - +
+ + + +
, t| f(0) = 0.
-
n
l i m ( f (1) )

| t
(A) 1 (B) 2 (C) 3 (D) ~l- -ti t
2. The sum of all coefficients in the expansion of (1 + 2z+ 3z
2
+ ........+ nz
n
)
2
is equal to
(1 + 2z+ 3z
2
+ ........+ nz
n
)
2
+ =| n || +| +| ;| t -
(A) S1 (B) Sn (C) Sn
2
(D) Sn
3
BEWARE OF NEGATIVE MARKING
HAVE CONTROL HAVE PATIENCE HAVE CONFIDENCE 100% SUCCESS
Space for Rough Work / +-- +| + ln, ||-
MATHEMATICS
(DATE : 08-03-2014)
TM
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KOTA(RAJASTHAN)
01CT313071 KOTA - 4/36
3.
7 3
2
x 0
cos x cos x
lim
x
-
is equal to
7 3
2
x 0
cos x cos x
lim
x
-
| t
(A)
1
21
(B)
2
21
(C)
4
21
(D)
8
21
4. If x y y x 5 + + - = , then
2
2
d y
dx
is equal to
l x y y x 5 + + - = , -
2
2
d y
dx
| t
(A)
2
25
-
(B)
2
25
(C)
2
5
(D)
2
5
-
5. Let A = {1, 2, .... ,10} and B = {1, 2, ..... , 5}
f: A B is a non-decreasing into function, then number of such functions is
n|-| A = {1, 2, .... ,10} -|| B = {1, 2, ..... , 5}
f: A B ~n=n|- ~---| i +n- t+ - , = +n-| +i = [;| t+
(A) 1001 (B) 1876 (C) 205 (D) 875
6.
1 1 1
2 1 3 2 4 3
sin sin sin
6 12 20
- - -

- - -
+ +

+ ......... is
1 1 1
2 1 3 2 4 3
sin sin sin
6 12 20
- - -

- - -
+ +

+ ......... t
(A)
2
p
(B)
3
p
(C)
4
p
(D)
5
p
(DATE : 08-03-2014)
MATHEMATICS
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KOTA(RAJASTHAN)
01CT313071 KOTA - 5/36
(ii) One or more options correct Type
(ii) (+ ;| ~l|+ =ti l+- +|
(D) out of which ONE or MORE are correct.
:= [| n 4 t l+- z- t + + z- n -| l+- (A), (B), (C) ~| (D) t ] l-n = (+ ;|
~l|+ =ti t+
7.
( )
{ }
( )
n
2 1 n
n
lim 2 1 ( 1)

+

+ - (where n N and [.], {.} denotes G.I.F. and {.} respective) is equal to :-
(A) 1 when n is even (B) 0 when n is odd
(C) 0 when n is even (D) 1 when n is odd
( )
{ }
( )
n
2 1 n
n
lim 2 1 ( 1)

+

+ - (t| n N -|| [.], {.} +nz|% nt-|n || + +n- ~ || z| +n- +| +-

+-| t :-
(A) 1 n =n t (B) 0 n l|n t
(C) 0 n =n t (D) 1 n l|n t
8. All the natural numbers, sum of whose digits is 8 are arranged in ascending order then the 170th
number in the list does not contain the digit
=|i |- =[;|( l-+ ~ +| +| ;| 8 t +| <+ - +n n l|- +- 170
th
=[;| l--- ~ + +| t| -ti
+-i t +
(A) 2 (B) 3 (C) 4 (D) 5
9. f : R R is a continuous functions such that
x
2
2
0
f(t)
f(x) (1 x ) 1 dt
1 t

= + +

+

then
f : R R (+ =-- +n- t l+
x
2
2
0
f(t)
f(x) (1 x ) 1 dt
1 t

= + +

+

-
(A) f(1) = 2e (B) f ' (1) = 4e (C) f(0) = 1 (D) f '(1) = 1
10. The sum of the greatest and the smallest terms in (x + 12)
21
is zero then x can take values.
(x + 12)
21
n nt-|n , n| -|n +| ;| z| -; t + - x l--- n|- t| + =+-| t +
(A) 10 (B) 21 (C) 28 (D) 6
MATHEMATICS
(DATE : 08-03-2014)
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KOTA(RAJASTHAN)
01CT313071 KOTA - 6/36
(iii) Paragraph Type
(iii) ~- - +|
This section contains 1 paragraph each describing theory, experiment, data etc. Three questions
relate to paragraphs. Each question of paragraph has only one correct answer among the four choices
(A), (B), (C) and (D).
:= [| n l=z|--| ] || ~| ~| + | ~|l +| z|| - |n| 1 ~- - t+ ~- - = = l|- -i- z-
t + ~- - n t z- + -| l+- (A), (B), (C) ~| (D) t l-n = + n ,+ =ti t +
Paragraph for Questions 11 to 13
z- 11 = 13 + ln ~- -
If a, b, c are distinct non-zero complex numbers such that |a| = |b| = |c|.
l a, b, c -i- l|| ~z|-; =l-n = [;|, := +| t l+ |a| = |b| = |c|.
11. If one of the roots of the equation az
2
+ bz + c = 0 has modulus 1 then a, b, c are in
(A) A.P. (B) G.P. (C) H.P. (D) None
l =ni+| az
2
+ bz + c = 0 +| ,+ n n n|| + 1 t+ - a, b, c t
(A) A.P. (B) G.P. (C) H.P. (D) +| : -ti
12. If az
2
+ bz

+ c = 0 and bz
2
+ cz + a = 0 each has a root having modulus 1 then the points a, b, c in the
complex plane are
(A) collinear (B) vertices of an equilatral triangle
(C) vertices of a scalane triangle (D) vertices of a right angled triangle
l az
2
+ bz

+ c = 0 -|| bz
2
+ cz + a = 0 n + +| ,+ nn n||+ 1 t+ - a, b, c =nln -n n t +
(A) =n|i; (B) =n|t lz| + z|i|
(C) l|n|t lz| + z|i| (D) =n+| | lz| + z|i|
13. If az
2
+ bz + c = 0 and bz
2
+ cz + a = 0 have a root of modulus 1 then the equations az
2
+ bz + c = 0 and
bz
2
+ cz + a = 0
(A) cannot have a common root (B) have both roots common
(C) have exactly one common root (D) data insufficient
l az
2
+ bz + c = 0 -|| bz
2
+ cz + a = 0 n + +| ,+ n n n|| + 1 t + - =ni+| az
2
+ bz + c = 0 -||
bz
2
+ cz + a = 0
(A) +| : -|l-a n n -ti (B) |-| n n -|l-a t
(C) + n ,+ -|l-a n n (D) |-+|i | -ti
(DATE : 08-03-2014)
MATHEMATICS
TM
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KOTA(RAJASTHAN)
01CT313071 KOTA - 7/36
SECTIONII : Matrix-Match Type
| - II : nl +=n n +|
This Section contains 1 question. Question has four statements (A, B, C and D) given in Column I and
five statements (P, Q, R, S and T) in Column II. Any given statement in Column I can have correct
matching with ONE or MORE statement(s) given in Column II. For example, if for a given question,
statement B matches with the statements given in Q and R, then for the particular question, against
statement B, darken the bubbles corresponding to Q and R in the ORS.
:= [| n 1 z- t + z- n +| nn I n 4 +|- (A, B, C ~| D) ~| +| nn II n 5 +|- (P, Q, R, S ~| T) t +
+| nn I +| +|: |i +|- +| nn II + ,+ +|- ;| ,+ = ~l|+ +|-| = n n [||-| t + -|t| + ln,] l, t, z-
n ;l +|- B +|-| Q ~| R = n n [||-| t ] -| ~| ~|(=(ORS) n -= z- + ln +|- B + =|n- Q ~| R =
=-l-|- n n| +| +|n| +il +
1. 8 players P
1
, P
2
, ........ P
8
of equal strength are paired in four pairs in first round, two pairs in second
round and one pair in final randomly, in a knock out tournament. Find the probability that
Column-I Column-II
(A) P
1
does not reach the final (P)
3
4
(B) P
1
and

P
2
play against each other during the course of tournament (Q)
1
4
(C) P
1
is the champion, P
2
is the runner up (R)
1
420
and P
3
, P
4
reached in the second round
(D)P
1
is the champion and P
1
and P
2
did not play against each other (S)
1
14
(T)
1
840
8 l|n|l+ ;| P
1
, P
2
, ........ P
8
+| -| ; n| n | = |n -| n ; ln- l+| |-| t + | ; n l,-i; -| -||
(+ ; n ~l--n n -| ,+ [|n n |l+-| a|- +| l+
Column-I Column-II
(A) P
1
~l--n -| n -ti t - (P)
3
4
(B) P
1
-|| P
2
(+ = + l-| n [| n (Q)
1
4
(C) P
1
l -|] P
2
-l-| -|| (R)
1
420
P
3
, P
4
l,-i; -| n t -
(D) P
1
l-| -|| P
1
, P
2
(+ = + l-| n - [| n (S)
1
14
(T)
1
840
MATHEMATICS
(DATE : 08-03-2014)
TM
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KOTA(RAJASTHAN)
01CT313071 KOTA - 8/36
SECTION III : Integer Value Correct Type
| III : || + n|- =ti +|
No question will be asked in section III / | III n +| : z- -ti t+
SECTION-IV : (Integer Value Correct Type)
[|-IV : ( || + n|- =ti +|)
This section contains 6 questions. The answer to each question is a single digit Integer, ranging from
0 to 9 (both inclusive)
:= [| n 6 z- t + + z- +| --| 0 = 9 -+ (| -| z||lnn) + i- +| ,+n ~ +i ; || +
t +
1. The least value of n for which (n2)x
2
+ 8x + n + 4 > sin
1
(sin12) + cos
1
(cos12) " x R,
where n N
n +| t ---n n|- l=+ ln, (n2)x
2
+ 8x + n + 4 > sin
1
(sin12) + cos
1
(cos12) " x R,
t| n N t %
2. Given f(x) =
2
2
if | x | 1
| x |
a bx if | x | 1
>
where a, b R. If f(x) is differentiable at x = 1 then (2a+b) is equal to

l| t f(x) =
2
2
if | x | 1
| x |
a bx if | x | 1
>
t| a, b R, l f(x), x = 1 ~+n-i; t ] -| (2a+b) +| n|- t %

(DATE : 08-03-2014)
MATHEMATICS
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KOTA(RAJASTHAN)
01CT313071 KOTA - 9/36
3. If
1 1 1
3 a 4 b 5 c
a b c

+ = + = +

when a, b, c are positive numbers and ab + bc + ca = 1 then
2 2 2
2 2 2
1 a 1 b 1 c
5
1 a 1 b 1 c
- - -
+ + =

+ + +
.........
l
1 1 1
3 a 4 b 5 c
a b c

+ = + = +

a, b, c |-|n+ |-l+ = [;|( t+ -|| ab + bc + ca = 1 -
2 2 2
2 2 2
1 a 1 b 1 c
5
1 a 1 b 1 c
- - -
+ + =

+ + +
.........
4. Let M be any point M on the arc AB of circumcircle of right angled triangle ABC and the maximum
value of AM + BM + CM is 29N , where a = 3, b = 4, c = 5. Then N is ...............
n|-| M =n+| | lz| ABC + l -| l|- -| AB +| : l- t -|| AM + BM + CM +| ~l|+-n n|-
29N t + t| a = 3, b = 4, c = 5 - N t ...............
MATHEMATICS
(DATE : 08-03-2014)
TM
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KOTA(RAJASTHAN)
01CT313071 KOTA - 10/36
5. Let f(x) =
n 2 n 2
n n
n
sin x cos
lim
sin x cos x
+ +
+
+
for 0 x
2
p
, if ( )
2
0
A
f x dx
B
p
p+
=
, then (A+B) is equal to

l f(x) =
n 2 n 2
n n
n
sin x cos
lim
sin x cos x
+ +
+
+
, 0 x
2
p
+ ln, , l ( )
2
0
A
f x dx
B
p
p+
=
, - (A+B) | t
6. f(x) is a countinous function such that f(2x) - f(x) = x " xR and f(0) = 1. then
2
0
f(x) dx =
.....
n|-| l+ f(x) (+ =-- +n- := +| t l+ f(2x) - f(x) = x " xR ~| f(0) = 1, -
2
0
f(x) dx =
.....
(DATE : 08-03-2014)
PHYSICS
TM
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KOTA(RAJASTHAN)
01CT313071 KOTA - 11/36
PART-2 : PHYSICS
||-2 : ||l-+i
[|-I : (i) + n ,+ =ti l+- +|
=ti t+
1. A cylindrical tube filled with water (m
w
= 4/3) is closed at its both ends by two silvered plano-convex
lenses as shown in the figure. Refractive indices of lenses L
1
and L
2
are 2.0 and 1.5 while their radii of
curvature are 5 cm and 9 cm respectively. A point object is placed some where at a point O on the axis
of cylindrical tube. It is found that the object and image coincide with each other after every reflection.
The length of the cylindrical tube is :-
n (m
w
= 4/3) = |i ,+ n-|+| -ni + | -| l=| +| l-z|- =| | =n-n| -|n (l--) n =| }|| + l|
| t + n =| L
1
-|| L
2
+ ~- -| + +nz|% 2.0 -|| 1.5 t --+i +-| lz|( +nz|% 5 cm 9 cm t + :=
n-|+| -ni +i ~-| l+=i l- O ,+ l- l- +| || | t + ;t l-|- t| -| t l+ l- -|| :=+|
l-l- + |- - + z-|- ,+ = + = |-i t + n-|+| -ni +i n-|: t
m
2
m
1 m
w
O
L
1
L
2
(A) 82 cm (B) 92 cm (C) 72 cm (D) 18 cm
PHYSICS
(DATE : 08-03-2014)
TM
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KOTA(RAJASTHAN)
01CT313071 KOTA - 12/36
2. In the circuit shown in figure, A is a sliding contact which can move over a smooth rod PQ.
Resistance per unit length of the rod PQ is 1 ohm/m. Initially slider is just left to the point P and
circuit is in the steady state. At t = 0 slider starts moving with constant velocity v = 5 m/s towards
right. Current in the circuit at t = 2 sec is :-
(A) 1 amp (B) less than 0.5 amp
(C) more than 1 amp (D) in between 0.5 to 1.0 amp
R=20W L=2H
30V
A V
P Q
lz| - l| n A (+ =i =+ (sliding contact) t | l+ l-+-i + PQ l- + =+-| t + + PQ +i
l- ,+| + n-|: +| l-|| 1 W/m t + |-| n n|: l- P + ai+ |i ~| t -|| l| ||i ~|| n
t + t = 0 n|: v = 5 m/s + l-- = |i ~| l- +-| |-| + -| t + t = 2 sec l| n /|||
t| i
(A) 1 (l- (B) 0.5 (l- = +n
(C) 1 (l- = ~l|+ (D) 0.5 = 1.0 (l- + i-
(DATE : 08-03-2014)
PHYSICS
TM
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KOTA(RAJASTHAN)
01CT313071 KOTA - 13/36
3. An electron and a proton each travel with equal speeds around circular orbits in the same uniform
magnetic field, as shown in the diagram (not to scale). The field is into the page on the diagram. Because
the electron is less massive than the proton and because the electron is negatively charged and the proton
is positively charged :-
(A) the electron travels clockwise around the smaller circle and the proton travels counterclockwise
around the larger circle
(B) the electron travels counterclockwise around the smaller circle and the proton travels clockwise
around the larger circle
(C) the electron travels clockwise around the larger circle and the proton travels counterclockwise around
the smaller circle
(D) the electron travels counterclockwise around the larger circle and the proton travels clockwise around
the smaller circle
B
(+ :n + | - -|| ,+ || - ,+ ti =n - -+i; {|= n -||+| +-||~| + -|| ~| =n|- -|n| = l- +- t
=| l+ l-= n z|| | | t (;t n|- -ti t |+ ;t {| = l-= +| n ~- +i ~| ln|- t + :n + |- +
| |- = t-+| t| - + +|| , :n + |- + +|| lz|- | |- + /|-| lz|- t| - + +|| %&
(A) :n + | - |i +-|| n l-|||-i -|| | | - i +-|| n |n|-i ?| | - +-| t +
(B) :n + | - |i +-|| n |n|ni -|| || - i +-|| n l-|||-i ?| | - +-| t +
(C) :n + | - i +-|| n l-|||-i -|| | | - |i +-|| n |n|-i ?| | - +-| t +
(D) :n + | - i +-|| n |n|ni -|| ||- |i +-|| n l-|||-i ?| | - +-| t +
PHYSICS
(DATE : 08-03-2014)
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 14/36
4. The diagram shows a modified meter bridge, which is used for measuring two unknown resistances at
the same time. When only the first galvanometer is used, for obtaining the balance point, it is found at
point C. Now the first galvanometer is removed and the second galvanometer is used, which gives
balance point at D. Using the details given in the diagram, find out the value of R
1
and R
2
:-
l-= n ,+ = z||l|- ni = - z|| | | t l=+| -| ,+ ti =n; | ~a|- l-||| + n|- t - l+| |-|
t + = - n- l- |-- +- + ln, |n - -|ni +| + l+| |-| t -| ;t l- C |-- t|-| t + ~
|n - -| ni +| t|+ l,-i; - -| ni +| + +- =-n- l- D |-- t| -| t + R
1
R
2
+ n|- t| %&
G G
R
2
R
1
R
B
D C
A
AB = L; AC = L/4 and AD = 2L/3
(A) R
1
= 5R/3, R
2
= 4R/3 (B) R
1
= 4R/3, R
2
= R
(C) R
1
= 4R/3, R
2
= 5R/3 (D) R
1
= R, R
2
= R/3
5. In the shown figure (1) and (2), capacitors are in the steady state. Charging batteries are removed and
switches S
1
and S
2
are closed at time t = 0. The plot of lnI (I is the current in the resistor) in against time
t in the resistor R
1
and R
2
are shown by the graphs 1 and 2 respectively in the figure (3). Choose the
INCORRECT option :-
(A) If e
1
= 2e
2
, R
1
must be equal to 2R
2
(B) If R
1
= R
2
, C
1
must be less than C
2
(C) If C
1
= C
2
, R
1
must be less than R
2
(D) R
1
C
1
is equal to R
2
C
2
(1)
e
1
R
1
S
1
C
1
(2)
e
2
R
2
S
2
C
2
(3)
(1)
(2)
lnI
t
lz| - l-= (1) -|| (2) n = ||l= ||i ~|| n t + ~| z|- l| +| t|+ =n; t = 0 l- S
1
S
2
+|
+ - t + l-|| R
1
R
2
n |lt- /||| I + ln, lnI -|| =n; t + n/; ~| | l-= (3) n +nz|% ~| | 1 -||
2 ,|| z|| t + n- l+- -l-, %&
(A) l e
1
= 2e
2
t| -| R
1
l-lz-- : = 2R
2
+ - -; t||+
(B) l R
1
= R
2
t| -| C
1
l-lz-- : = C
2
= +n t| |+
(C) l C
1
= C
2
t| -| R
1
l-lz-- : = R
2
= +n t| |+
(D) R
1
C
1
+| n|- R
2
C
2
+ - -; t +
(DATE : 08-03-2014)
PHYSICS
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 15/36
6. Three medium with refractive index n
1
, n
2
and n
3
(n
1
> n
2
> n
3
> 1) are as shown in Figure. The two
beams are parallel to each other, with a beam-1 passes only through the medium I and III, and beam-2-
through the medium II and III. Determine the angle between the beams in the medium III.
(A)
1 1
1 2
sin sin
sin sin
n n
- -
q q
-

(B)
1 1 3 3
1 2
n sin n sin
sin sin
n n
- -
q q
-

(C)
1 1 1 2
3 3
n sin n sin
sin sin
n n
- -
q q
-

(D) None of these
q
I
2
n = 1
II
III
n
2
n
1
n
3
1
~- -|+ n
1
, n
2
-|| n
3
(n
1
> n
2
> n
3
> 1) |n -i- n|/;n l-= n z|| t + | -| ,+ = + =n|-- t
-|| 1 + n n|/;n I -|| III = =+-| t ~| -2 n|/;n II -|| III = =+-| t + n|/;n III n |
+ n/; +| | t| | %&
(A)
1 1
1 2
sin sin
sin sin
n n
- -
q q
-

(B)
1 1 3 3
1 2
n sin n sin
sin sin
n n
- -
q q
-

(C)
1 1 1 2
3 3
n sin n sin
sin sin
n n
- -
q q
-

(D) :-n = +| : -ti
PHYSICS
(DATE : 08-03-2014)
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 16/36
(ii) (+ ;| ~l|+ =ti l+- +|
~l|+ =ti t+
7. If an endoergic nuclear reaction is brought about by bombarding a stationary nucleus with a projectile
then INCORRECT statement(s) is/are:-
(A) kinetic energy of the projectile must be equal to the magnitude of Q-value of the reaction
(B) kinetic energy of the projectile must be less than the magnitude of the Q-value of the reaction
(C) the kinetic-energy of the projectile must be more than the magnitude of Q-value of the reaction
(D) the momentum will not be conserved in such a nuclear reaction
l l+=i l| -|l|+ -|-; + +|- + +n ,+ -n|-| i -|l|+i; ~l|l+| =--- t|-i t| -| l---
n = n- +|-!+|-| +| - l- %&
(A) := -|-; +i l- -| l-lz-- -| ~l|l+| + Q-n|- + ln|| + | t|i+
(B) := -|-; +i l- -| l-lz-- -| ~l|l+| + Q-n|- + ln|| = +n t| i+
(C) := -|-; +i l- -| l-lz-- -| ~l|l+| + Q-n|- + ln|| = ~l|+ t| i+
(D) ( =i -|l|+i; ~l|l+| n = = l-|- -ti t|-|+
(DATE : 08-03-2014)
PHYSICS
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 17/36
8. In the figure, AB is a given real object and its image is A'B'. Comment on the nature of the lens used to
make the image and the position of the lens.
(A) The lens used can be converging
(B) The lens used can be diverging
(C) The lens could be located between object and the image
(D) The lens could be located to the right of the image
B'
A'
A
B
lz| - l-= n AB (+ |-l+ l- t -|| A'B' :=+| l-l- t + l-l- + l-n| | + ln, + n-= +i
+ l- -|| :=+i l|l- + | n =ti +|-!+|-| +| - l-, %&
(A) + n-= ~l|=|i t| =+-| t +
(B) + n-= ~=|i t| =+-| t +
(C) t n -= l- -|| l-l- + n/; l|- t| =+-| t +
(D) t n -= l-l- + | i ~| l|- t| =+-| t +
PHYSICS
(DATE : 08-03-2014)
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 18/36
9. A very small circular loop of radius a is initially coplanar and concentric with a much larger circular loop
of radius b (>>a). A constant current I is passed in the large loop which is kept fixed in space and the
small loop is rotated with angular velocity w about a diameter. The resistance of the small loop is R & its
self inductance is negligible. The current in the larger loop is clockwise. (Here q is to be measured from
axis of large ring)
(A) The current in the small loop as a function of time is
2
0
a I sin t
2bR
p w w
(B) The current in the small loop as a function of time is
2
0
a I cos t
2bR
p w w
(C) Torque that must be exerted on the small loop to rotate it, is
2
2
0
b I sin t
R 2b
p w w

(D) Torque that must be exerted on the small loop to rotate it, is
2
2
0
a I sin t
R 2b
p w w

w
a
b
I
(+ a lz| +| t - || -||+| n |-| n lz| b (>>a) |n ,+ t - -||+| n + =n-ni; -||
= +-:i; t + ,+ l-- /||| I +| n = || |-| t | =nl n l| l+| | t -|| | n +| |= + =|-|
+| |i; w = ?| | - +|| |-| t + | n +| l-|| R t :=+| + -.; t + n n /||| l-|||-i
t (t| q +| n|- n +i ~-| = l+| | t + )
(A) =n; + +n- + : n | n n /||| +| n|-
2
0
a I sin t
2bR
p w w
t||+
(B) =n; + +n- + : n | n n /||| +| n|-
2
0
a I cos t
2bR
p w w
t| |+
(C) | n +| ?| | - +|- + ln, := n| n|| | +| n|-
2
2
0
b I sin t
R 2b
p w w

t| -| -|lt(+
(D) | n +| ?| | - +|- + ln, := n| n|| | +| n|-
2
2
0
a I sin t
R 2b
p w w

t| -| -|lt(+
(DATE : 08-03-2014)
PHYSICS
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 19/36
10. Positive charge Q is distributed uniformly throughout an insulating sphere of radius R, centered at the
origin. A particle with positive charge Q is placed at x = 2 R on the x axis.
(A) The electric potential at x =
R
2
is
0
49Q
96 R p
(B) The electric field at x =
R
2
is 2
0
Q
72 R p
(C) Electric field at x =
R
2
is 2
0
17Q
72 R p
(D) Electric potential at x =
R
2
is
0
3Q
2 R p
(+ R lz| + + -|n+ | n ] l=+| + -: n n l- t ] /|-| z| Q +| ,+=n|- : = l-l- l+| |-| t +
(+ Q |-| z| |n +| +| x-~-| x = 2R || |-| t %&
(A) x =
R
2
l- l|
0
49Q
96 R p
t +
(B) x =
R
2
l - {| = 2
0
Q
72 R p
t +
(C) x =
R
2
l - {| = 2
0
17Q
72 R p
t +
(D) x =
R
2
l- l|
0
3Q
2 R p
t +
PHYSICS
(DATE : 08-03-2014)
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 20/36
(iii) ~- - +|
(A), (B), (C) and (D).
:= [| n l=z|--| ] || ~| ~| + | ~|l +| z|| - |n| 1 ~- - t+ ~- - = = l|- -i- z-
z- 11 = 13 + ln ~- -
As shown in figure, a thin spherical shell of radius R has a fixed charge +q distributed uniformly over its
surface. A small circular section (radius r << R) of charge is removed from the surface.
lz| - l-= n R lz| |n ,+ -n |n|+| +|z| l-- ~|z| +q :=+i =-t ,+=n|- : = l-i- t +
:=+i =-t = ~|z| +| ,+ | | -||+| [| (lz| r << R) ~n + l| |-| t +
R
w
+z
z
P
11. The electric field just inside and just outside the sphere at the hole is :-
:= l: | n + ai+ ~- -|| ai+ |t l - {| = t| | :-
(A) 2
0
q
4 R pe
(B) 0 (C) 2
0
q
2 R pe
(D) 2
0
q
8 R pe
(DATE : 08-03-2014)
PHYSICS
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 21/36
FOR THE NEXT QUESTION NO. (12) : Have following setup, the cut section is replaced and the
sphere is set in motion rotating with constant angular velocity w = w
0
about the z-axis.
~n z- (12) + ln, % := || n || | = z|||- l+| |-| t ] l=n + t, [| +| |= |+ | n
+| z-~-| + =|-| l-- +| |i; w = w
0
= ?| | - +|| |-| t +
12. The line integral of the magnetic field ( Bdz
) along the z-axis is :-

z-~-| + ~-lz| --+i; {| = +| |i; =n|+n ( Bdz
) t| | :-
(A)
0 0
q
4
m w
p
(B)
0 0
q
2
m w
p
(C)
0 0
q
3
m w
p
(D)
0 0
2q
3
m w
p
FOR THE NEXT QUESTION NO. (13) : Now the sphere's angular velocity increases linearly with
time w = w
0
+ kt.
~n z- (13) + ln, % ~ | n + +| |i; +| =n; + =|| w = w
0
+ kt + ~- =| l|+ : = <+ || |-|
t +
13. The line integral of the electric field (
P
E.d
) around the circular path P located at the centre of the

sphere is (Assume that the normal to the plane containing the path is along the +z axis and that the radius
r
p
<< R) :-
| n + + -: l|- -|i; | P + -|| ~| l - {|= +| |i; =n|+n (
P
E.d
) t|| (t | l= -n n t
n|-| -= -n ~l|n- + z ~-| + ~- lz| t -|| lz| r
p
<< R t ) %-
(A)
2
0 P
kr q
2R
m
(B)
2
0 P
kr q
3R
m
(C)
2
0 P
kr q
6R
m
(D)
2
0 P
kr q
4R
m
PHYSICS
(DATE : 08-03-2014)
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 22/36
| - II : nl +=n n +|
n ;l +|- B +|-| Q ~| R = n n [||-| t ] -| ~| ~|(=(ORS) n -= z- + ln +|- B + =|n- Q ~| R =
=-l-|- n n| +| +|n| +il +
1. Column-I shows position vector as function of time for a particle. Match the characteristic of the motion
with their description in column-II.
Column-I Column-II
(A) A particle has its position as a function (P) Angular momentum of the system
of time given by ( )
0 0
r t r v t = +
r r r
where about the origin is conserved.
0
r
r
and
0
v
r
are non-zero constants.
(B) A particle has its position vector as (Q) The particle may be charged and
function of time given by moving in a uniform electric and magnetic
( )
( )
2
0 0
= +
r
r t v t c t k +
( ) ( )
0 0

cos sin a t i a t j w w + field, no other force acts on it
where
0
a
r
and
0
v
r
, c
0
are non-zero
constant. (angle between
0
v
r
and
0
a
r
is 90 < q < 180)
(C) A particle is moving in a plane with (R) Projection of particle on x or y axis is
its position vector given by simple harmonic motion.
( )
( ) ( )
0 0

sin cos r t a t i b t j w w = +
r
where a
0
, b
0
(a
0
b
0
) and w are
positive constant.
(D) A particle is moving in a plane (S) Particle may be moving under the influence
with position vector of force obeying inverse square force law
( )
( ) ( )
0 0

cos sin r t a t i a t j w w = +
r
where a
0
and w are positive constant.
(T) Area swept by position vector of particle
in equal time interval is equal.
(DATE : 08-03-2014)
PHYSICS
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 23/36
--|-I n ,+ +| + ln, =n; + +n- + : n l|l- =lz| +| z|| | | t + :-+| --|-II n l, , +|-| =
lnn|- l+l(+
--|-I --|-II
(A) (+ +| +i l|l- =n; + +n- + : n (P) n n l- + =|-| l-+|; +| +||i; = = l-|- t +
( )
0 0
r t r v t = +
r r r
,|| ln|i |-i t ] t|
0
r
r
-||
0
v
r
~z|-; ~- t +
(B) (+ +| +| =n; + +n- + : n l|l- =lz| (Q) t +| ~| lz|- t| =+-| t -|| =n l -
( )
( )
2
0 0
= +
r
r t v t c t k +
( ) ( )
0 0

cos sin a t i a t j w w + --+i; {|= n l-z|in t , := +| : ~-; n
,|| l| |-| t ] t|
0
a
r
,
0
v
r
-|| c
0
~z| -; l--| + +| - -ti t +
t (
0
v
r

0
a
r
+ n/; +| | 90 < q < 180 t )
(C) (+ +| l+=i -n n l-z|in t l=+| l|l- =lz| (R) x | y ~-| +| +| -| =n ~|- l- t +
( )
( ) ( )
0 0

sin cos r t a t i b t j w w = +
r
}|| l| |-|
t ] t| a
0
, b
0
(a
0
b
0
) -|| w |-|n+ l--| + t +
(D) (+ +| l+=i -n n l-z|in t l=+| l|l- =lz| (S) +| +n n l-n +i |n-| +- |n
( )
( ) ( )
0 0

cos sin r t a t i a t j w w = +
r
,|| l| |-| n + ~|i- l-z|in t| =+-| t +
t ] t| a
0
-|| w |-|n+ l--|+ t +
(T) +| + l|l- =lz| }|| =n|- =n; ~--|n n
=n|- {| z+n -; l+| |-| t +
| III : || + n|- =ti +|
PHYSICS
(DATE : 08-03-2014)
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 24/36
[|-IV : ( || + n|- =ti +|)
:= [| n 6 z- t + + z- +| --| 0 = 9 -+ (| -| z||lnn) + i- +| ,+n ~ +i ; || + t +
1. The K
a
X-ray of molybdenum has wavelength 71 pm. If the energy of a molybdenum atom with a
K electron knocked out is 23.32 keV, what will be the energy (in keV) of this atom when an L electron
is knocked out? Approximate your answer to nearest integer (Take hc = 1242 eV-nm)
n| ln -n +i K
a
X-l+| +i - /; 71 pm t| -i t + ;l n| ln -n n|| l=+| K :n + | - |t l-+n |
t| ] +i -| 23.32 keV t| -| ,+ L :n + | - + |t l-+n- := n|| +i -| (keV n ) +| t| i ~-| --|
l-+-n ||+ n + (hc = 1242 eV-nm)
2. Figure shows a cylindrical conducting rod of diameter d and length l >> d is uniformly charged in vacuum
such that electric field near its surface and far from its ends is E
0
. Electric field at r >> l on the axis of
the cylinder is
0
2
3E d
4Nr
l
. Then find the value of N.
|= d -|| n-|: l >> d |ni ,+ n-|+| -|n+ + +| l-| - n ,+ =n|- : = := +| ~| lz|- l+|
|-| t l+ :=+i =-t + -i+ -|| :=+ l=| = l - {|= E
0
|-- t| -| t + n- +i ~-| r >> l l -
-|=
0
2
3E d
4Nr
l
t| -| N +| n|- a|- + +
l
d
r
(DATE : 08-03-2014)
PHYSICS
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 25/36
3. Figure shows a mirrored equiconvex lens placed at 12 cm below water. Find position of object above
the surface of water (in cm) such that its image coincides with itself.
l-= n ,+ |- n| =n| -|n n = z|| | | t | l+ n =-t = 12 cm -i- l|- t + n =-t = l+=i l-
+| l+--| - (cm n ) || | -|l+ :=+| l-l-] l- + = |-i t|
m
g
=3/2
R=30cm
1
2
c
m
m
air
=1
\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \
\
\ \ \ \ \ \ \ \ \ \ \ \ \ \ \
O
m
W
=4/3
4. An infinitely long cylinder of radius R is made of an unusual exotic material with refractive index 1
(Figure). The center of the cylinder O lies along the y-axis. A narrow laser beam is directed along the y
direction from the lower plate. The laser source is at a horizontal distance x from the diameter in the y
direction. The angle of incidence is 10. If total deviation suffered by ray is d (in degree) as it comes out,
write answer as
10
d
.
(+ ~--- n-| R lz| +| n-] ,+ ~=|n|-; || l=+| ~- -| + (1) t ] = -| t~| t] l-= |+ n-
+| + - O, y-~-| + ~-lz| l|- t + l--ni -n = ,+ -n| n y-lz|| n ~|l-- t| -| t + ;t n n| -
y-lz|| n |= = {| l- i x l|- t + ~|-- +| | 10 t + ;l l+| + |t l-+n- l+| n --- +n
l-n- d (l i) t| -|
10
d
+| n|- a|- +il +
q
r
q
i
O
y
x
incident ray
emergent ray
PHYSICS
(DATE : 08-03-2014)
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 26/36
5. A disc of radius r is made of a material of negligible resistance and can rotate about a horizontal shaft. A
smaller disc of radius r is fixed onto the same shaft and has a massless cord wrapped around it, which is
attached to a small object of mass m as shown. Two ends of a resistor of resistance R are connected to
the perimeter of the disc and to the shaft by wiping contacts. The system is then placed into a uniform
horizontal magnetic field B and mass m is released. Find the constant angular velocity (in rad/s) with which
the disc will rotate after a certain time. If your answer is w give value of
20
w
. Data : r = 10 cm, r = 2 cm,
R = 0.01 W, B = 0.2 T, m = 50 g.
(+ r lz| +i -+-i -.; l-| | |n || = -i t -|| ;t ,+ {| l- z|| + + =| -| ?| | - + =+-i t + ,+
r lz| |ni | i -+-i +| := z||+ |+ ,+ :n|-ti- =i :=+ -|| ~| n i |-i t | l-z|- =|
m :n|- + ,+ | l = i t: t + l-| | R |n ,+ l-| |+ + | -| l=| +| -+-i + ln| -|| z||+
= | + - t + := l-+|; +| ~ =n {| l- --+i; {|= B n |+ :n|- m +| l|n||| = | | |-| t +
(+ l-lz-- =n; + z-|- ;t -+-i l= l-- +| |i; = ?| | - + i -=+| n|- (rad/s n ) a|- +il(+ ;l
~|+| --| w t| -|
20
w
+| n|- lnl|, , r = 10 cm, r = 2 cm, R = 0.01 W, B = 0.2 T, m = 50 g nil(+
r
m
B
R
r
B
6. A long cylinder with uniformly charged surface and cross-sectional radius a = 1.0 cm moves with a
constant velocity v = 10 m/ s along its axis. An electric field strength at the surface of the cylinder is
equal to E = 0.9 kV/cm. If the resulting convection current, that is, the current caused by mechanical
transfer of a charge is a A. Then fill 10a. (
0
= 8.85 10
12
C
2
/N-m
2
)
(+=n|- : = ~| lz|- a -|| a = 1.0 cm ~- | +| lz| |n| ,+ n-| n- :=+i ~-| + ~- lz|
v = 10 m/ s + l-- = l- +-| t + := n- + a l - {| = =|n +| n|- E = 0.9 kV/cm t + ;l
(+ ~| z| + ;| lz+ ||-|--| + +|| --- /||| | l+ l||ni = t- /||| t ] +| n|- a A t| -| 10a a|-
+il(+ (
0
= 8.85 10
12
C
2
/N-m
2
)
(DATE : 08-03-2014)
CHEMISTRY
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 27/36
PART-3 : CHEMISTRY
||-3 : =|-
[|-I : (i) + n ,+ =ti l+- +|
=ti t+
1. A quantity of aluminium has a mass of 54.0 g. What is the mass of the same number of magnesium
atoms? (At. wt. Al = 27, Mg=24)
n -ilz|n + l+-- n|- n --- ti n|| -l|- t| l-- +i 54.0 g (- lnl-n n n|| ~| +i =[;|
-l|- t ? (At. wt. Al = 27, Mg=24)
(A) 12 g (B) 24 g (C) 48 g (D) 97 g
2. + CH
3
CH=CH
2

D

4 3
PO H
A
+

D
O H ). 2 (
, O . ) 1 (
3
2
B + C
2 2 4
NH OH/ H conc.H SO
C D E
+
D

Product C reacts with NaOH/I
2
but does not show any reaction with ammoniacal silver nitrate.
Product E is
+ CH
3
CH=CH
2

D

4 3
PO H
A
+

D
O H ). 2 (
, O . ) 1 (
3
2
B + C
2 2 4
NH OH/ H conc.H SO
C D E
+
D

-| C, NaOH/I
2
+ =|| ~l|l+| +-| t -- ~n|l-- l=- -|: + =|| l+| -ti +-| t ] -|
E t :-
(A) (CH
3
)
2
=NOH (B) CH
3
CH
2
CONH
2
(C) CH
3
CONHCH
3
(D) CH
3
COCH
3
CHEMISTRY
(DATE : 08-03-2014)
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 28/36
3. The monomer that can undergo radical, cationic and anionic polymerisation with equal ease:
l---lnl|- n = +| -=| ,+n+ n n+] /|-|l-+ -|| +|~|l-+ t n+i+| =n|- = +- t :
(A) MeC=CH
2
Me
(B) PhCH=CH
2
(C) CH
2
= CHCH
3
(D) CH
2
=CHCN
4. Electrolytic reduction is commmercially employed for the extraction on which of the following metals?
l---lnl|- n = l+= /||- + l-+| | + ln, - ~|-i; ~-- +| |=|l+ - +- l+| |-|
t ?
(A) Al (B) Cu (C) Ag (D) Fe
5. Which of the following ion does not dissolve in excess of aqueous ammonia
l---lnl|- n = +| -=| ~|- ni; ~n|l-| + ~|l|+; n ln ; -ti t| -| t +
(A) Ag
+
(B) Cu
2+
(C) Al
3+
(D) Zn
2+
6. Pick the incorrect statement (s) for [Fe(H
2
O)
5
(NO)]SO
4
(spin only magnetic moment =
15BM
)
(A) It is formed when NaNO
3
is treated with saturated solution of FeSO
4
in presence
of conc. H
2
SO
4
(B) Oxiation state of Fe is +2
(C) It is an outer-orbital complex
(D) Fe is sp
3
d
2
hybrid.
[Fe(H
2
O)
5
(NO)]SO
4
(-+| - -+i; ~|| | =
15BM
) + ln, ~=; +|- +| -- +il, %
(A) :=+| l-n| | NaNO
3
+| =|- H
2
SO
4
+i -l|l- n FeSO
4
+ = - -- ln- + =|| l+| }|| t|-| t
(B) ~|- +i ~| +=i+| ~|| +2 t +
(C) t ,+ |t ; +-|+ =+n t +
(D) Fe, sp
3
d
2
=+l- t +
(DATE : 08-03-2014)
CHEMISTRY
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 29/36
(ii) (+ ;| ~l|+ =ti l+- +|
~l|+ =ti t+
7. Given that : DG
f
(CuO) = 30.4 kcal/mole
DG
f
(Cu
2
O) = 34.98 kca/mole T = 298 K
Now on the basis of above data which of the following predictions will be most appropriate under the
standard conditions.
(A) The reaction between Cu
2
O and O
2
would be spontaneous
(B) The reaction between CuO and O
2
would be spontaneous
(C) The reaction between CuO and O
2
would be non spontaneous
(D) Finely divided form of CuO kept in excess O
2
would be converted to a mixture of CuO and Cu
2
O
(having more of Cu
2
O)
l| t~| t % DG
f
(CuO) = 30.4 kcal/mole
DG
f
(Cu
2
O) = 34.98 kca/mole T = 298 K
-| +- ~| + | + ~||| n|-+ ~||~| l--- n = +| -=| ~- n|- =| l|+ =ti t :-
(A) Cu
2
O -|| O
2
+ n/; ~l|l+| -% t| i
(B) CuO -|| O
2
+ n/; ~l|l+| -% t| i
(C) CuO -|| O
2
+ n/; ~l|l+| ~-| t| i
(D) CuO +| = -n - | O
2
+ ~|l|+; n |- CuO -|| Cu
2
O + ln| (Cu
2
O +| ~|l|+; t|-| t ) n
ll- - t| |
CHEMISTRY
(DATE : 08-03-2014)
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 30/36
8. The possible product(s) of the following reaction is/are
l--- ~l|l+| n =-||l- -| t !t

COOH
COOH
COOH
COOH

4 10
P O
D
(A)
O
O
O
O
O
O
(B)
HOOC
O
O
O
COOH
(C)
COOH
COOH
O
O
O
(D)
O
O
O
O
O
O
9. In which of the following reaction a precipitate is formed ?
(A) BaCl
2
+ H
2
SO
4
(dilute) (B) AgNO
3
+ HCl (dilute)
(C) SrCO
3
+ H
2
SO
4
(dilute) (D) BaCl
2
+ Ca(OH)
2
l--- n = +| -=i ~l|l+| n ~-| --| t ?
(A) BaCl
2
+ H
2
SO
4
(-- ) (B) AgNO
3
+ HCl (-- )
(C) SrCO
3
+ H
2
SO
4
(-- ) (D) BaCl
2
+ Ca(OH)
2
10. Pick the paramagnetic species
~- - -+i; |l-| +| - l-,
(A) N
2
O (B) NO
2
(C) NO (D)N
2
O
4
(DATE : 08-03-2014)
CHEMISTRY
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 31/36
(iii) ~- - +|
(A), (B), (C) and (D).
:= [| n l=z|--| ] || ~| ~| + | ~|l +| z|| - |n| 1 ~- - t+ ~- - = = l|- -i- z-
z- 11 = 13 + ln ~- -
A hydrogen-like atom (atomic number Z) is in a higher excited state of quantum number n. This
excited atom can make a transition to the first excited state by successively emitting two photons of
energies 10.20 eV and 17.00 eV respectively. Alternatively, the atom from the same excited state can
make a transition to the second excited state by successively emitting two photons of energy 4.25 eV
and 5.95 eV respectively.
t|: | - + =n|- n|| (n|| +n| + Z) ----| --|l- ~|| l=+i +| n = [;| n t ] n -l|- t + ;t
--|l- n|| +n|- | +| | -| l-+i -| +nz| % 10.20 eV -|| 17.00 eV t +| -=- + |n --| l-
~|| n ||-|--l- t| =+-| t + = l+- + : n =n|- --|l- ~|| = n|| +| ||-|--| | +n|-
+||-| l-+i -| +nz| % 4.25 eV -|| 5.95 eV +| -=- + l,-i ; --|l- ~|| n ||-|--l- t|
=+-| t +
11. The principle energy level from which transition takes place to first and second excited state :
t n[; -| - l== |n l,-i; --|l- ~|| n ||-|--| t|-| t %
(A) n = 4 (B) n = 6 (C) n = 5 (D) n = 7
12. The hydrogen like species which corresponds to the above transition :
t|: | - + =n|- |l- | l+ - +- ||-|--| = =-l-|- t :
(A) He
+
(B) Be
3+
(C) Li
2+
(D) None
13. If in the above sample ions, de-excitation takes place from the given transition state upto ground state
then how many spectral lines will be observed in visible range :
- +- = -n ~|-| n l--|- i t : = +n| ~|| = l----|n -| - n t|-| t -| z ; |= n l+--i
+ n ||( l-|- t| i :
(A) 1 (B) 2 (C) 3 (D) 4
CHEMISTRY
(DATE : 08-03-2014)
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 32/36
| - II : nl +=n n +|
n ;l +|- B +|-| Q ~| R = n n [||-| t ] -| ~| ~|(= (ORS) n -= z- + ln +|- B + =|n- Q ~| R =
=-l-|- n n| +| +|n| +il+
1. Match compounds of Column-I with their tendency to react with some reagent given in Column-II
Column I Column II
(A) HCHO (P) Reacts with [Ag(NH
3
)
2
]
+
(B) CH
3
CHO (Q) Reacts with Fehling solution
(C) CH
3
COCH
3
(R) Makes yellow precipitate of CHI
3
with NaOH/I
2
(D) HCOOH (S) Makes 2 different molecules of cyanohydrin
(T) Reacts with 2, 4 DNP molecule
--|-I n l ;| l+| +| --|-II n l + ~l|+n+| = --+i l+|z|in-| + ~||| lnn|-
+il, %
--|-I --|-II
(A) HCHO (P) [Ag(NH
3
)
2
]
+
+ =|| l+| +-| t
(B) CH
3
CHO (Q) + tln ln- + =|| l+| +-| t
(C) CH
3
COCH
3
(R) NaOH/I
2
+ =|| in| ~-| -|-| t +
(D) HCOOH (S) =|-| t|:l - + | l|| ~| -|-| t +
(T) 2, 4 DNP ~| + =|| l+| +-| t +
| III : || + n|- =ti +|
(DATE : 08-03-2014)
CHEMISTRY
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 33/36
[|-IV : ( || + n|- =ti +|)
:= [| n 6 z- t + + z- +| --| 0 = 9 -+ (| -| z||lnn) + i- +| ,+n ~ +i; || +
t +
1. For the reaction A products, the following data is given for a particular run.
time (min.) : 0 5 15 35
[A]
M
: 1 1/2 1/4 1/8
Determine the order of the reaction.
A -|] ~l|l+| n ln, l+=i llz| ||l+ -|| + l--- ~| + l t
=n; (ln-) : 0 5 15 35
[A]
M
: 1 1/2 1/4 1/8
~l|l+| +i +| l a|- +il(+
2. The total residual activity in a patient after receiving an injection containing
99
Tc must not be more
than 0.01 mCi, after 36.0 hours. If sample injected have the initial activity 0.64mCi. The half-life of
99
Tc
would be (in hours)
99
Tc +| : +z|- l+=i ni +| n|- ~z||l|- l+|z|in-| 36 | | 0.01 mCi = ~l|+ |-- -ti t :
l =-n : +z|- +i |l-|+ l+|z|in-| 0.64 mCi t ] -|
99
Tc +i ~z ~| (?|| n) +| t| i
3. When a graph is plotted between log x/m and log p, it is straight line with an angle 45 and intercept
0.3010 on y-axis. If initial pressure is 0.3 atm, then 6 10
y
gm of gas is adsorbed per gm of adsorbent,
then find value of y ?
log x/m -|| log p + n/; |+ [|i -| |-| t -| ,+ =n || |-- t| -i t | x-~-| = 45 +| +| | -|-i
t -|| y-~-| 0.3010 ~ -| +|-i t + ;l |l-|+ | 0.3 atm t|] ~l|z|||+ + l- |n }||
6 10
y
gm = ~l|z|| l|- t| -i t ] -| y +| n|- a|- +| ?
CHEMISTRY
(DATE : 08-03-2014)
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 34/36
4. For the following reaction
C
Diamond
+ O
2
CO
2
(g) ; DH = 97.0 kcal
C
Graphite
+ O
2
CO
2
(g) ; DH = 94.0 kcal
The heat required to change 24 g of C
graphite
C
diamond
, in kcal would be
l--- ~l|l+| + ln,
C
Diamond
+ O
2
CO
2
(g) ; DH = 97.0 kcal
C
Graphite
+ O
2
CO
2
(g) ; DH = 94.0 kcal
24 |n C
graphite
C
diamond
, n l-- + ln, ~|z+ -n| kcal n t| i+
5. The number of carbon atoms whose type of hybridization changed in the given reaction is/are
i : ~l|l+| n +| - n|| ~| +i = [;| t !t l-+i = +| ~|| n l- - t| -| t+
Cl (excess)
2
Sunlight
Product
6. Find the number of species from the following which undergoes redox change on treatment with
water.
(i) NO
2
(ii) ClO
2
(iii) XeF
2
(iv) XeF
4
(v) XeF
6
(vi) N
2
O
4
(vii) SiF
4
(viii) Cl
2
O
7
(ix) BF
3
(x) F
2
i : |l-| n = n + =|| -|-; ~l|l+| - |ni |l-| +i = [;| a|- +il(+
(i) NO
2
(ii) ClO
2
(iii) XeF
2
(iv) XeF
4
(v) XeF
6
(vi) N
2
O
4
(vii) SiF
4
(viii) Cl
2
O
7
(ix) BF
3
(x) F
2

08-03-2014
TM
Path to success
KOTA(RAJASTHAN)
KOTA - 35/36 01CT313071
11. | I
(i) || n 6 t l+- z- t + t z- n -| l+-
(A), (B), (C) ~| (D) t l-n = (+ =ti t +
(ii) || n 4 t l+- z- t + t z- n -| l+-
(A), (B), (C) ~| (D) t l-n = (+ ;|
~l|+ =ti t +
(iii) || n l=z|--|] || ~| ~|+| ~|l +| z||- |n|
1 ~-- t + ~-- = =l-|- -i- z- t + ~--
-i- z- t + ~- - n t z- + -| l+- (A),
(B), (C) ~| (D) t l-n = + n ,+ =ti t +
12. | II n 1 z- n l += = n n +| +| t +
13. | III n ,+ |i z- -ti t +
14. | -IV n 6 z- t + + z- +| --| 0 = 9 -+
(|-| z||lnn) + i- +| ,+n ~ +i; || + t+
D. ~ +- ;| -| :
15. | -I (i & iii) + t z- n + n =ti --|| (--|) |n
=|i nn| ( n n) +| +|n| +- 3 ~ + ~| +| :
|i n n| +|n| -ti +- z| -; (0) ~ + |- l+|
| |+ ~-; =|i l|l-| n +||n+ ,+ (1) ~ + |-
l+| | |+
16. | -I(ii) n t z- n + n =ti --| |n n n
(BUBBLE) +| +|n| +- 4 ~ + ~| +|: |i n n|
+|n| -ti +- z| -; (0) ~ + |- l+| || := [|
+ z-| n n- --| - +| : +||n+ ~ + -ti l
| +
17. |II + z- + ln, , l=+ -l-- --| |n ! |
+| +|n| l+| t ~| t -| + l+ + ln, ~|+| 2 ~ +
l | + ~-% := [| + + z- + ~l|+-n
8 ~ + t + := [| n n- --| ! --|| + ln, +| :
+||n+ ~ + -ti l | +
18. | -IV n t z- n + n =ti --| |n n n
(BUBBLE) +| +|n| +- 4 ~ + ~| +|: |i n n|
+|n| -ti +- z| -; (0) ~ + |- l+| || := [|
+ z-| n n- --| - +| : +||n+ ~ + -ti l
| +
19. g = 10 m/s
2
+- + ] -+ l+ ~-; +| : n|- -ti
l| | t|+
11. SECTION I
(i) Contains 6 multiple choice questions. Each
question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
(ii) Contains 4 multiple choice questions. Each
question has four choices (A), (B), (C) and (D)
out of which ONE or MORE are correct.
(iii) Contains 1 paragraph each describing theory,
experiment, date etc. Three questions relate to
paragraph. Each question of paragraph has
ONLY ONE correct answer among the four
choices (A), (B), (C) and (D)
12. SECTION II contains 1 question of Matrix Match
Type.
13. There is no questions in SECTION-III
14. Section-IV contains 6 questions The answer to each
question is a single digit integer, ranging from
D. Marking scheme :
15. For each question in Section-I (i & iii), you will be
awarded 3 marks if you darken all the bubble(s)
corresponding to only the correct answer(s) and
zero mark if no bubbles are darkened. In all other
cases minus one (1) mark will be awarded
16. For each question in Section-I (ii), you will be
awarded 4 marks if you darken the bubble
corresponding to the correct answer and zero mark
if no bubbles are darkened No negative marks will
be awarded for incorrect answers in this section.
17. For question in Section II, you will be awarded
2 marks for each row in which you have darkened
the bubble(s) corresponding to the correct answer.
Thus, each question in this section carries a
maximum of 8 marks. There is no negative marking
for incorrect answer(s) for this section.
18. For each question in Section-IV, you will be awarded
4 marks if you darken the bubble corresponding to
the correct answer and zero mark if no bubbles are
darkened No negative marks will be awarded for
incorrect answers in this section.
19. Take g = 10 m/s
2
unless otherwise stated.
08-03-2014 TARGET : JEE (Main + Advanced) 2014
TM
Path to success
KOTA(RAJASTHAN)
01CT313071 KOTA - 36/36
Corporate Office
ALLEN Career Institute,
SANKALP, CP-6, Indra Vihar, Kota (Rajasthan)-324005,
Trin : +91 - 744 - 2436001 Fax : +91-744-2435003,
E-Mail: info@allen.ac.in Website: www.allen.ac.in
TM
Name of the Candidate / i-|||i +| -|n
I have read all the instructions and shall
abide by them.
n - =|i ~- z|| +| <+ ln| t ~| n --+|
~z; |n- + |+
Signature of the Candidate/ i-|||i + t-|-|
Form Number / +| n = [;|
I have verified all the information filled
in by the Candidate.
i-|||i }|| |i : |-+|i +| n- | -
ln| t +
Signature of the Invigilator /l-i-|+ + t-|-|

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D

+ - (t| n N -|| [.], {.} +nz|% nt-|n || + +n- ~ || z| +n- +| +-

where a, b R. If f(x) is differentiable at x = 1 then (2a+b) is equal to

t| a, b R, l f(x), x = 1 ~+n-i; t ] -| (2a+b) +| n|- t %

, then (A+B) is equal to

) along the z-axis is :-

) around the circular path P located at the centre of the

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