Documente Academic
Documente Profesional
Documente Cultură
Series OSR/1/C
Code No.
amob Z.
56/1/1
Roll No.
Code number given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
Please check that this question paper contains 30 questions.
Please write down the Serial Number of the question before
attempting it.
15 minutes time has been allotted to read this question paper. The question
paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the
students will read the question paper only and will not write any answer on
the answer-book during this period.
A{YH$V_ AH$ : 70
Maximum Marks : 70
1
P.T.O.
gm_m` {ZX}e :
(i)
(ii)
Z-g`m 1 go 8 VH$ A{V bKw-Cmar` Z h & `oH$ Z Ho$ {bE 1 AH$ h &
(iii)
(iv)
(v)
(vi)
Amd`H$VmZwgma bmJ Q>o~bm| H$m `moJ H$a| & H$Hw$boQ>am| Ho$ Cn`moJ H$s AZw_{V Zht h &
General Instructions :
(i)
(ii)
(iii)
(iv)
(v)
(vi)
1.
(bcc)
How many atoms per unit cell (z) are present in bcc unit cell ?
2.
XeF2 H$s
4.
SiO2
2-~mo_monoQ>oZ
IUPAC
Zm_ {b{IE
8.
CH3 NH2
Ama
(CH3)3N
Out of CH3 NH2 and (CH3)3N, which one has higher boiling point ?
9.
O~ EH$ Admnerb {dbo` EH$ {dbm`H$ _| KwbVm h Vmo {dbm`H$ H$m dmn Xm~ H$go
^m{dV hmoVm h ?
(b)
EH$ A{^{H$`m, A + B CnmX, Ho$ {bE doJ {Z`_, Rate = k[A]1 [B]2 go
{X`m J`m h & A{^{H$`m H$s H$mo{Q> `m h ?
W_ H$mo{Q> A{^{H$`m Ho$ {bE doJ {Z`VmH$ k H$s BH$mB {b{IE &
(a)
(a)
Write the unit of rate constant k for the first order reaction.
3
P.T.O.
11.
12.
(i)
Roasting
(ii)
Calcination
H2SO4
(ii)
R>mog
PCl5
13.
(i)
H2SO4
(ii)
Solid PCl5
(i)
gH$_U YmVwE (Zn, Cd Ama Hg H$mo N>moS>H$a) R>mog (H$R>moa) Ama C JbZmH$
Ama dWZmH$ dmbr hmoVr h &
(ii)
gH$_U YmVwAm| H$s W_ loUr _| Am`ZZ EWpn`m (W_ Ama {Vr`) A{Z`{_V
$n go n[ad{VV hmoVr h &
AWdm
The transition metals (with the exception of Zn, Cd and Hg) are
hard and have high melting and boiling points.
(ii)
The ionisation enthalpies (first and second) in the first series of the
transition elements are found to vary irregularly.
OR
14.
VO2 Cr2O7
MnO 4
(ii)
VO2 Cr2O7
15.
MnO 4
16.
(i)
(ii)
Kolbes reaction
17.
(i)
Propene to Propan-2-ol
(ii)
2
?
56/1/1
(i)
(ii)
P.T.O.
18.
byH$mog H$s CZ A{^{H$`mAm| H$m {ddaU Xr{OE {Oh| BgH$s Iwbr mIbm gaMZmAm| mam
Zht g_Pm`m Om gH$Vm h &
H$mna H$m KZd 8.95 g cm3 h & BgHo$ {H$Q>b H$s \$bH$ Ho$pV KZr` gaMZm hmoVr
h & H$mna na_mUw H$s {`m `m h ?
(na_mUw `_mZ Cu = 63.5 g mol1, NA = 6.02 1023 mol1)
The density of copper is 8.95 g cm3. It has a face centred cubic structure.
What is the radius of copper atom ?
(Atomic mass Cu = 63.5 g mol1, NA = 6.02 1023 mol1)
20.
5 kg
Ob Ho$ gmW Hw$N> E{WbrZ bmBH$mb, HOCH2CH2OH, AmnH$s H$ma H$s erVbZ
Umbr _| S>mbm OmVm h & `{X Ob-bmBH$mb {db`Z H$m {h_mH$ 15.0C hmo, Vmo
{db`Z H$m dWZmH$ `m hmoJm ?
(Ob Ho$ {bE Kb = 0.52 K kg mol1 Ama Kf = 1.86 K kg mol1)
EH$ A{^{H$`m _| hmBS>moOZ noamgmBS>, H2O2 (Obr`), H2O (l) Ama O2 (g) _|
AnK{Q>V hmoVm h & A{^{H$`m H2O2 _| W_ H$mo{Q> H$s h Ama doJ {Z`VmH$
k = 1.06 103 min1 h &
(i)
H2O2
(ii)
{VXe Ho$
15%
56/1/1
(i)
(ii)
22.
23.
(i)
Adsorption
(ii)
Peptization
(iii)
Sol
[Co(NH3)5Cl]Cl2
(ii)
K3[Fe(CN)6]
(iii)
[NiCl4]2
(IUPAC) Zm_
{b{IE
AWdm
{ZZ H$mbog Am`Zm| _| go `oH$ Ho$ H$m{eH$ g_md`{d`m| H$s gaMZmE Amao{IV
H$s{OE :
[Cr(C2O4)3]3, [PtCl2(en)2]2+, [Cr(NH3)2Cl2(en)]+
Write down the IUPAC name for each of the following complexes :
(i)
[Co(NH3)5Cl]Cl2
(ii)
K3[Fe(CN)6]
(iii)
[NiCl4]2
OR
56/1/1
(a)
CH3Br
(ii)
(CH3)3CCl
`m
SN2
CH3I
`m
CH3Cl
7
P.T.O.
(b)
3
(a)
(b)
25.
CH3Br or CH3I
(ii)
(CH3)3CCl or CH3Cl
26.
(i)
(ii)
(iii)
56/1/1
(i)
Polythene
(ii)
(iii)
Polyvinyl chloride
Bakelite
8
27.
`oH$ Ho$ {bE EH$ Cn`w$ CXmhaU Ho$ gmW {ZZ nXm| H$s `m`m H$s{OE
(i)
{dgH$m_r
(ii)
EoQ>{gS> ({VAb)
(iii) Im n[aajH$
28.
(i)
Disinfectants
(ii)
Antacids
(iii)
Food preservatives
(a)
EH$ {dwV-AnKQ>` Ho$ {db`Z Ho$ {bE MmbH$Vm Ama _moba MmbH$Vm nXm| H$mo
n[a^m{fV H$s{OE & Vmn_mZ ~XbZo Ho$ gmW CZHo$ n[adVZ na {Q>nUr H$s{OE &
(b)
EH$ MmbH$Vm gob H$m _m{nV {VamoY 100 ohm Wm & n[aH${bV H$s{OE
(i) {d{e> MmbH$Vm Ama (ii) {db`Z H$s _moba MmbH$Vm &
(KCl = 74.5 g mol1 Ama gob pWamH$ = 1.25 cm1)
2, 3
AWdm
(a)
(b)
AgNO3
(ii)
H2SO4
960 kJ &
(a)
(b)
56/1/1
P.T.O.
(a)
29.
(ii)
(b)
(a)
(b)
(i)
P4 + NaOH + H2O
(ii)
XeF4 + O2F2
(a)
56/1/1
N2O3
(ii)
BrF3
(b)
nXmWm] Ho$ {ZZ g_yhm| H$mo `oH$ g_yh Ho$ AmJo {XE JE JwUY_ Ho$ H$_ _|
`dpWV H$s{OE :
(i)
NH3, PH3, AsH3, SbH3 ~T>Vo hE dWZmH$ _mZm| Ho$ H$_ _|
(ii) O, S, Se, Te G$Um_H$ {M Ho$ gmW BboQ>mZ bpY EWnr Ho$ ~T>Vo
H$_ _|
(iii) F2, Cl2, Br2, I2 Am~Y {d`moOZ EWnr Ho$ ~T>Vo H$_ _|
(a)
P4 + NaOH + H2O
(ii)
XeF4 + O2F2
10
2, 3
(b)
(ii)
(iii)
(a)
(b)
30.
N2O3
(ii)
BrF3
(ii)
(iii)
(a)
(b)
{ZZ `w_m| _| AVa H$aZo Ho$ {bE amgm`{ZH$ OmM H$m dUZ H$s{OE
(i)
EWZb Ama monZb
(ii) ~oOpS>hmBS> Ama EogrQ>mo\$sZmoZ
(iii) monoZ-2-AmoZ Ama monoZ-3-AmoZ
2, 3
AWdm
(a)
56/1/1
P.T.O.
(b)
(a)
Describe :
(b)
(i)
Aldol condensation
(ii)
Cannizzaro reaction
(ii)
(iii)
(a)
(b)
56/1/1
4-chloropentan-2-one
(ii)
But-2-en-1-al
12