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PREPARATION, CHARACTERIZATION AND TESTING OF COCONUT OIL BASED HYBRID FUELS
1.2 IMPORTANCE
The importance of this study is reflected in the recent move by the government of the Fiji
Islands to introduce biofuels in Fiji. This is being implemented through the Technical
Working Group (TWG) in biofuel energy development programme (Department of
Energy – Fiji), and the National Biofuels Energy Dialogue.
The recent increase in world oil prices, and Pacific Nations increasing concern over their
energy security coupled with the growing awareness of the environmental problems
associated with the use of petroleum fuels, has led to the renewed interest on biomass-
based fuels. The motivations for using these fuels are twofold, its environmental benefits
and its impact on the economy. These fuels are non-toxic, renewable sources of energy,
which do not contribute to the net global carbon dioxide build-up. For a country that
heavily relies on imported petroleum oils for its energy needs, but that has an abundant
supply of alternative energy source (in particular coconut), the use of coconut oil will
certainly have a positive impact on the country’s economy in terms of foreign reserves
savings. Their use could also revitalize the rural economies, since a growing demand for
coconut oil will result in increased production in such area. With such incentives, the
need for further research based on locally available resources is both real and significant.
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PREPARATION, CHARACTERIZATION AND TESTING OF COCONUT OIL BASED HYBRID FUELS
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PREPARATION, CHARACTERIZATION AND TESTING OF COCONUT OIL BASED HYBRID FUELS
to burn it has to vaporise to some extent and this is dependant on the viscosity. The
viscosity of an oil is related to the number of carbon atoms in a molecule. As the number
[14]
of carbon atoms increases, it gets progressively oilier, waxier and finally solid . For a
good fuel, the viscosity should be low, which would translate into a more volatile fuel.
The saponification value (SV) is the measure of the average length of carbon chains. The
higher the SV, the lower the average carbon chains. Oils with shorter carbon lengths
readily auto-ignite on injection into the combustion chamber reducing the extent of
ignition lag. The iodine value (IV) is the measure of the unsaturated bonds in the
[19]
hydrocarbon chain . The higher the IV, the higher the potential for the oil to form
gums, coke and varnishes. This is a damaging characteristic of vegetable oils if it were to
[20]
be used in a CI engine . It can lead to build up on the injectors, gumming up piston
[21]
rings, glazing cylinder walls and formation of coke. Previous investigators who
carried out experiments on crude palm oil having an IV of 54 have reported valve
sticking as the main cause of engine performance degradation. The cetane number (CN)
is a measure of the combustion quality of diesel fuel during compression ignition. Cetane
number is actually a measure of a fuel's ignition delay; the time period between the start
[22]
of injection and start of combustion (ignition) of the fuel . The higher the CN, the
lower the self-ignition temperature. Fuels having higher CN are suited for CI engines.
CNO has an order of 60-70 CN, which is higher than petroleum diesel and other common
vegetable oils.
CNO has low IV, high SV and high CN. This makes CNO the most suitable alternative
vegetable oil fuel for diesel engines [5, 7, 8]. The only drawback in terms of fuel properties
is the high viscosity, which this research aims to overcome using the blending and the
microemulsification techniques.
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PREPARATION, CHARACTERIZATION AND TESTING OF COCONUT OIL BASED HYBRID FUELS
The vegetable oils may be blended to reduce the viscosity with diesel and/or ethanol in
presence of some additives to improve the properties of diesel as well as vegetable oil
with ethanol. The blends of conventional diesel fuel with vegetable oils have also been
called hybrid fuels and microemulsion-based fuels are sometimes also termed “hybrid
fuel”.
1.5 OBJECTIVES
This study is to investigate the technical feasibility and potential for hybrid fuels,
prepared using the microemulsification technique, as an alternative to petroleum diesel in
compression ignition engines by:
a) blending coconut oil (CNO) with ethanol and determining the limit of stability of
the blend at room temperature.
b) using the microemulsification technique to prepare CNO based hybrid fuel
c) determining the relevant fuel properties such as the viscosity, energy content,
density, saponification value, iodine value, cetane number and the melting point.
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PREPARATION, CHARACTERIZATION AND TESTING OF COCONUT OIL BASED HYBRID FUELS
d) Testing the engine performance using the blend and hybrid fuel to find the
efficiency using the various test fuels.
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PREPARATION, CHARACTERIZATION AND TESTING OF COCONUT OIL BASED HYBRID FUELS
1.9 REFERENCE
[1] Peterson, C.L., 1983. Winter rape oil fuel for diesel engines, Journal of American
Oil Chemists Society, Vol.60, No. 8, pp 1579-1587.
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diesel engine fueled with palm oil diesel, Journal of American Oil Chemists
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[3] Ryan, T.W., 1984. Effects of vegetable oil properties on injection and combustion
in two different diesel engines, Journal of American Oil Chemists Society, Vol.61,
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[4] Etherington, Dan, M., and David, H., 1995. Coconut oil as Fuel: Final Report,
Phase IIA. Australian and Pacific Science Foundation.
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Department of Chemical Engineering, H. B. Technological Institute, Kanpur,
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PREPARATION, CHARACTERIZATION AND TESTING OF COCONUT OIL BASED HYBRID FUELS
[9] Reddy, M.C.S., 2006, Hybrid Fuel-Fuel of the Future, Advances in Energy
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[10] Solly, R., 1982. Coconut oil and coconut-ethanol derivatives as a fuel for diesel
engines. University of the South Pacific, Fiji.
[11] Cruz, I.E., 1977. Alternative Fuels for Internal Combustion Engines, National
Research Council of the Philippines.
[12] Galloway, D.J., and Ward, J.F., Comprehensive testing of modern compression
ignition engines in extended operation on vegetable oil, Natural Philosophy
Research Report No. 64, James Cook University of North Queensland.
[13] Roberts, J., 1996. Environmental Impacts of using Coconut Oil as Fuel in the
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H., 2001, The effect of coconut oil and diesel fuel blends on diesel engine
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PREPARATION, CHARACTERIZATION AND TESTING OF COCONUT OIL BASED HYBRID FUELS
[18] Diaz, R.S, Coconut for Clean Air, Asian Institute of Petroleum Studies
Incorporation, Manila, Philippines.
[19] Kopial, T., Pumwa. J., and Turlom, S., “Effects of reducing coconut oil viscosity
on engine performance” (2004), PNG University of Technology, Lae, Papua New
Guinea
[20] Etherington, D., Mahendrarajah, S., and Kennedy, O., ‘Biofuel energy from
Coconut for the South Pacific Economies: Technology, Economics and
Institutions’, New and Alternative Energy Symposium, 3rd Pacific Science
Congress, Sydney 5-9th July 1999.
[21] Yu, C.W., Bari, S., and Lim, T.H., ‘The Effects of Prolonged Use of Vegetable
Oils on Different Engine Parts and Performance’, Proceedings of 4th International
Conference on Mechanical Engineering, Department of Mechanical Engineering,
Bangladesh University of Engineering and Technology, Vol.1, pp 1, 26-28th
December 2001.
[22] http://en.wikipedia.org/wiki/Cetane_number
{Accessed on 10th December 2007]
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oil/alcohol microemulsion fuel, Journal of American Oil Chemists Society, 1984,
61 (10),1627-1632.
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PREPARATION, CHARACTERIZATION AND TESTING OF COCONUT OIL BASED HYBRID FUELS
[25] Neuma de Castro Dantas T., A.C.da Silva and A.A.D.Neto, 2001, New
microemulsion systems using diesel and vegetable oils, Fuel, 80, 75-81.
[26] Ziejewski M., K.R.Kaufman, A.W.Schwab and E.H.Pryde, 1884, Diesel engine
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American Oil Chemists Society, 61(10), 1620-1626.
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