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The product is corrosive and harmful if ingested: the concentrated solution produces serious damage on contact with skin and eyes. If swallowed, it may cause internal and mouth burns. Product Code 721 / 2 CHIMEC S.p.A. Via Ardeatina Km 22,500 00040 S. Palomba - Pomezia (ROMA)
The product is corrosive and harmful if ingested: the concentrated solution produces serious damage on contact with skin and eyes. If swallowed, it may cause internal and mouth burns. Product Code 721 / 2 CHIMEC S.p.A. Via Ardeatina Km 22,500 00040 S. Palomba - Pomezia (ROMA)
The product is corrosive and harmful if ingested: the concentrated solution produces serious damage on contact with skin and eyes. If swallowed, it may cause internal and mouth burns. Product Code 721 / 2 CHIMEC S.p.A. Via Ardeatina Km 22,500 00040 S. Palomba - Pomezia (ROMA)
Trade name : CHIMEC 7268 Chemical family : quaternary ammonium compounds : organic sulphur derivate : in water solution. Type of product and use : microbiocide. Company identification Responsible for placing on the market : CHIMEC S.p.A. Address and telephone nr : CHIMEC S.p.A. - Via Ardeatina Km 22,500 00040 S. Palomba - Pomezia (ROMA) Tel. +39.06.918251 - Fax +39.06.91825260 e-mail: infosds@chimec.it 2 Hazards identification Important hazards : the product is corrosive and harmful if ingested: the concentrated solution produces serious damage on contact with skin and eyes. If swallowed, it may cause internal and mouth burns. 3 Composition / information on ingredients Hazardous component(s) : alkyl dimethyl benzyl ammonium chloride. Corrosive(C). R:22,34. LD50 oral: 400 mg/Kg (rat). CAS Nr.68989-00-4 Conc. : 50 - 60 % : 5-chloro-2-methyl-4-isothiazolin-3-one. Toxic (T), Corrosive (C). R:23/24/25,34, 43,50. DL50 oral: 457 mg/Kg (rat). DL50 dermal: 660 mg/Kg (rabbit). TLV:TWA 0.1 mg/m3. CAS Nr. 26172-55-4 Conc. : 5 - 10 % 4 First-aid measures First aid MATERIAL SAFETY DATA SHEET Trade Name CHIMEC 7268 Issue Date: 23/03/2006 This MSDS complies with Directives 91/155/EC, 93/112/EC, 2001/58/EC, 2008/58/EC, 2001/60/EC and their amendments. Product Code 721/2 CHIMEC S.p.A. Via delle Ande 19 00144 Roma Tel. +39.06.918251 Page 1 \ 5 Inhalation : remove the exposed person from contaminated area; keep warm and in fresh air. : if victim has trouble breathing, transport to medical care and give supplemental oxygen. : in case of loss of consciousness, give artificial respiration. - Skin contact : take off immediately all contaminated clothing. : wash thoroughly with soapy water. : if irritation persists, seek medical advice. - Eye contact : wash with plenty of water,for at least 15 minutes, keeping the lids well open. : seek medical advice. - Ingestion : rinse the mouth with clean water; give plenty of water, seek medical advice. : do not give anything by mouth to an unconscious or convulsing person. 5 Fire - fighting measures Extinguishing media - Suitable : carbon dioxide, dry chemicals, foam, water spray ( or fog). - Not suitable : in case of large fire, water may be ineffective Fire/explosion hazards : avoid breathing the fumes. : avoid static build up; must be earthed. Fire-fighting procedures : fire fighters and others who may be exposed to the products of combustion, should be equipped with NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. : when exposed to flames or high temperatures encountered during fire conditions, sealed containers may rupture because of the build up of internal pressure: cool containers with water and remove. : the contaminated water used for extinguishing must be disposed of in accordance with local legislation. 6 Accidental release measures After spillage / leakage - on soil : isolate the dangerous area, wear protective clothing. Remove all sources of ignition and contain the spill with inert materials. : then collect in suitable containers and dispose of or burn at approved site. : avoid dispersion of large quantities of product in sewers or waterways. - on water : if spilled product is going into water courses or drain and soil or vegetation are contaminated, advise legal authority and take measures to minimize effects on the aquatic environment. 7 Handling and storage Handling : avoid contact with skin and eyes. : handle this product near emergency showers, emergency eye-wash and with independent breathing protection. : protect eyes from vapour/spray. : do not breathe vapour/spray. : take precautionary measures against static discharge during blending and transfer operations. : wear suitable respiratory equipment. : a localized aspiration is necessary if the warmed product forms vapours. Storage : store in well closed boxes. : store in a fresh and well-ventilated place, away from incompatible substances. : keep containers in store rooms with security electric plants and protection from atmospheric discharge. Suitable storage materials : carbon steel, natural or butylic rubber, polystyrene, polyethylene, polypropylene, PVC. Not suitable storage materials : possibility of slight attack on ferrous metals. 8 Exposure controls / personal protection CHIMEC S.p.A. Via delle Ande 19 00144 Roma Tel. +39.06.918251 Page 2 \ 5 Trade Name CHIMEC 7268 Occupational exposure limits : this product is a complex mixture and contains following substances with recommended or approved OEL limits: TLV (mg/m3) : ---- TLV (ppm) : ---- Personal protection - Respiratory protection : a localized aspiration is necessary if the warmed product forms vapours. : protective mask in case of exposure to vapours formed by warmed product. - Skin protection : protective gloves in neoprene or latex, approved for protection against chemical substances (EC seal - Directives 89/686 and 93/68). - Eye protection : goggles or face shield with safety glasses. - Others : appropriated protective clothing. : eyewash bottle with clean water. Industrial hygiene : ventilate thoroughly the working place. : do not eat or drink when handling this product. : remove all contaminated clothing and remove protective clothing when the work is completed. : handle in accordance with good industrial hygiene and safety procedures. 9 Physical and chemical properties Appearance Physical state at 20C : liquid. Colour : yellow. Odour : characteristic. Change in physical state -760 mm Hg Freezing point (C) : n.d. Boiling point (C) : ca. 100 Pour point (ASTM D97) (C) : n.d. Density at 20C (gr/cm3) : 0.975 0.01 Viscosity at 20C (cP) : < 100 Solubility in water (% weight) : complete. Soluble in : water. pH value (concentrated product) : 4.0 - 8.0 Flash point (ASTM D 93) (C) : > 100 Auto-ignition temperature (C) : n.d. Explosion limits - Lower (% vol) : n.d. - Upper (% vol) : n.d. Thermal decomposition (C) : stable if utilized under normal conditions. Further information : The physical and chemical properties reported in this document are not to be considered Technical Specifications, and therefore they do not constitute a contractual obligation. 10 Stability and reactivity Conditions to avoid : hot organic chemical vapours or mists can suddenly and without warning combust when mixed with air: ignition can occur at typical elevated temperature process conditions. : any proposed use in such processes should be evaluated thoroughly to assure safe operating conditions. Substances to avoid : none to our knowledge. On combustion forms : burns producing chlorine and other equally toxic substances. : may release oxides of carbon and other toxic gases and vapours. Hazardous decomposition products : no hazardous decomposition products. Hazardous reactions : may react violently with strong oxidizers. CHIMEC S.p.A. Via delle Ande 19 00144 Roma Tel. +39.06.918251 Page 3 \ 5 Trade Name CHIMEC 7268 11 Toxicological information Rat oral LD50 (mg/kg) : ---- Rabbit dermal LD50 (mg/kg) : ---- Rat inhalation LC50 (ppm) : ---- Inhalation : vapours or fog inhalation at high temperature may produce irritation of respiratory tract. Dermal toxicity : skin damages caused by prolonged and repeated contact. Ingestion : burning effects in mouth, throat and stomach with abdominal cramps. Corrosivity / Irritating capacity - skin : corrosive. : may produce dermatitis and burns. - eyes : corrosive. : direct contact may cause conjunctivitis and corneal lesions. Sensitization : no evidence of this effect is shown. Carcinogenicity : no evidence of this effect is shown. Mutagenicity : no evidence of this effect is shown. Teragenicity : no evidence of this effect is shown. 12 Ecological information Information on ecological effects : utilize in accordance with good working practice and avoid to disperse the product in the environment. Mobility : with a correct disposal in biological treatment system, are not expected problems for the degradation activity of activated sludge. 96 Hour-LC50-fish (mg/l) : ---- Persistence and degradability : readily degradable. Biodegradation (%) : the product is not readily biodegradable. Bioaccumulative potential : the product has been shown to present no bioaccumulation hazard in aquatic plants or fish. WGK class (Germany) : 2 - hazardous. AOX : the product does not contain organic halons. 13 Disposal considerations Disposal : dispose in a safe manner in accordance with local/national regulations. : do not dispose in a sink, drain or in the immediate environment. : of the methods of disposal currently available, it is recommended that an alternative be selected according to the following order of preference, based upon environmental acceptability: : 1 - recycle or rework if at all feasible; 2 - incinerate at an authorized facility; 3 - treat at an acceptable waste treatment facility. Disposal of packaging : dirty containers of product must be recycled or disposed by an authorized facility. : empty containers can retain product residues and may be hazardous: do not use heat, sparks, open flames, or cigarettes on near empty container. 14 Transportation information - ADR/RID/IATA Proper shipping name : Corrosive liquids, n.o.s. ADR Class : 8 - Corrosive substances. Packaging group : II Risk Label(s) : 8 - Corrosive. Subsidiary Risk Label(s) : none. Danger identification number (upper) : 80 CHIMEC S.p.A. Via delle Ande 19 00144 Roma Tel. +39.06.918251 Page 4 \ 5 Trade Name CHIMEC 7268 Substance identification number (lower) : 1760 Tremcard type : C UN Number. : 1760 IMO-IMDG IMO class : 8 - Corrosive substances. Risk Label : 8 - Corrosive. Subsidiary Risk Label : none. Proper shipping name : Corrosive liquids, n.o.s. Contains : alkyl dimethyl benzyl ammonium chloride : organic sulphur derivate Packaging group : II Emergency Schedule (EmS) : F-A, S-B Segregation Group : IMDG Code segregation group - none 15 Regulatory information UE - Symbol(s) : Corrosive:C - Contains : alkyl dimethyl benzyl ammonium chloride : organic sulphur derivate - R Phrase(s) : R 22 :Harmful if swallowed. : R 34 :Causes burns. - S Phrase(s) : S 26 :In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : S 28 :After contact with skin, wash immediately with plenty of soap and water. : S 36/37/39 :Wear suitable protective clothing, gloves and eye/face protection. : S 45: In case of accident or if you feel unwell, seek medical advice immediately (show the label when possible). 16 Other information Further information : R 22 :Harmful if swallowed. : R 23/24/25 :Toxic by inhalation, in contact with skin and if swallowed. : R 34 :Causes burns. : R 43 :May cause sensitization by skin contact. : R 50 :Very toxic to aquatic organisms. Sources of key data used : N.Irving SAX - Dangerous properties of Industrial Materials ( Sixth edition) - Edited by Van Nostrand Reinhold Company - 1984 : TLV - Threshold Limit Values for Chemical Substances in Work Environment - Adopted by ACGIH - 2000 : A.D.R. - European Agreement concerning the international carriage of Dangerous Goods by Road - United Nation Publication : Karel VERSCHUEREN - Handbook of Environmental data on organic chemicals - 1977 Information for medical staff Revised chapters : The chapters indicated by " ********** " have been modified with the present version of this MSDS. ST1 - 721/2 18/08/2003 - 1 The information reported on this MSDS results from our present state of knowledge on safety regulations and is not to be considered as a guarantee of any specific product property. CHIMEC cannot be held responsible for any injury or damage deriving from the improper application of the product. CHIMEC S.p.A. Via delle Ande 19 00144 Roma Tel. +39.06.918251 Page 5 \ 5 Trade Name CHIMEC 7268
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