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F
]
/T
gw
= 30F
/T
gw
= 10F
Chromatograph Repeatability and
Reproducibility
The repeatability and reproducibility of a typical
gas chromatograph is described in the GPA 2261 stan-
dard
12
. The stated values are contained in column 3
of Table 1. The standard does not provide a value for
hydrogen, in the current example the tabulated value
is set equal to the nitrogen value.
Calibration Standard
The chromatograph is calibrated using a gravi-
metric gas standard. The uncertainty (by mass) in a
typical calibration standard is:
U = 1% (u = 0.58%) for components that make
up between 2% and 49% of the mixture
U = 2% (u = 1.16%) for components that make
less than 2% of the mixture
The calibration standard uncertainty values are
contained in column 4 of Table 1. The uncertainty in
the mass of methane (U = 0.25%) is calculated based
on the uncertainties of the other components of the
mixture.
Sensitivity Coefficient
This component accounts for the sensitivity in cal-
culated compressibility to the uncertainty in compo-
sition. In other words, how much uncertainty in cal-
culated compressibility results from the uncertainties
in columns 3 and 4 in Table 1.
The partial derivative in Eq. 4 cannot be deter-
mined by conventional methods because of the com-
plexities in the state equation, a Monte Carlo simula-
tion
13
is used as an alternative. This method is based
on generating multiple unique gas compositions by
randomly varying the mole fraction for each compo-
nent. The standard deviation of a component random
variance is selected to match the combined effect of
the values contained in columns 3 and 4 of Table 1.
The present analysis is based on 2500 simulated
gas compositions. The standard deviation values are
u = 0.19% for Z
f
and u = 0.002% for Z
b
. These val-
ues account for the uncertainties associated with the
chromatograph repeatability and reproducibility and
calibration standard.
t n e n o p m o C n o i t c a r F e l o M [ R d n a R U ] % [ d t S l a C U ] %
e n a h t e M 5 1 0 8 . 0 9 2 . 0 5 2 . 0
e n a h t E 8 8 9 0 . 2 0 . 1 0 . 1
e n a p o r P 0 2 0 0 . 2 0 . 1 0 . 1
e n a t u B - n 3 0 0 9 . 0 0 . 2 0 . 2
e n a t u B - i 1 0 0 9 . 0 0 . 2 0 . 2
e n a t n e P - n 0 0 0 4 . 0 0 . 3 0 . 2
e n a t n e P - i 0 0 0 4 . 0 0 . 3 0 . 2
+ 6 C 0 0 0 2 . 0 0 . 0 1 0 . 2
n e g o r t i N 2 8 9 4 . 1 0 . 2 0 . 2
e d i x o i D n o b r a C 1 9 9 3 . 0 0 . 3 0 . 2
n e g o r d y H 0 0 0 4 . 0 0 . 2 0 . 2
Table 1: Gas Components
VOLUME AT FLOWING CONDITIONS
The volume flow is measured using either a tur-
bine or ultrasonic meter. The uncertainties for using
these meters are specified by the AGA 7
14
and AGA
9
15
standards. For operation at higher flowrates the
uncertainties are 1.0% (u = 0.58%) for the turbine
meter and 0.7% (u = 0.41%) for the ultrasonic
meter. Performance of either meter at lower flowrates
will have higher uncertainties, the low flow condi-
tions are not considered in this example.
REDUCING THE UNCERTAINTY
The uncertainty values for all sixteen components
for turbine meter based measurement are contained
in Table 2. Column 2 shows uncertainty components
expressed as percentages of mean values. Column 3
show the percent contribution to combined uncertainty
made by each component, they are calculated based
on
% 100
2
-
!
!
"
#
$
$
%
&
y
xi
u
u
. The summary in Table 2 is a pow-
erful tool in allocating measurement resources based
on measurement uncertainty. The turbine meter, for
example, is the largest contributor to uncertainty. It
represents the best return on an investment intended
to reduce uncertainty. The ambient temperature ef-
fects, on the other hand, contribute very little uncer-
tainty. The overall uncertainty cannot be reduced by
investing in reduced uncertainty in ambient tempera-
ture effects.
The current example concludes with a hypotheti-
cal calibration of the turbine meter. The calibration
data are contained in Figure 3, the y-axis is percent
shift in K Factor from a nominal values. The data are
well within AGA 7 specifications, the uncertainty can
be reduced as a result. The fitted curve is slightly
nonlinear, the K Factor changes with flowrate. This
will require a more complex flow computer algorithm.
The solid lines in Fig. 3 represent the 95% confidence
interval, 95% of the data are within the interval. The
interval width is 0.2% (u = 0.1%) which accounts
for random effects present during the calibration pro-
cess. The uncertainty of the hypothetical calibration
facility flowrate measurement is 0.25% (u=0.13%)
which accounts for systematic effects associated with
the facility itself. In the current example these two
components make up the uncertainty associated with
the turbine meter measurement. The recalculated un-
certainty is u
Vb
= 0.39%, the details are contained in
Table 3. Having reduced the turbine meter uncer-
tainty, it can be seen that other components now domi-
nate the uncertainty. The gas chromatograph and pres-
sure transducer stability are two examples.
GENERAL DISCUSSION
It is important to emphasize that the analysis pre-
sented above is intended as an example only. Appli-
cable numerical values need to be determined for a
real uncertainty analysis. In addition, several poten-
tial uncertainty components have been neglected in
the interest of simplifying the example. These include,
but are not limited to:
flowmeter installation effects
gas sampling
wet gas
pulsating flow
Considerable analysis was required to estimate
uncertainties of components that ended up contribut-
ing very little uncertainty. Two examples are the heat
transfer and the chromatographic analysis determi-
nation of base compressibility. Unfortunately, the
magnitude of an uncertainty component is unknown
until the analysis is complete.
Figure 3: Turbine Meter Calibration
Data
-0.6
-0.3
0.0
0.3
0.6
20 40 60 80 100
Flowrate [%max]
K
F
a
c
t
o
r
S
h
i
f
t
[
%
]
A number of advanced concepts of uncertainty
analysis are not included in the interest of simplifying
the example. These components can significantly
change the results of an uncertainty analysis, they
cannot be ignored in a real analysis. One concept is
correlated effects
5
where some components of un-
certainty will cancel out if the sensitivity coefficients
are equal but opposite in sign. In some analyses the
presence of correlated components will increase un-
certainty. A valuable tool in advanced uncertainty
analyses is statistical process control
16, 17
. This tool
provides two benefits, it monitors the stability of a
measurement process and identifies sources of ran-
dom effects. Finally, the current example briefly il-
lustrated the turbine meter calibration process. Simi-
lar reductions in uncertainty are possible by imple-
menting calibration processes for the pressure, tem-
perature and gas composition measurements. In gen-
eral calibration replaces a smaller number of Type B
estimates with larger number of Type A estimates.
Calibration generally results in a more complex analy-
sis but lower uncertainty. The complexity arises in
part due to advanced concept of measurement trace-
ability.
REFERENCES
1. ANSI/ASME MFC-2M, Measurement Uncer-
tainty for Fluid Flow in Closed Conduits, Ameri-
can Society of Mechanical Engineers, 1988
2. ANSI/ASME PTC 19.1, Measurement Uncer-
tainty, American Society of Mechanical Engi-
neers, 1990.
3. ISO 5168, Measurement of Fluid Flow - Estima-
tion of Uncertainty of a Flow Rate Measurement,
International Organization for Standardization,
1978
4. Abernethy, R. B. et al, Handbook Uncertainty in
Gas Turbine Measurements, AEDC-TR-73-5,
Arnold Engineering Development Center, 1973
5. ISO Guide to the Expression of Uncertainty in
Measurement, International Organization for
Standardization, 1994
6. Taylor, B. N., and Kuyatt, "Progress Report on
the Implementation of the ISO Guide to the Ex-
pression of Uncertainty in Measurement", Proc.
1994 Meas. Sci. Conf, 1994
7. ANSI/ASME PTC 19.1, Test Uncertainty,
American Society of Mechanical Engineers,
1998.
8. Kegel, Thomas, "Basic Measurement Uncer-
tainty," 74th International School of Hydrocar-
bon Measurement, Tulsa, Oklahoma, May 25-27,
1999.
9. Wadsworth, H. M., Handbook of Statistical Meth-
ods for Engineers and Scientists, McGraw-Hill,
1990.
10. Doebelin, E., O., Measurement Systems: Appli-
cations and Design, McGraw Hill, 1975.
11. Starling, K. E. and Savidge, J. L.,Compressibility
Factors of Natural Gas and Other Related Hy-
drocarbon Gases, Transmission Measurement
Committee Report No. 8, American Gas Asso-
ciation, 1994.
12. GPA 2261 Analysis for Natural Gas and Similar
Gaseous Mixtures by Gas Chromatography, Gas
Processors Association.
13. Basil, M. and Jamieson, A. W., Uncertainty of
Complex Systems by Monte Carlo Simulation,
North Sea Flow Measurement Workshop,
Gleneagles, 26 29, October 1998.
14. ___,Measurement of Fuel Gas by Turbine
Meters, Transmission Measurement Committee
Report No. 7, American Gas Association, 1981.
15. ___,Measurement of Gas by Multipath Ultra-
sonic Meters, Transmission Measurement Com-
mittee Report No. 9, American Gas Association,
1998.
16. Kegel, T. M., "Statistical Control of the Measure-
ment Process," 6th Pipeline Conference, Merida,
Yucatan, Mexico, Nov. 14-16, 2001.
17. Kegel, T. M., "Quality Control Program of the
CEESI Ventura Calibration Facility," FLOMEKO,
Gronigen, The Netherlands, May 2003.
t n e n o p m o C
d r a d n a t S
] % [ y t n i a t r e c n U ] % [ n o i t u b i r t n o C
e r u s s e r P
n o i t a c i f i c e p S e c n a m r o f r e P d e n i b m o C 4 1 1 . 0 0 8 . 2
y t i l i b a t S 4 0 2 . 0 5 9 . 8
t c e f f E e r u t a r e p m e T t n e i b m A 4 4 0 . 0 2 4 . 0
e r u s s e r P c i r t e m o r a B 1 1 0 . 0 3 0 . 0
n o i t i s i u q c A a t a D 3 9 0 . 0 5 8 . 1
e r u t a r e p m e T
n o i t a c i f i c e p S e c n a m r o f r e P d e n i b m o C 9 2 0 . 0 9 1 . 0
y t i l i b a t S 9 2 0 . 0 9 1 . 0
t c e f f E e r u t a r e p m e T t n e i b m A 6 0 0 . 0 1 0 . 0
e b o r P D T R 3 7 0 . 0 3 1 . 1
s t c e f f E r e f s n a r T t a e H 2 0 0 . 0 < 1 0 . 0
n o i t i s i u q c A a t a D 6 1 1 . 0 8 8 . 2
y t i l i b i s s e r p m o C e s a B
n o i t a u q E e t a t S 0 6 0 . 0 7 7 . 0
h p a r g o t a m o r h C 2 0 0 . 0 < 1 0 . 0
y t i l i b i s s e r p m o C g n i w o l F
n o i t a u q E e t a t S 0 6 0 . 0 7 7 . 0
h p a r g o t a m o r h C 0 9 1 . 0 6 7 . 7
e m u l o V g n i w o l F
e u l a V 7 A G A 0 8 5 . 0 7 2 . 2 7
Table 2: First Summary of Uncertainty Components
t n e n o p m o C
d r a d n a t S
] % [ y t n i a t r e c n U ] % [ n o i t u b i r t n o C
e r u s s e r P
n o i t a c i f i c e p S e c n a m r o f r e P d e n i b m o C 4 1 1 . 0 3 4 . 8
y t i l i b a t S 4 0 2 . 0 3 9 . 6 2
t c e f f E e r u t a r e p m e T t n e i b m A 4 4 0 . 0 5 2 . 1
e r u s s e r P c i r t e m o r a B 1 1 0 . 0 8 0 . 0
n o i t i s i u q c A a t a D 3 9 0 . 0 5 5 . 5
e r u t a r e p m e T
n o i t a c i f i c e p S e c n a m r o f r e P d e n i b m o C 9 2 0 . 0 6 5 . 0
y t i l i b a t S 9 2 0 . 0 6 5 . 0
t c e f f E e r u t a r e p m e T t n e i b m A 6 0 0 . 0 2 0 . 0
e b o r P D T R 3 7 0 . 0 0 4 . 3
s t c e f f E r e f s n a r T t a e H 2 0 0 . 0 < 1 0 . 0
n o i t i s i u q c A a t a D 6 1 1 . 0 5 6 . 8
y t i l i b i s s e r p m o C e s a B
n o i t a u q E e t a t S 0 6 0 . 0 3 3 . 2
h p a r g o t a m o r h C 2 0 0 . 0 < 1 0 . 0
y t i l i b i s s e r p m o C g n i w o l F
n o i t a u q E e t a t S 0 6 0 . 0 3 3 . 2
h p a r g o t a m o r h C 0 9 1 . 0 3 3 . 3 2
e m u l o V g n i w o l F
y r o t a r o b a L 5 2 1 . 0 0 1 . 0 1
y t i l i b i c u d o r p e R d n a y t i l i b a t a e p e R 0 0 1 . 0 6 4 . 6
Table 3: Second Summary of Uncertainty Components