TEST 10

CHAPTER 2: CARBON COMPOUNDS

NAME : .

CLASS: .

1. (a) Diagram A shows how compound Q is formed from a type of alcohol.


(i)Name one alcohol that has four carbon atoms. Draw its structural formula.


[2 marks]

(ii)Based on your answer in (a)(i), what is the name of compound P and compound Q?
P:
Q:

[2 marks]

(iii)State three chemical properties of compound P and three chemical properties of
compound Q.
P:


Q:



[6 marks]

(b) Alkenes, alcohols and esters are three different homologous series. Construct a
table to show the general formula, the functional group and the name of a member
in each of the series.















[10 marks]


2. The flow chart below shows a series of reactions of organic compounds.

(a) Suggest possible answers for substances, H, G, J and K.

H:
G:
J:
K:

[2 marks]

(b) Write a chemical equation for the cracking of hydrocarbon H.

[1 mark]

(c) What type of reaction does hydrocarbon G undergo?

[1 mark]

(d) State an observation for the conversion of compound J to compound K using acidified
potassium dichromate(VI).

[1 mark]

(e) State the change in the oxidation state of chromium in the reaction in (d).

[2 marks]

(f) Draw the structural formula of C
6
H
12
O
2
.

[1 mark]

(g) What is a unique property of C
6
H
12
O
2
?

[1 mark]

(h) Compound G undergoes addition polymerisation. Name the polymer formed.

[1 mark]


3. The structure of ethene is as shown below:


(a) (i) What is the molecular formula of ethene?

[1 mark]
(ii) What is the functional group of ethene?

[1 mark]

(b) (i) Write an equation for the complete combustion of ethene.

[1 mark]
(ii) How many moles of carbon dioxide are produced from the complete combustion
of 2 moles of ethene?

[2 marks]
(iii)Calculate the volume of carbon dioxide, measured at room temperature and
pressure, produced from the complete combustion of 5 g of ethene.
Given that the relative atomic mass of H = 1, C = 2 and the molar volume of any
gas is 24dm
3
mol
-1
at room temperature and pressure.

[2 marks]

(c) (i) State two changes that occur when ethene is reacted with hydrogen.


[2 marks]
(ii) Give one industrial application of this reaction.

[1 mark]


4. A reaction scheme is shown below.



(a) In process I, ethene is reacted with steam in the presence of phosphoric acid catalyst.

(i) Name process I.

[1 mark]
(ii) Write an equation for the reaction in process I.

[1 mark]
(iii) Name the product of process I.

[1 mark]


(b) Process II produces a compound Q.

(i) Name compound Q.

[1 mark]
(ii) Under what conditions is compound P changed into compound Q?


[2 marks]


(c) In process III, compound P and compound Q are reacted together to produce
compound R.

(i) Name process III.

[1 mark]
(ii) Draw the structural formula of compound R.







[1 mark]
(iii) Name the catalyst used in process III.

[1 mark]


(d) Process IV produces two products, one of which is compound S. Compound S is a
gas at room conditions and has a molar mass of 44 g mol
-1
.

(i) Name compound S.

[1 mark]
(ii) Write an equation for the reaction in process IV.

[1 mark]




Answers:
1.
(a) (i) Butan-1-ol / Butan-2-ol
CH
3
CH
2
CH
2
CH
2
OH / CH
3
CH
2
CH(OH)CH
3


(ii) P: but-1-ene / but-2-ene
Q: butan-1-ol / butan-2-ol

(iii) P: - undergoes hydrogenation to produce butane
- undergoes hydration to form butanol
- reacts with acidified KMnO
4
to form a diol
Q: - undergoes dehydration to form butene
- reacts with carboxylic acid to form ester
- undergoes oxidation to form carboxylic acid

(b) Homologous
series
General formula Functional group
Name of
member
Alkene C
n
H
2n
C=C ethene
Alcohol C
n
H
2n+1
OH OH ethanol
Ester C
n
H
2n+1
COOC
m
H
2m+1


ethyl ethanoate

2.

(a) H: C
5
H
12

G: C
3
H
6

J: C
3
H
7
OH
K: C
2
H
5
CO
2
H

(b) C
5
H
12
C
2
H
6
+ C
3
H
6


(c) Addition reaction/ hydration

(d) Orange acidified potassium dichromate(VI) turns green.

(e) +6 +3

(f)



(g) It is a liquid with sweet smell.

(h) Polypropene


3.

(a) (i) C
2
H
4

(ii) Carbon-carbon double bond

(b) (i) C
2
H
4
(g) + 3O
2
2CO
2
(g) + 2H
2
O(l)
(ii) From the equation:
1 mole of C
2
H
4
produces 2 moles of CO
2
.
2 moles of C
2
H
4
produce 2 2 = 4 moles of CO
2
.
(iii) Number of moles of C
2
H
4

mass
=
molar mass
5 g
=
28 g mol
-1

= 0.1786 mol
1 mole of C
2
H
4
produces 2 moles of CO
2
.
Number of moles of CO
2
produced
= 0.1786 2
= 0.3572 mol
Volume of CO
2

= number of moles molar volume
= 0.3572 mol 24 dm
3
mol
-1

= 8.5728 dm
3


(c) (i) Ethene changes into a saturated hydrocarbon ethane
Its molar mass increases by 2 units.
(ii) Industrial manufacture of margarine


4.

(a) (i) Hydration
(ii) C
2
H
4
(g) + H
2
O(g) C
2
H
5
OH(l)
(iii) Ethanol

(b) (i) Ethanoic acid
(ii) Add acidified potassium manganate(VII) solution to compound P. Then, heat the
mixture under reflux.

(c) (i) Esterification
(ii)

(iii) Concentrated sulphuric acid

(d) (i) Carbon dioxide
(ii) C
2
H
5
OH(l) + 3O
2
(g) 2CO
2
(g) + 3H
2
O(l)