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Shielding constant for Ne is 4.15 and the effective nuclear charge on Na+ and F- are respectively
(A) 4.85 6.85
(B) 5.85 6.85
(C) 6.85 4.85
(D) 4.85 4.85
Electron gain enthalpy and ionization energy of an atom are a and +b eV respectively. The
electronegativity of that atom on Mulliken scale is given by
(A) a b
(B) (b a )/2
(C) a + b
(D) (a + b)/2
The atomic radii of Li is 1.23 A0 and ionic radius of Li+ is 0.76 A0. The fraction of the volume occupied by
2s electron in Li is
(A) 0.764
(B) 0.184
(C) 0.595
(D) 0.236
Photons of monochromatic light having just sufficient energy to ionize Ar-atom are incidened over the
mixture of inert gases He, Ne, Ar, Kr and Xe. The mixture will contain
(A) He, Ne gases; Ar+, Kr+, Xe+ ions
(B) He+, Ne+ ions; Ar, Kr, Xe gases
+
+
+
+
+
(C) He , Ne , Ar , Kr , Xe gases
(D) He+, Ne+, Ar+ ions and Kr, Xe gases
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If EA1 and EA2 for oxygen atom are -142 kJ mol and 844 kJ mol-1. The energy released to form
2 O + 2 e 2 O - will be
(A) 986
(B) 702
(C) 284
(D) 1688
Dipole moment of K+Cl- is 3.336 x 10-29 cm and it is 80 ionic in nature. The inter ionic distance between K+
and Cl- in A0 is
(A) 1.30
(B) 2.60
(C) 3.9
(D) 1.20
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+
Bond Order for CO and NO are respectively
(A) 3.5, 3.0
(B) 2.5, 3.0
(C) 2.5, 2.5
(D) 3.0, 2.5
Bond Order for N2+ and N2- are same. Which relation is correct for N2+ and N2- ?
(A) Bond Energy of N2+ = Bond Energy of N2(B) Bond Energy of N2+ > Bond Energy of N2+
(C) Bond Energy of N2 < Bond Energy of N2
(D) Bond Energy of N2+ < > Bond Energy of N2The electron gain enthalpy of fluorine atom is 333 kJ mol-1 and dissociation energy of F2 is 158.8 kJ mol-1
Energy released during the formation of 2g F- from 2g F2 ( atomic weight = 40 )
(A) 33.3 kJ
(B) 7.94 kJ
(C) 25.36 kJ
(D) 41.24 kJ
The ionization enthalpy of Li is 5.40 eV. If ionization energy of H-atom is 13.6 eV, the effective charge
acting upon outermost shell of Li is
(A) 1.26
(B) 2.52
(C) 0.63
(D) 3.0
Which of the molecule is hypovalent but has complete octet
(A) AlCl3
(B) PH3
(C) PCl3
(D) SF4
Which of the following molecule does not possess hypervalent nature ?
(A) IF7
(B) SF4
(C) BF3
(D) SF6
The species not having same bond order is :
(A) N2+
(B) O2+
(C) NO
(D) NO+
Least basic trihalide is
(A) NF3
(B) NCl3
(C) NBr3
(D) NI3
Least acidic trihalide is
(A) BF3
(B) BCl3
(C) BBr3
(D) BI3.
During the reaction C2H4 + 3 O2 2 CO2 + 2 H2O; the hybridized state of C changes from
(A) sp2 to sp
(B) sp to sp2
(C) sp3 to sp
(D) sp to sp3
Which of the following is T shaped ?
(A) XeOF2
(B) XeO3
(C) XeOF4
(D) XeF4
Number of and double bonds in P4O10 are respectively
(A) 12, 4
(B) 6, 4
(C) 8, 2
(D) 10, 4
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B2
N2
O2O2
(P) paramagnetic
(Q) undergoes oxidation
(R) undergoes reduction
(S) Bond Order greater than equal to 2
(T) Mixing of s and p orbitals
EB6778471D6A4601614A80F52592798C4D4F2E707CC4DED4CFC9CC6FAF5441FA7CF1