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EEAdvancedExam
QuesPaper1
Code-9
JEE-ADVANCE 2014
PHYSICS
JEE (MAIN)2014
25 MAY 2014
PART A # PHYSICS
1.
n1
Air
2.
Q1
E1
Q2
E2
n2
(A) | f1 | = 3R
(B) | f1 | = 2.8R
(C) | f2 | = 2R
(D) | f2 | = 1.4R
E1
(A) E 1
2
E1 1
(B) E K
2
Q1 3
(C) Q K
2
C1 2 K
(D) C K
2
1/2
1/2
167RT = 640 J mole ;
1/2
1/2
140RT = 590 J mole . The molar masses M
in grams are given in the options. Take the values of
4.
10
for each gas as given there.)
M
10
7
)
20 10
x
0t
cos
6
3
10 3
)
28 5
x
100t
cos
3
3
10
9
)
32 16
5x
250 t
cos
6
3
5x
cos 250t
2
10 17
)
36 32
(1)
PHYSICS
Code-9
5.
At time t = 0, terminal A in the circuit shown in the
figure is connected to B by a key and an alternating
current I (t) = I0 cos (wt), with I0 1A = and w = 500 rad
s1 starts flowing in it with the initial direction shown
in the figure. At t
7.
7
, the key is switched from B
6w
JEE-ADVANCE 2014
In the figure, a ladder of mass m is shown leaning
against a wall. It is in static equilibrium making an
angle with the horizontal floor. The coefficient of
friction between the wall and the ladder is 1 and
that between the floor and the ladder is 2. The
normal reaction of the wall on the ladder is N1 and
that of the floor is N2. If the ladder is about to slip,
then :-
B D
2
C = 20 F
50 V
R = 10
mg
2
mg
2
mg
(C) 1 0 2 0 and N2 1
1 2
7
is 1 103 C.
6w
7
is clockwise.
6w
8.
(D) Q = 2 103 C.
6.
V1
R1
R2
V2
R3
(A) 2 > 1
(B) m1 > m2
(C) From the central maximum, 3rd maximum of 2
(A) V1 = V2 and R1 = R2 = R3
than 2
(2)
mg
2
2
(A) Q 4r0
(B) r0
13.
JEE-ADVANCE 2014
Consider an ellipticaly shaped rail PQ in the vertical
plane with OP = 3 m and OQ = 4 m. A block of mass
1 kg is pulled along the rail from P to Q with a force
of 18 N, which is always parallel to line PQ (see the
figure given). Assuming on fritional losses, the kinetic
energy of the block when it reaches Q is (n10)
Joules. The value of n is (take acceleration due to
gravity = 10 ms2)
Q
4m
O
14.
3m
2n
resistance, it becomes an
249
15.
p
12.
16.
O
Y
F
F
(3)
PHYSICS
Code-9
9.
Let E1 (r), E2 (r) and E3 (r) be the respective electric
fields at a distance r from a point charge Q, an
inifinitely long wire with constant linear charge density
, and an infinite plane with uniform charge density
. If E1 (r0) = E2 (r.0) = E3 (r0) at a given distance r0,
then :-
PHYSICS
Code-9
17.
Airplanes A and B are flying constant velocity in the
same vertical plane at angle 30 and 60 with respect
to the horizontal respectively as shown in figure. The
19.
JEE-ADVANCE 2014
Two parallel wires in the plane of the paper are
distance X0 apart. A point charge is moving with
speed u between the wires in the same plane at a
distance X1 from one of the wires. When the wires
carry current of magnitude l in the same direction,
the radius of curvature of the path point charge is R1.
In contrast, if the currents l in the two wires have
directions opposite to each other, the radius of
X0
curvature of the path is R2. If X 3 , the value of
1
60
30
18.
R1
R 2 is
20.
a=2 ms
0.2 ms1
0.3 ms
4m
(4)
Code-9
JEE-ADVANCE 2014
CHEMISTRY
JEE (MAIN)2014
25 MAY 2014
PART B # CHEMISTRY
21.
25.
22
26.
NH2
acetic anhydride
X2
CH2Cl 2
NH2
C(CH 3)3
Z
H
N
CH3
O
(A)
+ CH3COOH
NH2
O
NH2
+ CH3COOH
H
N
(B)
O
H
N
(C)
Irreversible
CH3
CH3
Pext = 0
Pext = 0
Product (s)
+ H2O
H
N
CH3
O
P2,V2,T2
P1,V1,T1
(D)
Thermal insulation
(A) q = 0
(B) T2 = T1
(C) P2 V2 = P1V1
(D) P2V2 = P1V1
24.
The correct statement (s) for orthoboric acid is /are :(A) It behaves as a weak acid in water due to self
ionization.
(B) Acidity of its aqueous solution increases upon
addition of ethylene glycol.
(C) It has a three dimensional structure due to
hydrogen bonding.
(D) It is a weak electrolyte in water.
27.
(5)
In a galvanic cell, the salt bridge :(A) does not participate chemically in the cell
reaction.
(B) stops the diffusion of ions from one electrode to
another.
(C) is ncessary for the occurrence of the cell
reaction.
(D) ensures mixing of the two electrolytic solutions.
CHEMISTRY
Code-9
28.
Upon heating with Cu2S, the reagents(s) that give
copper metal is/are :(A) CuFeS2
(B) CuO
(C) Cu2O
(D) CuSO4
29.
30.
31.
32.
33.
2+
2
XeF4, SF4, SiF4, BF4 , BrF4 , [Cu(NH3)4] , [FeCl4]
2
2
,[CoCl4] and [PtCl4] .
Defining shape on the basis of the location of X and
Z atoms, the total number of species having a square
planar shape is
34.
35.
36.
MX 2 dissociates into M
and X ions in an
aqueous solution, with a degree of dissociation
() of 0.5. The ratio of the observed depression of
freezing point of the aqueous solution to the value
of the depression of freezing point in the absence
.
of ionic dissociation is
37.
38.
39.
40.
(6)
JEE-ADVANCE 2014
Among PbS, CuS, HgS, Mns, Ag2 S, NiS, Cos, Bi2S3
and SnS2, the total number of BLACK coloured
sulphides is.
2+
23
Code-9
JEE-ADVANCE 2014
MATHS
JEE (MAIN)2014
25 MAY 2014
PART C # MATHS
41.
Let f: , R be given by
2 2
f(x) : (log (sec x + tan x))3.
Then
(A) f(x) is an odd function
(B) f(x) is a one-one function
(C) f(x) is an onto function
(D) f(x) is an even function
42.
43.
Let f: (0 ) R be given by
x
f(x) =
1
x
1
t
t
46.
47.
48.
dt
1
y and z x , then:-
1
= 0, for all x (0, )
x
(C) f(x) + f
(A) b (b. z) (z x)
(C) a.b (a.y)(b.z)
45.
49.
(B) a (a. y) (y z)
(D) a (a. y) (z y)
if x a,
0
x
g(x) f(t)dt if a x b,
a
b
f(t)dt
if x b.
a
(7)
MATHS
Code-9
50.
From a point P (), perpendicular PQ and PR
are drawn respectively on the lines y = x, z = 1 and
y = x , z = 1, If P is such that QPR is a right
angle then the possible value(s) of is (are):(A)
(B) 1
(C) 1
JEE-ADVANCE 2014
56.
(D) 2
of
3 d
4x
(1 x 2 )5 dx is.
The value of 0
2
dx
52.
53.
57.
54.
55.
. If a b b c pa qb rc , where p, q and r
3
p2 2q2 r 2
are scalars, then the value of
is:q2
b
is an
a
51.
a2 a 14
is:a 1
58.
10 x
is:10
ax sin(x 1) a 1
which lim
x 1
x sin(x 1) 1
1
is:4
59.
60.
(8)
J
EEAdvancedExam
QuesPaper2
Code-4
JEE-ADVANCE 2014
PHYSICS
JEE (MAIN)2014
25 MAY 2014
PART A # PHYSICS
1.
2.
4.
1
(radius of Earth) has
10
the same mass density as Earth. Scientists dig a
R
well of depth
on it and lower a wire of the same
5
length and of linear mass density 103 kgm1 into it.
If the wire is not touching anywhere, the force
applied at the top of the wire by a person holding it
in place is (take th radius of Earth = 6 106 m and
the acceleration due to gravity on Earth is
10 ms2):(A) 96 N
(B) 108 N
(C) 120 N
(D) 150 N
5.
A planet of radius R
6.
90
7.
40.0 CM
h
(A) 60 0.15
(C) 60 0.25
2S
(A) bpg cos( )
2S
(C) bpg cos( / 2)
(1)
2S
(B) bpg cos( )
2S
(D) bpg cos( / 2)
PHYSICS
Code-4
8.
Charges Q, 2Q and 4Q are uniformly distributed in
three dielectric solid spheres 1, 2 and 3 of radii R/2,
R and 2R respectively, as shown in figure. If
magnitudes of the electric fields at point P at a
distance R from the centre of spheres 1, 2 and 3 are
E1, E2 and E3 respectively, then :-
P
R
2Q
10.
JEE-ADVANCE 2014
A point source S is placed at the bottom of a
transparent block of height 10 mm and refractive
index 2.72. It is immersed in a lower refractive index
liquid as shown in the figure. It is found that the light
emerging from the block to the liquid forms a circular
bright spot of diameter 11.54 mm on the top of the
block. The refractive index of the liquid is :-
4Q
Liquid
Block
R
S
R/2
Sphere 1
Sphere 2
2R
Sphere 3
(A) 1.21
(B) 1.30
(C) 1.36
(D) 1.42
Wire 1
d
a
Wire 2
(A)
t
11.
12.
(B)
t
(C)
t
K
(D)
t
(1)
(3)
(2)
0I2a2
d
30I2a 2
d
(2)
(4)
0I2a2
2d
30I2a 2
2d
Code-4
JEE-ADVANCE 2014
16.
for a given pistion speed the rate (volume per unit time)
at which the liquid is sprayed will be proportional to
17.
3
5
R, CP = R, and those for
2
2
5
7
R, CP = R.
2
2
P.
Q.
13.
14.
R.
S.
18.
(A)
(B)
(C)
(D)
Q2
Q1
(2a, 0) (a, 0)
P.
Q.
R.
S.
15.
List I
Q1, Q2, Q3, Q4 all
positive
Q1, Q2, positiver; Q3, Q4
negative
Q1, Q4 positive; Q2 Q3
negative
Q1, Q3 positive; Q2 Q4
negative
Code
(A) P-3, Q-1, R-4, S-2
(C) P-3, Q-1, R-2, S-4
Q3
Q4
(+a, 0) (+2, 0)
List II
1. +
2.
3.
+y
4.
PHYSICS
PHYSICS
Code-4
19.
Four combinations of two thin lenses are given in
List I. The radius of curvature of all curved surfaces
is r and the refractive index of all the lenses is 1.5.
Match lens combinations in List I with their focal
length in List II and select the correct answer using
the code given below the lists.
List I
List II
P.
1.
2r
Q.
2.
r/2
20.
JEE-ADVANCE 2014
A block of mass m1 = 1 kg another mass m2 = 2 kg,
are placed together (see figure) on an inclined plane
with angle of inclination . Various values of are
given in List I. The coefficient of friction between the
block m1 and the plane is always zero. The coefficient
of static and dynamic friction between the block m2
and the plane are equal to = 0.3. In List II expressions
for the friction on block m2 are given. Match the correct
expression of the friction in List II with the angles given
in List I. and choose the correct option. The
acceleration due to gravity is denoted by g.
[Useful information : tan (5.5) 0.1 ; tan (11.5)
0.2 ; tan (16.5) 0.3 ]
m1
m2
R.
3.
S.
4.
Code
(A) P-1, Q-2, R-3, S-4
(C) P-4, Q-1, R-2, S-3
P.
Q.
R.
S.
(4)
List I
= 5
= 10
= 15
= 20
Code
(A) P-1, Q-1, R-1, S-3
(C) P-2, Q-2, R-2, S-4
List II
1.
m2g sin
2.
(m1+m2) g sin
3.
m2g cos
4.
(m1+m2) g cos
(B) P-2, Q-2, R-2, S-3
(D) P-2, Q-2, R-3, S-3
Code-4
JEE-ADVANCE 2014
Chemistry
JEE (MAIN)2014
25 MAY 2014
PART B # CHEMISTRY
21.
27.
(A)
(B)
(C)
(D)
23.
(A) 4
(B) 3
(C) 2
(D) 1
28.
29.
24.
and
(II)
and
(III)
The correct order of their boiling point is :-
25.
30.
26.
(A) Be2
(B) B2
(C) C2
(D) N2
(B) SO2Cl2
(C) SCl2
(D) POCl3
(A) 0
(C) 2
(5)
(B) 1
(D) 3
Code-4
Chemistry
31.
32.
34.
35.
M1, Q and R, respectively are:(A) Zn2+, KCN and HCl (B) Ni2+, HCl and KCN
(C) Cd2+ , KCN and HCl (D) Co2+ , HCl and KCN
36.
37.
33.
(B)
(A)
(B)
(C)
(D)
(B) Na2HPO4
(D) KOH
Code :
CH CH O
(C)
JEE-ADVANCE 2014
The correct statement with respect to product Y is :(A) It gives a positive Tollens test and is a functional
isomer of X.
(B) It gives a positive Tollens test and is a geometrical
isomer of X.
(C) It gives a positive iodoform test and is a functional
isomer of X.
(D) It gives a positive iodoform test and is a
geometrical isomer of X.
(D)
H
(6)
P
4
3
2
1
Q
2
1
1
3
R
3
4
3
4
S
1
2
4
2
P.
1. p d antibonding
Q.
2. d d bonding
R.
3. p d bonding
S.
4. d d antibonding
39.
JEE-ADVANCE 2014
Different possible thermal decomposition pathways
for perosysters are shown below, match each
opathway from List with an appropriate structure from
List II and select the correct answer using the code
given below the lists.:List-I
List - II
(P)
Pathway P
(1)
(Q) Pathway Q
(2)
(R)
Pathway R
(3)
(S)
Pathway S
(4)
Code :
(A)
(B)
(C)
(D)
40.
P
2
4
2
4
Q
1
3
3
1
R
3
1
1
3
S
4
2
4
2
Match the four starting materials (P,Q,R,S) given in List-I with the corresponding reaction schemes (I,II,III,IV)
provided in List-II and select the correct answer using the code below the lists.
List-I
List-II
P. H
H
1. Scheme-I
C7H6N2O3
OH
Q.
2. Scheme-II
OH
(i) Sn/HCl (ii)CH3COCl(iii) conc. H2SO4
? (iv) HNO3(v) dil. H2SO4. Heat (vi) HO
C6H6N2O3
NO2
R.
3. Scheme-III
(i) Red hot iron, 873 K (ii) fuming HNO3, H2SO4, heat
(iii) H2S. NH3 (iv) NaNO2, H2SO4 (v) hydrolysis
C6H5NO3
NO2
S.
4. Scheme-IV
CH3
(i) Conc. H2SO4, 60C
? (ii) conc. HNO3, conc. H2SO4 (iii) dil. H2SO4, heat
Code :
(A)
(B)
(C)
(D)
P
1
3
3
4
Q
4
1
4
1
R
2
4
2
3
S
3
2
1
2
(7)
C6H5NO4
Chemistry
Code-4
38.
Match the orbital overlap figure shown in List-I with
the describption given in List-II and select the correct
answer using the code given below the lists:List-I
List-II
Code-4
JEE-ADVANCE 2014
PHYSICS
JEE (MAIN)2014
25 MAY 2014
PART C # MATHS
41.
(C)
42.
43.
44.
45.
3y
2x(x c)
3y
4x(x c)
(B)
(D)
46.
x2
f(x) =
3y
2c(x c)
3y
4c(x c)
47.
3
2
f(0) = 0, Then
f(x) dx is:-
48.
(A)
3
2
(B)
3
4
(C)
6
4
(D)
6
2
49.
1
(B)
3
(D)
equation
in (1, 1) satisfying
dx x 2 1
1 x2
2
3
t )dt
For x [0, 2], If F(x) = f(x) for all x (0, 2), then
F(2) equals:(A) e2 1
(B) e4 1
(C) e 1
(D) e4
(C)
f(
0
1
(A)
2
3
4
(8)
log(1 2 )
(A)
(B)
(C)
(D)
0
log(1 2 )
0
log(1 2 )
0
log(1 2 )
0
2(eu e u )16 du
(eu e u )17 du
(eu e u )17 du
2(eu e u )16 du
Code-4
50.
Coefficient of x11 in the expansion of
(1 + x2)4 (1+ x3)7 (1 + x4)12 is:(A) 1051
(B) 1106
(C) 1113
(D) 1120
51.
1 h
29
105
57
(C)
105
(B)
55.
(A)
(C)
1
(D)
2
56.
9
(A)
105
10
(B)
105
11
(C)
105
7
(D)
105
54.
1
t
(C)
a(t 2 1)2
t3
(B)
(D) 0
and
f(x)dx = 1, is
2. 2
(B)
t 1
t
(D)
t2 1
t
R.
3x 2
2 (1 e x ) dx equals
3. 4
S.
21
1 x
1 cos 2x log
dx
1 x
2
equals
21
1 x
0 cos 2x log
dx
1 x
4. 0
(t 2 1)2
(A)
2t 3
List-I
List-II
P. The number of polynomials f(x) with 1. 8
non-negative integer coefficients of
degree 2, satisfying f(0) = 0
(C)
(D)
(C) -
1
t
1
The value of g is:2
(A)
(B) 2
53
105
57.
53.
(1 t)a 1 dt
1
The value of g is :2
(A)
52.
a(t 2 1)2
(B)
2t 3
(D)
(A)
(B)
(C)
(D)
a(t 2 2)2
t3
(9)
P
3
2
3
2
Q
2
3
2
3
R
4
4
1
1
S
1
1
4
4
PHYSICS
JEE-ADVANCE 2014
Paragraph For Questions 55 and 56
Code-4
58.
JEE-ADVANCE 2014
List-I
List-II
1. 1
PHYSICS
60.
3
.
2
1 2
d2 y(x)
dy(x)
x
Then y(x) (x 1)
2
dx equals
dx
n1
n1
If k 1 ak ak 1 = k 1 ak .ak 1 ,
on the ellipse
3. 8
4. 9
1
1 = 1 2
tan1
tan1
tan x 2 is
2x 1
4x 1
(A)
(B)
(C)
(D)
59.
P
4
2
4
2
Q
3
4
3
4
R
2
3
1
1
S
1
1
2
3
Let f 1 : R R , f 2 : [0, ) R, f 3 :R R
and f4: R [0, ) be defined by
| x | if
f1(x) = x
if
e
x 0,
x 0;
f2(x) = x2;
sin x if
f3(x) =
if
x
x 0,
x0
and
if
f2 (f1(x))
f4(x) = f (f (x)) 1 if
2 1
List-I
P. f4 is
Q. f3 is
R. f2 0 f1 is
S. f2 is
P
(A) 3
(B) 1
(C) 3
(D) 1
Q
1
3
1
3
1.
2.
3.
4.
R
4
4
2
2
R.
x 0,
x 0.
List-II
onto but not one-one
neither continuous nor one-one
differentiable but not one-one
continuous and one-one
S
2
2
4
4
(10)
(A)
(B)
(C)
(D)
List-II
1. true
2. false
| 1 z1 | | 1 z 2 |....| 1 z9 |
equals
10
3. 1
2k
cos
equals
10
4. 2
x2 y2
1 is
6
3
List-I
P. For each zk there exists a zj
such that zk . zj = 1
Q. There exists a k {1,2,....,9} such
that z1. z = zk has no solution z in
the set of complex numbers.
S. 1
2k
2k
i sin
Let zk = cos
;k 1,2,....,9.
10
10
P
1
2
1
2
k 1
Q
2
1
2
1
R
4
3
3
4
S
3
4
4
3