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Calibration table
Water
(mL)
Methanol
(mL)
Mol water
(g/mol)
Mol
methanol
(g/mol)
Total mol
(g/mol)
Methanol
(mol
fraction)
Methanol
(wt %)
Refractive
index
10
0.556
0.000
0.556
0.000
0.00
1.333
9
8
1
2
0.500
0.444
0.025
0.049
0.525
0.493
0.047
0.100
4.60
9.90
1.334
1.337
0.389
0.074
0.463
0.160
16.0
1.339
6
5
4
4
5
6
0.333
0.278
0.222
0.099
0.123
0.148
0.432
0.401
0.370
0.229
0.307
0.400
22.92
30.70
40.0
1.341
1.343
1.342
0.167
0.173
0.339
0.509
50.9
1.434
2
1
0
8
9
10
0.111
0.056
0.000
0.198
0.222
0.245
0.309
0.277
0.247
0.641
0.799
1.000
64.10
79.90
100.00
1.340
1.336
1.329
Component
Water
Methanol
3
0.1
3
0.3
3
0.5
3
1.0
3
2.0
3
3.0
1
2.0
1
3.0
1
5.0
Temperature (C)
Vapour
Liquid
91.8
96.7
87.2
92.2
86.7
88.3
81.4
85.8
77.0
82.6
75.6
78.9
71.0
75.6
68.1
70.2
66.3
67.8
GRAPH
Graph of RI vs Mol Fraction
1.44
Refractive Index
1.42
1.4
1.38
1.36
1.34
1.32
0
0.2
0.4
0.6
0.8
1.2
Mol Fraction
0.025
0.02
0.015
0.01
0.005
0
0
0.005
0.01
0.015
0.02
0.025
0.03
0.035
Temperature (C)
100
80
60
Vapor
40
Liquid
20
0
0
0.005
0.01
0.015
0.02
0.025
0.03
0.035
CALCULATION.
Sample calculation of methanol mol fraction from calibration table.
Water
: 2mL
Methanol : 8mL
Mole of water :
Mole of methanol :
Therefore,
0.047
. P A
can be
Therefore,
Antoines Constant:
Temperature
(C)
80.5- 293.63
15.1-103.83
80-210
5.15853
1569.613
-34.846
5.20409
1581.341
-33.50
5.31301
1676.569
-21.728
Reference
Ambrose,
Sprake, et al.,
1975
Ambrose and
Sprake, 1970
Hirata and
Suda, 1967
= 0.02762
When T = 87.2 C (360.2 K)
= 0.02367
When T = 86.7 C (359.8 K)
{
= 0.02334
When T = 81.4 C (354.4 K)
{
= 0.01934
When T = 77.0 C (350 K)
{
= 0.016521
= 0.01569
When T = 71.0 C (344 K)
{
= 0.01322
When T = 68.1 C (341.1 K)
{
= 0.01184
When T = 66.3 C (339.3)
{
= 0.01105
=0.03242
=0.02799
When T = 88.3 C (361.3 K)
{
=0.02456
When T = 85.8 C (358.8 K)
{
=0.02255
When T = 82.6 C (355.6 K)
{
=0.02018
=0.017695
When T = 75.6 C (348.6 K)
{
=0.015698
When T = 70.2C (343.2 K)
{
=0.01283
When T = 67.8 C (340.8 K)
{
=0.01171