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Information about the Haber Process, the effects of temperature, pressure and concentration on equilibrium, yield and rate of reaction. Info on catalyst as well
Information about the Haber Process, the effects of temperature, pressure and concentration on equilibrium, yield and rate of reaction. Info on catalyst as well
Information about the Haber Process, the effects of temperature, pressure and concentration on equilibrium, yield and rate of reaction. Info on catalyst as well
Observations: Increasing the temperature increased the pressure exerted by the molecules, as indicated by the increase in the number shown by the Pressure Indicator. As temperature increases and enters the reaction vessel, thermal energy is converted into kinetic energy, making the molecules move faster, and increasing the number of collisions. Thus, the rate of reaction also increases. This in turn increases the pressure. Conversely, decreasing the temperature lowered the pressure as the molecules moved slower, and less collision were induced. Thus, the rate of reaction decreases. However, once the reaction reaches equilibrium at higher temperatures, less ammonia is produced as in the reaction with lower temperatures. This is due to the nature of the equilibrium system of the reaction. As it is exothermic, an increase in temperature will cause the system to favour the reverse reaction, decreasing the yield of ammonia. Conversely, a decrease in temperature will cause the system to favour the forward reaction, increasing the yield of ammonia. Therefore, a balance between high temperatures, which will increase the rate of reaction, and cooler temperatures, which will increase the yield of ammonia, has to be reached to maximise production of ammonia.
Exp. 5: The Best Conditions for Ammonia Production - 1 A high pressure is maintained through the addition of N 2 and H 2 reactants to replace the extracted ammonia. Increasing the pressure increased the rate of ammonia production, while decreasing the pressure decreased the rate of ammonia production.
Exp. 6: The Best Conditions for Ammonia Production - 2 High pressure needs to be maintained to make sure the yield of ammonia does not decrease. As the pressure decreases, two things happen: the rate of reaction of particles decreases, and the system will favour the reverse reaction. Both these things decrease the yield of ammonia. Generally, increasing the temperature increased the rate of ammonia production, while decreasing the temperature decreased the rate of ammonia production. However, once the temperature reaches 580 degrees Celsius, the production of ammonia units per hour remains constant. This result conflicts with the results in Exp. 4, due to the fact that Exp. 6 is an open system. This means that the ammonia is already extracted from the reaction vessel before the reverse reaction can occur as in Exp. 4, due to high temperatures. Therefore, in Exp. 6, the rate of ammonia production does not decrease as the temperature increases, due to the open system.
Exp. 7: The Conditions for Economic Ammonia Production - 3 We discovered that the most economical way to produce ammonia was to increase pressure and decrease temperature, as this would produce more ammonia, at a lower cost. Having high temperatures like 580 degrees Celsius increased the production costs, and lowered the production of ammonia.
The Prediction of Mineral Solubilities in Natural Waters: A Chemical Equilibrium Model For The Na-Ca-CI-S04-H20 System, To High Temperature and Concentration