s2s CEI Workbook

Read Me First
This workbook is a calculation method for the Dow Chemical's Chemical Exposure Index which gives a quick estimate of
the ERPG2 and ERPG3 footprint of a standard scenario described in the guidance book S2S_Chemical_Exposure_Index.doc
The scenarios are described in this guidnce book as is the mathematics of the method which are incorported into the
spreadsheet. There are 3 release types provided:
Piping release or
vessel nozzle
release
This calculation allows you to input hole sizes
for releases, but assumes that any pipe
of a diameter greater than 2 inch will not
fail in a guillotine fracture. See the scenario
section of the guidance document
S2S_Chemical_Exposure_Index.doc
Overflow or relief
when discharge
quantity known.
Hose Release
This calculation allows you to input hose sizes

for releases. It assumes that 'full bore'
failure occurs
See the scenario
section of the guidance document
S2S_Chemical_Exposure_Index.doc
This calculation allows you to use known

discharge rates.
Emergency Response Planning Guidelines and Physical Properties are provided for many common materials.
The reference to level 2 Risk Analysis can be found in the Progressive Process Safety Management Systems within S2S.
Please note that several cases have been filled in on this spreadsheet as examples.
11/21/2014
1/9
252387294.xls.ms_office
Results Summary
Plant
Chlorination
Unit
Case 1
store V101
Substance
Chlorine in pressurised
store
store
store
Case 3
Case 4
11/21/2014
Distance ERPG2 (Liquid Release) Metres
Pipe leak
Hose leak
Relief or overflow
Other - write description
in this cell
Pipe leak
Hose leak
Relief or overflow
in this cell
Pipe leak
Hose leak
Relief or overflow
in this cell
Pipe leak
Hose leak
Relief or overflow
in this cell
Case 2
Case 5
Scenario
10 minute release of
anhydrous ammonia at
7000 kg/hr flow rate
Distance ERPG2 (Gas Release) Metres
16932
3571
817
891
5245
3709
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
Pipe leak
1267
Hose leak
#VALUE!
Relief or overflow
0 in this cell
2/9
#VALUE!
1160
#VALUE!
926
ERPGs and Physical Properties
Molecular
Weight
Acetone cyanohydrin *
Acrolein
Acrylic acid
Acrylonitrile *
Allyl chloride
Ammonia
Benzene
Bromine
Butadiene
n-butyl acrylate
n-butylisocyanate
Carbon disulfide
Carbon monoxide
Carbon tetrachloride
Chlorine
Chlorine trifluoride
Chloroacetyl chloride
Chloroform *
Chloropicrin
Chlorosulfonic acid
Chlorotrifluoroethylene
Crotonaldehyde
Diketene
Dimethylamine
Epichlorohydrin
Ethyl chloride *
Ethylene dichloride *
Ethylene oxide *
Formaldehyde
Hexachlorobutadiene
Hexafluoroacetone
Hydrogen bromide *
Hydrogen chloride
Hydrogen cyanide
Hydrogen fluoride
Hydrogen sulfide
Isobutyronitrile
2-isocyanatoethyl methacrylate
Methacrylonitrile *
11/21/2014
85.1
56.1
72.1
53.1
76.5
17
78.1
159.8
54.1
128.2
99.1
76.1
28
153.8
70.9
92.5
112.9
119.4
164.4
116.5
116.5
70.1
82.1
45.1
92.5
64.5
99
44.1
30
260.8
166
80.9
36.5
27
20
34.1
69.1
155.2
67.1
Boiling
Point
(C)
52.5
141.4
77.2
44.8
-33.4
80.1
58.7
-4.4
46.3
-191.5
76.8
-34
106
61.7
112
-28.2
102.4
6.9
116.4
12.3
83.5
10.5
-66.7
-85
25.7
19.6
-60.3
90.3
ERPG-1
ERPG-1
ERPG-2
(mg/m3)
(ppm)
(mg/m3)
35
1
147
76
125
104
7
442
131
0.2
156
629
9
4
2.5
244
2
10
476
29
17
184
76
13192
405
90
12
107
7
66
30
11
16
42
141
1
27
6
22
9
17
1
22
0.26
0.04
3
126
3
0.38
0.25
1
2
95
6
3
2
8
1
32
10
4
4
0.14
28
-
0.1
2
10
3
25
0.2
10
0.05
0.01
1
200
20
1
0.1
0.05
0.1
0.4
20
2
1
1
2
1
3
3
3
5
0.1
10
-
ERPG-2
3/9
ERPG-3
(ppm)
(mg/m3)
10
0.5
7
50
2210
35
163
40
939
150
522
1
33
200
11060
25
1310
0.05
4
50
1557
350
100
4718
3
58
1
38
0.5
23
50
24413
0.3
10
2.1
30
100
1429
10
143
5
168
100
922
20
378
5000
100
50
901
10
31
10
320
1
339
20
248
20
224
10
28
20
41
30
139
50
565
0.1
6
10
-
ERPG-3
(ppm)
3
750
75
300
750
5
5000
250
1
500
500
750
20
10
5
5000
1.5
6.3
300
50
50
500
100
500
25
30
50
75
150
25
50
100
200
1
-
Vapour
Liquid
Heat
Latent
Ratio of
Pressure Density Capacity
Heat
Cp/Hv
(kPa)
(kg/m3) (J/kg-C)
(J/kg)
(1/C)
36
835.1 2.00E+03 5.37E+05
0.0037
0.5
1046.7 1.80E+03 6.95E+05
0.0026
14
778.7 2.06E+03 6.31E+05
0.0033
48.6
932.1 1.53E+03 3.73E+05
0.0041
1013.1
602.2 4.74E+03 1.16E+06
0.0041
12.7
874.5 1.74E+03 4.30E+05
0.004
28.5
3106.4 4.65E+02 1.96E+05
0.0024
0.7
894.5 1.82E+03 3.61E+05
0.005
2.6
886.6 1.60E+03 4.07E+05
0.0039
48.3
1256.3 1.09E+03 3.61E+05
0.003
15.2
1582.9 8.24E+02 2.11E+05
0.0039
779.4
1400.3 9.85E+02 2.47E+05
0.004
3.3
1410.8 1.17E+03 3.62E+05
0.0032
26.3
1480.8 9.54E+02 2.61E+05
0.0037
3.4
1646 8.55E+02 2.36E+05
0.0036
641.9
1292 1.20E+03 1.46E+05
0.0082
4.8
849.4 2.00E+03 5.45E+05
0.0037
205.9
650.4 2.77E+03 5.61E+05
0.0049
2.3
1175.1 1.44E+03 4.51E+05
0.0032
160.3
893 1.62E+03 3.74E+05
0.0043
10.6
1247.1 1.31E+03 3.54E+05
0.0037
174.4
867.7 2.07E+03 5.61E+05
0.0037
515.6
728.7 2.55E+03 7.13E+05
0.0036
0
1673.9 6.83E+02 2.14E+05
0.0032
2359.7
1760.3 1.02E+03 1.59E+05
0.0064
4812.5
804.9 3.40E+03 2.36E+05
0.0144
123
983.3 -7.04E+02 3.72E+05
-0.0019
2022.4
767.2 2.33E+03 4.11E+05
0.0057
0
1095.9 1.83E+03 3.58E+05
0.0051
9.5
795.5 1.99E+03 4.89E+05
0.0041
ERPGs and Physical Properties
Molecular
Weight
Methanol
Methyl chloride
Methyl iodide
Methyl isocyanate
Methyl mercaptan
Monomethylamine
Perfluoroisobutylene
Phenol
Phosgene
Phosphorous pentoxide
Propylene oxide *
Styrene
Sulfur dioxide
Sulfuric acid (Sulfur trioxide)
Sulfuryl fluoride *
Tetrafluoroethylene
Titanium tetrachloride
Toluene diisocyanate *
Trimethylamine
Vinyl acetate
Vinyl chloride *
Vinylidene chloride *
11/21/2014
32
50.5
141.9
57.1
48.1
31.1
218.1
94.1
98.9
141.9
58.1
104.2
64.1
98.1
102.1
100
189.7
174.2
59.1
86.1
62.5
96.9
Boiling
ERPG-1 ERPG-1 ERPG-2 ERPG-2 ERPG-3 ERPG-3 Vapour
Liquid
Point
Pressure Density
(C)
(mg/m3)
(ppm)
(mg/m3)
(ppm)
(mg/m3)
(ppm)
(kPa)
(kg/m3)
64.5
262
200
1310
1000
6551
5000
17
786.7
-24.1
826
400
2065
1000
577.3
916.9
145
25
290
50
726
125
0.058
0.025
1
0.5
12
5
62
947.8
6
0.01
0.005
49
25
197
100
202.2
857.7
-6.3
13
10
127
100
635
500
349.1
655.9
1
0.1
3
0.3
181.9
38
10
192
50
770
200
0.1
1070.6
7.5
1
0.2
4
1
190.3
1361.7
5
1
25
4
100
17
34.2
119
50
594
250
1782
750
71.9
823.7
145.2
213
50
1065
250
4259
1000
0.8
902
-10
1
0.3
8
3
39
15
393.6
1352.4
44.4
2
0.5
10
2.5
30
7.5
417
100
1252
300
1748
1321
818
200
4090
1000
40902
10000
3249.7
880.9
5
1
20
3
100
13
1.4
1715.8
252.9
1
0.2
0
1210.8
2.9
0.1
242
100
1209
500
221.5
625.5
72.8
18
5
264
75
1760
500
15.3
925.4
-13.8
2556
1000
12781
5000
395.7
903.2
31.7
198
50
793
200
79.7
1204
4/9
Heat
Capacity
(J/kg-C)
2.54E+03
1.62E+03
1.44E+03
1.89E+03
3.10E+03
2.05E+03
1.03E+03
2.09E+03
1.75E+03
1.41E+03
1.50E+03
3.48E+03
7.43E+02
1.52E+03
2.29E+03
1.76E+03
1.55E+03
1.16E+03
Latent
Ratio of
Heat
Cp/Hv
(J/kg)
(1/C)
1.20E+06
0.0021
3.76E+05
0.0043
4.90E+05
0.0029
4.87E+05
0.0039
7.77E+05
0.004
6.22E+05
0.0033
2.37E+05
0.0043
4.80E+05
0.0043
4.22E+05
0.0041
3.57E+05
0.0039
1.28E+05
0.0117
6.31E+04
0.0551
2.16E+05
0.0034
3.92E+05
0.0039
3.68E+05
0.0062
4.03E+05
0.0044
3.20E+05
0.0048
2.74E+05
0.0042
Chemical Exposure Index Calculation

Plant:
Unit of Process Plant:
Calculation by:
Material in case studied
Date:
Chlorination
store V101
Gowland
Chlorine in pressurised store
January 4 2006
Piping release or vessel nozzle release
Level 2 Risk Analysis is triggered

(Liquid
Release)
(Gas Release)
Distance travel by ERPG2 concentration Metres (Liquid

Release)
Distance travel by ERPG2 concentration Metres (Gas
Release)
Diameter of hole mm
50.8
Diameter of hole mm
50.8
Diameter of hole mm
100
Diameter of hole mm
100
16932
3571
Hose Release

Release)
Release)
(Liquid
Release)
(Gas Release)
817
891
Overflow or relief when discharge quantity known. Please enter

Release)
Release)
(Liquid
Release)
(Gas Release)
5245
3709
Liquid release rate L kg/sec

Airborne Gas Release (inventory exhausted within 5
minutes)
50
100

Plant:
Calculation by:
Date:
#VALUE!
#VALUE!
Release)
Release)
(Liquid
Release)
(Gas Release)
Diameter of hole mm
Diameter of hole mm
#VALUE!
#VALUE!
Hose Release
#VALUE!
#VALUE!
Release)
Release)
(Liquid
Release)
(Gas Release)
Diameter of hole mm
Diameter of hole mm
#VALUE!
#VALUE!

#VALUE!
(Liquid
Release)
#VALUE!
(Gas Release)

Release)
Release)
#VALUE!
#VALUE!

minutes)

Plant:
Calculation by:
Date:
#VALUE!
#VALUE!
Release)
Release)
(Liquid
Release)
(Gas Release)
Diameter of hole mm
Diameter of hole mm
#VALUE!
#VALUE!
Hose Release
#VALUE!
#VALUE!
Release)
Release)
(Liquid
Release)
(Gas Release)
Diameter of hole mm
Diameter of hole mm
#VALUE!
#VALUE!

#VALUE!
(Liquid
Release)
#VALUE!
(Gas Release)

Release)
Release)
#VALUE!
#VALUE!

minutes)

Plant:
Calculation by:
Date:
#VALUE!
#VALUE!
Release)
Release)
(Liquid
Release)
(Gas Release)
Diameter of hole mm
Diameter of hole mm
#VALUE!
#VALUE!
Hose Release
#VALUE!
#VALUE!
Release)
Release)
(Liquid
Release)
(Gas Release)
Diameter of hole mm
Diameter of hole mm
#VALUE!
#VALUE!

#VALUE!
(Liquid
Release)
#VALUE!
(Gas Release)

Release)
Release)
#VALUE!
#VALUE!

minutes)

Plant:
Calculation by:
Date:
10 minute release of anhydrous ammonia at 7000 kg/hr flow rate

Release)
Release)
(Liquid
Release)
(Gas Release)
Diameter of hole mm
50.8
Diameter of hole mm
50.8
1267
1160
Hose Release
#VALUE!
#VALUE!
Release)
Release)
(Liquid
Release)
(Gas Release)
Diameter of hole mm
Diameter of hole mm
#VALUE!
#VALUE!

#VALUE!
Release)
Release)
(Liquid
Release)
(Gas Release)
#VALUE!
926

minutes)

s2s CEI Workbook

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Read Me First

This calculation allows you to input hose sizes

This calculation allows you to use known

Distance ERPG2 (Liquid Release) Metres

Distance ERPG2 (Gas Release) Metres

ERPGs and Physical Properties

ERPGs and Physical Properties

Chemical Exposure Index Calculation

Piping release or vessel nozzle release

Level 2 Risk Analysis is triggered

Distance travel by ERPG2 concentration Metres (Liquid

Level 2 Risk Analysis is triggered

Overflow or relief when discharge quantity known. Please enter

Liquid release rate L kg/sec

Chemical Exposure Index Calculation

Overflow or relief when discharge quantity known. Please enter

Distance travel by ERPG2 concentration Metres (Liquid

Liquid release rate L kg/sec

Chemical Exposure Index Calculation

Overflow or relief when discharge quantity known. Please enter

Distance travel by ERPG2 concentration Metres (Liquid

Liquid release rate L kg/sec

Chemical Exposure Index Calculation

Overflow or relief when discharge quantity known. Please enter

Distance travel by ERPG2 concentration Metres (Liquid

Liquid release rate L kg/sec

Chemical Exposure Index Calculation

10 minute release of anhydrous ammonia at 7000 kg/hr flow rate

Piping release or vessel nozzle release

Level 2 Risk Analysis is triggered

Overflow or relief when discharge quantity known. Please enter

Liquid release rate L kg/sec

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