Solution-For-Wb-Jee-2012 Phy - Chem (Page 21 - 35)

Q. 1 Q.
30 carry one mark each

1. In a mercury thermometer the ice point (lower fixed point) is marked as 10
o
and the steam point (upper fixed point) is
marked as 130
o
. At 40
o
C temperature, what will this thermometer read?
(A) 78
o
(B) 66
o
(C) 62
o
(D) 58
o
Ans : (D)
Hints :
40 0 T 10
100 0 130 10
T = 58
o
2. The magnetic flux linked with a coil satisfies the relation = 4t
2
+ 6t + 9 Wb, where t is the time in second. The e.m.f.
induced in the coil at t = 2 second is
(A) 22 V (B) 18 V (C) 16 V (D) 40 V
Ans : (A)
Hints :
d
| | 8t 6
dt
at t = 2 s. | | = 22 V
3. Water is flowing through a very narrow tube. The velocity of water below which the flow remains a streamline flow is
known as
(A) Relative velocity (B) Terminal velocity (C) Critical velocity (D) Particle velocity
Ans : (C)
4. If the velocity of light in vacuum is 3 10
8
ms
1
, the time taken (in nanosecond) to travel through a glass of thickness
10 cm and refractive index 1.5 is
(A) 0.5 (B) 1.0 (C) 2.0 (D) 3.0
Ans : (A)
Hints :
8
8 o
C 3 10
C 2 10 m/ s
1.5
2
8
d 10 10
t
c 2 10
= 0.5 ns
5. A charge +q is placed at the orgin O of X Y axes as shown in the figure. The work done in taking a charge Q from
A to B along the straight line AB is
(A)
0
qQ a b
4 ab
(B)
0
qQ b a
4 ab
(C) 2
0
qQ b 1
4 b a
(D) 2
0
qQ a 1
4 b b
Ans : (A)
Hints : B A
0
Qq 1 1
W Q V V
4 b a
=
0
qQ a b
4 ab
Code -
WBJEE - 2012 (Answers & Hints) Physics & Chemistry
akash nslllula - Regd. Office: Aakash Tower, Plot No.-4, Sector-11, Dwarka, New Delhi-110075 Ph.: 011-47623456 Fax : 011-47623472
(1)
ANSWERS & HINTS
for
WBJEE - 2012
SUB : PHYSICS & CHEMISTRY
(2)
6. What current will flow through 2 k resistor in the circuit shown in the figure?
(A) 3 mA (B) 6 mA (C) 12 mA (D) 36 mA
Ans : (A)
Hints : R
eq
6 3
6 8k
6 3
,
3
3
V 72
I 9 10 A
R 8 10
,
3
1
1
I I 3 10 A
3
, I
1
= current through 2 k
7. In a region, the intensity of an electric field is given by

E 2i 3j k in NC
1
. The electric flux through a surface
S 10i m
2
in the region is
(A) 5 Nm
2
C
1
(B) 10 Nm
2
C
1
(C) 15 Nm
2
C
1
(D) 20 Nm
2
C
1
Ans : (D)
Hints :
e
E.S = 20 Nm
2
C
1
8. A train approaching a railway platform with a speed of 20 ms
1
starts blowing the whistle. Speed of sound in air is 340
ms
1
. If the frequency of the emitted sound from the whistle is 640 Hz, the frequency of sound to a person standing on
the platform will appear to be
(A) 600 Hz (B) 640 Hz (C) 680 Hz (D) 720 Hz
Ans : (C)
Hints : a 0
s
V 340
n .n 640 680Hz
V V 320
9. A straight wire of length 2 m carries a current of 10 A. If this wire is placed in a uniform magnetic field of 0.15 T making
an angle of 45
o
with the magnetic field, the applied force on the wire will be
(A) 1.5 N (B) 3 N (C)
3 2
N (D)
3
2
N
Ans : (D)
Hints :
o
3
F i l B i lBsin 10 2 0.15 sin45 .N
2
10. What is the phase difference between two simple harmonic motions represented by 1
x Asin t
6
and x
2
= A
cos ( t)?
(A)
6
(B)
3
(C)
2
(D)
2
3
Ans : (B)
Hints : 1 2
X Asin t , X Asin t
6 2
2 1
t t
2 6
=
3
11. Heat is produced at a rate given by H in a resistor when it is connected across a supply of voltage V. If now the
resistance of the resistor is doubled and the supply voltage is made V/3 then the rate of production of heat in the
resistor will be
(A) H/18 (B) H/9 (C) 6H (D) 18H
Ans : (A)
Hints :
2
2 2
V
V 1 V H
3
H ,H .
R 2R 18 R 18
(3)
12. Two elements A and B with atomic numbers Z
A
and Z
B
are used to produce characteristic xrays with frequencies
A
and
B
respectively. If Z
A
: Z
B
= 1 : 2, then
A

B
will be
(A) 1 :
2
(B) 1 : 8 (C) 4 : 1 (D) 1 : 4
Ans : (D)
Hints : a(z b) , Ignoring screening effect (i.e. b=0),
2
A A
A B
Z 1
Z 4
13. The de Broglie wavelength of an electron moving with a velocity c/2 (c = velocity of light in vacuum) is equal to the
wavelength of a photon. The ratio of the kinetic energies of electron and photon is
(A) 1 : 4 (B) 1 : 2 (C) 1 : 1 (D) 2 : 1
Ans : (A)
Hints :
2
2
e
1 c 1
K m mc
2 2 8
,
e
e
h h 2h
c
p mc
m
2
n
e p
k
p
=K.E. of photon
2
hc mc
p 2
e
p
k 1
k 4
14. Two infinite parallel metal planes, contain electric charges with charge densities + and respectively and they are
separated by a small distance in air. If the permittivity of air is
0
then the magnitude of the field between the two
planes with its direction will be
(A) /
0
towards the positively charged plane (B) /
0
towards the negatively charged plane
(C) /(2
0
) towards the positively charged plane (D) 0 and towards any direction
Ans : (B)
15. A box of mass 2 kg is placed on the roof of a car. The box would remain stationary until the car attains a maximum
acceleration. Coefficient of static friction between the box and the roof of the car is 0.2 and g = 10 ms
2
.
This maximum acceleration of the car, for the box to remain stationary, is
(A) 8 ms
2
(B) 6 ms
2
(C) 4 ms
2
(D) 2 ms
2
Ans : (D)
Hints : a
max
= g =0.2 10 = 2 m/s
2
16. The dimension of angular momentum is
(A) M
0
L
1
T
1
(B) M
1
L
2
T
2
(C) M
1
L
2
T
1
(D) M
2
L
1
T
2
Ans : (C)
Hints : [L]= [m r v] = [M
1
L
2
T
1
]
17. if
A B C
and A,B,C have scalar magnitudes of 5, 4 , 3 units respectivley then the angle between A and C is
(A) cos
1
(3/5)
(B) cos
1
(4/5)
(C) /2
(D) sin
1
(3/4)
Ans : (A)
Hints :
1
3
3
Cos ; Cos
5
5
18. A particle is travelling along a straight line OX. The distance x (in meters) of the particle from O at a time t is given by
x = 37 + 27 t t
3
where t is time in seconds. The distance of the particle from O when it comes to rest is
(A) 81 m (B) 91 m (C) 101 m (D) 111 m
Ans : (B)
Hints :
2
dx
v 27 3t 0
dt
, t = 3 sec. x = 37 + 27 3 3
3
, = 37 + 81 27 = 91 m
(4)
19. A particle is projected from the ground with kinetic energy E at an angle of 60
0
with the horizontal. Its kinetic energy
at the highest point of its motion will be
(A)
E / 2
(B) E / 2 (C) E / 4 (D) E / 8
Ans : (C)
Hints :
2 o 2 2
i f
1 1 1 1 E
K E mu ,K E m(ucos60 ) mu
2 2 2 4 4
20. A bullet on penetrating 30 cm into its target loses its velocity by 50%. What additional distance will it penetrate into
the target before it comes to rest?
(A) 30 cm (B) 20 cm (C) 10 cm (D) 5 cm
Ans : (C)
Hints :
2
2 2
2 2
V V V
V 2a(0.3)..........(1), 0 2as a ..............(2)
2 4 8s
From (1) and (2) s = 10 m
21. When a spring is stretched by 10 cm, the potential energy stored is E. When the spring is stretched by 10 cm more,
the potential energy stored in the spring becomes
(A) 2 E (B) 4 E (C) 6 E (D) 10 E
Ans : (B)
Hints :
2
0 0
1
E kx , x 10cm
2
2
1
E kx
2
, x = 10 + 10= 20 cm = 2 x
0
2
0
1
k(2x ) 4E
2
22. Average distance of the earth from the Sun is L
1
. If one year of the Earth = D days, one year of another planet whose
average distance from the Sun is L
2
will be
(A)
1
2
2
1
L
D
L
days (B)
3
2
2
1
L
D
L
days (C)
2
3
2
1
L
D
L
days (D)
2
1
L
D
L
days
Ans : (B)
Hints :
3 3
2 2
2 3 2 2 2
2
1 1 1
T L L
T L D D
T L L
23. A spherical ball A of mass 4 kg, moving along a straight line strikes another spherical ball B of mass 1 kg at rest.
After the collision, A and B move with velocities v
1
ms
1
and v
2
ms
1
respectively making angles of 30
o
and 60
o
with
respect to the original direction of motion of A. The ratio
1
2
v
v
will be
(A)
3
4
(B)
4
3
(C)
1
3
(D)
3
Ans : (A)
Hints : Apply conservation of momentum along Normal
m
1
V
1
sin 30
o
= m
2
V
2
sin 60
o
1
2
V 3
V 4
24. The decimal number equivalent ot a binary number 1011001 is
(A) 13 (B) 17 (C) 89 (D) 178
Ans : (C)
Hints : (1011001)
2
= 1 2
6
+ 0 2
5
+1 2
4
+ 1 2
3
+ 0 2
2
+ 0 2
1
+ 1 2
0
= 64 + 16 + 8 + 1 =89
(5)
25. The frequency of the first overtone of a closed pipe of length l
1
is equal to that of the first overtone of an open pipe of
length l
2
. The ratio of their lenghts (l
1
: l
2
) is
(A) 2 : 3 (B) 4 : 5 (C) 3 : 5 (D) 3 : 4
Ans : (D)
Hints :
1
1 2 2
l 3 2v 3
.v
4l 2l l 4
26. The I V characteristics of a metal wire at two different temperatures (T
1
and T
2
) are given in the adjoining figure. Here,
we can conclude that
(A) T
1
> T
2
(B) T
1
< T
2
(C) T
1
= T
2
(D) T
1
= 2T
2
Ans : (B)
Hints :
I 1
V R
= slope of curve,
R T
greater the slope smaller will be temperature. T
1
< T
2
.
27. In a slide calipers, (m + 1) number of vernier divisions is equal to m number of smallest main scale divisions. If d unit
is the magnitude of the smallest main scale division, then the magnitude of the vernier constant is
(A) d/(m+1) unit (B) d/m unit (C) md/(m+1) unit (D) (m+1)d/m unit
Ans : (A)
Hints :
m d
L.C 1 d
m 1 m 1
28. From the top of a tower, 80 m high from the ground, a stone is thrown in the horizontal direction with a velocity of 8
ms
1
. The stone reaches the ground after a time t and falls at a distance of d from the foot of the tower. Assuming
g = 10 ms
2
, the time t and distance d are given respectively by
(A) 6 s, 64 m (B) 6 s, 48 m (C) 4 s, 32 m (D) 4 s, 16 m
Ans : (C)
Hints : time of flight (t) =
2h 2 80
4s x 8 4 32m
g 10
29. A Wheatstone bridge has the resistances 10 , 10 , 10 and 30 in its four arms. What resistance joined in parallel
to the 30 resistance will bring it to the balanced condition?
(A) 2 (B) 5 (C) 10 (D) 15
Ans : (D)
Hints : for a balanced bridge. R = 10 ,
30 x
10 30x 300 10x 20x 300, x 15
30 x
30. An electric bulb marked as 50 W200 V is connected across a 100 V supply. The present power of the bulb is
(A) 37.5 W (B) 25 W (C) 12.5 W (D) 10 W
Ans : (C)
Hints : P
actual consume
=
2
2
s
r
r
V 100 50
P 50 12.5W
V 200 4
(6)
Q. 31 - Q. 40 carry two marks each
31. A magnetic needle is placed in a uniform magnetic field and is aligned with the field. The needle is now rotated by an
angle of 60
0
and the work done is W. The torque on the magnetic needle at this poition is
(A)
2 3
W (B)
3
W (C)
3
2
W (D)
3
4
W
Ans : (B)
Hints :
o
MB
W MB(1 cos ) MB(1 cos60 )
2
,
o
MB
MBsin MBsin60 3 3W
2
32. In the adjoining figure the potential difference between X and Y is 60 V. The potential difference between the points M
and N will be
(A) 10 V (B) 15 V (C) 20 V (D) 30 V
Ans : (D)
Hints :
eq net MN
1
90C
C C
3
C C 3 , q 90C V 30V
2 2 C
33. A body when fully immersed in a liquid of specific gravity 1.2 weighs 44 gwt. The same body when fully immersed in
water weighs 50 gwt. The mass of the body is
(A) 36 g (B) 48 g (C) 64 g (D) 80 g
Ans : (D)
Hints : mg vg = 44, = density of liquid, mg 1.2 vg = 44 ..............(1), = density of water
mg vg = 50.............(2), (1) 1.2 (2) M = 80 g
34. When a certain metal surface is illuminated with light of frequency , the stopping potential for photoelectric current
is V
0
. When the same surface is illuminated by light of frequency
2
, the stopping potential is
0
V
4
. The threshold
frequency for photoelectric emission is
(A)
6
(B)
3
(C)
2
3
(D)
4
3
Ans : (B)
Hints : e V
0
= h
0
.........(1),
0
eV
4
h
2
0
.........(2), solving equation (1) and (2) ,
0
3
35. Three blocks of mass 4 kg, 2 kg, 1 kg respectively are in contact on a frictionless table as shown in the figure. If a
force of 14 N is applied on the 4 kg block, the contact force between the 4 kg block, the contact force between the 4
kg and the 2 kg block will be
(A) 2 N (B) 6 N (C) 8 N (D) 14 N
Ans : (B)
Hints :
2 net
net
F 14
a 2m/ s R 3 2 6N
m 7
(7)
36. Let L be the length and d be the diameter of cross section of a wire. Wires of the same material with different L and
d are subjected to the same tension along the length of the wire. In which of the following cases, the extension of wire
will be the maximum?
(A) L = 200 cm, d = 0.5 mm (B) L = 300 cm, d = 1.0 mm
(C) L = 50 cm, d = 0.05 mm (D) L = 100 cm, d = 0.2 mm
Ans : (C)
Hints :
TL L
L L
AY A
37. An object placed in front of a concave mirror at a distance of x cm from the pole gives a 3 times magnified real image.
If it is moved to a distance of (x + 5) cm, the magnification of the image becomes 2. The focal length of the mirror is
(A) 15 cm (B) 20 cm (C) 25 cm (D) 30 cm
Ans : (D)
Hints :
1
uf ( x)( f) 4
v ,v 3x x f.........(1)
u f x f 3
,
2
(x 5)( f )
v , 2x 10 3f
x 5 f
.............(2)
so f = 30 cm
38. 22320 cal of heat is supplied to 100 g of ice at 0
o
C. If the latent heat of fusion of ice is 80 cal g
1
and latent heat of
vaporization of water is 540 cal g
1
, the final amount of water thus obtained and its temperature respectively are
(A) 8g, 100
o
C (B) 100 g, 90
o
C (C) 92g, 100
o
C (D) 82g, 100
o
C
Ans : (C)
Hints : total energy required to melt and boil at 100
o
C is
(Q)
min
= 8000 + 10000 = 18000 cal, (Q
required
)
min
< Q
given
for amount of vapour 22320=18000+m 540
m = 8 gm. temperature = 100
o
C and water remaining = 92 gm.
39. A progressive wave moving along xaxis is represented by
2
y Asin t x
. The wavelength ( ) at which the
maximum particle velocity is 3 times the wave velocity is
(A) A / 3 (B) 2A / (3 ) (C) (3/4) A (D) (2/3) A
Ans : (D)
Hints :
2 2
A 3 A
3
40. Two radioactive substances A and B have decay constant 5 and respectively. At t = 0, they have the same number
of nuclei the ratio of number of nuclei of A to that of B will be (1/e)
2
after a time interval of
(A)
1
(B)
1
2
(C)
1
3
(D)
1
4
Ans : (B)
Hints :
5 t
1
t 2
2
N e 1 1
, t
N 2 e e
Q. 41 - Q. 70 carry one mark each
41. Li occupies higher position in the electrochemical series of metals as compared to Cu since
(A) the standard reduction potential of Li
+
/Li is lower than that of Cu
2+
/Cu
(B) the standard reduction potential of Cu
2+
/Cu is lower than that of Li
+
/Li
(C) the standard oxidation potential of Li/Li
+
is lower than that of Cu/Cu
2+
(D) Li is smaller in size as compared to Cu
Ans : (A)
Hints : E
Li
+
/Li
= 3.04V ; E
Cu
2+
/Cu
= 0.34V
(8)
42.
11
Na
24
is radioactive and it decays to
(A)
9
F
20
and -particles (B)
13
Al
24
and positron (C)
11
Na
23
and neutron (D)
12
Mg
24
and -particles
Ans : (D)
Hints :
24
24 0
12
11 1
Na Mg e
(n/p = 1.18) (n/p=1)
43. The paramagnetic behavior of B
2
is due to the presence of
(A) 2 unpaired electrons in
b
MO (B) 2 unpaired electrons in MO
(C) 2 unpaired electrons in MO (D) 2 unpaired electrons in
b
MO
Ans : (A)
Hints :
_
2 *2 2 *2
2 1s 1s 2s 2s
B (10 e)
44. A 100 ml 0.1 (M) solution of ammonium acetate is diluted by adding 100 ml of water. The pH of the resulting solution
will be (pK
a
of acetic acid is nearly equal to pK
b
of NH
4
OH)
(A) 4.9 (B) 5.0 (C) 7.0 (D) 10.0
Ans : (C)
Hints : Hydrolysis of a salt of weak acid and weak base
pH = 7 + (pK
a
pK
b
) = 7
a b
[ pK pK ]
45. In 2-butene, which one of the following statements is true ?
(A) C
1
-C
2
bond is a sp
3
- sp
3
-bond (B) C
2
-C
3
bond is a sp
3
- sp
2
-bond
(C) C
1
-C
2
bond is a sp
3
- sp
2
-bond (D) C
1
-C
2
bond is a sp
2
- sp
2
-bond
Ans : (C)
Hints :
But-2-ene
46. The well known compounds, (+)- lactic acid and () lactic acid have the same molecular formula, C
3
H
6
O
3
. The correct
relationship between them is
(A) constitutional isomerism (B) geometrical isomerism (C) identicalness (D) optical isomerism
Ans : (D)
Hints :
They are enantiomers and correct relationship between them is optical isomerism.
47. The stability of Me
2
C=CH
2
is more than that of MeCH
2
CH = CH
2
due to
(A) inductive effect of the Me group (B) resonance effect of the Me group
(C) hyperconjugative effect of the Me group (D) resonance as well as inductive effect of the Me group
Ans : (C)
Hints : Me
2
C = CH
2
is more stable than MeCH
2
CH = CH
2
due to hyperconjugative effect.
(6 number of H) (2 number of H)
(9)
48. Which one of the following characteristics belongs to an electrophile ?
(A) It is any species having electron deficiency, which reacts at an electron rich C-centre
(B) It is any species having electron enrichment that reacts at an electron deficient C-centre
(C) It is cationic in nature
(D) It is anionic in nature
Ans : (A)
Hints : Fact
49. Which one of the following methods is used to prepare Me
3
COEt with a good yield?
(A) Mixing EtONa with Me
3
CCl
(B) Mixing Me
3
CONa with EtCl
(C) Heating a mixture of (1:1) EtOH and Me
3
COH in presence of conc. H
2
SO
4
(D) Treatment of Me
3
COH with EtMgl
Ans : (B)
Hints :
3
+
3
3
+ CH
3
CH
2
Cl N
S 2
3 2 3
3
3
Williamsons synthesis (S
N
2) given by 1 alkyl halide.
50. 58.5 gm of NaCl and 180 gm of glucose were separately dissolved in 1000 ml of water. Identify the correct statement
regarding the elevation of boiling point (b.p.) of the resulting solutions.
(A) NaCl solution will show higher elevation of b.p.
(B) Glucose solution will show higher elevation of b.p.
(C) Both the solutions will show equal elevation of b.p.
(D) The b.p. elevation will be shown by neither of the solutions
Ans : (A)
Hints : For NaCl (i = 2) for glucose (i = 1),
Hence NaCl solution will show higher elevation of bp (Colligative property) as both are one Molar Solution.
51. Equal weights of CH
4
and H
2
are mixed in an empty container at 25
o
C. The fraction of the total pressure exerted by H
2
is
(A) 1/9 (B) 1/2 (C) 8/9 (D) 16/17
Ans : (C)
Hints : Let equal weights be w g.
mole fraction of
2
w / 2
H
w / 2 w / 16 9
Partial pressure = mole fraction Total pressure
2
H
8
p
9
Total Pressure
52. Which of the following will show a negative deviation from Raoults law?
(A) Acetone-benzene (B) Acetone-ethanol
(C) Benzene-methanol (D) Acetone-chloroform
Ans : (D)
Hints : Acetone chloroform due to formation of intermolecular Hydrogen bonding
(10)
53. In a reversible chemical reaction at equilibrium, if the concentration of any one of the reactants is doubled, then the
equilibrium constant will
(A) also be doubled (B) behalved
(C) remain the same (D) become one-fourth
Ans : (C)
Hints : Equilibrium constant does not depend on conc. It is only a function of temperature
54. Identify the correct statement from the following in a chemical reaction.
(A) The entropy always increases
(B) The change in entropy along with suitable change in enthalpy decides the fate of a reaction
(C) The enthalpy always decreases
(D) Both the enthalpy and the entropy remain constant
Ans : (B)
Hints : Spontaneity of a reaction is decided by a combined effect of suitable change in values of enthalpy and
entropy. [ G = H T S]
55. Which one of the following is wrong about molecularity of a reaction?
(A) It may be whole number or fractional
(B) It is calculated from reaction mechanism
(C) It is the number of molecules of the reactants taking part in a single step chemical reaction
(D) It is always equal to the order of elementary reaction
Ans : (A)
Hints : Molecularity can never be a fraction.
56. Which of the following does not represent the mathematical expression for the Heisenberg uncertainty principle?
(A) x. p h/(4 ) (B) x. v h/(4 m) (C) E. t h/(4 ) (D) E. x h/(4 )
Ans : (D)
Hints : Fact.
57. The stable bivalency of Pb and trivalency of Bi is
(A) due to d contraction in Pb and Bi
(B) due to relativistic contraction of the 6s orbitals of Pb and Bi, leading to inert pair effect
(C) due to screening effect
(D) due to attainment of noble liquid configuration
Ans : (B)
Hints : Lower oxidation state becomes more stable for group 14 and group 15 elements as we move down the group
due to inert pair effect. Hence Pb
+2
and Bi
+3
are more stable.
58. The equivalent weight of K
2
Cr
2
O
7
in acidic medium is expressed in terms of its molecular weight (M) as
(A) M/3 (B) M/4 (C) M/6 (D) M/7
Ans : (C)
Hints : Cr
2
O
7
2
+ 14H
+
+ 6e
2Cr
+3
+ 7H
2
O
Number of electrons gained by one ion = 6
Eq.wt
M
6
59. Which of the following is correct ?
(A) radius of Ca
2+
< Cl
-
< S
2-
(B) radius of Cl
-
< S
2-
< Ca
2+
(C) radius of S
2-
= Cl
-
= Ca
2+
(D) radius of S
2-
< Cl
-
< Ca
2+
Ans : (A)
Hints : Ca
+2
, S
2
, Cl
are isoelectronic (consist of 18e
) and for isoelectronic species, ionic radii

e
z
(11)
60. CO is practically non-polar since
(A) the -electron drift from C to O is almost nullified by the -electron drift from O to C
(B) the -electron drift from O to C is almost nullified by the -electron drift from C to O
(C) the bond moment is low
(D) there is a triple bond between C and O
Ans : (A)
Hints : Factual
61. The number of acidic protons in H
3
PO
3
are
(A) 0 (B) 1 (C) 2 (D) 3
Ans : (C)
Hints : Number of OH group is 2 hence dibasic in nature.
62. When H
2
O
2
is shaken with an acidified solution of K
2
Cr
2
O
7
in presence of ether, the ethereal layer turns blue due to
the formation of
(A) Cr
2
O
3
(B) CrO
4
2-
(C) Cr
2
(SO
4
)
3
(D) CrO
5
Ans : (D)
Hints : K
2
Cr
2
O
7
+ H
2
SO
4
+ 4H
2
O
2
ether
2CrO
s
+ K
2
SO
4
+ 5H
2
O
(Blue)
63. The state of hybridization of the central atom and the number of lone pairs over the central atom in POCl
3
are
(A) sp, 0 (B) sp
2
, 0 (C) sp
3
, 0 (D) dsp
2
, 1
Ans : (C)
Hints : Number of lone pairs on P atom = 0
64. Upon treatment with l
2
and aqueous NaOH, which of the following compounds will form iodoform?
(A) CH
3
CH
2
CH
2
CH
2
CHO (B) CH
3
CH
2
COCH
2
CH
3
(C) CH
3
CH
2
CH
2
CH
2
CH
2
OH ( D) CH
3
CH
2
CH
2
CH(OH)CH
3
Ans : (D)
Hints : Iodoform reaction is given by all alcohols having .
65. Upon treatment with Al(OEt)
3
followed by usual reactions (work up), CH
3
CHO will produce
(A) only CH
3
COOCH
2
CH
3
(B) a mixture of CH
3
COOH and EtOH
(C) only CH
3
COOH (D) only EtOH
Ans : (A)
Hints : 3
Al(OEt)
CH COCH CH
O
This reaction is known as Tischenko reaction
(12)
66. Friedel-Crafts reaction using MeCl and anhydrous AlCl
3
will take place most efficiently with
(A) Benzene (B) Nitrobenzene (C) Acetophenone (D) Toluene
Ans : (D)
Hints : As CH
3
group in toluene activates the benzene ring for electrophilic substitution reaction.
67. Which one of the following properties is exhibited by phenol?
(A) It is soluble in aq. NaOH and evolves CO
2
with aq. NaHCO
3
(B) It is soluble in aq. NaOH and does not evolve CO
2
with aq. NaHCO
3
(C) It is not soluble in aq. NaOH but evolves CO
2
with aq. NaHCO
3
(D) It is insoluble in aq. NaOH and does not evolve CO
2
with aq. NaHCO
3
Ans : (B)
Hints :
+
+
2
(Soluble in aqueous NaOH)
Phenol is less acidic than H
2
CO
3
. So it cannot liberate CO
2
from NaHCO
3
(aq).
68. The basicity of aniline is weaker in comparison to that of methyl amine due to
(A) hyperconjugative effect of Me-group in MeNH
2
(B) resonance effect of phenyl group in aniline
(C) lower molecular weight of methyl amine as compared to that of aniline
(D) resonance effect of NH
2
group in MeNH
2
Ans : (B)
Hints :
2
2
+
Here delocalisation of lone pair of nitrogen.
2 3
No delocalisation of lone pair
69. Under identical conditions, the S
N
1 reaction will occur most efficiently with
(A) tert-butyl chloride (B) 1-chlorobutane
(C) 2-methyl-1-chloropropane (D) 2-chlorobutane
Ans : (A)
Hints : Reactivity order for S
N
1 reaction in case of alkyl halide is 3> 2> 1
70. Identify the method by which Me
3
CCO
2
H can be prepared
(A) Treating 1 mol of MeCOMe with 2 moles of MeMgl (B) Treating 1 mol of MeCO
2
Me with 3 moles of MeMgl
(C) Treating 1 mol of MeCHO with 3 moles of MeMgl (D) Treating 1 mol of dry ice with 1 mol of Me
3
CMgl
Ans : (D)
Hints : Reaction
+ +
(13)
Q. 71 to Q. 80 carry two marks each.
71. 20 ml 0.1 (N) acetic acid is mixed with 10 ml 0.1 (N) solution of NaOH. The pH of the resulting solution is (pK
a
of acetic
acid is 4.74)
(A) 3.74 (B) 4.74 (C) 5.74 (D) 6.74
Ans : (B)
Hints : CH
3
COOH + NaOH CH
3
COONa + H
2
O
Initial 20 ml 0.1N 10ml 0.1N 0 meq
= 2 meq = 1 meq
Final 1 meq 0 meq 1 meq
Mixed solution behaves as acidic buffer
a
[Salt]
pH pK log
[Acid]
= 4.74 + log
1
1
= 4.74
72. In the brown ring complex [Fe(H
2
O)
5
(NO)]SO
4
, nitric oxide behaves as
(A) NO
+
(B) neutral NO molecule (C) NO
(D) NO
2
Ans : (A)
Hints : NO ligand when attached to Fe behaves as positively charged ligand.
73. The most contributing tautomeric enol form of MeCOCH
2
CO
2
Et is
(A) CH
2
= C(OH)CH
2
CO
2
Et (B) MeC(OH) = CHCO
2
Et
(C) MeCOCH = C(OH)OEt (D) CH
2
= C(OH)CH = C(OH) OEt
Ans : (B)
Hints :
74. By passing excess Cl
2
(g) in boiling toluene, which one of the following compounds is exclusively formed?
(A) (B) (C)
3
(D)
3
Ans : (D)
Hints :
Free Radical
benzylic substitution
(14)
75. An equimolar mixture of toluene and chlorobenzene is treated with a mixture of conc. H
2
SO
4
and conc. HNO
3
.
Indicate the correct statement from the following
(A) p-nitrotoluene is formed in excess
(B) equimolar amounts of p-nitrotoluene and p-nitrochlorobenzene are formed
(C) p-nitrochlorobenzene is formed in excess
(D) m-nitrochlorobenzene is formed in excess
Ans : (A)
Hints :
CH
3
is activating group due to +I effect and hyperconjugation.
But for Cl, I > + R effect.
CH
3
is weakly activating and Cl is weakly deactivating
76. Among the following carbocations : Ph
2
C
+
CH
2
Me(I), PhCH
2
CH
2
CH
+
Ph (II), Ph
2
CHCH
+
Me (III) and Ph
2
C(Me)CH
2
+
(IV),
the order of stability is
(A) IV > II > I > III (B) I > II > III > IV (C) II > I > IV > III (D) I > IV > III > II
Ans : (B)
Hints :
Number of resonating structures decide stability in I and II.
77. Which of the following is correct?
(A) Evaporation of water causes an increase in disorder of the system
(B) Melting of ice causes a decrease in randomness of the system
(C) Condensation of steam causes an increase in disorder of the system
(D) There is practically no change in the randomness of the system when water is evaporated
Ans : (A)
Hints : Evaparation increases randomness as liquid water is converted to water vapours.
78. On passing C Ampere of current for time t sec through 1 litre of 2 (M) CuSO
4
solution (atomic weight of Cu = 63.5),
the amount m of Cu (in gm) deposited on cathode will be
(A) m = Ct / (63.5 96500) (B) m = Ct/ (31.25 96500)
(C) m = (C 96500) / (31.25 t) (D) m = (31.25 C t) / 96500
Ans : (D)
Hints : 1000 ml 2(M) CuSO
4
2(M) CuSO
4
solution contains 2 moles Cu
+2
Cu
2
+ 2e Cu
2F 63.5g q = c t coulomb
or, 2 96500C
63.5 31.25 Ct
m Ct g
2 96500 96500
(15)
79. If the 1
st
ionization energy of H atom is 13.6 eV, then the 2
nd
ionization energy of He atom is
(A) 27.2 eV (B) 40.8 eV (C) 54.4 eV (D) 108.8 eV
Ans : (C)
Hints :
H
2
13.6
E
n
1
H
E 13.6eV
1
He
E
2
2
z
13.6
n
2
2
13.6
1
= 54.4eV
The 2
nd
IE = E
1
He
E = 0 (54.4) eV = 54.4 eV
80. The weight of oxalic acid that will be required to prepare a 1000 ml (N/20) solution is
(A) 126/100 gm (B) 63 / 40 gm (C) 63 / 20 gm (D) 126 / 20 gm
Ans : (C)
Hints : M.wt. of H
2
C
2
O
4
. 2H
2
O is 126 (n.factor = 2) , E.wt =
126
2
= 63
no. of gm equivalent
N
volume of solution in L
1 w / 63 63
w gm
20 1 20

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Q. 1 Q.

30 carry one mark each

are isoelectronic (consist of 18e

) and for isoelectronic species, ionic radii

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