SAMPLE PAPER-2014

Time-3 hrs CBSE-CLASS-XII m.m -70

Q1. Write the products obtained when phenylethylether is treated with
HI?
Q2. Name the type of potential difference created in hemholtz electrical
double layer.
Q3. Right the IUPAC name of
CH
2
(Cl)CO CH
2
CONH
2
Q4. What type of linkage is present in monomers of DNA?
Q5. Which of the following comp has a lone pair of electron at central
atom?
H
2
S
2
O
7
, H
2
SO
3
, H
2
SO
4
, H
2
S
2
, H
2
S
2
O
8

Q6. Complete the following rk
n
:
CH
3
CH=CH
2
HBr X NaI Y
Peroxide dryacetone
Q7. Iodo form is antiseptic. Give one reason for this support.
Q8. Gabriel phthalimide synthesis is preferred for prep. Of 1
0
amine
how?
Q9. Write the names associated with the following rk
n
.
A) RCONH
2
+ Br
2
+ NaOH R-NH
2
+Na
2
CO
3
+ NaBr+2 H
2
O
B) Ar
+
N
2
X
-
Cu
2
Cl
2
ArCl+N
2



C) R-NH
2
CHCl
3
R-NC + KCl+H
2
O
+ KoH
D) ArN
+
2
Cl

Cu/ HBr Ar-Br+N
2

Q10. KF has CCP st. calculate the radius of unit cell of the side of the
cube or edge length is 400 pm. How many F
-
ions and octahedral voids
are there in this unit cell.
Q11. Give reason:
a) Why is frenkel defect found in AgCl?
b) Gicve the difference between P dopped and Ga dopped semi
conductor.
Q12. Describe the const. Of H
2
-O
2
fuel cell and rk
n
s taking place in it.
Q13. State Raoults law for a solution containing volatile liquids. Explain
with suitable eg. Maximum boiling azeotroe.
Q14. Give chemical rk
n
to support following
a) H
2
SO
4
has low volatility.
b) Iodide ions can be oxidized by oxygen in acidic medium.
Q15. Purpose mehchaminsm of rk
n
?
(-)-2-bromo octane reacts with sodium hydroxide and form (+)- octane -
2-ol.
Q16. What is flux? What is its role in the metallurgy of Fe and Cu?
Q17. The sum of ist and 2
nd
3
rd
and 4
th
I.E of Ni and Pt given below:
I.E
1
+ I.E
2
I.E
3
+I.E
4

Ni 2.49 8.80
Pt 2.66 6.70
a) Which is the most common o.s of Ni and Pt? why.
b) Out of two name the metal which form compounds in +4 state and
why?
Q18. Describe a chemical test to distinguish between
a) Aniline and N-ethylaniline
b) N-methylpropanamine and N-ethyl-N-methyl ethanamine.
Q19. Give reason:
a) Why does alkaline medium inhibit the rustiong of iron?
b) Why does dry cell become dead after long time?
c) Why is Zn is better than Sn in protecting Fe from corrosion?
Q20. Write the rk
n
for
a) Prep. Of PHBV polymer
b) Prep. Of neoprene.
c) Give oone use of nylon-6,6.
Q21.a) Write the zwitter ion st. of para-aminobenzenesulphonic acid.
b)What is invert sugar?
c) Name the Vit. responsible for
I) night blindness
II) poor coagulation of blood.
Q22. Write chemical eq
n
for
a) oxidation of nitrite ion by MnO
4
-
in H
+

b) acidification of potassium chromate solution.
c) Disproportionation of Mn(2+) in acid solution.
Q23. Acc. For the following:
a) Ortho-nitrophenol is more acidic than ortho methoxy phenols.
b) Acohols are easily protonated than phenols.
c) The relative ease of dehydration of alcohols 1
0
< 2
0
<3
0

Q24. On dissolving 19.5g of CH
2
FCOOH in 500g of H
2
O a depression
of 1
0
C in f.Pt is observed. Calculate Vant hoff factor and dissociation
constant.
Q25. Name one comp:
i) A) Which act as antipyretic and analgesic both.
c) Which act as antiseptic and disinfectant both.
Ii) explain: a) broad spectrum antibiotics.
c) Anionic detergent.
Q26. I) H of chemisorptions is higher than physisorption why?
ii) What is colloidion?
iii) Differentiate between peptization and coagulation.
Q27 a) State hybridization and magnetic behaviiour of [Cr(CO)
6
]
b)What are the factors which influence the crystal field splitting
energy?
c)Which is more stable and why.
d) K
4
[Fe (CN)
6
] or K
3
[Fe(CN)
6
]
Q28. A) An orange solid A on heating gives colourless gas B. B in dry
condition is passed over heated Ca to give a solid C. the solid form blue
coloured comp. E in rk
n
with CuSo
4
. Identify all and give eq
n
.
Q29. A comp A having mol. Formula C
2
H
4
O on oxidation gives B
(C
2
H
4
O
2
) A reacts with dill NaoH and on heating form C. C in catalytic
hydrogenation gives D. identify A, B, C, and D and write down the rk
n

involved.
Q30. A) Illustrate graphically the effect of caralyst on activation energy.
c) Catalysts have no effect on eqlb
m
constant. Why?
d) The dec. of A into product has value of K as 4.5x10
3
at 300 K and
Ea is 60KJ. Calculate the temp at which K will be 1.5 x 10
4
.