Documente Academic
Documente Profesional
Documente Cultură
Inorganic Chemistry Third Ed. Gary L. Miessler, Donald A. Tarr, 2004, Pearson Prentice Hall
http://en.wikipedia.org/wiki/Expedia
Sandwich compounds
Cluster compounds
Staggered rings
Eclipsed rings
Skew rings
superscript
Bridging ligand -
Subscript indicating the number of metal atoms bridged.
Strong donor
ability of CO
Strong acceptor
ability of CO
Good for 18electron rule
metal-to-ligand bonding
or back-bonding
-Increase stability
-Low-spin configuration
-Result of transfer of
negative charge away from
the metal ion
Ligand-to metal bonding
-decrease stability
-high-spin configuration
16 electron complexes
might be stable
Square-planar
complexes have
important catalytic
behavior
More detail
analysis is
necessary
2. Reductive carbonylations
Distance of H-H
the metal is electron rich and donate
strongly to the * of H2 ???
with CO and NO ???