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A Combustion File downloaded from the IFRF Online Combustion Handbook
ISSN 1607-9116
Combustion File No:
248
Version No:
Date:
13-10-2003
Author(s):
Barrie Jenkins
Source(s):
Author
Sub-editor:
Barrie Jenkins
Referee(s):
Marc Vansnick
Status:
Published
Sponsor:
1. Background
In a shaft kiln there are three zones in which distinct operations involving heat transfer
take place. They are:
The quality of the lime is most influenced by the conditions in the calcination zone.
Here, heat must be supplied at a temperature above the calcination temperature; which
consequently results in a sufficiency of heat in the combustion gases and dissociated
carbon dioxide to adequately heat the stone in the preheating zone. Unless the
required product is a hard burnt lime, or dead burnt lime, the rate of heating in the
calcination zone must be carefully controlled to ensure that there are no 'hot spots' or
cool channels. Most of the design variations of shaft kilns are attempts to address this
aspect of the kiln performance.
Single shaft
2.
3.
Annular
4.
Inclined
The following pages give brief descriptions of typical kilns of each type, and a summary
table of their operating characteristics is given at the end of this file.
West kilns
Waste Gas
170C
8-9m
Submerged
Take-off 370C
20% of
Waste Gas
4-5m
1200-1300C
Oil Vapour
5 burners
5m
Primary Air
Secondary Air
Fi
2 1 S h of iWest
f WKiln Kil
Fig 1 Schematic
zone, where it meets the cooling zone air and some recycled flue gas. An original
schematic is shown in Fig 1. The original oil-firing concept was later abandoned for
simple rotating oil injection onto the stone bed, and they have also been successfully
operated using natural gas as the fuel.
Esjornsson
This kiln is of Swedish design in which the preheating zone is hexagonal, tapering into a
rectangular burning zone of approximately 3.0m by 1.2m, and then opening out into a
square cooling/discharge zone. A separate gasification unit is used to provide the heat
to the calcining zone. Water sprays cool the gasified fuel before being injected into the
calcining zone at two levels.
Azbe
There are a large number of Azbe kilns in the USA, and other parts of the world, and
there are a number of variations as the technology has developed. Typically, these kilns
are of curved rectangular cross section, with a multiple level refractory burner beam
for fuel, air and flue gases at the base of the burning zone on the longer kiln axis.
Westofen
Waste Gas
13m
4m 80-100C
Throttle
6 burners
Oil
150C
2:1 air:waste
gas ratio
Throttle
Primary Air @3bar
Secondary Air
Chisaki Koma
This kiln design of Japanese origin is
based on fixed bed preheater
Maerz
Combustion
and cooling
air compressor
Cimprogetti
The Cim-Reversy kiln operates in a similar manner to the Maerz kiln, but is formed from
two D shaped chambers, flat sides adjacent, which gives a very short gas transfer duct,
thus reducing the propensity for dust settling and deposition. These kilns have also
been designed for small stone operation.
Voest-Alpine
The Valec kiln is a double shaft design using cylindrical shafts in the same manner as the
Maerz design.
5. Annular Kilns
Primary air
Hot air
waste
gas
Heat
Exchanger
Recycled
Waste Gas
Upper
burners (5)
Fuel
Lower
Burners (5)
Beckenbach
Most of the kiln shaft has an annular crosssection with five gasified fuel entry ports at
each of two levels in the kiln, and staggered so
as to deflect the charge as it falls in the
outer annular space. Some of the waste gases
go up the central cylinder space together with
air from the cooling zone, and this can be
deflected back to the lower burners and thus
regulate the temperature.
Fig 5 Double cylinder annular kiln
6. Inclined Kilns
There are two types of inclined kilns, which have been developed to cater for small
stone.
Double Incline
3m
Stone and
Coke
Oil or Gas
2 or more burners
1200 - 1300C
9m
Oil or Gas
7m
Combustion air
IAF Multi-Chamber
The IAF multi-chamber kiln was first built in 1972, and an improved design was
introduced in 1987. The kiln is basically rectangular in cross-section, but is stepped into
a number (4 to 6) of combustion chambers through the burning zone, which allows a
degree of control of combustion conditions to suit the burning requirements of the
stone.
Rate of
Output
Feed
Size
Fuels
Mixed feed
West
Esjornsson
Fercalx (UC)
Azbe
Westofen
SIC CBK
SIC HPK
Chisaki
10 - 300
30-170
50-100
40-800
50-150
100
40-80
15-125
30-100
30 - 150
60-130
100-150
80-350
60-200
30-120
40-150
25-120
5-40
C.W
G.O.C
G.GF
G.O.C
G.GF
O
G
G.O.C
G.O.C
1-5
0.5 - 3
1.35
2
1-3
n/d
n/d
1-2
1-3
Maerz
Standard
Maerz Finelime
100-800
25-200
G.O.C
100-300
10-30
Cimprogetti
100-400
Voest Alpine
TPD
Shaft
Shaft
Shaft
Shaft
Shaft
Shaft
Shaft
Shaft
Top
Shaped
Shaft
Double
Shaft
Double
Shaft
Double
Shaft
Double
Shaft
Double
Shaft
Annular
Double
Incline
Multichamber
mm
Lime
Reactivity
Quality
CaCO3%
Capital
Cost
Running
Cost
Product
Control
Energy
Usage
Energy
Usage
Low
Variable
n/d
High
High
n/d
n/d
High
Variable
Relative
Basis
Low
Low
Low
Medium
Low
n/d
Low
Medium
Medium
Relative
Basis
Low
High
High
Medium
High
n/d
High
High
Medium
Relative
basis
Medium
Medium
n/d
n/d
Poor
n/d
Medium
Medium
n/d
MJ/kg
lime (fuel)
4.0 6.0
4.2 5.0
5.4
5.5
4.2 5.0
4.2 5.0
4.4
4.4
4.6 5.2
kWh/t
(power)
5-15
25
30
30
10 - 15
25
20
20
40
1-2
High
High
Low
Good
3.6 4.2
25 - 40
1-2
High
High
Low
Medium
3.6 4.2
35 - 45
25-125
G.O.C
1.8
High
High
Low
Good
3.8 4.2
22
up to 300
10-150
n/d
1-2
High
High
Low
Good
3.8 4.2
25 - 35
SIC
150-400
20-120
G.O.C
n/d
n/d
High
Low
Good
3.6 4.2
25 - 35
Beckenbach
Beckenbach
80-850
120
10-250
10-60
G.O.GF
G.O
0.5 - 2
0.6
High
n/d
High
Medium
Low
Medium
Good
n/d
4.0 4.6
4,000
18 - 35
20 - 30
IAF
40-225
20-150
G.O.C
0.3 - 1
Medium
Medium
High
n/d
4,200
20 - 45
Glossary terms
Anthracite - The highest rank coal characterised by low volatile matter - always less
than 10% - and high carbon content it has a semi-metallic lustre and is capable of
burning, relatively easily, without smoke see also Semi-anthracite.
Burner beam A water cooled or refractory conduit passing horizontally across a shaft
kiln through which air and/or fuel is injected into the bed of material. There are usually
multiple injection ports in each beam
Calcination -The heating of a substance so that a physical, or chemical change occurs. In
the case of limestone this refers to the dissociation of calcium and magnesium
carbonates
Calorific value - The quantity of energy released as heat when a unit of fuel is
completely combusted
Carburetor A chamber in which liquid fuel and air are premixed prior to ignition
Dead burnt lime Sintered quicklime, which does not slake readily under normal
conditions
Finelime Manufactures trade name for shaft kiln designed to process small (10-30mm)
limestone lumps
Flash vaporize To evaporate fuel oil by spraying on to a hot surface
Hard burnt lime Lime that has been sintered as a result of over-burning at a high
temperature
Lime A general term for the various forms of calcium oxide and/or hydroxide with
lesser amount of magnesium oxide and/or hydroxide
Lime Reactivity A measure of the rate at which quicklime reacts with water. The
terms very high, high, moderate, medium and low are used as broad classifications.
These can be related to a variety of standard tests
Limestone - Sedimentary rock composed mainly of calcium carbonate derived from the
shells and skeletons of marine micro-organisms.
Metallurgical coke - A dark porous solid fuel, mainly carbon, formed as a pyrolysis or
carbonisation product of coal, produced either as by-product of Town Gas production or
as the main product of Coke Ovens metallurgical or hard coke. Optimum Coke
properties depend upon the end-use which include presently, the main energy supply and
ore reducing agent in blast furnaces, and in former times a domestic and industrial
smokeless fuel and a basic fuel for gas producers
Quicklime Consists mainly of calcium oxide and magnesium oxide, which, when
incorporated into a mortar mix slowly hardens in air by reaction with atmospheric carbon
dioxide
Shaft kiln Generic name for a vertical, refractory lined furnace in which a gravity
driven packed bed of material is processed
Stoichiometric - In a combustion system, the fuel and comburent supply ratio necessary
to burn completely, all the hydrocarbons and other combustible species present in a fuel
Keywords
Minerals; processing; lime; shaft; kiln; calcination; limestone;
Sources
[1] Oates J A H, Lime and Limestone, Chemistry and Technology, Production and Uses,
Wiley-VCH, 1998, ISNB 3-527-29527-5
[2] Boynton R S, Chemistry and Technology of Lime and Limestone, John Wiley & Sons,
1980, ISBN 0-471-02771-5
[3] Wingate M, Small Scale Lime Burning, Intermediate Technology Publications, 1985,
ISBN 0-946688-01-X
Acknowledgements
None
File Placing
[Minerals processing]; [Lime]; [Processes and equipment]
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[Open Domain]
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