2012 PETROLIAM NASIONAL BERHAD (PETRONAS)

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whether express or implied, as to the accuracy or completeness of the facts presented. PETRONAS disclaims responsibility from any liability arising
out of reliance on the contents of this publication. Group Health, Safety & Environment Division
13th March 2014
HSE Dept PRSB
Agenda
2
9.30 - 9.45 : Ice Breaking
9.45 - 10.00 : Introduction to SHOC
10.00 - 10.15 : Regulatory Requirements
- CLASS
- USECHH
10.15 - 10.30 : Morning Tea Break
10.30 - 12.30 : SHOC Approach
- Identification
- Assess & Evaluate
- Control
- Response
12.30 - 2.00 : Lunch
2.00 - 3.30 : Continue on SHOC Approach
3.30 - 3.45 : Afternoon Tea Break
3.45 - 3.30 : Case Study
3.30 - 4.30 : Test & End
2010 PETROLIAM NASIONAL BERHAD (PETRONAS)
Name/Nickname
Current Department
Experience in handling of
chemical
Personal Expectation
ICE BREAKER
MODULE CONTENT
A. Introduction to SHOC
B. Company & Regulatory
Requirements
C. SHOC Approach
D. Case Study
E. Test
PART A: INTRODUCTION TO SHOC
5
Part A: Introduction to SHOC
6
TRAINING OBJECTIVES
To provide awareness on safe handling of
chemicals
To inculcate safe work practice when handling
chemicals
To comply with USECHH & CLASS
requirements
Our own incidents
8
Chemical burn due to contact with alkaline degreaser during cleaning of unloading area
Our own incidents
9
Sulfuric acid pin-hole leak at level transmitter
lower tapping of storage tank
Leak contained inside storage tank dike and
recovered
No human injury
Our own incidents
10
Human error caused the transfer of another reactive chemical Catalyst C (i.e
Ethyl Chloroformate) into Catalyst D vessel
No human injury
Our own incidents
11
Mercury exposure exceeding the Permissible Exposure Limits (PEL) during
maintenance activities
Consequences Chemical Accidents
Consequences
Harmful to
people
(P)
Damage to
property/
environment
(E)
Damage to
property
(A)
Damage to
company
reputation
and business
(R)
Important to handle chemical
safely
PART B: REGULATORY
REQUIREMENTS
13
Part B: Regulatory Requirements
14
Classification Packaging and Labeling (CPL) Chemicals Classification, Labeling And Safety Data Sheets
Safety & Health Regulations Related to
Chemicals in Malaysia
15
Factory and Machinery Act 1967
Factories and Machinery (Lead) Regulations
Factories and Machinery (Asbestos Process) Regulations
Factories and Machinery (Mineral Dust) Regulations
Occupational Safety and Health Act 1994
Use and Standard of Exposure to Chemical Hazardous to Health (USECHH)
Poison (Sodium Hydroxide) Regulations
Poison Act and 1974
Poison (Sodium Arsenite) Ordinance and Regulations
The list could be more.
Occupational Safety and Health Act
(OSHA) 1994 - Act 514
CLASS: Chemicals
Classification, Labeling
And Safety Data Sheets)
Regulations 2013
USECHH: Use and
Standards of Exposure of
Chemicals Hazardous to
Health Regulations 2000.
Example of DOSH Guidelines on Chemical
Management
17
Assessment of the health risks arising from the use of
hazardous chemicals in the workplace (2000)
Guidelines on the control of chemicals hazardous to
health (2001)
Guidelines on medical surveillance (2001)
Guidelines on monitoring of airborne contaminant for
chemicals hazardous to health (2002)
Guidelines on storage of hazardous chemicals (2005)
Guidelines on OSH for design, inspection, testing and
examination of LEV system (2008)
Beyond legal guidelines, we have several
PTS related to chemical management
60.1400.01 Health Risk Assessment
60.1502 Chemical Management Program
60.1502.01 Benzene
60.1502.02 Asbestos
60.1502.03 Volatile Organic Carbons
60.1502.04 Mercury Management
Guidelines
60.1502.05 Man-made Mineral Fibres
60.1509 Local Exhaust Ventilation Testing
60.2107 Welding And Cutting
60.2113 Handling Bulk Liquids at a Jetty
60.2112 Laboratory HSE
18
CLASS: Introduction
19
Evolution of CPL to CLASS
20
OSHA
1994
CPL 1997
GHS
2003,
Purple
Book
CLASS
2013
Classification based on
EU, labeling on MS and
CSDS on ILO
Recommendations 177
Classification based on
Globally Harmonized
System of Classification
and Labeling of Chemicals
(GHS)
Supplier to ensure that all chemicals
are well classified, packaged, labelled
furnished with CSDS
User to ensure all chemicals received
in well packaged and labelled
containers, together with CSDS
CLASS : Chemicals Classification, Labeling And
Safety Data Sheets) Regulations 2013
Responsibilities
Comparison between CPL and CLASS
22
CPL CLASS
Chemical Classification
Five (5) categories of Health Effects
Five (5) categories of Physico chemical
Environmental hazard is not included.
Eleven (11) categories of Health Hazards
Sixteen (16) categories of Physical Hazards
Three (3) categories of Environmental
Hazards
Labeling
5 elements 6 elements
Safety Data Sheets
16 elements 16 elements (different order)
Precautionary Statement
S Phrases P codes
Hazard Statement
R Phrases H codes
Signal Word
Not Specified Warning or Danger
Chemical Classification (Health)
HEALTH EFFECTS
Very toxic
Toxic
Harmful
Corrosive
Irritants
HEALTH HAZARD CLASSES
Acute Toxicity
Germ Cell Mutagenicity
Carcinogenicity
Reproductive Toxicity
Specific Target Organ Toxicity (Single)
Specific Target Organ Toxicity (Repeated)
Skin Corrosion/Irritation
Serious Eye Damage/ Eye Irritation
Respiratory Sensitisation
Skin Sensitisation
Aspiration Hazard
CLASS CPL
Chemical Classification (Physical)
CPL CLASS
PHYSICOCHEMICAL
Explosive
Oxidizing
Extremely flammable
Highly flammable
Flammable
PHYSICAL HAZARDS
Explosives
Oxidizing Liquids
Oxidising Solids
Oxidising Gases
Organic Peroxides
Flammable Gases
Flammable Aerosols
Flammable Liquids
Flammable Solids
Gases under Pressure
Self-Reactive Substances
Pyrophoric Liquids
Pyrophoric Solids
Self-Heating Substances
Substances which on contact with water emits
flammable gases
Corrosive to Metals
Chemical Classification (Environment)
CPL CLASS
ENVIRONMENTAL HAZARD CLASSES
Hazardous to Aquatic Environments
(acute)
Hazardous to Aquatic Environment
(chronic)
Hazardous to the ozone layer
ENVIRONMENTAL HAZARD CLASSES
Not Specified
Hazard Symbols/Pictograms
CPL HAZARD SYMBOLS CLASS HAZARD PICTOGRAMS
Labeling Elements
LABEL ELEMENTS
Name of hazardous chemical
Details of supplier
Danger symbols & indication of danger
Nature of special risks
Safety precautions
LABEL ELEMENTS
Product identifier/ingredient disclosure
Supplier identification
Hazard pictograms
Hazard statements
Precautionary statement
Signal words
CLASS CPL
Signal Word
Not specified
DANGER
For severe hazards
CLASS CPL
WARNING
For less severe hazards
Precautionary Statements
CLASS CPL
S-phrase Safety Phrases
S2 Keep out of reach of
children.
S16 Keep away from sources
of ignition - No Smoking
S28 After contact with skin,
wash immediately with
plenty of.....(to be
specified by the
manufacturer)
P-code Precautionary Statement
P102 Keep out of reach of
children.
P210 Keep away from
heat/sparks/open flame. -
No smoking.
P264 Wash hands thoroughly
after handling.
Hazard Statements
CLASS CPL
R-phrase Risk Phrase
R12 Extremely flammable
R25 Toxic if swallowed
R27 Very toxic in contact
with skin
R43 May cause
sensitisation by skin
contact
H-code Hazard Statement
H220 Extremely flammable gas
H301 Toxic if swallowed
H310 Fatal in contact with skin
H317 May cause an allergic
skin reaction
CLASS Label Format
Label Application (CPL)
Label Application (CLASS)
SDS Content Comparison
CPL
1. Product, company identification
2. Composition information on ingredient
3. Physical, chemical properties
4. Hazards identification
5. First aid measures
6. Fire fighting measures
7. Accidental release measures
8. Handling and storage
9. Exposure controls, personal protection
10.Stability and reactivity
11. Toxicological information
12. Ecological information
13. Disposal considerations
14. Transport information
15. Regulatory information
16. Other information
CLASS
1. Product and company information
2. Hazards identification
3. Composition information on ingredients
4. First aid measures
5. Fire fighting measures
6. Accidental release
7. Handling and storage
8. Exposure controls, personal protection
9. Physical, chemical properties
10. Stability and reactivity
11. Toxicological information
12. Ecological information
13. Disposal considerations
14. Transport information
15. Regulatory information
16. Other information
34
USECHH: Introduction
35
Employers Responsibilities
USECHH: Use and Standards of Exposure to
Chemicals Hazardous to Health Regulations 2000
1. Register of Chemicals Hazardous to Health
(Chemical Register)
2. Permissible Exposure Limit (PEL)
3. Chemical risks are assessed and controlled
(CHRA)
4. Level of chemical exposure is monitored
5. Health Surveillance
Employers Responsibilities
USECHH: Use and Standards of Exposure to
Chemicals Hazardous to Health Regulations 2000
6. Provision of PPE and responsibility to wear
7. Information (CSDS)
8. Label/Re-label
9. Warning Sign
10. Medical Removal Protection
11. Training/Instruction
12. Record Keeping
USECHH: Use and Standards of Exposure to
Chemicals Hazardous to Health Regulations 2000
1. Follow instruction or work procedures
(e.g. PTW)
2. Participate in any activities carried out
by their employer to ensure
compliance to the regulations (e.g.
personal monitoring, medical
surveillance)
3. Wear and maintain any PPE supplied to
them
Employees Responsibilities
PART C: SHOC APPROACH
39
Health Risk Management Concept
40
Health Surveillance
Exposure Monitoring
Health Risk Assessment
Q
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t
i
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a
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Q
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i
t
a
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Chemical Management In Line with HEMP
Concept
41
Identify health hazards and their
harmful effects (acute/chronic)
Assess the potential risk to the
Business by
Plotting each hazard on the RAM
Are Control and Recovery
measures adequate to
control health risks to ALARP?
Medium or High
Risk
Low Risk
Yes
No
Develop and
Implement
Remedial Action
Plan
Manage for continuous
improvement
Dont know - obtain
further information
Review
Document
Initial
Assessment
Detailed
Assessment
Hazard
Exposure
Hazard
Probability
PART C: SHOC APPROACH
SHOC Approach: (1) Identification
43
Identification
1. What is
chemical?
Chemical hazardous to health
Forms of chemicals
2. Health effects of
chemicals
Acute
Chronic
3. Sources of
chemical
information
Safety Data Sheet (SDS)
Chemical Register
Warning Sign
Labels
Identification
44
What is chemical/hazardous chemical?
Chemical health effects
Source of chemical information
Chemical
chemical elements, or
compound or mixture
thereof, whether natural or
synthetic, but does not
include micro - organism
Chemical Hazardous to Health
listed in Schedule I or II
(USECHH, 2000)
possess any of the properties
categorised in Part B of
Schedule I of CPL, 1997
comes within the definition of
pesticide under the Pesticides
Act, 1974
is listed in the First Schedule of
the EQA (Schedule Waste)
Regulations, 2005
45
1. What is chemical/hazardous
chemical?
Chemical Forms
46
Forms
Solid
Liquid
Gas
Vapor
Fume
Mist
Chemical Changes Its Form
Example of various forms of chemical
in workplaces
Water mist from stone
grinding
Fumes from welding
activities
Chemical vapor from
open container
Common Chemicals in PETRONAS
Benzene,
n-Hexane,
Mercury (Hg)
Hydrogen sulphide (H2S)
Methanol
Carbon tetrachloride
(CCl4)
Hydrazine
Carbon monoxide (CO)
Vinyl chloride monomer
(VCM)
Chronic
dermatitis due
to prolonged
exposure to
chemicals
Mesothelioma
from exposure to
asbestos
Depend on exposure and individual susceptibility
ACUTE
Effects that are
caused by a single
exposure
Effects that are resulted from
repeated or prolonged exposures
CHRONIC
2. Chemical Health Effects
Skin irritation
Eye irritation
Dizziness
Nausea
Headache
Throat & Nose
Irritation
Loss of consciousness
Acute Health Effects
Skin disease
Lung disease
Liver/ Kidney dysfunction
Blood disorder
Carcinogenic - cancer
Teratogenic - effects to fetus
Mutagenic - defective genes
Chronic Health Effects
Identification of Health Effects
HEALTH HAZARD CLASSES
Acute Toxicity
Germ Cell Mutagenicity
Carcinogenicity
Reproductive Toxicity
Specific Target Organ Toxicity (Single)
Specific Target Organ Toxicity (Repeated)
Skin Corrosion/Irritation
Serious Eye Damage/ Eye Irritation
Respiratory Sensitisation
Skin Sensitisation
Aspiration Hazard
Chemical
Register
Safety
Data
Sheet
(SDS)
Warning
Sign
Labeling
3. Source of chemical information
Chemical Register
55
Introduction
All chemicals manufactured, used or stored
shall be registered.
Chemical register shall be kept by individual
department.
Chemical register should be kept together
with SDS
SECTION A Company Information
SECTION B List and details of Chemical
Hazardous to Health for every process or
location
SECTION C Name of person who prepared
and reviewed
Chemical Register Contents
Section A Company Information
Section B List of Chemicals Hazardous to
Health
Section C Preparer Information
Safety Data Sheet (SDS)
61
Introduction
Based on GHS
16 elements
62
SDS Content
9. Physical, chemical
properties
10. Stability and reactivity
11. Toxicological information
12. Ecological information
13. Disposal considerations
14. Transport information
15. Regulatory information
16. Other information
63
1. Product and company
information
2. Hazards identification
3. Composition information
on ingredients
4. First aid measures
5. Fire fighting measures
6. Accidental release
7. Handling and storage
8. Exposure controls,
personal protection
1. Product and Company Information
Identification of the substance or mixture and of the supplier;
GHS Product Identifier
Other means of identification
Recommended use of the chemical and
restrictions on use
Suppliers details (including name, address,
phone number etc.)
Emergency phone number
Product and Company Information
65
2. Hazard Identification
GHS classification of the substance/mixture and
any national or regional information
GHS label elements, including precautionary
statements. (Hazard symbols may be provided as
a graphical reproduction of the symbols in the
black and white or the name of the symbol e.g.
flame, skull and crossbones);
Other hazards which do not result in the
classification (e.g. dust explosion hazard) or are
not covered by the GHS.
66
Hazard Identification
67
3. Composition Information on
Ingredients
Substance
Chemical identity;
Common name, synonyms, etc.;
CAS number and other unique identifiers
Impurities and stabilizing additives which are themselves
classified and which contribute to the classification of a
substance.
Mixture
The chemical identity and concentration or concentration
ranges of all ingredients which are hazardous within the
meaning of the GHS and are present above their cut-off
levels.
Composition Information on
Ingredients
69
4. First Aid Measures
Description of necessary measures,
subdivided according to the different routes of
exposure, i.e. inhalation, skin and eye contact
and ingestion;
Most important symptoms/effects, acute and
delayed.
Indication of immediate medical attention and
special treatment needed, if necessary.
70
First Aid Measures
71
5. Fire Fighting Measures
Suitable (and unsuitable) extinguishing media.
Specific hazards arising from the chemical
(e.g. nature of any hazardous combustion
products).
Special protective equipment and precautions
for fire-fighters.
72
Fire Fighting Measures
73
6. Accidental Release
Personal precautions, protective equipment
and emergency procedures.
Environmental precautions.
Methods and materials for containment and
cleaning up.
74
Accidental Release
75
7. Handling & Storage
Precautions for safe handling.
Conditions for safe storage, including any
incompatibilities.
76
Handling & Storage
77
8. Exposure Controls & PPE
Control parameters e.g. occupational
exposure limit values or biological limit values.
Appropriate engineering controls.
Individual protection measures, such as
personal protective equipment.
78
Exposure Controls & PPE
79
9. Physical & Chemical Properties
Appearance (physical state,
color etc.);
Odor;
Odor threshold;
pH;
Melting point/freezing
point;
Initial boiling point and
boiling range;
Flash point;
Evaporation rate;
Flammability (solid, gas);
Upper/lower flammability
or explosive limits;
Vapor pressure;
Vapor density;
Relative density;
Solubility(ies);
Partition coefficient: n-
octanol/water;
Auto-ignition temperature;
Decomposition
temperature;
Viscosity.
80
Physical & Chemical Properties
81
10. Stability & Reactivity
Reactivity;
Chemical stability;
Possibility of hazardous reactions;
Conditions to avoid (e.g. static discharge,
shock or vibration);
Incompatible materials;
Hazardous decomposition products.
82
Stability & Reactivity
83
11. Toxicological Information
Concise but complete and comprehensible description of
the various toxicological (health) effects and the available
data used to identify those effects, including:
Information on the likely routes of exposure
(inhalation, ingestion, skin and eye contact);
Symptoms related to the physical, chemical and
toxicological characteristics;
Delayed and immediate effects and also chronic effects
from short and long term exposure;
Numerical measures of toxicity (such as acute toxicity
estimates).
84
Toxicological Information
85
12. Ecological Information
Ecotoxicity (aquatic and terrestrial, where
available);
Persistence and degradability;
Bioaccumulative potential;
Mobility in the soil;
Other adverse effects.
86
Ecological Information
87
13. Disposal Considerations
Description of waste residues and information
on the their safe handling and methods of
disposal, including the disposal of any
contaminated packaging.
88
Disposal Considerations
89
14. Transport Information
UN number;
UN proper shipping name:
Transport hazard class(es);
Packing group, if applicable
Environmental hazards (e.g.: Marine pollutant (Yes/No));
Transport in bulk (according to Annex II of MARPOL 73/78
and the IBC Code);
Special precautions which a user needs to be aware of, or
needs to comply with, in connection with the transport or
conveyance within or outside their premises
90
Transport Information
91
15. Regulatory Information
Safety, health and environmental regulations
specific for the product in question.
92
Regulatory Information
93
16. Other Information
Fill in additional information as needed.
94
Other Information
95