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CHEMISTRY UNIT 2
Key words
Ores
Bauxite
Haematite
Metal
Economical
Extract
Purified
Reduction
Reactivity
Electrolysis
Phytomining
Bioleaching
Displacement
Blast furnace
Alloy
Mixtures
Compounds
Steel
Transition metals
Density
Corrosion
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C1.3.1
Extracting metals
a) Ores contain enough metal to make it economical to extract the metal. The
economics of extraction may change over time.
Two common ores are bauxite (aluminium ore, Al2O3) and haematite (iron ore Fe2O3)
Bauxite
b) Ores are mined and may be concentrated before the metal is extracted and
purified.
c) Unreactive metals such as gold are found in the Earth as the metal itself but most
metals are found as compounds that require chemical reactions to extract the metal.
d) Metals that are less reactive than carbon can be extracted from their oxides by
reduction with carbon.
In simple terms reduction is the removal of oxygen:
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Al2O3
reduction
Al
Fe2O3
reduction
Fe
Iron oxide (haematite) can be reduced with carbon in the blast furnace to make iron
as carbon is more reactive than iron. So carbon is able to reduce iron oxide.
e) Metals that are more reactive than carbon, such as aluminium, are extracted by
electrolysis of molten compounds. The use of large amounts of energy in the
extraction of these metals makes them expensive.
f) Copper can be extracted from copper-rich ores by heating the ores in a furnace
(smelting). The copper can be purified by electrolysis. The supply of copper-rich ores
is limited.
Copper is extracted from its ores by chemical processes that involve heat or
electricity.
Copper-rich ores are being depleted and traditional mining and extraction have
major environmental impacts.
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g) New ways of extracting copper from low grade ores are being researched to limit
the environmental impact of traditional mining.
Copper can also be extracted by phytomining, or by bioleaching:
phytomining uses plants to absorb metal compounds when they grow. The plants
are burned to produce ash that contains the metal compounds. The metals can then
be extracted from the ash.
bioleaching uses bacteria that can live by using the energy of the bond between
sulfur and copper. This separates the metal from the ore.
It has the advantage that it is very energy efficient typically using only 30% to 50 % of
the traditional method. It has the disadvantage that it is very slow.
i) Aluminium and titanium cannot be extracted from their oxides by reduction with
carbon. Current methods of extraction are expensive because:
there are many stages in the processes
large amounts of energy are needed.
j) We should recycle metals because extracting them uses limited resources and is
expensive in terms of energy and effects on the environment
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C1.3.2
Alloys
a) Iron from the blast furnace contains about 96% iron. The impurities make it brittle
and so it has limited uses.
Cast iron is useful because it is strong in compression.
b) Most iron is converted into steels.
Steels are alloys since they are mixtures (not compounds) of iron with carbon.
Some steels contain other metals such as nickel, chromium and tungsten.
Alloys can be designed to have properties for specific uses.
Low-carbon steels are easily shaped, high-carbon steels are hard, and stainless
steels are resistant to corrosion.
Type of steel
Percentage of
carbon
Uses
Mild steel
Up to 0.25%
Medium carbon
steel
0.25% to 0.45%
0.45% to 1.50%
Car parts
Surgical instruments eg
scalpel
c) Most metals in everyday use are alloys. Pure copper, gold, iron and aluminium are
too soft for many uses and so are mixed with small amounts of similar metals to
make them harder for everyday use.
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C1.3.3
a) The elements in the central block of the periodic table are known as transition
metals.
Like other metals they are good conductors of heat and electricity and can be bent or
hammered into shape. They are useful as structural materials and for making things
that must allow heat or electricity to pass through them easily.
b) Copper has properties that make it useful for electrical wiring and plumbing.
Copper:
is a good conductor of electricity and heat
can be bent but is hard enough to be used to make pipes or tanks
it can easily be joined together
does not react with water
it is non-magnetic
it is antibacterial
c) Low density and resistance to corrosion make aluminium and titanium useful
metals.
Aluminium
1) Low density and strength make aluminium ideal for construction of aircraft,
lightweight vehicles, and ladders. An alloy of aluminium called duralumin is
often used instead of pure aluminium because of its improved properties.
2) Easy shaping and corrosion resistance make aluminium a good material
for drink cans and roofing materials.
3) Corrosion resistance and low density leads to its use for greenhouses
and window frames.
4) Good conduction of heat leads to its use for boilers, cookers and
cookware.
5) Good conduction of electricity leads to its use for overhead power cables
hung from pylons (low density gives it an advantage over copper).
6) High reflectivity makes aluminium ideal for mirrors, reflectors and heat
resistant clothing for fire fighting.
Titanium is 60% heavier than aluminium, but it is much stronger. It is nearly half as
light as steel, but it is equally strong.
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1. Metal or non-metal
Place the following in the correct column:
Shiny
Dull
Brittle
Ductile
Good conductor
Poor conductor
Malleable
Sonorous
Metal
Non-metal
Concentrated
..
..
Reducing agent
..
..
3. For each of these state if the metal will reduce the oxide
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5. Metal Y will reduce copper oxide but not iron oxide which possible metals could
it be?
6. Which of the following metals are found in the Earth as an element and not a
compound? Circle the correct answer:
Magnesium
Gold
Copper
Tin
Iron
7. Which of the following metals could not be extracted from its ore with carbon?
Circle the correct answer
Zinc
Tin
Copper
Aluminium
Iron
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11. Give four reasons why copper often used for electrical wiring and for plumbing?
1.
2.
3.
4.
12.
1.
2.
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14. Match the properties of aluminium to its uses. The property can be used more
than once.
Low density
Strength
Cookware
Corrosion resistance
Drink cans
Low density
Ladders
Mirrors
High reflectivity
Window frames
12 |
Gold is often extracted from ores that contain very small percentages of the metal,
but iron is only extracted from ores with a large percentage of the metal. Explain why.
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14 |
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Transition metals
Iron
Aluminium
Titanium
metal: ..
Reason 1
.
Reason 2
.
Car bodies
metal: ..
Reason 1
.
Reason 2
.
3. Artificial hip joint
base
metal: ..
Reason 1
.
Reason 2
.
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Disadvantage
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Economic
Environmental
(a)
(b)
Brass is an alloy.
What is an alloy?
....................................................................................................................................
....................................................................................................................................
(1)
(c)
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(i)
(ii)
(d)
The amount of copper-rich ores is estimated to last only a few more years. New houses
need several kilometres of copper wire.
(i)
Explain why the need to use so much copper will cause a problem in the future.
..........................................................................................................................
..........................................................................................................................
(1)
(ii)
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Q2.
(ii)
(iii)
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(b)
Suggest two reasons why a 2p coin made in 1991 is now worth 3.3p.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
(2)
(Total 5 marks)
Q3.
What is an ore?
....................................................................................................................................
....................................................................................................................................
(2)
(b)
Some metals are obtained by removing oxygen from the metal oxide.
What name do we give to this chemical reaction?
....................................................................................................................................
(1)
(c)
Name one metal which must be extracted from its melted ore by electrolysis rather
than by using carbon.
....................................................................................................................................
(1)
(Total 4 marks)
Q4.
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Q5.
Copper is a widely used metal. The main ore of copper contains copper sulfide. Copper can
be extracted from copper sulfide in a three stage process.
(a)
(ii)
Explain why there would be an environmental problem if the gas from this reaction
were allowed to escape into the atmosphere.
..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
(2)
(b)
(c)
During the third stage the copper can be purified as shown in the diagram.
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(i)
What is the name of the type of process used for this purification?
..........................................................................................................................
(1)
(ii)
(d)
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Q6.
(i)
Give one reason that the company could give for the need to quarry the iron ore.
..........................................................................................................................
..........................................................................................................................
(1)
(ii)
The people who live in the village do not want the quarry because it would decrease
the value of their homes.
Suggest two other reasons why the villagers do not want the quarry.
1 .......................................................................................................................
..........................................................................................................................
2 .......................................................................................................................
..........................................................................................................................
(2)
(b)
(i)
(ii)
(iii)
Pure iron is relatively soft. The iron from the blast furnace is hard and brittle. The
diagram below represents iron from the blast furnace.
Use the diagram to explain why iron from the blast furnace is hard and brittle.
..........................................................................................................................
..........................................................................................................................
..........................................................................................................................
(2)
(Total 8 marks)
Q7.
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(1)
(ii)
Iron can be produced by reacting iron oxide with carbon in a blast furnace.
What type of reaction produces the iron?
...........................................................................................................................
...........................................................................................................................
(1)
(iii)
carbon
iron
carbon dioxide
.....C
................... +
...................
(2)
(b)
Explain the differences in the properties of pure iron and cast iron by referring to the
diagrams.
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
.....................................................................................................................................
..................................................................................................................................... (3)
(c)
The diagram shows the way in which iron is extracted, used and recycled.
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27 |
Q8.
Aluminium has many uses because of its low density, good electrical conductivity, flexibility
and resistance to corrosion.
The main steps in the extraction of aluminium are shown in the flow chart.
(a)
Use the information in the flow chart to suggest the benefits of recycling aluminium.
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
(3)
(b)
Pure aluminium is rarely used for the construction of large objects. Small amounts of other
metals are usually mixed with aluminium.
Explain why.
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
....................................................................................................................................
(2)
(Total 5 marks)
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Q9.
Use the Reactivity Series of Metals on the Data Sheet to help you to answer this question.
The table gives information about the extraction of some metals.
Metal
Date of discovery
Main source
Gold
Known to ancient
civilisations
In the Earth as
the metal itself
Physically separating it
from the rocks it is
mixed with
Zinc
1500
Zinc carbonate
Reduction by carbon
Sodium
1807
Sodium chloride
Electrolysis
(a)
Explain why gold is found mainly as the metal itself in the Earth.
.....................................................................................................................................
.....................................................................................................................................
(1)
(b)
(c)
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Q10.
Iron that is extracted from its oxide by carbon reduction in a blast furnace is called cast
iron. Cast iron contains about 4% carbon. This carbon makes cast iron very brittle.
Carbon steels can be made by the following processes.
Blowing oxygen into molten cast iron to remove most of the carbon.
Adding a calculated amount of carbon.
Sometimes different metals may also be added to the molten carbon steels.
(i)
Suggest how blowing oxygen into molten cast iron removes most of the carbon.
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
........................................................................................................................... (2)
(ii)
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(b)
The percentage of iron and steel recycled in the UK has been increasing.
Year
1998
25
2000
35
2002
42
2004
46
2006
57
The UK government has set targets for the percentage of iron and steel to be recycled.
In 2006 the target was exceeded.
Suggest two reasons why the UK government wants to encourage recycling of iron and
steel.
1 ..................................................................................................................................
.....................................................................................................................................
2 ..................................................................................................................................
.....................................................................................................................................
(2)
(Total 5 marks)
Q11.
Copper is found in the Earths crust as an ore containing copper sulfide. Large areas of
land, where this ore was once quarried, are contaminated with low percentages of copper
sulfide. Copper would be too expensive to extract from this contaminated land using the
traditional method of quarrying and then heating in a furnace.
(a)
It would be too expensive to extract from this land by the traditional method.
Explain why.
...............................................................................................................
...............................................................................................................
(1)
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(ii) Extracting copper from this land by the traditional method would have a major environmental
impact.
Give one reason why.
...............................................................................................................
...............................................................................................................
(1)
(b)
One way to extract the copper from land that contains low percentages of copper sulfide
is by bioleaching. Bioleaching uses bacteria. The bacteria produce a solution of copper
sulfate.
It is possible to get copper from a solution of copper sulfate using scrap iron.
(i)
(ii)
Why can iron be used to get copper from copper sulfate solution?
...............................................................................................................
...............................................................................................................
(1)
(c)
A new way to extract the copper from land that contains low percentages of copper sulfide
is phytomining.
Phytomining uses plants. Plants are grown on this land and absorb copper compounds
through their roots.
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(i)
(ii)
Q12.
(a)
Aluminium
883
8.2
Platinum
16720000
0.0000001
Iron
216
4.1
Gold
8236800
0.0000001
Use information in the table to suggest why gold and platinum are very expensive metals.
.....................................................................................................................................
.....................................................................................................................................
(1)
(b)
Name the element that is removed from the ores when they are reduced.
...........................................................................................................................
(1)
(ii)
33 |
Use the reactivity series on the Data Sheet to suggest a metal that would reduce
aluminium ore.
...........................................................................................................................
(1)
(c)
Aluminium is made by the reduction of molten aluminium ore, using a very large amount
of electricity.
(i)
(ii)
Most metals are extracted from ores, which are mined from the Earths crust.
Q13.
(i)
(ii)
(b)
The chemical equation shows a reaction that occurs when iron is produced.
Fe2 O3 + ..... CO
(i)
Balance the equation above by writing the correct numbers in the spaces in the
equation.
(2)
(ii)
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(c)
(i)
Some metals can not be extracted from their ores by heating with carbon. These
metals are extracted by electrolysis.
Name one metal that is extracted by electrolysis.
.............................................................................................................
(1)
(ii)
Suggest two reasons why metals extracted by electrolysis are often more expensive
than iron.
1. .........................................................................................................
.............................................................................................................
2. .........................................................................................................
.............................................................................................................
(2)
(Total 10 marks)
Q14.
(a)
(b)
Use the diagram to explain what happens to the atoms in the metal of electrode B used
for electroplating during electrolysis.
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......................................................................................................................
......................................................................................................................
......................................................................................................................
......................................................................................................................
......................................................................................................................
......................................................................................................................
......................................................................................................................
......................................................................................................................
(4)
(c)
Use the diagram to explain how the key becomes electroplated with the metal used for
electroplating.
......................................................................................................................
......................................................................................................................
......................................................................................................................
......................................................................................................................
......................................................................................................................
(3)
(Total 9 marks)
Q15.
The diagram shows a circuit that is used in a torch. Electrons flow through this circuit.
(a)
(b)
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(c)
The table shows some properties of the metals used in the electrical circuit.
Metal
Melting point in
C
Boiling point in
C
Copper
1083
2582
Lithium
179
1317
3370
5930
Tungsten
(i)
Use information from the table to suggest the order of reactivity for copper, lithium
and tungsten.
most reactive
..........................................................
..........................................................
least reactive
..........................................................
(2)
(ii)
(d)
37 |
Draw a ring around the correct word in the box to complete the sentence.
dense.
Argon is used in the light bulb because it is
solid.
unreactive.
(1)
(Total 6 marks)
Q16.
Copper is found in the Earths crust as an ore containing copper sulfide. Large areas of
land, where this ore was once quarried, are contaminated with low percentages of copper
sulfide. Copper would be too expensive to extract from this contaminated land using the
traditional method of quarrying and then heating in a furnace.
(a)
Extracting copper from this land by the traditional method would have a major
environmental impact.
Give two reasons why.
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
(2)
(b)
One way to extract the copper from land that contains low percentages of copper sulfide
is by bioleaching. Bioleaching uses bacteria. The bacteria produce a solution of copper
sulfate.
It is possible to get copper from a solution of copper sulfate using scrap iron.
(i)
38 |
(ii)
Q17.
Nearly all zinc is obtained from ores that also contain lead. The metals zinc and lead can
be extracted by reducing their oxides using carbon.
(a)
(b)
The melting points and boiling points of lead and zinc are given in the table.
Metal
Lead
Zinc
Melting point in C
328
420
Boiling point in C
1740
907
11.34
7.14
(i)
(ii)
Suggest how zinc can be separated from the lead in the condenser.
..............................................................................................................
..............................................................................................................
..............................................................................................................
(2)
(Total 5 marks)
Q18.
The hip joint between the femur and pelvis sometimes has to be replaced.
Early hip replacement joints were made from stainless steel.
(a)
Use the particle diagram to complete the percentages of metals in this stainless steel.
40 |
Percentage (%)
Iron, Fe
72
Chromium, Cr
Nickel, Ni
(2)
(b)
(ii)
Suggest why pure iron would not be suitable for a hip replacement joint.
...........................................................................................................................
...........................................................................................................................
(1)
(iii)
Use the particle diagram to help you to explain why stainless steel is harder than
pure iron.
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(2)
(Total 6 marks)
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