CHM 1120 EXAM I SECTION 004/005 02/12/14

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Be sure to show all of your work clearly (partial credit) and circle your final answers.
Dont forget to label your answers with the correct units when appropriate.
Use the following information to answer questions 1-3.
You have a 4.0 L aqueous solution containing 0.365 moles of CaCl2 and it has a density of 1.01013 g/mL.
1) What is the osmolarity of the solution shown above? (3 pts.)

2) Compared to a 0.125 M aq. NaCl solution, the aq. solution above will have a freezing point that is: (3 pts.)
a)
b)
c)
d)

lower than that of the aq. NaCl solution

higher than that of the aq. NaCl solution
that same as that of the aq. NaCl solution
not enough information provided to answer

3) If a human red blood cell (~ 0.3 osmol) was placed in the aqueous CaCl2 solution above: (3 pts.)
a)
b)
c)
d)
e)

cell lysis of the red blood cell would occur

we would consider the aqueous CaCl2 solution to be hypertonic with respect to the red blood cell
we would consider the aqueous CaCl2 solution to be isotonic with respect to the red blood cell
cell crenation of the red blood cell would occur
none of the above

Use the following three molecules to answer questions 4-6.

4) What is the strongest intermolecular force that exists between molecules A and B? (2 pts.)

5) What is the strongest intermolecular force that exists between molecules A and C? (2 pts.)

6) What is the strongest intermolecular force that exists between 2 molecules of A? (2 pts.)

SPRING 2014, CHM 1120, SECTIONS 004/005, EXAM I, PAGE 1 of 8

Use the following information to answer questions 7-10.

7) What is the overall reaction order for the reaction represented in the data table and graph? (2 pts.)

8) Use the correct integrated rate law to calculate the value of the rate constant (k) for this reaction? (6 pts.)

9) How many seconds does it take for the concentration of [A] to reach 10.042775 M? (6 pts.)

10) What is the concentration of [A] after 5 minutes? (6 pts.)

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Use the following information to answer questions 11-17.

2A + 3B 4C + D
Experiment
1
2
3

T = 25 oC

[A] M [B] M
0.12
0.06
0.12
0.12
0.24
0.06

A = 4.73 x 107 s-1

Initial Rate (M /s)

23
92
46

11) Write the rate expressions with respect to all four species involved in the reaction shown above. (8 pts.)

12) Calculate the individual reaction orders with respect to both A and B. (4 pts.)

13) Write the rate law for the reaction shown above. (2 pts.)

14) What is the overall reaction order for the reaction shown above? (2 pts.)

15) Calculate the value of the rate constant (k) for the reaction shown above? (6 pts.)

16) Calculate the value of the energy of activation (Ea) for the reaction shown above? (6 pts.)

17) Calculate the value of the rate constant (k) for the reaction shown above when run at 100 oC? (6 pts.)

SPRING 2014, CHM 1120, SECTIONS 004/005, EXAM I, PAGE 3 of 8

Use the following information to answer questions 18-26.

Concentrations after 30 seconds:

[A] = 0.60 M

[B] = 0.40 M

[C] = 0.60 M

[D] = 1.60 M

18) Write the equilibrium expression for the reversible reaction shown above. (3 pts.)

19) What is the value of the reaction quotient (Qc) after the reaction above has proceeded 30 seconds? (6 pts.)

20) Based on your calculated value of Qc, which direction will the reversible reaction proceed? (2 pts.)
21) What are the equilibrium concentrations of all of the species found in the equilibrium expression? (12 pts.)

22)

22) Calculate the value KP for the reaction shown above. (3 pts.)

23) The reaction can best be described as (circle one):

exothermic

24) In this reaction, thermal energy considered a (circle one):

endothermic

reactant

product

(1 pt.)
(1 pt.)

25) After reaching equilibrium, the temperature of the reversible reaction shown above is increased. (1 pt.)
What would the reaction need to do in order to re-establish equilibrium?

26) After reaching equilibrium, more C is added to the reversible reaction shown above. (2 pts.)
Describe what will happen to each of the other compounds found in the equilibrium expression?

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SCRATCH PAPER

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SCRATCH PAPER

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SCRATCH PAPER

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