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Sri Chaitanya IIT- JEE Academy

RAMAN BHAVAN - VIJAYAWADA
CHEMISTRY ASSIGNMENT
[V A GROUP ELEMENTS]
Sec : J**&G**
Date : 16-04-11
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1. Explain with reason
1.
Why oxygen is a gas phosphorous is solid.
2.
A bottle of liquid ammonia should be cooled before opening why?
3.
Formation of ammonia from its elements at constant pressure is accompanied by decrease in
volume. Explain.
4.
Ammonia is a good complexing agent than phosphine. Why?
5.
Ammonia is a liquid with high boiling point but phopsphine is a gas with least boiling point among
the Vth group halides. Explain.
6.
Bond angle in ammonia is greater than phosphine why?
7.
Commercial N2 is passed through copper chips kept in ammonia solution for removing oxygen.
8.
Nitrous oxide supports combustion more vigorously than air.
9.
Burning of magnesium in NO continues while burning sulphur in NO extinguishes.
10.
Nitric acid acts only as an oxidizing agent while nitrous acid can act both as an oxidizing and
reducing agent.
11.
NO becomes brown when released in air.
12.
Pure conc. HNO3 is colourless but on long standing turns yellow in sunlight.
13.
Red phosphorous is denser and chemically less reactive than white phosphorous.
14.
Red phosphorous is less volatile than white phosphorous.
15.
Though HNO3 is stronger than HNO2 the H3PO2, H3PO3 and H3PO4 are approximately have equal
strength.
16.
PCl5 is ionic in solid state and conducts current in fused state.
17.
Noble metals like gold and platinum are in soluble in mineral acids but dissolves in aqua region.
18.
The experimentally determined N-F bond lengths in NF3 is greater than the sum of the single bond
covalent radii of nitrogen and fluorine.
19.
Though the electronegativities of nitrogen and chlorine are equal, chlorine is more reactive than
nitrogen.
20.
Nitrogen and bismuth donot form penta halides.
21.
Why quick lime rather than fused CaCl2, P4O10 or H2SO4 is used to dry ammonia.
22.
PH3 is weaker base than NH3.
23.
PCl5 is known but PI5 is unknown.
24.
Dipolemoment of NH3 is greater than NF3.
25.
NCl3 is unstable explosive substance but NF3 is stable.
26.
NF3 do not hydrolyse but NCl3 hydrolyse
27.
In the hydrolysis NCl3 liberates ammonia but PCl3 do not liberate PH3.
28.
Copper dissolves in HNO3 but not in HCl
29.
NO2 is paramagnetic and brown colour but N2O4 is diamagnetic and is colourless.
2. Give relevant equation with conditions for the following preparation
1.
NO from nitric acid
2.
Nitric acid from air
3.
White phosphorous form bone ash.
4.
Ammonium sulphate from gypsum, ammonia and CO2.
State with balances equations what happens when
1.
Calcium phosphate is heated with a mixture of sand and carbon.
2.
White phosphorous is boiled with strong solution of caustic soda.
3.
Elemental phosphorous on heating with conc.HNO3
4.
Calcium carbide is treated with nitrogen.

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5.
6.
7.
8.
9.
10.
11.
12.

Water is added to calcium cyanamide.

Cl2 is passed through liquour ammonia
Gold is treated with aquaregia
A mixture of air and ammonia when passed over hot platinum gauze.
Nitrogen is obtained in the reaction of aqueous ammonia with KMnO4.
Tin metal is boiled with conc.HNO3
Very dilute nitric acid on heating with zinc or magnesium.
Phosphorous is treated with an acidified CuSO4 solution.
3. True or False
1.
NO is acidic oxide.
2.
N2O is diamagnetic
3.
NO2 is paramagnetic
4.
NO is the anhydride of nitrous acid.
5.
N2O5 can be prepared by the dehydration of HNO3 with P4O10
6.
The covalency of nitrogen in N2O5 is four.
7.
Sodium Bismuthate is a reducing agent.
8.
Antimony has no oxyacid.
9.
Aluminium can reduce very dilute nitric acid to ammonium nitrate.
10.
The modern process for the manufacture of nitric acid is Birkland and Eyde method.
4.Match the following
1. Laughing gas
a) phosphorous acid
(i) strong dehydrating agent
2. Nitrous anhydride
b) hydrazoic acid
(ii) strongest acidic oxide of N2
3. Anhydride of nitric acid c) ammonia
(iii) reducing agent
4. Anhydride of HPO3
d) nitrogen trioxide
(iv) explosive
5. Acid hydride of N2
e) nitrous oxide
(v) good complexing agent
6. Basic hydride of N2
f) nitrogen pentoxide
(vi) good supporter of combustion
7. Dibasic acid
g) phosphorous pentoxide (vii) least stable oxide of N2

1.
2.
3.
4.
5.
6.
7.

8.
9.
10.

6. Multiple Choice Questions with only one answer

Sodium nitrate decomposes on heating to give
1) N2
2) O2
3) NO2
4) Na2O
By heating a mixture of ammonium sulphate and sodium nitrate we get
1) ammonium nitrate 2) NaNH4SO4
3) nitrogen 4) nitrous oxide
The compound which gives a mixture of two gases on heating
1) NaNO3
2) NH4NO2 3) Pb(NO3)2
4) NH4NO3
Nitrous oxide is prepared in the laboratory
1) combination of nitrogen and oxygen
2) reduction of NO
3) reduction of nitric acid
4) thermal decomposition of NH4NO3
Which of the following is used to dry ammonia
1) conc.H2SO4
2) CaO
3) P2O5
4) anhydrous CaCl2
Explosive hydride of nitrogen
1) N3H
2) N2H4
3) NH3
4) N4H4
It is recommended that ammonia bottles be opened after cooling in ice for some time. This is
because
1) it brings tears to eyes
2) it has high vapour pressure
3) it is corrosive liquid
4) it is mild explosive
Which one of the following is not an acid salt
1) Na.H2PO2 2) NaH2PO3 3) NaH2PO4 4) Na2HPO4
When NH4OH is added to copper sulphate solution blue colour is obtained due to the formation of
1) Cu(NH3)4SO4
2) Cu(NH4SO4)2
3) Cu(OH)2 4) CuO
By adding P2O5 to HNO3
1) a precipitate of yellow colour is formed 2) phosphorous gets free
3) oxide of nitrogen is formed
4) ammonia is evolved

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15.
16.
17.
18.
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21.
22.
23.
24.
25.
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27.
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31.
32.
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Phosphorous is manufactured by heating in an electric furnace the mixture of
1) bone ash and coke
2) bone ash and silica
3) bone ash, silica and coke 4) bone ash, NaCl and coke
Nitrolim is obtained by passing nitrogen over
1) heated mixture of Al2O3 and carbon
2) calcium carbide
3) carborundum
4) heated aluminium
The gas that turns to brown when mixed with air
1) N2O
2) NO
3) N2O3
4) NO2
Which of the following is used as anaesthetic
1) NH3
2) N2O
3) NO
4) NO2
When ammonia is heated with CO2 under pressure, the product is
1) (NH4)2CO3
2) NH2CONH2
3) NH2COONH4
4) NH4HCO3
Percentage of nitrogen in urea is about
1) 70
2) 63
3) 47
4) 28
A white precipitate will be obtained by the hydrolysis of
1) PCl5
2) NCl3
3) BiCl3
4) AsCl3
When treated with nitric acid which of the following liberates hydrogen
1) Zn
2) Cu
3) Mg
4) Hg
The raw material for the manufacture of nitric acid by Birkland and Eyde method is
1) Ammonia 2) Air 3) nitrogen dioxide 4) chile salt petre
White phosphorous may be removed from red phosphorous by
1) sublimation
2) distillation 3) dissolving in CS2 4) heating with an alkali solution
White phosphorous reacts with caustic soda. The products are PH3 and NaH2PO2. The reaction is
an example of
1) oxidation 2) reduction 3) neutralization
4) both oxidation and reduction
The least basic halide of nitrogen
1) NF3
2) NCl3
3) NBr3
4) NI3
The bonds present in N2O5 are
1) only ionic 2) only covalent
3) covalent and coordinate 4) covalent and ionic
Concentrated nitric acid oxidizes cane sugar to
1) CO2 and H2O
2) CO and H2O
3) CO, CO2 and H2O 4) Oxalic acid and water
Skin becomes yellow in conc. HNO3 because
1) proteins are converted in to xnthoproteins
2) HNO3 acts as a dehydrating agent
3) Nitrocellulose is formed
4) HNO3 acts as an oxidizing agent
Nitrates of all metals
1) insoluble in water 2) soluble in water 3) unstable 4) coloured
Which oxide of nitrogen forms a brown coloured complex with Fe(II) ion
1) N2O
2) NO
3) N2O3
4) NO2
Red phosphorous is made by heating white phosphorous in the presence of an inert gas at
temperature
1) 60oC
2) 200oC
3) 240oC
4) 100oC
When phosphine is bubbled through a solution of silver nitrate is precipitated
1) silver
2) silver phosphide 3) silver oxide
4) none
PH3 produces smoky rings when it comes in contact with air. This is because.
1) it is inflammable 2) it combines with water vapour
3) it combines with nitrogen 4) it contains impurity of P2H4
Which gas is obtained when urea reacts with nitrous acid
1) N2
2) NO
3) N2O
4) NO2
Nitrogen percentage is the highest in fertilizer
1) ammonium sulphate
2) CAN
3) Urea
4) Calcium cyanamide
Which of the following properties of white phosphorous are shared by red phosphorous
1) it phosphorescences in air 2) it burns when heated in air

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4) it reacts with NaOH to give PH3

34.
35.
36.
37.
38.

39.
40.
41.

42.
43.
44.
45.
46.
47.
48.
49.
50.
51.

52.
53.

3) it dissolves in CS2
Arsenic is detected by
1) ring test 2) Lucas test 3) Lake test 4) Marsh test
Liquid ammonia is used as refregirant because
1) it has high dipolemoment 2) it has high solubility in water
3) of its basicity
4) it has high heat of evaporation
The yellow colour often shown by nitric acid can be removed by
1) bubbling air through warm acid 2) boiling the acid
3) passing ammonia through acid 4) adding little Mg powder
Which of the following nitrogen oxide is mixed anhydride of nitrous and nitric acids.
1) NO
2) N2O3
3) NO2
4) N2O5
Which of the following nitrogen oxide is a white solid
1) NO
2) NO2
3) N2O3
4) N2O5
PCl5 is kept in well stoppered bottles because
1) it is highly volatile
2) it reacts readily with moisture
3) it reacts with oxygen
4) it is explosive
Anhydride of HPO3 is
1) P2O3
2) P2O4
3) P2O5
4) PO3
Phosphate + conc. HNO3 + (NH4)2Mo O4 soln. yellow precipitate. The composition of yellow
precipitate is
1) (NH4)3PO4.Mo O3
2) (NH4)3PO4.12Mo O3 3) (NH4)2PO4.12Mo O3 4)
NH4PO4.Mo O3
Which of the following can not be used as a phosphatic fertiliser
1) super phosphate of lime 2) phosphatic slag
3) ammonium
phosphate 4) phosphorite mineral
Concentrated nitric acid reacts with iodine to give
1) HI
2) HOI
3) HOIO2 4) HOIO3
Which of the following is a tetrabasic acid
1) hypophosphorous acid
2) orthophosphoric acid
3) metaphosphoric acid
4) pyrophosphoric acid
Nitrous anhydride is
1) NO
2) N2O3
3) N2O4
4) N2O5
Covalency of nitrogen in nitric acid is
1) 0
2) 3
3) 4
4) 5
When concentrated nitric acid is heated it decomposes to give
1) oxygen and nitrogen
2) nitric oxide
3) oxygen 4) nitrogen
dioxide and oxygen
In P4O10 the number oxygen atoms bonded to each phosphorous atom is
1) 2.5
2) 3
3) 4
4) 5
When Bismuth chloride is poured into large volume of water, the white
precipitate produced is
1) Bi(OH)3 2) Bi2O3
3) Bi2Cl8
4) BiOCl
When ammonia is passed over heat CuO it is oxidized to
1) HNO2
2) N2O
3) N2
4) NO2
The CN- ion and N2 are isoelectronic. But in contrast to CN-, N2 is chemically
inert because of
1) low bond energy
2) absence of bond polarity 3) unsymmetrical
electron distribution
4) presence of more number of electrons in bonding orbitals
Which oxide does not act as reducing agent
1) NO
2) NO2
3) N2O
4) N2O5
Which of the following has three electron bond in its structure

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55.
56.
57.
58.

59.
60.
61.
62.
63.
64.
65.

66.
67.
68.

69.
70.

71.
72.

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1) nitrous oxide 2) dinitrogen trioxide 3) nitric oxide
4) nitrogen
pentoxide
Mixture used in Holmes signal is
1) CaC2 and CaCl2
2) CaCl2 and Ca3P2
3) CaC2 and C3N2 4) CaC2 and
Ca3P2
Blasting of TNT is done by mixing
1) NH4Cl
2) NH4NO3 3) NH4NO2 4) (NH4)2SO4
The number of hydroxyl groups in pyrophosphoric acid is
1) 3
2) 4
3) 5
4) 7
The order of the boiling points of V th group hydrides is
1) NH3 > PH3 > AsH3 > SbH3 2) PH3 < AsH3 < SbH3 < NH3
3) PH3 > AsH3 > SbH3 > NH3 4) NH3 < PH3 < AsH3 < SbH3
Nitrogen can be purified from the impurities of oxides of nitrogen and
ammonia by passing through
1) a solution of K2Cr2O7 acidified with H2SO4
2) concentrated HCl
3) alkaline solution of pyrogallol
4) a solution of KOH
Which does not give ammonia with water
1) Mg3N2
2) AlN
3) CaCN2
4) Ca(CN)2
Sodium nitrate on heating with zinc dust and sodium hydroxide gives
1) NaNO2
2) NH3
3) NO2
4) N2O
Which one of the following is used as anaesthetic
1) NH3
2) N2O
3) NO
4) NO2
The best absorbent for ammonia is
1) water 2) H2SO4 3) NaO
4) NaOH
When SO2 reacts with nitrous acid the compound formed is
1) H2S
2) S
3) SO3
4) H2SO4
The Nesslers reagent contain the ion
1) Hg22+
2) Hg2+
3) HgI24) HgI42NH4Cl is used to clean metal surfaces because
1) it dissociates into NH3 and HCl on heating 2) NH3 forms a soluble
complex with metal
3)NH4Cl forms a volatile chloride
4) none
The vapour density of NH4Cl is almost half the expected value because it
1) is a salt of a strong acid 2) sublimes on heating 3) dissociates
completely 4) none
In smoke screens calcium phosphide is used because it
1) catches fire easily 2) burns and gives soot
3) forms phosphine
which gives smoke 4) none
A glass tube containing molten antimony breaks upon solidification of
antimony due to
1) expansion
2) exothermic reaction 3) conversion of explosive antimony
4) none
Light blue colour of nitrous acid is due dissolved
1) O2
2) N2
3) N2O
4) N2O3
Bones glow in the dark because
1) they contain a shining material 2) they contain red phosphorous
3) white phosphorous changes into red phosphorous
4) white phosphorous undergoes slow combustion with air
NH3 gas can be collected by the displacement of
1) mercury
2) water 3) brine
4) conc. H2SO4
The decomposition temperature is highest for
1) AsH3
2) NH3
3) PH3
4) SbH3

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73.

Glacial phosphoric acid is

1) H3PO4 2) HPO3
3) H4P2O7 4) H3PO2
74. Which of the following coagulates white of an egg
1) orthophosphoric acid
2) metaphosphoric acid
3) hypophosphoric acid
4) pyrophosphoric acid
75. Fuming nitric acid is
1) conc. HNO3 + NO2 2) conc.HNO3 + NO3
3) conc. HNO3 + N2O3 4) conc. HNO3 + NO
76. Phosphine reacts with copper sulphate solution to form
1) copper 2) copper phosphide 3) copper phosphate 4) copper
phosphite
77. Which of the following is Schweitzers reagent
1) [Cu(NH3)4]SO4
2) [Ag(NH3)2]Cl 3) Cu(NH3)2Cl
4) K4[Fe(CN)6]
78. Which of the following acids possesses oxidizing, reducing and complex
forming properties
1) HCl
2) HNO2
3) H2SO4 4) HNO3
79. Pearl white is
1) BiOCl
2) SbOCl 3) NOCl
4) AsOCl
80. Ammonium salts are oxidized in the soil to nitrite by
1) denitrifying bacteria 2) nitrifying bacteria
3) ammonifying bacteria
4) nitrosifying bacteria
81. Rain water some times contain NH4NO3 because lightening in the sky causes
the air to react and produce oxides of nitrogen and
1) H2
2) NH3
3) CO2
4) noble gases
82. Antimony dissolves in aqua regia to yield
1) SbCl3
2) Sb2O5
3) SbCl5
4) antimony nitrate
83. Which of the following is strongest base
1) AsH3
2) SbH3
3) PH3
4) NH3
84. The basic oxide is
1) N2O5
2) P2O5
3) As2O5
4) Sb2O5
85. When phosphorous is heated with conc.HNO3 it reduces the acid to
1) NO
2) NO2
3) N2O3
4) N2O5
86. Which of the following statements regarding nitrogen molecule is not correct
1) amongst the homonuclear diatomic molecules of second period thebond
dissociation enthalpy is
maximum for nitrogen molecule
2) amongst the homonuclear diatomic molecules of second period, the bond
length is minimum for N2
molecule
3) Nitrogen molecule is paramagnetic in nature
4) Nitrogen reacts with metals and non metals at high temperatures forming
ionic and covalent nitrides
87. Which of the following statements regarding phosphorous is not true?
1) phosphorous belongs to group 15 of the periodic table
2) the element phosphorous is obtained by heating rock phosphite with coke
and sand in an electric
furnace at about 1700-1800k
3) the formula of phosphorous is P4
4) black phosphorous is the least stable form of all allotropes of phosphorous
88. Semiconducting form of phosphorous is
1) white
2) red
3) black
4) yellow
89. Which of the following statements regarding white phosphorous is not correct?
1) it is non poisonous
2) it glows in dark
3) it has low ignition temperature 4) it is powerful reducing agent

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90. Nitrosonium ion is isoelectronic with
1) NO
2) CO
3) NO2
4) CO2+
91. In the brown ring test of nitrate ion the compound formed is
1) [Fe(H2O)5NO]2+
2) [Fe(H2O)5NO]3+
3) [Fe(H2O)4(NO)2]2+
4) [Fe(H2O)3(NO)3]2+
92. Which of the following equations is not correctly formulated
1) concentrated HNO3 acquires yellow coloration due to the reaction 4HNO3
4NO2 + 2H2O + O2
2) Cu + 4HNO3(dil) Cu(NO3)2 + 2H2O + 2NO2
3) 4Zn + 10HNO3 4Zn(NO3)2 + 5H2O + N2O
4) P4 + 20HNO3 4H3PO4 + 4H2O + 20NO2
93. The volume of ammonia gas obtained when 6 dm3 of H2 reacts with excess of
nitrogen (all volumes measured at STP) would be
1) 2 dm3 2) 3 dm3 3) 4 dm3 4) 6 dm3
94. Which of the following statements regarding metaphosphoric acid is not
correct
1) it is also known as glacial phosphoric acid 2) it is a transparent liquid
3) it is a monobasic acid
4) it produces orthophosphoric acid
on treating with water
95. The anhydride of orthophosphorous acid is
1) P4O6
2) P4O8
3) P4O10
4) P2O4
96. Which of the following equations is not correctly formulated
1) P4O10 + 6H2O (cold) 4H3PO4 2) P4 + 20HNO3 I2 4H3PO4 + 20NO2 +
4H2O
3) PCl5 + 4H2O H3PO4 + 5HCl
4) Ca3(PO4)2 + 3H2SO4 3CaSO4 + 2H3PO4
97. Which of the following statements regarding pyrophosphoric acid is not
correct?
1) it is obtained by heating equimolar mixture of ortho and meta phosphoric
acid at 100oC
2) on boiling with water it produces orthophosphoric acid
3) on strong heating it produces orthophosphoric acid
4) it forms four series of salts eg:NaH3P4O7, Na2H2P4O7, Na3HP4O7 and Na4P4O7
98.

Phosphorous acid has

1) one hydrogen atom attached to phosphorous
2) two hydrogen atoms attached to phosphorous
3) three hydrogen atoms attached to phosphorous
4) no hydrogen atom attached to phosphorous
99. Which of the following statements regarding N2O4 is not correct?
1) the molecules of N2O4 is planar
2) the molecule of N2O4 contains
week N-N bond
3) in liquid N2O4, NOCl acts as a base
4) the dipolemoment of N2O4 is zero
100. Copper metal on treatment with dil. HNO 3 produce a gas A. A when passed through acidic
solution of stannous chloride a nitrogen containing compound B is obtained. B on reaction with
nitrous acid produces a gas C. Then C is
1) NO
2) NO2
3) N2O
4) N2
101. Arrange the following in decreasing order of bond angle NH3, PH3, NF3, PF3
1) NH3 > NF3 > PF3 > PH3
3) NF3 > NH3 > PH3 > PF3

102. P4O10 + PCl5 ?

2) NH3 > PF3 > NF3 > PH3

4) PH3 > PF3 > NH3 > NF3

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1) POCl3
2) PCl5
3) P4
4) PCl3
103.
BothNF3andNCl3arecovalentbuttheydifferintheextentofhydrolysisbecause:
1)NF3ismorestablethanNCl3andhydrolysisproductofNF3,thatisHFO,doesnotexist
2)dipolemomentofNF3isgreaterthanthatofNCl3
3)electronegativityofFisgreaterthanthatofCl
4)Clcanexpanditsoctetbyusingdorbitals
d p bondingisshownin:
104.
1) NO3 , NO2 , N3 ,CN
3) NH3 , PH3 , BiH3

1.
2.
3.
4.

5.
6.
7.
8.
9.
10.
11.
12.
13.

14.
15.

2) P2 O3 , P2O5 , PO34
4) CO, NO, CO2 , NO2

7. MULTIPLE CHOICE QUESTIONS WITH MORE THAN ONE

ANSWER
White phosphorous (P4) has
1) six P-P single bonds
2) four P-P single bonds
3) four lone pairs of electrons
4) PPP angle of 60o
Ammonium nitrate
1) is a fertilizer 2) is an explosive
3) gives N2O on heating
4)
gives N2 on heating
Which of the following is/are acid salt
1) NaH2PO2 2) NaH2PO3 3) NaH2PO4 4) Na2HPO3
When concentrated nitric acid is added to phosphorous pentoxide
1) nitric anhydride will be formed
2) nitrous anhydride will be formed
3) dehydration of nitric acid takes place 4) metaphosphoric acid will be
formed
Oxygen gas will be liberated along with an oxide of nitrogen, on heating
1) NaNO3 2) (NH4)2Cr2O7
3) Pb(NO3)2
4) AgNO3
The compounds which does not leave any residue on heating
1) NaNO3 2) NH4NO2 3) Hg(NO3)2
4) NH4NO3
The oxyacids of phosphorous that can be prepared by dissolving P4O10 in water
1) H3PO3 2) H3PO4 3) HPO3
4) H4P2O7
The oxyacids of phosphorous that can be prepared by heating orthophosphoric
acid
1) H3PO3 2) HPO3
3) H3PO2 4) H4P2O7
Ammonia cannot be dried by
1) H2SO4 2) P2O5
3) CaO(anhydrous)
4) CuSO4
Which are correct for N2O
1) laughing gas 2) nitrous oxide 3) not a linear molecule
4) good
supporter of combustion than air
(NH4)2Cr2O7 on heating gives
1) Cr2O3
2) N2
3) H2CrO4 4) NH3
Which are correct statements
1) NO is heavier than air
2) the formula of nitrous anhydride is N2O5
3) N2 diffuses faster than NO
4) NH3 can be used as refrigerent
Nitrogen (1) oxide can be produced by the
1) thermal decomposition of NH4NO3
2) disproportionate of N2O4
3) thermal decomposition of NH4NO2
4) interaction of hydroxyl amine and
HNO3
NO2 can be obtained by heating
1) KNO3
2) Pb(NO3)2 3) Cu(NO3)2 4) AgNO3
Ammonia, on reaction with hypochlorite anion, can form
1) NO
2) NH4Cl
3) N2H4
4) HNO2

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16.

Identify the correct statements?

1) The hydrolysis products of BiCl3 are BiOCl and HCl

2) Red P4 is less volatile than white P4

3) Reducing properties of Hypo phosphorous acid is due to O-H bonds

4) Hypo phosphoric acid has one P-O-P bond
17. Inthefollowingstatements,selectthecorrectstatement:
1) N CH3 3 haspyramidalstructure
2) N SiH3 3 showsplanararrangement
3)SiCishighlyvolatile
4)SiO2iscalledsilane
18. cantbeobtainedby
1)heatingof NH 4 NO3 or NH 4 NO2
2)heatingof NH 4Cl or NH 4 2 CO3
3)heatingof NH 4 NO3 withNaOH4)reactionofAlNorMg3N2orCaCN2withH2O
Assertion (A) & Reason (R) type questions
1) Both A and R are true and R is correct explanation of A
2) Both A and R are true and R is not correct explanation of A
3) A is true but R is false
4) A is false but R is true
1.
Assertion (A) : The B.P of NH3 is greater than BiH3
Reason (R) : NH3 is associative liquid due to H-bonds
2.

Assertion (A) : H3PO4 is also known as glacial phosphoric acid

Reason (R) : H3PO4 on strong hearing gives P4O10