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Regulated substance
Classification of the
pure substance
S phrases
Classification of the
25% C R34-37
substance according to
10-25% Xi R36/37/38
its concentration (in %)
Concentration range in
< 10%
the preparation
Substances with the R33 phrase (if 1%) or the R64 phrase (if 1%) or sensitising substances (if 0.1%): NO.
OTHER SUBSTANCES WITH WORKPLACE EXPOSURE LIMITS: NO.
OTHER INFORMATION: contains also not classified salts.
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As the product is used at ambient temperature during a short time, the values below are generally not reached. They
depend on the treatment time, the surface area treated and on the quality of the workshop air extraction.
EXPOSURE LIMIT VALUES IN AIR
France: decision of 26
October 2007
Directives 91/322/EC,
2000/39/EC, 2006/15/EC
PERSONAL PROTECTION
Provide a shower, a powerful tap and sink unit and an eye basin near the workplace.
Respiratory protection: during brush electrolysis, provide as far as possible an inhaling of the sprays / vapours where
they are created and extraction out of the premises. If insufficient, work in a ventilated room and wear a filtering
FFP3 mask (EN 149:2001 standard) or a B2P3 cartridge (EN 405:2002 standard).
Hand protection: wear gloves (in latex, nitrile or neoprene).
Eye protection: wear glasses with lateral protections or a facial screen. Do not wear contact lenses.
Skin protection: wear overalls and safety boots.
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9 - PHYSICAL AND CHEMICAL PROPERTIES
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Codes: 10005, DPR 5075, Safety Data Sheet, document code: FDS 10005
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12 - ECOLOGICAL INFORMATION
There are no ecological data on the preparation.
Prevent any material from entering drains or waterways or earth.
In general, a pH lower than 5 is fatal.
ECOTOXICITY
Bibliographic data concerning hydrochloric acid:
FISHES - LC50 (24 h) = 369 mg/L, DAPHNIAS - EC50 (24 h) = 213 mg/L, ALGAE - LC50 (120 h) = 25.5 mg/L.
Immediate ionization in aquatic environment.
Harmful for the aquatic organisms because of the acidic pH.
MOBILITY - PERSISTENCE AND DEGRADABILITY - BIOACCUMULATIVE POTENTIAL OTHER ADVERSE
EFFECTS
High mobility and persistence under ionic state. The involved substances are not bioaccumulative.
According to the applicable EC directives, it is not appropriate to apply theN symbol DANGEROUS FOR THE
ENVIRONMENT to this preparation.
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13 - DISPOSAL CONSIDERATIONS
This product and water used for rinsing must not be thrown away notably because of their acidity and their content in
metals after use. They must be processed within the firm or destroyed by an approved organization.
Contaminated packaging if not re-used with the same product is also special waste to be sent to an approved
organization for recycling or disposal.
Classification according to the commission directive 2000/532/EC of 3 May 2000 and its modifications (in particular
2001/118/EC, OJ L47). Use the mandatory documents to follow-up the waste products.
06 03 13* or Solid salts and solutions containing heavy metals
11 01 05*
Pickling acids
11 01 11*
Aqueous rinsing liquids containing dangerous substances
15 01 10*
Packaging containing residues of or contaminated by dangerous substances
As the volume of rinsing water is small, it can be added to the waste solutions.
NOTE: in addition to the community provisions, it can be specific legislative and administrative, national or local
provisions on this topic.
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14 - TRANSPORT INFORMATION
A.D.R. (road transport)
Hydrochloric acid, class 8, classification code C1, packaging group III, hazard label model 8, restricted quantities LQ7,
hazard identification n 80, material identification n 1789.
I.M.D.G. (sea transport)
Hydrochloric acid, UN N 1789, class 8, packaging group III, subsidiary risk label: not applicable, restricted quantities 5
L, stowing and separation: category C, safety sheets F-A, S-B.
I.A.T.A. (air transport)
Hydrochloric acid, UN N 1789, class 8, subsidiary risk: not applicable, risk label: CORROSIVE, packaging group III,
Passenger and Cargo aircraft: packaging instructions 819, maximum quantity per package: 5 L, Cargo aircraft only:
packaging instructions 821, maximum quantity per package: 60 L, instruction IDC 8L.
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15 - REGULATORY INFORMATION
This safety data sheet has been established in accordance with the Corrigendum to Regulation (EC) n 1907/2006 of the
European Parliament and of the Council of December 18, 2006, OJ L136, 29.05.2007.
th
The preparation labelling has been established in compliance with the directive 67/548/EC (until the 29 adaptation:
directive 2004/73/EC of April 29, 2004) and the directive 1999/45/EC reviewed in last in January 23, 2006 by the
directive 2006/8/EC.
EC LABELLING:
Is not classified but contains at least one dangerous compound with a non regulated concentration (with regard
th
to the 67/548/EC directive until the 29 modification).
A safety data sheet is available.
Aqueous acidic preparation containing in particular less than 10 % hydrochloric acid.
S26: in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: wear suitable gloves and eye/face protection.
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Codes: 10005, DPR 5075, Safety Data Sheet, document code: FDS 10005
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HEALTH SURVEILLANCE
Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to
chemical agents at work
An appropriate health surveillance of workers must be carried out according to the risk.
For each worker who undergoes this health surveillance, individual health and exposure records are to be made and kept
up-to-date.
Other paragraphs in the French version of this safety data sheet summarize French rules regarding:
health surveillance,