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1 Identification of the substance & the company

Identification of the substance


Trade name : CHIMEC 7268
Chemical family : quaternary ammonium compounds
: organic sulphur derivate
: in water solution.
Type of product and use : microbiocide.
Company identification
Responsible for placing on the
market
: CHIMEC S.p.A.
Address and telephone nr : CHIMEC S.p.A. - Via Ardeatina Km 22,500
00040 S. Palomba - Pomezia (ROMA)
Tel. +39.06.918251 - Fax +39.06.91825260
e-mail: infosds@chimec.it
2 Hazards identification
Important hazards : the product is corrosive and harmful if ingested: the concentrated solution produces serious
damage on contact with skin and eyes. If swallowed, it may cause internal and mouth burns.
3 Composition / information on ingredients
Hazardous component(s) : alkyl dimethyl benzyl ammonium chloride.
Corrosive(C). R:22,34.
LD50 oral: 400 mg/Kg (rat).
CAS Nr.68989-00-4 Conc.
: 50 - 60 %
: 5-chloro-2-methyl-4-isothiazolin-3-one.
Toxic (T), Corrosive (C). R:23/24/25,34,
43,50.
DL50 oral: 457 mg/Kg (rat). DL50 dermal:
660 mg/Kg (rabbit).
TLV:TWA 0.1 mg/m3.
CAS Nr. 26172-55-4 Conc.
: 5 - 10 %
4 First-aid measures
First aid
MATERIAL SAFETY DATA SHEET
Trade Name CHIMEC 7268
Issue Date: 23/03/2006
This MSDS complies with Directives 91/155/EC, 93/112/EC, 2001/58/EC, 2008/58/EC, 2001/60/EC and their amendments.
Product Code 721/2
CHIMEC S.p.A.
Via delle Ande 19
00144 Roma
Tel. +39.06.918251
Page 1 \ 5
Inhalation : remove the exposed person from contaminated area; keep warm and in fresh air.
: if victim has trouble breathing, transport to medical care and give supplemental oxygen.
: in case of loss of consciousness, give artificial respiration.
- Skin contact : take off immediately all contaminated clothing.
: wash thoroughly with soapy water.
: if irritation persists, seek medical advice.
- Eye contact : wash with plenty of water,for at least 15 minutes, keeping the lids well open.
: seek medical advice.
- Ingestion : rinse the mouth with clean water; give plenty of water, seek medical advice.
: do not give anything by mouth to an unconscious or convulsing person.
5 Fire - fighting measures
Extinguishing media
- Suitable : carbon dioxide, dry chemicals, foam, water spray ( or fog).
- Not suitable : in case of large fire, water may be ineffective
Fire/explosion hazards : avoid breathing the fumes.
: avoid static build up; must be earthed.
Fire-fighting procedures : fire fighters and others who may be exposed to the products of combustion, should be
equipped with NIOSH approved positive pressure self-contained breathing apparatus and full
protective clothing.
: when exposed to flames or high temperatures encountered during fire conditions, sealed
containers may rupture because of the build up of internal pressure: cool containers with water
and remove.
: the contaminated water used for extinguishing must be disposed of in accordance with local
legislation.
6 Accidental release measures
After spillage / leakage
- on soil : isolate the dangerous area, wear protective clothing. Remove all sources of ignition and
contain the spill with inert materials.
: then collect in suitable containers and dispose of or burn at approved site.
: avoid dispersion of large quantities of product in sewers or waterways.
- on water : if spilled product is going into water courses or drain and soil or vegetation are contaminated,
advise legal authority and take measures to minimize effects on the aquatic environment.
7 Handling and storage
Handling : avoid contact with skin and eyes.
: handle this product near emergency showers, emergency eye-wash and with independent
breathing protection.
: protect eyes from vapour/spray.
: do not breathe vapour/spray.
: take precautionary measures against static discharge during blending and transfer operations.
: wear suitable respiratory equipment.
: a localized aspiration is necessary if the warmed product forms vapours.
Storage : store in well closed boxes.
: store in a fresh and well-ventilated place, away from incompatible substances.
: keep containers in store rooms with security electric plants and protection from atmospheric
discharge.
Suitable storage materials : carbon steel, natural or butylic rubber, polystyrene, polyethylene, polypropylene, PVC.
Not suitable storage materials : possibility of slight attack on ferrous metals.
8 Exposure controls / personal protection
CHIMEC S.p.A.
Via delle Ande 19
00144 Roma
Tel. +39.06.918251
Page 2 \ 5
Trade Name CHIMEC 7268
Occupational exposure limits : this product is a complex mixture and contains following substances with recommended or
approved OEL limits:
TLV (mg/m3) : ----
TLV (ppm) : ----
Personal protection
- Respiratory protection : a localized aspiration is necessary if the warmed product forms vapours.
: protective mask in case of exposure to vapours formed by warmed product.
- Skin protection : protective gloves in neoprene or latex, approved for protection against chemical substances
(EC seal - Directives 89/686 and 93/68).
- Eye protection : goggles or face shield with safety glasses.
- Others : appropriated protective clothing.
: eyewash bottle with clean water.
Industrial hygiene : ventilate thoroughly the working place.
: do not eat or drink when handling this product.
: remove all contaminated clothing and remove protective clothing when the work is completed.
: handle in accordance with good industrial hygiene and safety procedures.
9 Physical and chemical properties
Appearance
Physical state at 20C : liquid.
Colour : yellow.
Odour : characteristic.
Change in physical state -760
mm Hg
Freezing point (C) : n.d.
Boiling point (C) : ca. 100
Pour point (ASTM D97) (C) : n.d.
Density at 20C (gr/cm3) : 0.975 0.01
Viscosity at 20C (cP) : < 100
Solubility in water (% weight) : complete.
Soluble in : water.
pH value (concentrated product) : 4.0 - 8.0
Flash point (ASTM D 93) (C) : > 100
Auto-ignition temperature (C) : n.d.
Explosion limits
- Lower (% vol) : n.d.
- Upper (% vol) : n.d.
Thermal decomposition (C) : stable if utilized under normal conditions.
Further information : The physical and chemical properties reported in this document are not to be considered
Technical Specifications, and therefore they do not constitute a contractual obligation.
10 Stability and reactivity
Conditions to avoid : hot organic chemical vapours or mists can suddenly and without warning combust when mixed
with air: ignition can occur at typical elevated temperature process conditions.
: any proposed use in such processes should be evaluated thoroughly to assure safe operating
conditions.
Substances to avoid : none to our knowledge.
On combustion forms : burns producing chlorine and other equally toxic substances.
: may release oxides of carbon and other toxic gases and vapours.
Hazardous decomposition
products
: no hazardous decomposition products.
Hazardous reactions : may react violently with strong oxidizers.
CHIMEC S.p.A.
Via delle Ande 19
00144 Roma
Tel. +39.06.918251
Page 3 \ 5
Trade Name CHIMEC 7268
11 Toxicological information
Rat oral LD50 (mg/kg) : ----
Rabbit dermal LD50
(mg/kg)
: ----
Rat inhalation LC50 (ppm) : ----
Inhalation : vapours or fog inhalation at high temperature may produce irritation of respiratory tract.
Dermal toxicity : skin damages caused by prolonged and repeated contact.
Ingestion : burning effects in mouth, throat and stomach with abdominal cramps.
Corrosivity / Irritating capacity
- skin : corrosive.
: may produce dermatitis and burns.
- eyes : corrosive.
: direct contact may cause conjunctivitis and corneal lesions.
Sensitization : no evidence of this effect is shown.
Carcinogenicity : no evidence of this effect is shown.
Mutagenicity : no evidence of this effect is shown.
Teragenicity : no evidence of this effect is shown.
12 Ecological information
Information on ecological effects : utilize in accordance with good working practice and avoid to disperse the product in the
environment.
Mobility : with a correct disposal in biological treatment system, are not expected problems for the
degradation activity of activated sludge.
96 Hour-LC50-fish (mg/l) : ----
Persistence and degradability : readily degradable.
Biodegradation (%) : the product is not readily biodegradable.
Bioaccumulative potential : the product has been shown to present no bioaccumulation hazard in aquatic plants or fish.
WGK class (Germany) : 2 - hazardous.
AOX : the product does not contain organic halons.
13 Disposal considerations
Disposal : dispose in a safe manner in accordance with local/national regulations.
: do not dispose in a sink, drain or in the immediate environment.
: of the methods of disposal currently available, it is recommended that an alternative be
selected according to the following order of preference, based upon environmental
acceptability:
: 1 - recycle or rework if at all feasible;
2 - incinerate at an authorized facility;
3 - treat at an acceptable waste treatment facility.
Disposal of packaging : dirty containers of product must be recycled or disposed by an authorized facility.
: empty containers can retain product residues and may be hazardous: do not use heat, sparks,
open flames, or cigarettes on near empty container.
14 Transportation information
- ADR/RID/IATA
Proper shipping name : Corrosive liquids, n.o.s.
ADR Class : 8 - Corrosive substances.
Packaging group : II
Risk Label(s) : 8 - Corrosive.
Subsidiary Risk Label(s) : none.
Danger identification number
(upper)
: 80
CHIMEC S.p.A.
Via delle Ande 19
00144 Roma
Tel. +39.06.918251
Page 4 \ 5
Trade Name CHIMEC 7268
Substance identification number
(lower)
: 1760
Tremcard type : C
UN Number. : 1760
IMO-IMDG
IMO class : 8 - Corrosive substances.
Risk Label : 8 - Corrosive.
Subsidiary Risk Label : none.
Proper shipping name : Corrosive liquids, n.o.s.
Contains : alkyl dimethyl benzyl ammonium chloride
: organic sulphur derivate
Packaging group : II
Emergency Schedule (EmS) : F-A, S-B
Segregation Group : IMDG Code segregation group - none
15 Regulatory information
UE
- Symbol(s) : Corrosive:C
- Contains : alkyl dimethyl benzyl ammonium chloride
: organic sulphur derivate
- R Phrase(s) : R 22 :Harmful if swallowed.
: R 34 :Causes burns.
- S Phrase(s) : S 26 :In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
: S 28 :After contact with skin, wash immediately with plenty of soap and water.
: S 36/37/39 :Wear suitable protective clothing, gloves and eye/face protection.
: S 45: In case of accident or if you feel unwell, seek medical advice immediately (show the label
when possible).
16 Other information
Further information : R 22 :Harmful if swallowed.
: R 23/24/25 :Toxic by inhalation, in contact with skin and if swallowed.
: R 34 :Causes burns.
: R 43 :May cause sensitization by skin contact.
: R 50 :Very toxic to aquatic organisms.
Sources of key data used : N.Irving SAX - Dangerous properties of Industrial Materials ( Sixth edition) - Edited by Van
Nostrand Reinhold Company - 1984
: TLV - Threshold Limit Values for Chemical Substances in Work Environment - Adopted by
ACGIH - 2000
: A.D.R. - European Agreement concerning the international carriage of Dangerous Goods by
Road - United Nation Publication
: Karel VERSCHUEREN - Handbook of Environmental data on organic chemicals - 1977
Information for medical staff
Revised chapters : The chapters indicated by " ********** " have been modified with the present version of this
MSDS.
ST1 - 721/2 18/08/2003 - 1
The information reported on this MSDS results from our present state of knowledge on safety regulations and is not to be considered as a
guarantee of any specific product property.
CHIMEC cannot be held responsible for any injury or damage deriving from the improper application of the product.
CHIMEC S.p.A.
Via delle Ande 19
00144 Roma
Tel. +39.06.918251
Page 5 \ 5
Trade Name CHIMEC 7268

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