Chemistry Test Series IV

2
Part-A
1.
What is the remainder when 163 + 173 + 183 + 193 is divided by 70?
(a) 0
2.
(b) 1
(b) 5
(b) 1
(b) 1kg
(b) 2 hours
(b) 6, 1
(b) 50 ft
(b) a/bc
(d) 4 hours
(c) 7, 1
(d) 2, 7
(c) 55 ft
(d) 49.5 ft
(c) abc/60
(d) bc/60a
(b) 200 kg
(c) 300 kg
(d) 400 kg
(b) 5
(c) 25
(d) 4
The value of 16log 4

(a) 16
11.
(c) 3 hours
Fresh grapes contain 68% water and dry grapes contain 20% water. How much fresh grapes are required
to obtained 80kg of dry grapes
(a) 100 kg
10.
(d) 3kg
From a leaking tab a drop come out in b minutes. If there are c drops in a liter, then in how many
hours one liter of water will be wasted
(a) 60 a/bc
9.
(c) 2kg
Manufacturer of a tennis ball anounced that their new ball is best in the market. If one were drop it from
any height, it would only rise to the extent of 10% of the height from which it was dropped. If the ball was
dropped 45 feet, how much would the ball travel before coming to rest.
(a) 45 ft
8.
(d) None of these
Rishabh and Richa solved a quadratic equation. In solving it, Rishabh made a mistake in the constant term
and got the roots as 6 and 2. While Richa made a mistake in the coefficient of x only and obtained the
roots as 7 and 1. The correct roots are
(a) 6, 7
7.
(c) 6
There are two candles of equal length and of different thickness. The thicker one lasts for 6 hours. The
thinner one lasts two hour less than the thicker one. Radha lights the two candles at the same time when
she went to bed, she saw the thicker one is twice the length of the thinner one. How long ago did Radha
light the two candles?
(a) 1 hour
6.
(d) 1
A king ordered that a golden crown be made from him from 8kg of gold and 2kg of silver. The goldsmith
took away some amount of gold and replaced it by an equal amount of silver and the crown when made,
weighed 10 kg. The king knew that under water gold lost 1/20th of its weight while silver lost 1/10th. When
crown was weighed under water, it was 9.25 kg. How much gold was stolen by the goldsmith
(a) 0.5kg
5.
(c) 0
Begin write positive integers (in decimal notation) sequenctly what is the 1000th digit written?
(a) 0
4.
(d) None of these
What is the remainder when 1527 + 2327 is divided by 19?

(a) 12
3.
(c) 69
Given that f ( y ) | y | / y and q is an non-zero real number. The value of | f ( q) f ( q ) | is

(a) 0
(b) 1
(c) 1
(d) 2
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3
12.
In the figure ABC / 2 and AD = 4DE = 2EB. What is the ratio of the area of CDE to that of
ABC .
C
(a) 1 : 3
13.
(b) 2 : 5
15.
(b) a 3
(c) a
3 1
(c) 60 to vertical
(d) 75 to vertical
(d)
2 1
5 kg of adulterated rice has 2% stones in it and the rest is rice. Half of the stone content was removed.
Now the percentage of stone content in it is
(b) 1
(c) 1.1
(d) 1.01
Seven identical cubes are arranged in a close packed single layer. If the area of the layer is Q and volume
of the layer is R, then the number of cubes in the collection is
(b) Q3/R2
(c) R2/Q3
(d) Q/R
In a bag containing only blue, red and green balls such that all but 15 are blue, all but 13 are red and all
but 12 are green. How many are red
(b) 7
(c) 25
(d) 20
In a group if 60% of people drink tea and 70% drink coffee, what is the maximum percentage of people
drinking either tea or coffee but not both
(a) 100%
19.
(d) 1:7
(b) 45 to vertical
(a) 13
18.
(c) 1 : 5
(a) 30 to vertical
(a) R/Q
17.
A uniform cylindrical containers is half filled with water. The height of the cylinder is gradually tilted until the
water touches the brin. At this stant, the container is inclined at
(a) 0.99
16.
A vertical pole put on the ground such that it is situated with one of the legs on a semi circle of radius a.
A man on the top of the semi circle find the angular height of the top of the pole to be 60. The height of
the pole is
(a) a 2
14.
(b) 70%
(c) 30%
(d) 10%
Statement - Like a fool person, I have also decided to go by bus.

Conclusion - (I) I am a fool (II) I am not a fool.
(a) Only I
20.
(b) Neither I nor II
(c) Either I or II
(d) Both are true
(c) Either I or II
(d) Both I and II
I. Where there is fire there is smoge.

II. Where there is smoge, there is a fire
(a) Only I
(b) Only II
21.
Part-B
Which molecule is inactive for rotational spectrum?
(a) SF4
(b) BrF3
(c) Ozone
(d) Tetrachloroethylene
22.
The ESR spectrum of methoxymethyl radical will appear as

(a) A triplet of quartets
(b) A triplet of quentets
(c) A quartet of quartets
(d) A doublet of quartets
23.
The point group of the given molecules (consider them rigid in lowest energy conformation)
B
Bicyclo[1.1.1]pentane
(a) C3v and C2v respectively

(c) D3d and D2d respectively
24.
(b) D3h and D2h respectively

(d) C3h and C2h respectively
Suppose we put a delta function bump in the centre of infinite square well
a
H1 x where is constant
2
Then first order correction to the second excited state is:

2
2
a
(c)
(d)
a
a
2
The standard entropy of the molecules CH2Cl2 (g), CHCl3(g) and CH3Cl(g) is in increasing order is
(a) 0
25.
26.
0
0
0
(a) SCH 2Cl2 SCHCl3 SCH3Cl
0
0
0
(b) SCH 2Cl2 SCH3Cl SCHCl3
0
0
0
(c) SCH3Cl SCH 2Cl2 SCHCl3
0
0
0
(d) SCH3Cl SCH2Cl2 SCHCl3
The molar enthalpy of combustion of isobutane and n butane are 2869 kJ/mole and 2877 kJ/mole respectively at 298K and 1atm. The H for conversion of 1 mole of n butane to one mole of isobutane
(a)
27.
(b)
8kJ
mole
(b)
(c)
(b) I xx I yy I zz
2869kJ
mole
(d) I xx I yy I zz
The minimum potential difference needed to reduce Al2O3 at 500C. The free energy for the decomposition
reaction
is
(a) 2.5
(b) 3.3
G 965 kJ
(c) 1.6
(d) 4.3
In metal carbonyls, the metal and CO orbitals which overlap one another to form a -bond are respectively
(b) nb and nb
(a) d and
30.
(d)
(c) I xx I yy I zz
2
4
Al2 O3
Al O 2
3
3
29.
2877kJ
mole
For CH3I molecule the moment of inertia I xx , I yy , I zz are related by

(a) I xx I yy I zz
28.
8kJ
mole
(d) d and *
(c) d p
Which of the following complexes has higher value of CFSE excluding pairing energy?
(a) Mn H 2O 6
(b) Co H 2 O 6
(c) Ni H 2 O 6
(d) Fe CN 6
5
31.
Arrange the following ligands in the increasing order of acceptor ability?

(a) Phen < CO < R3P < CN < NO
(b) Phen < NO < R3P < CN < CO
(c) Phen < R3P < CN < CO < NO
(d) R3P < Phen < CN < CO < NO
32.
Which of the following complexes is the strongest reducing agent?

(a) Cu NH 3 4
(b) Co NH3 6
(c) Co CN 6
(d) Co H 2 O 6
33.
Which of the following peptides is formed when Ala-Ser-Thr-Lys-Gly-Arg-Gly is treated with trypsin?
(a) Ala-Ser-Thr-Lys (b) Ala-Ser-Thr
(c) Arg-Ser-Gly-Ala (d) Ala-Ser-Thr-Lys-Gly
34.
The enzyme nitrogenase catalyze the activation and reduction of dinotrogen to ammonia, the nitrogenase are
composed of two metalloproproteins which are commonly referred to as the Fe protein and the MFe (M =
Mo, V and Fe) co-factor. The Fe-protein commonly in the nitrogenase is
(a) Fe2S2
(b) Fe4S4
(c) dimer of Fe4S4
(d) Fe3S4
35.
The blue-colour of copper blue protein is caused by

(a) LMCT
(b) MLCT
(c) d-d transition
36.
(d) M M charge transfer
Which one of the following amino acids liberates ammonia on mild hydrolysis and then yields a different amino
acid
(a) Tyrosine
(b) Alanine
(c) Asparagine
(d) Hydroxyproline
NH2
cbz-Cl
COOH
37.
NaOH
OH
(A)
TBDMS-Cl
Imidazole
(B)
(i) LiAlH4
(C)
(ii)
, H+
O
The major product C in the above reaction sequence is

NHCbz
NHTHP
(a)
(b)
O
OCbz OTBDMS
OTBDMS
NHTBMS
NHCbz
(c)
(d)
TBDMSO
OTHP
Ph
Ph
Ph
OTHP OTHP
HCOOH
THF/H2O
38.
(A)
H2/Pdc
(B)
MeOOC
OH
The major product B in the above synthetic transformation is:
6
HO
NH2
Ph
HN
(a) MeOOC
Ph
(b)
MeOOC
OH
OH
NH2
NH2
(c) MeOOC
(d) MeOOC
OH
39.
OH
The correct relation between compound (A) and (B) are

OH
OH
O
HO
OH
OH
(A)
40.
OH
(B)
(a) Identical
(b) diastereomers
(c) enantiomers
The major product P in the following reaction is
Ph
(OC)5W
BBr3
(d) Homomers
OMe
Ph
Ph
(b) (OC)4W
(a) (OC)4(Br3B)W
BBr2
OMe
Br
41.
(c) (OC)5W C
(d) (OC)4(Br)W
Ph
Ph
Which of the following sandwich compound is diamagnetic in their ground state.
(a) Cp2V
(b) Cp2Cr
(c) Cp2Mn
(d) Cp2Fe
hv
42.
O
The above reaction takes place via

(a) Norish type-I
(b) Peterno bucchi
(c) Norish type-II
(d) di-pi methane rearrangement
7
Cl
Br
Ag+, H2O
43.
The major product P is:

OH
OH
Br
Br
Cl
(a)
(b)
Me
44.
OH
(c)
170C
Cl
(d)
Et
The product P is
Me
(a)
45.
Me
Et
(b)
Et
Et
(c) both (a) and (b)
(d)
(c)
(d)
Me
Which of the following compound is aromatic
(a)
(b)
O
(i) PhMgBr
46.
(ii) H+
The major product P in the following reaction is

Ph
Ph
(a)
(b)
O
47.
Ph
Ph
(c)
OH
(d)
O
When a mixture of acetaldehyde and excess HCHO is heated with alkali which of the following product is
produced
H
(a) H3C
CH2
OH
(b)
CHO
(c) C(CH2OH)4
(d) (H3C)2C
CH2
OH
8
O
(i) Li, NH3
48.
CH3
(ii) CH2=CHCH2Br
The product P is
O
OH
(a)
OH
(b)
OH
(c)
(d)
CH3
CH3
CH3
49.
The species among the following which can act as a Bronsted acid as well as a base is
50.
(a) H3O
(b) HCO3
(c) SO 24
(d) NH 4
A colourless gas X, forms a brown coloured gas when mixed with air. The gas X is:
51.
52.
(a) NH3
(b) NO
(c) N 2 O
(d) NO 2
All elements in the third period have
(a) Three complete shells
(b) Three complete sub-shells
(c) Three valence electrons
(d) Three electrons less than octet
A sample of radioactive I133 gave with a Geiger counter 2150 counts per minute at a certain time and 2055
counts per minute exactly one hour later. The half life period of I133 will be
(a) 10.11 Hrs
(b) 15.33 Hr
(c) 22.63 Hrs
(d) 33.24 min
53.
The decreasing order of the size of the void is

(a) Cubic > tetrahedral > octahedral > trigonal (b) Trigonal > tetrahedral > octahedral > cubic
(c) Trigonal > octahedral > tetrahedral > cubic (d) cubic > octahedral > tetrahedral > trigonal
54.
The CsCl structure is observed in alkali halides only when the radius of the cation is sufficiently large to keep its
eight nearest neighbours anion from touching. The minimum value of r / r needed to prevent this contact will
be
(a) 0.155
(b) 0.225
(c) 0.414
(d) 0.732
55.
The coefficient of viscosity of a solution and its solvent respectively and 0 . The specific viscosity sp may
be expressed as
(a)
0
0
0
56.
The B.E.T adsorption, the value of K1 and KL were found to be 1.5 unit and 0.5 unit respectively. The value of
B.E.T. constant is
(a) 0.75
(b) 3
(c) 0.33
(d) None of these
57.
There are two solids X and Y and they dissociate into gas products as follows:
(b)
B g D g ;
X s

k P1 400
E g D g ;
Ys
k P2 800
(c)
(d)
At a fixed temperature, the pressure over excess solid X only is 40 atm and that over solid Y only is 60 atm.
The pressure over the solid pressure is
(a) 11.547 atm
(b) 23.094 atm
(c) 34.641 atm
(d) 69.282 atm
9
58.
2C D
Consider the equilibrium, 3A B
At equilibrium, the concentrations of A, B and C were observed 0.03, 0.01 and 0.006 molelitre1 respectively.
The initial concentration of A would have been
(a) 0.003
(b) 0.001
(c) 0.009
(d) 0.039
Cl
59.
II
III
Cl
Cl
Above molecules undergo reaction in the presence of base. Rate of reaction follows the order
(a) I > II > III
(b) III > II > I
(c) II > III > I
(d) II > I > III
CH3
60.
BF3
NaCN
OH
H3C
Et
CH3
CH3
(a)
CN
H3C
H3C
Et
61.
H3C
(b) NC
Cl
D
Et
Et
(a)
(b)
Ph
(c)
Ph
(d)
CH(CH3)(Et)
Et
CH(CH3)(Et)
Et
H3C
CH(CH3)(Et)
Et
Ph
Et
Ph
H3C
(d) None of the above
NH2/
Ph
(c) both (a) and (b)

Et
CH(CH3)(Et)
O
H
62.
KH/H2O
OH
OH
Me
(a)
(b)
(c)
HO
CH3
(d)
HO
Me
10
O
H2SO4
63.
D
Ph
OH
(a)
OH
(b)
(c)
Ph
64.
OH
Ph
OH
Ph
(d)
Ph
(c) Tb3
(d) Eu 3
Which of following ion has highest magnetic moment?

(a) Er 3
(b) Ho3
65.
Volume of water needed to mix 10 ml, 10N HNO3 to get 0.1 N HNO3?
(a) 990 ml
(b) 1020 ml
(c) 1010 ml
(d) 1000
66.
The increasing order of acidic strength of following acids

HNO3, HBr, H2SO4, HCl, HClO4 in water
67.
(a) HClO 4 HBr H 2SO 4 HCl HNO3
(b) HNO3 HCl HClO 4 H 2SO 4 HBr
(c) HClO 4 H 2SO4 HBr HCl HNO3
(d) None of the above
If fundamental vibrational frequency of F2 is 2.6761013 Hz, find out the vibrational partition function for F2 at
25C
(a) 2.31
68.
(b) 1.03
(c) 3.01
(d) 3.21
Consider the following

List-I
List-II
Order of reaction Half life time
(A) 2
(i)
0.693
k
(B) 1
(ii)
a
2k
(C) 3
(iii)
1
ak
3
2a 2 k
The correct match of the half lives with the order of reaction will be
(a) A-(iii), B-(iv), C-(i), D-(ii)
(b) A-(iii), B-(i), C-(iv), D-(ii)
(c) A-(iv), B-(i), C-(ii), D-(iii)
(d) A-(iv), B-(i), C-(iii), D-(ii)
(D) 0
(iv)
11
69.
For the reaction P Q R

S , experimental data for the measured initial rates is given below..
Expt. Initial conc. P Initial conc. Q Initial conc. R
M
M
M
1
2
3
4
0.2
0.4
0.4
0.1
0.5
0.5
2.0
0.25
Initial rate
Ms
1
8.0 105
3.2 104
1.28 10 3
4.0 10 5
0.4
0.4
0.4
1.6
The order of the reaction with respect to P, Q and R respectively is:

(a) 2 2, 1
(b) 2, 1, 2
(c) 2, 1, 1
(d) 1, 1, 2
70.
In an NMR experiment, the relative population difference N/N for 13C nuclei in the magnetic fields of (a)
0.5 T, (b) 2.5 T and (c) 15.0T at a temperature of 298K are in the ratio:
(a) 1 : 5 : 30
(b) e1 : e5 : e30
0.5/298
2.5/298
15/298
(c) e
:e
:e
(d) 30 : 5 : 1
Part-C
71.
Treatment of the unsaturated acid A with the reagents shown gives an unstable compound B which is converted
into stable compound C by treatment with base. The spectral data for compound C are as follows: IR: 1775,
1645 cm-1; H NMR: 4.18 (2H, s), 5.00 (2H, s), 6.18 (1H, s).
What are the structures of B and C?
Me
Br2
CO2H
Me
(PhCO2)2
Br
base
C5H6Br2O2
C5H5BrO2
C
B
Br
Br
Br
(a) Br
COOH
(b)
And
COOH
And
O
Br
Br
(c)
72.
Br
Br
(d)
Br
COOH And
O
COOH
And
A compound used as a moth repellant has three molecular ion peaks at m/z =146 (100%), 148 (65%) & 150
(10%) amu in its mass spectrum. A pair of smaller peaks are seen at m/z=111 (34%) & 113 (11%). The
infrared spectrum shows sharp absorption just above 3000 cm-1 region, and also at 1480 cm-1. The 1H nmr
shows a single sharp signal at = 7.2 ppm, and the 13C nmr has two signals ( =133 & 130 ppm ).
Cl
Cl
F
F
(a)
Cl
(b)
(c)
(d)
CH3
F
Cl
12
73.
74.
75.
76.
Which is the incorrect irreducible representation for D 3h point group?
D3h
E 2C3
3C 2
2S3
3 v
a
b
c
d
1 1
2 1
1
0
1
2
1
1
1
0
1 1
2 1
The Mullikan symbols for the correct irreducible representations in Q.73 are
(a) A '1 , A '2 and E ' respectively
(b) A '2 , E" and A '1 respectively
(c) A '2 , E ' and A"1 respectively
(d) E ', A"1 and E" respectively
The activity of liquid water at 9.3 bar pressure and TR is

[Given R = 0.083 litre bar/k-mole, TR = room temperature]
(a) e 18/TR
(b) e18/TR
(c) e 1.8/TR
(d) e1.8/TR
The wavefunction corresponding to energy = 0.618 of Butadiene. According to the Huckel orbital theory
is
(a) 0.3717 2pz1 0.6015 2pz 2 0.6015 2pz 3 0.317 2pz 4
(b) 0.6015 2pz1 0.3717 2pz 2 0.3717 2pz 3 0.6015 2pz 4
(c) 0.6015 2pz1 0.3717 2pz 2 0.3717 2pz 3 0.6015 2pz 4
(d) 0.3717 2pz1 0.6015 2pz 2 0.6015 2pz 3 0.3717 2pz 4
77.
p2
H
V x is
The value commutator [H, x] for the quantum mechanical hamiltonian
2m
(a)
78.
x '
i
(b)
4 x '
i
(a) e1
(Given that for electron
(b) e2
(d)
x '
2i
(c) e3
2
38 103 eV nm 2
2m
(d) e4
The frequencies of the first few vibronic transition to an excited electronic states are
Vibronic transition
obs / cm 1
0 0
39699.10 cm1
0 1
40786.8 cm1
41858.9 cm1
02
The value of e is
(a) 1103.3 cm1
80.
2 x '
i
An electron of energy 1 eV is moving along the x-axis where it encounters a 0.2 nm long region. Providing a
potential of 4.8 eV. The potential is zero everywhere else. The probability that the electron will go through this
region of higher potential is:
79.
(c)
dx
x
'
dt
(b) 2103.3 cm1
(b) 2206.6 cm1
(d) 4206.6 cm1
The EMF of concentration cell without EMF is

Cd | CdSO 4 s | PbSO 4 a1 | Pb | PbSO 4 a 2 | CdSO 4 s | Cd
RT a 1
RT a 2
(a) E F ln a
(b) F ln a
2
1
2RT a 1
(c) F ln a
2
2RT a 2
(d) F ln a
1
13
81.
The electron transfer reaction in the following reaction takes place via
2
Co NH 3 6 Fe CN 5 H 2 O
(a) Inner sphere mechanism
(c) Outer sphere mechanism
82.
Co H 2O 6
Fe CN 5 H 2 O
(b) Inner sphere mechanism without ligand transfor

(d) Either inner sphere or outer sphere mechanism
Which of the following substances show substaintal Jahn Teller distortion

2
(a) Cr H 2 O 6 , Cu H 2 O 6 , MnF2
(b) Cr H 2 O 6 , Cu H 2 O 6 , CrF2
2
(c) Mn H 2 O 6 , Cr H 2 O 6 , Cu H 2 O 6
2
(d) Ni H 2 O 6 , Cr H 2O 6 , Cu H 2 O 6
83.
Which of the following pairs of complexes shows labile and inert complexes respectively
(a) Co H 2O 6
(c) Co H 2O 6
84.
and Cu H 2 O 6
and Co H 2 O 6
(b) Cr H 2 O 6
(d) Ti H 2 O 6
and Co H 2 O 6
and Cr H 2 O 6
Lowest energy transition for CrF6 is

(a) 3 T2g 3 A 2g
(b) 3 T2g 3T1g
(c) 4 A 2g 4 T1g
(d) 4 T2g 4 A 2g
85.
Consider the following statement about carbohydrates

(1) Br2/H2O can be used to differentiate from a ketone
(2) All monosaccharides, whether aldose or ketose are reducing sugars
(3) Osazone formation destroys the configuration about C2 of an aldose, but does not affect the configuration
of the rest molecules.
(4) A pair of diastereomeric aldose with differ only in configuration about C2 is termed as pair of anomers.
Which of the above statements are correct
(a) 1, 3 and 4
(b) 2 and 4
(c) 1 and 4
(d) 1, 2 and 3
86.
Which of the following statements about hemoglobin is not true

(a) There is a H-bonding between an imidazole NH of a histidine and bound O2 group.
(b) In the deoxy form, the Fe(II) atom is in the high spin state and less about 0.5 out of the heme plane in the
direction of the histidine group.
(c) The dioxygen unit is bound in a bent fashion similar to the 2 superoxo type.
(d) Hemoglobin an 2 2 heterotetramer that binds O2 co-operatively, is found in red blood cells.
O
87.
HIO4
(A)
The major product B in the above reaction sequence is
HO
CH2
(CH2)4
Br2/H2O
(B)
(a) HCHO 3HCOOH CH 3COOH
(b) 3HCHO 2HCOOH CO2
(c) HCHO 3HCOOH OHC COOH
(d) 4HCOOH OHC COOH
14
O
88.
Ph
O
N
1. NaHMDS
or LDA
2. S
(P)
Ph
Ph
3. LiOH/H2O2
The major product P in the above reaction is
O
(a) Ph
Ph
OH (c) O
OH (b) Ph
NH2
OH
OH
(d) Ph
N
O
Ph
OH
Ph
OH
O
I
NH
CO2Me
N
89.
cat. Pd(OAc)2
Ph3P, Et3N
dioxane, 85C, 3h
HO
LiAlH4
78C
(P)
HO
The major product in the above reactions

O
HO
NH
N
HO
NH
(a)
(b)
HO
HO
HO
HO
NH
N
O
(c)
H3C
H3C
NH
(d)
O
H3C
H3C
15
90.
Consider the potential energy diagram for reaction about the C(2)C(3) bond in n-butane
c
6.9 kcal/mole
3.4
P.E.
b
0.6 kcal/mole
60
120
180
240
300
360
Torsion angle (degrees)
91.
The energy difference between partically eclipsed and skew conformation in kcal/mole is
(a) 2.8
(b) 2.9
(c) 3
(d) 5.4
When Fe(CO)5 is refluxed with cyclopentadiene compound (A) is formed which has the empirical formula
C8H6O3Fe and complicated 1H NMR spectrum has been observed. The compound A readily loses CO to
give compound B with two 1H NMR spectrum, one at negative chemical shift and one at around 5ppm,
subsequent heating of B results in the loss of H2 and the formation of a new compound C. Compound C has
single 1H NMR resonance and the empirical formula C7H5O2Fe compound A C obeys the 18 electron
rule.
Consider the above statements and data, which of the following statement is/are true about the compounds
AC
(a) Compound A has Cp in 3 -mode and no MH bond
(b) Compound B has Cp in 3 mode and having MH bond.
(c) Compound C has two MM bond and two Cp in 5 mode.
(d) Compound A has Cp in 3 mode and having MH bond.
92.
CF3I
Na Hg
The major product P in the given reaction is Co 2 CO 8
O
P
(a) Co CO 4 CF3
(b) Co CO 5 CF3
(c) Co CO 4 F
(d) Co CO 4 I
hv
93.
CH3
The major product P is:
(a)
OH
(b)
(c)
O
(d)
O
OH
16
O
94.
+ Cl2HC C
Cl
(i) Et3N,
(ii) Zn/CH3COOH
The product P is
(a)
O (c)
(b)
Cl
(i) MeLI
95.
(d)
Cl
Cl
Cl
Cl
(ii) PCC
O
The major product P is

O
O
Me
(a)
(b)
(c)
Me
96.
(d) No reaction
Me
The major product formed in the following reaction sequence is

1. m-CPBA
2. BF3.Et2O
OH
O
OH
(a)
97.
(b)
(c)
(d)
, unsaturated curboxlic acid X with I2 and NaHCO3 gives

OH
O
X
O
(a)
(b)
O
98.
(c)
(d)
O
O
The oxidising power of per halates follows the order

(a) ClO 4 BrO 4 IO 4
99.
(b) ClO 4 BrO 4 IO 4
(c) ClO 4 BrO 4 IO 4

(d) ClO 4 IO 4 BrO 4
Which one of the following bonds pattern is present in silicones
(a) Si O Si O Si
(b) Si C Si C Si C
(c) Si C Si O Si
(d) Si Si Si Si
17
100.
The first ionization potential in electron volts of nitrogen and oxygen atom are respectively given by
(a) 14.6, 13.6
(b) 13.6, 14.6
(c) 13.6, 13.6
(d) 14.6, 14.6
101.
In a sample of pitchblende the ratio of Pb 206 : U 238 0.3 :1 by weight. If the distintegration constant of U238 is
1.331010 per year and all Pb is supposed to be originated from uranium, the age of the mineral would be
(a) 1.35 109 yrs
(b) 4.12 109 yrs
(c) 2.24 109 yrs
(d) 6.14 109 yrs
102.
When X-rays from a palladium target having a wavelength of 58.1 pm are used, the (200) reflection of sodium
chloride occurs at an angle of 6.80. The density of sodium chloride is (Given: sin 6.80 ]= 0.1184)
(a) 3.999 g cm3
(b) 3.288 gcm3
(c) 3.999103 kg cm3 (d) 3.288103 kg m3
103.
Consider a polymer sample with

Number of molecules Mass
10
1000
50
2000
40
5000
The polydispersity index (P.D.I) of the sample is

121
31
1210
103
103
(b)
(c)
(d) None of these
31
121
961
In langmuir adsorption of a gas onto a solid surface the values of slope and intercept were found to be 40 pa
cm3 and 4 cm3 respectively. The value of distribution coefficient is:
(a) 0.5 Pascal
(b) 0.1 Pascal
(c) 0.5 Pascal1
(d) 0.1 Pascal1
The decomposition of PCl 5 into PCl3 and chlorine gas can be represented by the equilibrium
(a)
104.
105.
PCl3 g Cl2 g
PCl5 g
106.
For this equilibrium, the value of the equilibrium constant Kp was found to be Kp = 0.404. If the total pressure
at equilibrium was found to be 3.0 atm, the volume per cent of chlorine at equilibrium will be
(a) 25.5%
(b) 33.3%
(c) 45%
(d) 47%
2
The degree of dissociation of acetic acid in a 0.1 M solution is 1.1110 . The Ka value of the acid is
(a) 1.2459105
(b) 3.2459105
(c) 12.459105
(d) 5.2459105.
OH
NaN3
H
Et
107.
H3C
OTs
CH3
Et
Et
HO
HO
CH3
(a)
H3C
CH3
(b)
H
N3
CH3
CH3
CH3
HO
HO
Et
(c)
H3C
N3
N3
Et
(d)
H
CH3
N3
18
O
(i) NaOEt
NO2
108.
(ii) Zn/AcOH
Intermediate
[I]
OEt
I and P are
O
O
O
and
OEt
(a)
OEt
(b)
and
N
O
NH2
NH2
NH2
and
(c)
OEt
OEt
(d)
and
N
O
OEt
NH2
OTs
NH2NH2
109.
O
(A)
KOH
(B)
P-TsOH
A and B are
OTs
and
(a)
NNH2
NNH2
and
(b)
O
OTs
OTs
and
(c)
NNH2
NNH2
and
(d)
O
19
O
CH3
Ph
EtO
110.
CH2
CF3
OEt
NaH
H
O
CH3
CH3
Ph
Ph
(a)
H
F3C
(b)
CF3
F3C
O
H
CH3
CH3
Ph
Ph
H
(c) H
(d)
F3C
F3C
CF3
KH
111.
+ Ph
H
OH
(a)
H
CH3
ReRe
and Ph
CH3
OH
O
(b)
H
CH3
and Ph
ReSi
CH3
OH
(c)
CH3
H
and Ph
ReRe
CH3
OH
(d)
CH3
H
and Ph
ReSi
CH3
20
conc. HNO3
112.
Conc. H2SO4
NO2
NO2
(a)
(b)
(c)
(d)
NO2
NO2
113.
Ion exchange methods which of following pair undergo elution first?

(a) Ce3 , Pr 3
114.
(b) Sm3 , Gd 3
(c) Lu 3 , Tm3
(d) Dy3 , Ho3
Proton affinity of compounds are given

Proton Affinity
PA
HOO
1573 kJ mol1
PAO 2 1476 kJ mol1

PA
CH3O
159 kJ mol1
The correct order of acidity

(a) CH 3OH H 2 O 2 H 2O
(b) H 2 O H 2 O2 CH 3OH
(c) on the basis of PA of ions acidic strength can not be determined.
115.
(d) CH 3OH H 2 O H 2 O 2 (since it is an exceptional case)

A system consisting of 7 atoms of A and 5 atoms of B. If two identical containers having same system as
described, are joined together, the total partition function of the combined system ca be given as
4075q 7A q5B
(a)
7 5
116.
4035q 7A q5B
(b)
7 5
(c)
35 q 7A q5B
7 5
4096q 7Aq 5B
(d)
7 5
X
Y
For the reversible reaction,
k2
t 0
tt
a
ax
0
x
the integrated rate law is given by
1
k1 k 2 t
(I) X t a k k k 2 k1 e
1 2
1
k1 k 2 t
(II) X t a k k k1 k 2 e
1 2
1
(III) X t a k k
1 2
(a) I only
1
k1 k 2 t
(IV) X t a k k k1 k 2 e
2 1
(c) II and IV
(d) All are correct.
k1 k 2 t
k 2 k1 e
(b) III only
21
117.
For the enzyme catalysis, Michaelis-Menten suggested the following, mechanism

k'
ES
E S
k
1
k1"
ES P E
with 2.9102sec1 as the rate constant for the product formation, 2.4101 sec1 as the rate constant for
the dissociation of the enzyme substrate complex into enzyme & substrate and 5.5101 mol1ltr sec1 as
the rate constant for the formation of the enzyme substrate complex.
The value of the Michaelis-Menten constant (in mol ltr1) will be
(a) 0.2724
(b) 0.4890
(c) 0.7729
(d) None of these
118.
Given that the information that

Cu 2 2e Cu
E 0 0.35
Cu e Cu
E 0 0.52
Cu 2 Cl e CuCl
E 0 0.54
The value of Ksp for CuCl is
(a) 10+6
(b) 106
(c) 1.6107
119.
The formula for the standard deviation for a set of small sample of n measurements is
1
2
x i
(a) i 1
N 1
120.
(d) 1.6107
N
xi x
i 1
(b)
N 1
xi
i 1
(c) N N 1
N
2
xi
i 1
(d) N N 1
A system consists of gaseous H2, O2, H2O and CO2 where the amount of CO2 is specified and the equilibrium
2H 2 O g is known. The number of degrees of freedom of
constant for the reaction 2H 2 g O 2 g
the system is
(a) 2
(b) 3
(c) 4
(d) 5
22
Chemical Sciences Test Series-IV
Date: 07-12-2013
ANSWER KEY
PART-A
1. (a)
2. (c)
3. (d)
4. (d)
5. (c)
6. (c)
7. (c)
8. (a)
9. (b)
10. (c)
11. (d)
12. (d)
13. (c)
14. (c)
15. (d)
16. (b)
17. (b)
18. (b)
19. (c)
20. (b)
21. (d)
22. (a)
23. (b)
PART-B
24. (c)
25. (c)
26. (b)
27. (b)
28. (a)
29. (d)
30. (b)
31. (c)
32. (c)
33. (a)
34. (c)
35. (a)
36. (c)
37. (c)
38. (c)
39. (c)
40. (d)
41. (d)
42. (a)
43. (c)
44. (c)
45. (b)
46. (a)
47. (c)
48. (d)
49. (b)
50. (b)
51. (b)
52. (b)
53. (d)
54. (d)
55. (c)
56. (b)
57. (d)
58. (d)
59. (c)
60. (c)
61. (b)
62. (d)
63. (a)
64. (b)
65. (a)
66. (d)
67. (b)
68. (b)
69. (c)
70. (a)
PART-C
71. (a)
72. (c)
73. (d)
74. (c)
75. (a)
76. (b)
77. (a)
78. (d)
79. (a)
80. (b)
81. (c)
82. (b)
83. (c)
84. (d)
85. (d)
86. (c)
87. (c)
88. (b)
89. (a)
90. (a)
91. (d)
92. (d)
93. (b)
94. (b)
95. (a)
96. (d)
97. (d)
98. (b)
99. (a)
100. (a)
101. (c)
102. (d)
103. (c)
104. (b)
105. (a)
106. (c)
107. (c)
108. (b)
109. (a)
110. (a)
111. (c)
112. (a)
113. (c)
114. (b)
115. (d)
116. (a)
117. (b)
118. (b)
119. (b)
120. (b)

Chemistry Test Series IV

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2

The value of 16log 4

(d) None of these

(d) None of these

What is the remainder when 1527 + 2327 is divided by 19?

Given that f ( y ) | y | / y and q is an non-zero real number. The value of | f ( q) f ( q ) | is

Statement - Like a fool person, I have also decided to go by bus.

(b) Neither I nor II

(d) Both are true

(d) Both I and II

I. Where there is fire there is smoge.

The ESR spectrum of methoxymethyl radical will appear as

(a) C3v and C2v respectively

(b) D3h and D2h respectively

Then first order correction to the second excited state is:

For CH3I molecule the moment of inertia I xx , I yy , I zz are related by

Arrange the following ligands in the increasing order of acceptor ability?

Which of the following complexes is the strongest reducing agent?

The blue-colour of copper blue protein is caused by

(d) M M charge transfer

The major product C in the above reaction sequence is

The major product B in the above synthetic transformation is:

The correct relation between compound (A) and (B) are

The above reaction takes place via

(c) Norish type-II

(d) di-pi methane rearrangement

The major product P is:

(c) both (a) and (b)

Which of the following compound is aromatic

The major product P in the following reaction is

(i) Li, NH3

The decreasing order of the size of the void is

(d) None of the above

(c) both (a) and (b)

Which of following ion has highest magnetic moment?

The increasing order of acidic strength of following acids

(a) HClO 4 HBr H 2SO 4 HCl HNO3

(b) HNO3 HCl HClO 4 H 2SO 4 HBr

(c) HClO 4 H 2SO4 HBr HCl HNO3

(d) None of the above

Consider the following

For the reaction P Q R

The order of the reaction with respect to P, Q and R respectively is:

Which is the incorrect irreducible representation for D 3h point group?

(b) A '2 , E" and A '1 respectively

(c) A '2 , E ' and A"1 respectively

(d) E ', A"1 and E" respectively

The activity of liquid water at 9.3 bar pressure and TR is

(Given that for electron

(b) 2103.3 cm1

(b) 2206.6 cm1

(d) 4206.6 cm1

The EMF of concentration cell without EMF is

(b) Inner sphere mechanism without ligand transfor

Which of the following substances show substaintal Jahn Teller distortion

Lowest energy transition for CrF6 is

(b) 3 T2g 3T1g

Consider the following statement about carbohydrates

Which of the following statements about hemoglobin is not true

(a) HCHO 3HCOOH CH 3COOH

(b) 3HCHO 2HCOOH CO2

(c) HCHO 3HCOOH OHC COOH

(d) 4HCOOH OHC COOH