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Abstract
A commercial scale plant using electron beam irradiation was constructed to clean the ue gas from a coal red
thermal power plant at Chengdu in China. Operations began in September 1997 and the plant achieved its design
performance with the satisfactory recovery of by-product fertilizer for agricultural use. Another commercial plant is
now under construction at Nagoya, Japan and the operation will be started in November, 1999. 7 2000 Published
by Elsevier Science Ltd. All rights reserved.
Keywords: Electron beam purication; Fertilizer; FGD
1. Introduction
Air pollution and related acid rain have now become
a serious problem world wide. In particular, immediate
measures need to be taken for the reduction of sulfur
oxides and nitrogen oxides emitted in large quantities
from coal red power plants. Various technologies and
processes have been developed to reduce sulfur oxides
(SOx) and nitrogen oxides (NOx) emissions. One such
eective process using electron beam irradiation was
commercialized as the Electron Beam Flue Gas Treatment process (EBA process). The EBA process
removes SOx and NOx simultaneously by electron
beam irradiation with ammonia (Maezawa and Iizuka,
1997). This process converts these pollutants into a dry
by-product consisting of ammonium sulfate and ammonium nitrate, which can be used as an agricultural
fertilizer.
0969-806X/00/$ - see front matter 7 2000 Published by Elsevier Science Ltd. All rights reserved.
PII: S 0 9 6 9 - 8 0 6 X ( 9 9 ) 0 0 4 9 6 - X
496
4. Process ow
The EBA process consists of three main stages:
gas cooling, ammonia injection and electron beam
irradiation, and by-product collection and treatment.
The schematic process ow is shown in Fig. 2.
After y ash collection, the ue gas is passed
through a spray cooler at a ow rate of 300,000
m3/h (NTP) where it is cooled by water sprays. The
cooled gas is then introduced into the process
vessel and irradiated with electron beams after the
497
498
Table 1
Design specicationsa
300,000 m3/h (NTP) (equivalent to 90 MWe)
1508C
Gas ow rate
Gas temperature
Components
Initial SO2 content
Initial NOx content
Initial dust content
SOx scrubbing eciency
NOx scrubbing eciency
Treated dust content
a
6. Process performance
The boiler loading of the Chengdu Thermal Power
Plant changes continuously, causing uctuations in the
ue gas SO2 levels. Stable SO2 removal eciencies
above 80% are achieved as shown in Fig. 3, even
though SO2 levels may vary by up to 1200 ppm. It has
been shown that high removal eciencies can be
achieved with the EBA process by proper control of
the absorption rate of electron beam, ue gas temperature and ammonia injection ow rate.
7. By-product utilization
The amount of by-product recovered by this plant is
499
Table 2
Main process items
Spray cooler
Process vessel
Electron accelerator
DC high voltage power supply
Electrostatic precipitator
Induction draft fan
Table 3
By-product components
Ammonium sulfate
Ammonium nitrate
Others
91.9%
0.8%
7.3%
Table 4
Result of vegetable (lettuce) cultivation test
EBA by-product
Reference fertilizer
Ammonium sulphate
Ammonium Nitrate
No nitrogen
24.8
6.9
87.6
29
25.0
6.8
87.4
29
25.5
6.8
89.3
29
24.7
6.8
92.1
30
20.7
5.3
46.1
21
about 2.5 tons/h or 20,000 tons a year. The main component of the by-product is ammonium sulfate, containing approximately 20% nitrogen as the eective
fertilizer component, with an eciency similar to other
commercially available fertilizers. It can either be used
as a single-component fertilizer or as a starting material for chemical (mixed) fertilizers.
The by-product components are shown in Table 3.
Table 4 shows the results of vegetable cultivation tests
as a comparison with the recovered by-product.
8. EBA commercial plant in Japan
The second commercial scale EBA plant is now
under construction for the Chubu Electric Power Co.
at the Nishi-Nagoya Thermal Power Station Unit No.
1 (a heavy oil-red boiler with a power output of 220
MWe) to treat ue gas at a ow rate of 620,000 m3/h
(NTP). This plant will start in 1999. The rate of byproduct production is estimated at 4.5 tons/h.
9. Conclusion
The commercialization of the EBA process using
electron beam irradiation is moving ahead at a fast
References
Aoki, S., Okamoto, K., 1998. The electron-beam ue gas
treatment system. In: The 41st Radiation and Chemistry
Symposium, Kobe, Japan.
Izutsu, M., Okabe, R., 1997. Final development to commercialize EBA process, non-thermal plasma technology for
gaseous pollution control. In: Proceedings of The second
International Symposium Salvador, Brazil.
Maezawa, A., Iizuka, Y., 1997. Electron beam ue gas treatment process technology. In: International Congress of
Acid Snow and Rain, Niigata, Japan.
Namba, H., et al., 1998. Electron beam treatment of ligniteburning ue gas with high concentrations of sulfur dioxide
and water. Radiation Physics and Chemistry 53 (6), 673
681.
Tokunaga, O., 1998. A technique for desulfurization and
denitration of exhaust gases using an electron beam.
Science & Technology in Japan 16 (64), 4750.