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120
Volume 22,
No. 2
ABSTRACT-A description is given of the varied clinical applications of this cement; these
applications include its use as a filling material, as a sealant and as a luting agent.
Introduction
The first part of this series discussed the formulation, development and properties of glassionomer cements. The most practical version of
this cement was designated ASPA IV. The hydrophilic nature of this material, its good mechanical
strength and excellent adhesion to tooth structure
and certain metals are properties which can be
utilized to the maximum in several clinical applications. The recommended applications fo? ASPA IV
filling material are listed below
1. Sealing of occlusal pits and fissures.
2. Filling of occlusal fissures showing early
signs of caries.
cavities.
5. Restoration of Class V cavities not involving
large areas of labial enamel.
6. Repair of defective margins in restorations.
7. Restoration of erosion lesions without cavity
preparation.
A fine grained version of ASPA IV, ASPA IVA,
has been made available for further evaluation
as a luting agent. The only difference in formulation between this material and ASPA 1V filling
material being in the particle size distribution of
the powder. ASPA luting (ASPA IVA) has been
used for the following clinical applications.
1. Translucent luting cement.
2. Lining cement.
3. Sealing of occlusal pits and fissures.
121
J. W., and Wilson, A. D.-The clinical deve!opment of the glass-ionomer cements. 1. Formulations
and properties. Austral. D. J., 221, 31-37 (Feb.) 1977.
2 Wilson
A D. and Kent B E.-The
glass-ionomer
cem'ent. * a n;w translucent ciental filline material. J.
Appl b e m . Biotechnol. 21: 313 1971.8 Wilson.'A.
D., and Kent. 'B. E.-S;rgical
cement. Brit.
Pat. No. 1 316 129 1973.
4 Plant. S. C.--'Personal
'communication. 1972.
5 Rowe, R. H. W.-Personal
communication, 1972.
BSmith. D. C.-A
new dental cement. Brit. D. J.. 125:5,
?Xi-384 (Nov. 5 ) 1968.
7 Smith
D C-A
review of the zinc polycarboxylate
cehents. J.' Canada. D. A., 37:1, 22-29 (Jan.) 1971.
BBeagrie, G. S.. Main, J. H., and Smith, D. C.-Inflammatory reaction evoked by zinc polyacrylate and zinc
eugenate cements. A comparison. Brit. D. J., 132:9,
351-357 (May 2) 1972.
OSafer, D. S Avery, J. K., and Cox, C. F.-Pulpal
responses t 6 newly formulated restorative cements, liners,
sealers. International Association for Dental Research
49th General Session, Chicago, paper No. 830, 1971.
1oTruelove E L Mitchell D. F and Phillips R. W.Biologic &al;8tion of a'carbox'slate cement. i. D. Res.,
50:1 166 (Jan.-Feb.) 1971.
11Peters.' W. J., Jackson, R. W., Iwano, .K.,and Smith,
D. C.-The biological response to zinc polyacrylate
cement. Clin. Orthop., 88: 228-233, 1927.
1
~
Radial c o n g c r r l o n
Tangential rmrbn
Ln composite
resin matrix
I
Fig. 1.-The filler matrix interface in a composite resin
material and in the glass-ionomer cement. In the latter
material a laver of siliceous hydrogel connects the filler
core to the matfix.
Hotz P. McLean J . W Sced I and Wilson A . D.Thk bbnding oi glass-'ionomdr 'dements to metal and
tooth substrates. Brit. D.J., 142:2, 41-47 (Jan. 18)
1977.
122
TABLE 1
Fluoride eluted,
mg/cernent
0.75
1.22
0.29
0.14
0.08
1st day
1st week
2nd week
5th week
13th week
* Following
preparation.
Fig. 2.-a,
Tracing of a cross section through a molar
fissure which is easily detectable with a probe. These fissures will always exceed lOOpm in width. b, Fissure filled
with cement.
Fig 3.-a
Tracing of a cross section through a molar
fisshe of 'less than lOOpm in width. The base of these
fissures is difficult to fill with glass-ionomer cement as
shown in Fig. 2b.
reiteration of the most successful techniques together with certain modifications will be given.
Fissure sealing
The glass-ionorner ccment is only suitable for
sealing fissures in depth where the pit or fissure
orifice exceeds lOOpm14 (Fig. 2a,b). This size of
fissure should allow n sharp probe to enter the
crevice and is easily detectable. Fissures or pits
below lOOprn in size can only be treated if the
cement is over-built above the orifice (Fig. 3a,
b).
Recommended clinical technique:1. Isolate the tooth or teeth in one quadrant
with cotton rolls and dry the surface. Swab a solution of 50 per cent citric acid into the fissures and
work the acid into the depth of the crevices with
a sharp probe. Debris may be scraped out with
the probe. This treatment should not exceed one
minute.
2. Clean off the debris and acid with air/water
spray and dry thc tooth with warm air.
3. Dispense two drops of the polyacid liquid
onto a refrigerated glass slab. Sufficient powder is
then placed on one side of the liquid to provide
the required mix.
Note: refrigeration of the slab increases the
working time.
123
Fig. 4.-Two
mixes of cement powder are shown on the
left of the slab. The lower mix is made first at n thin
consistency of approximately 1.5g/ml. Further powder is
now drawn in to the top mix on the left lo give a plastic
consistency (P/L proportion of 3.0g/ml).
Fig. 5.-Thin
Fig. 7.-A
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retention. However, the treatment of early carious
fissures does present an entirely different problem.
An investigation of the potential of glass-ionomer
cement as a n occlusal fissure filling proved very
promising. A two-year study revealed that in only
a few cases was anatomical form lost and in n o
Fig. S.-Tracing of a typical filled fissure in an upper premolar where the dental caries has not mushroomed into the
dentine.
Another important application for the glassionomer cement would appear to be the repair of
faulty margins around restorations. Most clinicians
have faced the dilemma of what to do with extensive crown and bridgework where gingival erosion
has occurred or where marginal fit may not be acceptable around one or two units of metal/ceramic
work in an extensive splint. Remaking such restorations is not only expensive but removal of the
restoration after a short period of service undermines the patient's confidence.
Previous methods of repair generally involved
some sort of cavity preparation, with the subsequent insertion of a composite resin or similar
material. Phosphate bonded cements were unsatisfactory because of their rapid breakdown under
acid conditions.
Providing the margins are thoroughly cleaned
out, and the micro-leakage has not extended into
the depths of the restoration, then the sealing of
defective margins around crowns or inlays with
glass-ionomer cement is a practical proposition.
Generally, a radiograph combined with an examination with a sharp cxplorer will establish the
integrity of the internal surfaces of the tooth preparation. The cement should be firmly packed into
the crevice or eroded area and covered with a
cervical matrix in the same way as for the erosion
lesion. I t is then very convenient t o trim the set
material with sharp knives, since in this way, subgingival bleeding is avoided, which might contaminate the set cement. At the present time, no
signs of dissolution of these cement margins have
been observed during a three-year trial. The ability
of the glass-ionomer cement to retain its surface
in a potentially acid-producing stagnation area once
again supports the in vitro studies in the laboratory.
Luting cements
Although the polysalt gel stage of a freshly prepared glass-ionomer cement is susceptible to water
contamination, a very useful clinical property
appears to be in sight of achievement. By controlling the rate of ion-exchange it is possible to make
luting cements with a gel-like initial set that allows
the operator to remove the restoration within the
first five minutes of cementation. For example, if
dissatisfied with the fit of the restoration, or too
thick a mix has caused failure of seating, then
the operator is given the opportunity of starting
again. Glass-ionomer cements can be formulated
having the characteristics of a temporary cement,
such as Kerr's Temp-Bond, for the first five to
125
ten minutes, and then developing after one hour
properties characteristic of a silico-phosphate
cement such as high strength and ability to liberate
fluoride ions as a cariostatic measure. Such a
cement will also have the favourable qualities of a
polycarboxylate, including good wetting ability
combined with comparative inertness and, as previously illustrated, good resistance to acid attack.
A specially prepared glass-ionomer powder of
vcry fine grade, termed ASPA IVA, luting material
has now been used for over two years for the
cementation of all types of restorations. Further
studies are now in progress to assess its commercial
viability. The only clinical disadvantage observed
with this ncw cement is in the early stages of set.
As explained previously the cement sets in two
stages, the first gel-like set is due to calcium ioncxchange and the second stagc, where a rockhardness is achieved, is due to aluminium ionexchange. During the initial gel-stagc the salt
matrix is very susceptible t o attack by moisture,
so that if saliva contacts the luting cement the
material can be seriously weakened. Attack by
moisture will obviously be more severe a t low P/L
ratios so that at luting consistencies of 1.5g/ml it
is essential to protect the margins of the restoration from moisture for at least five minutes after
cementation. Providing the cement is protected
during calcium ion-exchange and a firm gel salt is
allowed to form, then the final result provides a
strong fluoride leachable glass cement with good
physico-chemical bonding.
This latter property is of great significance
since current work by Hotz and co-workers12 has
shown that ASPA IV cement will stick to tin or
tin oxide coated gold or platinum surfaces as described in Part I of these papers. The mechanism
for adhesive bonding is illustrated in Fig. 9 and
is particularly applicable to the construction of
bonded alumina crowns, or attachment of gold
inlays to tooth structure.
The bonding scheme postulated in Fig. 9 shows
how the glass-ionomer cement bonds dentine to the
tinned surface of platinum, and how tinned
platinum adheres to porcelain. The cssential bond
is the ionic one between oxygen anions and metal
cations. At the glass-ionomer cement/dentine interface oxygen anions at the surface of the dentine
and those contained in the cement carboxylate
groups are ionically linkcd by, most probably,
Ca'+ ions. At the glass-ionomer cement/treated
platinum intcrface oxygen anions a t the surface
of the tinncd and oxidized platinum are ionically
linked to those contained in thc cemcnt matrix
by Sn?+ ions. A similar ionic mechanism applies
to the porcelain/treated platinum surface where
oxygen atoms at the surface of both materials are
126
ionically linked by Sn'+ ions. Although the adhesive bonds at the various interfaccs differ, a
common feature to all is the bridging of oxygen
atoms by an ionic metal link.
CM'
Lining material
Within the limitations of this five-year development programme, the glass-ionomer cements would
appear t o have the abrasion resistance and low
thermal expansion of the silicate cement without
its liability to disintegrate rapidly in weak acids.
In addition, the glass-ionomer cements contain
leachable calcium fluoride which provides a cariostatic property in the material. It has not yet been
found possible t o produce a glass-ionomer cement
with the translucency of the composite resins or
with the latter's higher flexural strength. In other
Fig. 10.-Diagram showing sealing of dentine with a glassionomer cement and the attachment of a composite filling
over it using acid etching techniques.
as a universal restorative-improved
toughness for
posterior situations and a higher translucency or
lessened opacity for anterior fillings.
Another property which has been found important in cements based on poly(acrylic acid) is the
shelf life of the liquids. Some of the problems
encountered by clinicians with these materials can
be related to the increase in viscosity of the poly(acrylic acid) liquids during storage. Increases in
viscosity lead to difficulties in mixing, shorter
working time and lower P/L ratios, all of these
undesirable features producing lower strengths.
The cause of this phenomenon is as yet unknown:
it may be inherent.due to chain entanglement or
could be the result of slight contamination from
the containing vessel. It is important, therefore, to
avoid using liquids which have gelled or have a
high viscosity like glues. Crisp, Lewis and Wilson18
have described an acrylic/itaconic acid co-polymer
which, in 50 per cent m / m aqueous solution, has
a low viscosity (10 poise) compared with that of
similar solutions of poly(acrylic acid) 50 poise.
18
127
Department of Industry,
Laboratory of the Government Chemist,
Cornwall House,
Stamford Street,
London, SE1 9NQ,
England.