DALIC, B.P.

90139, 35501 VITRE CEDEX, FRANCE

service@dalicworld.com

26.05.2008
Code: 10021, document code: FDS10021

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SAFETY DATA SHEET

1 - IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY
IDENTIFICATION OF THE PREPARATION

INHIBITEUR N10 or ADDITIVE AC (code: 10021)

MAIN USE OF THE PREPARATION
This solution contains inhibitors that reduce the corrosion of steel.
It is used at ambient temperature, 10% diluted in tap water for rinsing after each etching step before localized DALIC
plating (with brush or sometimes with the DALISTICK tool). Its use permits to improve the adhesion of the coatings in
some plating ranges.
Specifically, the DALIC processes can be applied locally just where it is necessary, which means without immersion of
the part. Thus, only small quantities of solutions are stored or used.
COMPANY IDENTIFICATION
DALIC - ZI de Plagu - 41, rue des Eaux - B.P. 90139 - 35501 VITRE CEDEX, FRANCE
Manufacturer and Seller, tel.: (33) 2.99.75.36.99, fax: (33) 2.99.74.49.31.
For information: sclaverie@dalicworld.com, tel.: (33) 2.99.75.53.88.
RELEVANT OFFICIAL ADVISORY BODY (France): INRS / Orfila, tel. (33) 1.45.42.59.59.
________________________________________________________________________________________________
2 HAZARDS IDENTIFICATION
CHEMICAL NATURE
Alkaline aqueous preparation.
PRODUCT CLASSIFICATION ACCORDING TO 1999/45/EC and 67/548/EC
Preparation not classified as dangerous with regard to these directives.
MAIN HAZARDS
Adverse physicochemical effects
- Fire or explosion: this product is not considered as flammable or explosive.
Adverse effects on health
No particular effects but Diethanolamine is suspected to be a cutaneous and respiratory allergen on some sensitive
people.
Effects on the environment
This preparation doest not present a special risk to environment providing that the recommendations of the section 13
relative to disposal as well as the national or local provisions are followed. Refer also to the paragraphs 11, 13 and 15.
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3 - COMPOSITION / INFORMATION ON INGREDIENTS
COMPONENTS OR IMPURITIES CONTRIBUTING TO THE HAZARDS (according to 1999/45/EC and 67/548/EC)
Substances present in concentrations higher than the minimal level of danger: NO.
Substances present in concentrations lower than the minimal level of danger (if 1%): YES.
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DEA (25 adaptation)

(Diethanolamine)
Regulated substance
CAS N: 111-42-2
EC index N: 603-071-00-1
EC N: 203-868-0
Classification of the
Xn R22-48/22
Symbol:
pure substance
Xi R38-41
Xn
S phrases
(2) 26-36/37/39-46
No limit concentration in
67/548/EC >> 1999/45/EC
Classification of the
25%: Xn R22
substance according to
20%: Xi R38
its concentration (in %)
10%: Xn R48/22-41
5-10%: Xi R36
Concentration range in
< 5%
the preparation
Other substances with the R33 phrase (if 1%), the R64 phrase (if 1%) or sensitizing substances (if 0.1%): NO.
OTHER SUBSTANCES WITH WORKPLACE EXPOSURE LIMITS: NO.
OTHER INFORMATION: contains also not classified components.
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DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

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26.05.2008

Codes: 10021, Safety Data Sheet, document code: FDS10021

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4 - FIRST AID MEASURES

CONTACT WITH SKIN
Take off contaminated clothing and shoes. Wash immediately with plenty of water.
CONTACT WITH EYES
Rinse immediately with plenty of water for approximately 15 minutes. In case of pain, redness or visual discomfort, call
an ophthalmologist.
INHALATION
Theoretically, not applicable. Under abnormal conditions of use causing considerable inhalation, remove the casualty
from the contaminated area, let him take a rest in a well-ventilated room and seek medical advice.
INGESTION
Try to induce vomiting and give water to drink. Seek medical advice to decide to transfer or not into hospital.
PROTECTION OF THE FIRST-AIDERS
According to the situation, wear gloves, glasses, masks
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5 - FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA
Dry ice, chemical powders, special foam for polar liquids, water spray.
EXTINGUISHING MEDIA WHICH SHALL NOT BE USED
No contraindication.
SPECIFIC HAZARDS
Dangerous thermal decomposition products: decomposition of some components begins at 230C and auto-inflammation
may occur near 305C. Then the combustion gives notably nitrogen oxides and carbon oxides.
PROTECTION OF THE FIRE FIGHTERS
Because of the substances produced during thermal decomposition, use approved self-contained breathing equipment
and protective clothing.
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6 - ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Avoid contact with skin: wear at least gloves and preferably glasses.
ENVIRONMENTAL PRECAUTIONS
Do not allow the product to be thrown away. Recover as much as possible for processing within the firm or by an
approved centre.
METHODS FOR CLEANING UP
With water to remove all non-recoverable product. Before throwing rinsing water, check the pH is between 5.5 and 8.5.
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7 - HANDLING AND STORAGE
HANDLING
Use after dilution at 10% in tap water. Close containers (in PE) tightly after use with the original cap. Do not re-use
containers with another product.
STORAGE
Store in a room away from acid products, powerful oxidising agents, away from some metals (as copper, aluminium and
their alloys) and from nitrozating agents (for example, nitrites, nitrogen oxides). Keep in original containers only, between
5 and 30C, if possible away from direct sunlight. The maximum recommended shelf life is three years from the date of
manufacture under normal conditions of storage.
________________________________________________________________________________________________
8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
TECHNICAL MEASURES
No drinking, eating or smoking on the workplace.
Maintain the premises and the workplace in a perfect state of cleanliness and clean them frequently.
As the product is weakly concentrated and used at room temperature, the values below are not reached.
EXPOSURE LIMIT VALUES IN AIR
French decisions of 26 October 2007,
of 30 June 2004, INRS file ND 2098

Diethanolamine
Average value (8h):
3
3 ppm (or 15 mg/m ,
INRS file ND 2098)

Directives 2006/15/EC, 2000/39/EC and

91/322/EC
ACGIH
TLV-TWA: 2 mg/m3

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

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Codes: 10021, Safety Data Sheet, document code: FDS10021

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PERSONAL PROTECTION
Provide a shower, a powerful tap and sink unit and an eye basin near the work place.
Respiratory protection: no in normal conditions of use as described in the technical data sheet (ambient
temperature, 10% dilution).
Hand protection: wear gloves (in latex or nitrile for example).
Eye protection: wear glasses with lateral protections. Do not wear contact lenses.
Skin protection: wear overalls and safety boots.
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9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance: pale yellow liquid.
Odour: odourless.
pH: 10.5.
Relative density: 1.04
Solubility: miscible in water.
Boiling point: approximately 100C.
Crystallisation / melting point: -3C.
Flammability: nil.
Oxidising properties: nil.
Other properties: not applicable.
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10 - STABILITY AND REACTIVITY
STABILITY
Good at ambient temperature with water evaporation for only risk.
Good in humidity. Slow oxidation and slight possible yellowing with air and light.
CONDITIONS TO AVOID
Incompatible components, heat (decomposition of some constituents from 230C).
MATERIALS TO AVOID
In particular, if accidentally the preparation is in a concentrated or dehydrated state:
Exothermic reaction with acids, powerful oxidizers,
Attack of copper, aluminium and their alloys,
Reaction with nitrozating agents (for example, nitrites, nitrogen oxides). Some nitrosamines can grow in particular
conditions. They proved to be carcinogenic in animal experimentation.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS
The combustion gives notably nitrogen oxides and carbon oxides.
________________________________________________________________________________________________
11 - TOXICOLOGICAL INFORMATION
No data are available regarding the preparation. The evaluation of health hazards has been realised thanks to
directives 67/548/EC, 1999/45/EC and bibliographical data.
SKIN
The risk of skin allergies is probably very weak but it can appear on some sensitive people.
EYE MUCOSA
Is not classified as irritating.
RESPIRATORY SYSTEM
The risk of respiratory allergies is probably very weak but it can appear on some sensitive people.
IN CASE OF INGESTION
Possible gastrointestinal troubles.
OCCUPATIONAL DISEASES: tables n49 and 49a (France, aliphatic amines, ethanolamines).
________________________________________________________________________________________________
12 - ECOLOGICAL INFORMATION
There are no ecological data on the preparation.
ECOTOXICITY
Bibliographic data concerning Diethanolamine:
FISHES - LC50 (96 h) = 250 - 301 mg/L, DAPHNIAS - EC50 (48 h) = 55 mg/L, ALGAE - LC50 (72 h) = 75 mg/L.
MOBILITY - PERSISTENCE AND DEGRADABILITY - BIOACCUMULATIVE POTENTIAL OTHER ADVERSE
EFFECTS
According to the available data, the involved raw materials are easily biodegradable and are not bioaccumulative.
With regard to the applicable EC directives, it is not appropriate to apply theN symbol DANGEROUS FOR THE
ENVIRONMENT to this preparation.
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DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

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Codes: 10021, Safety Data Sheet, document code: FDS10021

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13 - DISPOSAL CONSIDERATIONS
This product, even if diluted at 10 %, must not be thrown away notably because of its alkaline pH. It must be processed
within the firm or destroyed by an approved organization.
Contaminated packaging if not re-used with the same product is also a special waste to be sent to an approved
organization for recycling or disposal.
Classification according to the commission directive 2000/532/EC of 3 May 2000 and its modifications (in particular
2001/118/EC, OJ L47). Use the mandatory documents to follow-up the waste products.
11 01 11*
15 01 10*

Aqueous rinsing liquids containing dangerous substances

Packaging containing residues of or contaminated by dangerous substances

NOTE: in addition to the community provisions, it can be specific legislative and administrative, national or local
provisions on this topic.
________________________________________________________________________________________________
14 - TRANSPORT INFORMATION
A.D.R. (road transport), I.M.D.G. (sea transport), I.A.T.A. (air transport)
Not regulated.
________________________________________________________________________________________________
15 - REGULATORY INFORMATION
This safety data sheet has been established in accordance with the Corrigendum to Regulation (EC) n 1907/2006 of the
European Parliament and of the Council of December 18, 2006, OJ L136, 29.05.2007.
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The preparation labelling has been established in compliance with the directive 67/548/EC (until the 29 adaptation:
directive 2004/73/EC of April 29, 2004) and the directive 1999/45/EC reviewed in last in January 23, 2006 by the
directive 2006/8/EC.
EC LABELLING: NO SPECIFIC RISK
Alkaline aqueous preparation.
Is not classified but contains at least one dangerous compound with a non regulated concentration (with regard to the
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67/548/EC directive until the 29 modification)
A safety data sheet is available.
S26: in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
HEALTH SURVEILLANCE
Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to
chemical agents at work
An appropriate health surveillance of workers must be carried out according to the risk.
For each worker who undergoes this health surveillance, individual health and exposure records are to be made and kept
up-to-date.
Other paragraphs in the French version of this safety data sheet summarize French rules regarding:

occupational diseases,

administrative declarations and rules (none),

environment laws regarding rinsing water treatment.

See the specific legislative and administrative, national or local provisions on these topics.
Additional information is provided in paragraphs 8, 11, 12, 13 and 14.
________________________________________________________________________________________________
16 - OTHER INFORMATION
RESTRICTION OF USE
For industrial use only.
We remain available to bring you the advice you may need.
R PHRASES OF THE PURE COMPONENTS LISTED IN SECTION 3
R22: harmful if swallowed.
R48/22: harmful: danger of serious damage to health by prolonged exposure if swallowed.
R38: irritating to skin.
R41: risk of serious damage to eyes.
R PHRASES OF THE PREPARATION ACCORDING TO THE SECTIONS 2 AND 15
None.
BIBLIOGRAPHIC REFERENCES
European directives, INRS files, safety data sheets of the components established by their manufacturers or distributors,
information of European Office of the chemical substances (ECB).
MODIFICATIONS
Updating in relation to the directives 2006/8/EC and 2006/15/EC, the corrigendum to regulation (EC) n 1907/2006
published in May 29, 2007 and French decisions of October 26, 2007.
Revised paragraphs: n2, 3, 8, 15, 16.

DALIC, B.P. 90139, 35501 VITRE CEDEX, FRANCE

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26.05.2008

Codes: 10021, Safety Data Sheet, document code: FDS10021

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OTHER INFORMATION
This sheet is provided to complement, not replace, the user instructions.
Information contained herein is bona fide and based on current knowledge relating to the product on the date of
publication. Furthermore, the attention of the user is drawn to the risks, which may be incurred when the product is used
for purposes other than those for which it is designed.
Information provided herein relates to this product only; it cannot take account of every situation, which may arise at
every work place. This safety data sheet therefore represents only a part of the information required for establishing a
safety programme.
Under no circumstances does this sheet dispense the user from the need to know and to apply all of the regulations
governing its activity, which are not all necessarily quoted herein in an exhaustive manner.
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