TD-4100XD Operator Training

Training Topics
Monitoring Applications
Principles of Operation
Application Sites
TD-4100XD
Components
User Interface
Calibration
Maintenance
Monitoring Application
Storm water Run-off
Bilge Water
Leaks from Heat Exchangers
Oil in Cooling Water
Hydrocarbons in Raw Drinking Water
and Wastewater
Oil in Produced Water
Principles of Operation
Fluorescence
1. Molecules are
excited by the
absorption of light.
2. Relaxation to lower
energy state.
3. Molecules return to
ground state by
emitting
fluorescent light.
M M
Emission

Em
= (E
1
-E
0
)/h
M
M
E
0
E
2
E
1
Excitation

Ex
= (E
2
-E
0
)/h
E
n
e
r
g
y
10
-8
sec
Fluorescence
1. Molecules are
excited by the
absorption of light.
2. Relaxation to lower
energy state.
3. Molecules return to
ground state by
emitting
fluorescent light.
M M
Emission

Em
= (E
1
-E
0
)/h
M
M
E
0
E
2
E
1
Excitation

Ex
= (E
2
-E
0
)/h
E
n
e
r
g
y
10
-8
sec

C I
F
The TD-4100XD
Fluorometer
Lamp
UV & Visible
Light
Excitation
Filter
Excitation Light
specific to sample
Emission
Filter
Sample
Cell
D
Light
Detector
Fluorescent
Light
specific to sample
Fluorescent
Light +
Stray Light
D
Emission
Filter
Excitation Light
specific to sample
The TD-4100XD
Fluorometer
Lamp
UV & Visible
Light
Excitation
Filter
Light
Detector
Fluorescent
Light
specific to sample
Fluorescent
Light +
Stray Light
Closed Loop
Drift Compensation
TD-4100, TD-4100XD
Light Pipe
Chopper
Sample
Cell
Sample
Cell
D
Excitation Light
specific to sample
The TD-4100XD
Fluorometer
Lamp
UV & Visible
Light
Excitation
Filter
Light
Detector
Emission
Filter
Closed Loop
Drift Compensation
TD-4100, TD-4100XD
Light Pipe
Chopper
Fluorescent
Light
specific to sample
Fluorescent
Light +
Stray Light
TD-4100XD Sample Cell
Non-fouling Falling
Stream Design
Water falls through air
to drain.
Water never touches
an optical surface.
Air Curtain
Prevents condensation
on optical windows.
Water temperature
can be up to 212F.
TD-4100XD
On-Line
Hydrocarbon
Monitor
On-Site, On-Line
TD-4100XD
Components
TD-4100XD Components
Air System
Air Curtain
Air Purge
Water Sampling System
Bubble Trap
Auto-valve
Falling Stream Flow Cell
Electronics & Optics
Lamp, Filters & Windows
Signal Processing
User Interface
Analog & Digital Outputs
Bubble Trap
Auto-valve
Air Purge Indicator
Air Curtain Control
Air Purge Control
Electronics
& Optics
Auto-valve Control
TD-4100XD Components
Flow Cell
Air System
Water Sampling System
Electronics & Optics
Air System
Air Purge Indicator
- Cyclops
* Green light purge on
* Remote pressure
indicator dry contact
switch
Air Purge Control
Air Curtain Control
Air Curtain Control
Air Pressure Gauge
Air Flow Meter
Air Pressure Adjust
Air Flow Adjust
Settings
Pressure: 10-20 psi
Flow Rate: 15 scfh
Air Purge (ATEX Zone II, C1D2)
Settings
Pressure: .25 inches
of water or until
green light turns on
Settings
Pressure: 5 psig
max.
Cyclops Air
Purge
Indicator
Air Pressure Adjust
Air Pressure Gauge
Wait 1 hour after
light turns green
before turning
instrument on!
Air Pressure Adjust
Air Pressure Gauge
Water Sampling System
Bubble Trap
Auto-valve
Flow Cell
Auto-valve Control
Bubble Trap
Inlet Valve
Drain Valve
Overflow Observation Port
Gas Vent
Pneumatic Auto-Valve Switch
System (P-AVS)
Auto-valve indicator
Auto-valve actuator
Auto-valve Control
-Open
-Off
-Auto
Falling Stream Flow Cell
Water Inlet
Desiccant Plug
View Port
Drain
Electronics & Optics
Electronics
& Optics
Electronics & Optics
LCD Display
Keypad
Lamp Housing
Lamp ON
Indicator
TD-4100XD (Cabinet Open)
TD-4100XD Alarms
Sample Level Alarms
Zero alarm
Early Warning alarm
High Alarm
System Alarm
Lamp
Chopper RPM
High Voltage
Cause audible BEEP and flashing ALM to
appear on the HOME screen.
Change the state of Relay A or Relay B.
Sample Level Alarms
Warn operators of significant changes in
sample concentration.
Can be monitored or not monitored.
Can be set to user-defined concentrations.
Can be configured with a user-defined delay.
Setting: 0.1 to 999.9 min.
Alarm Settings Relay Affected
Zero Alarm -999.999 to 999.999 Relay A
Early Warning Alarm 0.000 to 999.999 Relay B
High Alarm 0.000 to 999.999 Relay A
System Alarms
Notify operators of instrument malfunctions.
Change the state of Relay A.
System alarms are not affected by the user-
defined alarm delay.
System alarms are always monitored.
Cause Delay Alarm Normal
Lamp 1 min. OFF ON
Chopper RPM 2 min. <500 RPM 588 - 612 RPM
High Voltage 3 min. <25 or >1000 25 - 1000
LCD Display
User
Interface
Keypad
TD-4100XD Keypad
Go to
HOME screen
Back up
one screen
ESC 7 8 9
HOME
Adjust LCD
contrast,
Fine tune
sensitivity,
Enter negative
numbers
*
4 5 6
? 1 2 3
# 0
.
ENT
Clear numeric
entries
Enter values,
Toggle values,
Advance to next screen
User ID
Please input ID:

Please input ID:

8520
8 5 2 0
ENT
Default User ID: 8520
ESC
7 8 9
HOME
*
4 5 6
? 1 2 3
# 0
.
ENT
HOME Screen
Over
>999
10 PPM
CAL 28 DAYS AGO
HOME
During Normal Operation
ALM 15 PPM
CAL 28 DAYS AGO
During Alarm Condition
HiAlm
ESC
Current Alarm
HiAlm
ErlyWrn
No alarm
since last reset
Alarm History
or
* * * * *
Calibration Standard Values
0
12 PPM
CAL 28 DAYS AGO
HOME
0
<1> Hi Std Conc
<2> Low Std Conc
1
Hi Std Conc:
15.000 PPM
Type new value
15.000
New:
ENT
15.000
New: 30.000
(Same procedure for <2>)
ENT
30.000
New:
Concentration Units
1
12 PPM
CAL 28 DAYS AGO
HOME
Conc Units
Display Option
1
Unit Display:
PPM
ENT
Unit Display:
PPB
ENT
ENT
Unit Display:
NO UNIT
Relays A and B
2
12 PPM
CAL 28 DAYS AGO
HOME
1. Relay A: NO
2. Relay B: NC
2
Relay A Ctrl:
NO
Relay A Ctrl:
NC
1 ENT ENT
2
Relay B Ctrl:
NC
Relay B Ctrl:
NO
ENT ENT
Zero Alarm
3
12 PPM
CAL 28 DAYS AGO
HOME
3
ENT
1. Monitor: YES
2. Level: -1.000
1
2
Monitor Alarm:
YES
ENT
Monitor Alarm:
NO
ENT
-1.000
New:
Type new value
ENT
Zero alarm:
YES -1.000 PPM
-1.000
New: 2.000
2.000
New:
Type new value
-1.000
New: -2.000
-1.000
New: 2.000
Early Warning Alarm
4
12 PPM
CAL 28 DAYS AGO
HOME
Early Warning:
YES 50.000 PPM
4
1. Monitor: YES
2. Level: 50.000
ENT
Monitor Alarm:
YES
ENT
Monitor Alarm:
NO
ENT
1
50.000
New: 25.000
50.000
New:
2
Type new value
ENT
25.000
New:
High Alarm
5
12 PPM
CAL 28 DAYS AGO
HOME
High alarm:
YES 100.000 PPM
5
1. Monitor: YES
2. Level: 100.000
ENT
Monitor Alarm:
YES
ENT
Monitor Alarm:
NO
ENT
1
100.000
New: 75.000
100.000
New:
2
Type new value
ENT
75.000
New:
Alarm Delay
6
12 PPM
CAL 28 DAYS AGO
HOME
Alarm delay:
1.0 min
6
ENT
Type new value
ENT
1.0
New:
1.0
New: 5.0
5.0
New:
4 mA Output
7
12 PPM
CAL 28 DAYS AGO
HOME
4 mA output:
0.000 PPM
7
ENT
Type new value
ENT
5.000
New:
0.000
New: 5.000
0.000
New:
20 mA Output
8
12 PPM
CAL 28 DAYS AGO
HOME
20 mA output:
100.000 PPM
8
ENT
Type new value
ENT
50.000
New:
100.000
New: 50.000
100.000
New:
Relay A / Relay B Status
9
12 PPM
CAL 28 DAYS AGO
HOME
Relay A: Open
Relay B: Closed
9
Diagnostic Screens
*
Lamp ON 598 RPM
HV 325 Din: ON
*
Raw: 60.92
FS%: 60
ENT
Test: 1: Relay A
2: Relay B
ENT
ON / OFF
Relay A:
<ENT> to toggle
1
Relay A: ON
<ENT> to toggle
ENT ENT
Relay B:
<ENT> to toggle
2
(Same as for Relay A)
Oper: 986 Hrs
ENT
High Std: 102.8
Low Std: 8.9
ENT
Misc. Screens
Firmware Version Serial Data Output Rate (NA)
12 PPM
CAL 28 DAYS AGO
12 PPM
CAL 28 DAYS AGO
HOME HOME
TURNER DESIGNS
Ver P0-1F 1197
Serial data out:
every 10 sec
?
.
Calibration Change User ID
12 PPM
CAL 28 DAYS AGO
12 PPM
CAL 28 DAYS AGO
HOME HOME
1. Calibration
2. Cal data
Input MASTER ID:
ENT
#
User ID:
8520
ENT
Calibration
Calibration
1. Prepare a High
Concentration Standard
2. Prepare a Low
Concentration Standard.
3. Read fluorescence of
both standards while
flowing them through the
instrument.
4. Enter the concentrations
of both standards.
Calibration Bottles & Valves
Prepare Isopropyl Alcohol (IPA)
Standard
1. Pipette 100 L of oil into a 100 mL
volumetric flask.
2. Fill the flask to the mark with IPA.
3. Tightly cap the flask and shake it
vigorously to dissolve the oil.
a. Ultrasonic bath may be required for viscous oils.
b. Viscous oils may not completely dissolve.
Oil Concentration = 1000 ppm
Standard Solutions
1. Choose a Standard Solution concentration.
Example: 5 ppm
2. Using a graduated cylinder, add IPA
Standard to the 1 gallon Cal Solution bottle.
Add 3.79 mL IPA Standard for each 1 ppm.
Example: Add 18.95 mL IPA Standard to
make a 5 ppm Cal Solution.
3. Fill the Cal Solution bottle to the 1 gallon
mark with Blank water.
4. Tightly cap the bottle and shake it
vigorously.
Calibration Reset
12 PPM
CAL 28 DAYS AGO
HOME
1. Calibration
2. Cal data
ENT
<1> High <2> Low
<3> Reset Cal
1
Reset CAL deflts
Press <*> 5 times
3
* * * * *
ESC
CALIBRATION
reset to default
Calibration High Standard
12 PPM
CAL 28 DAYS AGO
HOME
1. Calibration
2. Cal data
ENT
<1> High <2> Low
<3> Reset Cal
1
ENT
Close inlet valve. Drain bubble trap.
Mount High Std calibration bottle.
Close drain valve. Open Auto-valve.
High Standard
Highest conc!
1
ENT
High Standard:
XXX.X
Open PVC valve.
Wait for readings to stabilize.
Must be <142.
High Standard:
XXX.X WAIT
High Standard:
YYY.Y
*
FINISHED!
Press <ENT>
Calibration Timing Hint
Press when water
level is near bottom of
label.
*
Open PVC valve.
Wait for readings to stabilize.
Readings must be <142
High Standard:
XXX.X
ENT
High Standard:
XXX.X WAIT
FINISHED!
Press <ENT>
*
Calibration Low Standard
12 PPM
CAL 28 DAYS AGO
HOME
1. Calibration
2. Cal data
ENT
<1> High <2> Low
<3> Reset Cal
1
ENT
2
Low Standard
Lower conc!
ENT
Low Standard:
XXX.X
Close inlet valve. Drain bubble trap.
Mount Low Std calibration bottle.
Close drain valve. Open Auto-valve.
Open PVC valve.
Wait for readings to stabilize.
Must be <142 & <High Standard
Low Standard:
XXX.X WAIT
Low Standard:
YYY.Y
*
FINISHED!
Press <ENT>
Calibration Abort
High Standard
Highest conc!
Low Standard
Lower conc!
FROM OR OR Beyond
<1> - Abort Cal
<ESC> - Continue
ESC
<1> High <2> Low
<3> Reset Cal
1
Viewing Calibration Data
12 PPM
CAL 28 DAYS AGO
HOME
1. Calibration
2. Cal data
ENT
High Std: 106.5
Low Std: 3.2
2
Raw Fluorescence
Slope: 0.0484
Inter: -0.1531
ENT Slope & Intercept
Calibration Standard Values
0
12 PPM
CAL 28 DAYS AGO
HOME
0
<1> Hi Std Conc
<2> Low Std Conc
1
Hi Std Conc:
15.000 PPM
Type new value
15.000
New:
ENT
15.000
New: 30.000
Same procedure for
<1> and <2>
ENT
30.000
New:
Concentration Units
1
12 PPM
CAL 28 DAYS AGO
HOME
Conc Units
Display Option
1
Unit Display:
PPM
ENT
Unit Display:
PPB
ENT
ENT
Unit Display:
NO UNIT
CheckPoint
Solid Standard
CheckPoint Solid Standard
CheckPoint Solid Standard Case
CheckPoint & adjustment tools
Inserting the CheckPoint
Remove the screw hole plugs
Adjust and inserting the
CheckPoint
Maintenance
Maintenance
Daily or Weekly
1. Inspect bubble trap overflow
2. Inspect falling stream and optical
windows (as viewed through view
port window).
3. Check air pressure and flow rate
4. Record CheckPoint fluorescence
As Required
1. Clean sample flow cell
2. Clean flex hoses
3. Clean bubble trap assembly
4. Clean drain assembly
5. Adjust air pressure and flow rate
Maintenance
Every 6 Months
1. Change lamp & recalibrate
2. Change desiccant plug
3. Change activated carbon filter
Every 5 Years
1. Change Battery Backup (NVRAM)
I. Record instrument settings
II. Replace NVRAM chip
III. Re-enter settings and
recalibrate Instrument
2023 North Gateway, Suite 101
Fresno, CA 93727 USA
Phone: +1 559 253-1414
FAX: +1 559 253-1090
Service@oilinwatermonitors.com
www.oilinwatermonitors.com