Documente Academic
Documente Profesional
Documente Cultură
ISBN: 978-3-902655-05-9
Editor: Dr. Maximilian Lackner MBA
Cover design: Nicole Hannig
Layout: Martin Dorn
2009 by ProcessEng Engineering GmbH. All rights reserved.
Preface
Dear Reader,
Ignition is the process of starting combustion. As such, it plays a critical role in all
technical combustion systems. Reliable ignition is important both for stationary and
mobile combustors. Ignition is known to affect the overall combustion process in
terms of pollutant formation, combustion efficiency and heat release.
This book is dedicated to ignition in technical systems, predominantly engines.
The electric spark plug has been used in appliances that rely on induced ignition for
more than 100 years, e.g. in Otto engines. Auto-ignition has been used for the same
time span, e.g. in Diesel engines.
In this book, alternative ignition systems are presented.
Leading authors from industry and academia describe promising, novel approaches
to induced ignition and also to auto-ignition.
Plasma jet ignition and laser plasma ignition are presented as potential future
systems for induced ignition. HCCI (homogeneous charge compression ignition)
combustion is discussed as a possible new technology for auto ignition in engines
based on a homogeneous charge, hence bridging the gap between Otto and Diesel
engine. Skip cycle ignition and HDDI (hot diluted diffusion ignition) mild combustion
are also discussed.
Laser ignition is presented for applications on a large-scale (cryogenic rocket
engines) and in micro-combustion. Finally, cool flames and ignition are discussed.
This book offers a technology update on selected alternative ignition technologies
with high relevance and a good potential of maturing to commercial use.
Hopefully this book offers new insights and stimulates new thoughts.
Maximilian Lackner
Editor
Table of contents
2
3
4
5
6
7
8
9
10
Introduction
1.1 Fundamentals of combustion
1.2 Fundamentals of ignition
1.3 Fundamentals of ignition systems
1.4 Electric spark plug and historic development
1.5 Alternative ignition systems
1.6 Alternative ignition systems in this book
1.7 References
Plasma jet ignition
HCCI combustion
Skip cycle ignition
Laser plasma ignition for cryogenic rocket engines
Laser ignition in microcombustion applications
HDDI mild combustion
Cool flames and ignition
Glossary
Further reading
5
5
7
10
11
12
12
13
17
41
63
85
97
133
151
173
195
Introduction
Ignition, as the initiating step of a combustion reaction, has several aspects. It can be
intended
undesirable
The term ignition is also used in the semiconductor industry for the start of a plasma reactor
[1] and in nuclear fusion for the point in time when the reaction can sustain itself without
external energy supply [2].
In the following section, some fundamentals on ignition and combustion are outlined.
1.1
Fundamentals of combustion
In a combustion process, fuel and oxidizer (comburent) are involved. The fuel is oxidized
(increase in oxidation state, loss of electrons), whereas the oxidizer is reduced. This is
shown schematically in equation 1 below:
C + O2 CO2
(eq. 1)
In equation 1, the oxidation state of carbon (C) increases from 0 to +4. Therefore,
combustion processes are a subset of oxidation reactions. Combustion can be defined as
an oxidation process that occurs fast and gives off heat. The fuel can be gaseous (e.g.
methane), liquid (e.g. gasoline) or solid (e.g. wood). It can be derived from a fossil source
(coal, oil), from waste or from biomass. The oxidizer is typically air (21% oxygen) or pure
oxygen. A combustion process can occur at various speeds, ranging from gentle oxidation
reactions such as wood combustions to fast deflagrations and detonations.
Fuel and oxidizer can be premixed or non-premixed prior to combustion. In the latter case,
combustion is said to be diffusion-controlled. A flame can be laminar or turbulent. Examples
are given in Table 1.
Flow type
Turbulent
Mixing type
Premixed
Otto engine
Non-premixed Diesel engine
Laminar
Bunsen burner
Candle, burning
piece of wood
Apart from these flames, the following special combustion modes exist [3]:
Catalytic combustion
Combustion in the solid phase
Cool flames
Glowing combustion
Smouldering combustion
Fig.1
Flames can further be characterized by the laminar flame speed and the adiabatic flame
temperature.
Typical values are ~1950C (CH4/air) to ~2100C (H2/air), both at atmospheric pressure and
at = 1 [4]. The highest flame temperature is reached by dicyanoacetylene (carbon
subnitride, NC-CC-CN) burning in oxygen: 4990C [5]. Combustion processes are
radical chain reactions [6].
Common pollutants from combustion processes are unburnt hydrocarbons (HC) including
polycyclic aromatic hydrocarbons (PAH), CO, NO x , SO2, soot and particulate matter (PM, fine
and ultrafine particles) [6]. Carbon dioxide (CO2), due to global warming concerns, is also
seen as a pollutant [7]. Another ubiquitous combustion product, water (H2O), can contribute
to global warming, too, under certain conditions [8].
Dioxins [9] and corrosion-promoters such as alkali metals and chlorine can also be seen as
pollutants. Pollutant abatement strategies work
pre-combustion,
during combustion or
post-combustion.
A recent trend in combustion research is carbon dioxide capture and storage or carbon
capture and storage (CCS) [16], a variety of technologies to remove CO2 from combustion
and to dispose of it, e.g. under the ground. This CO2 sequestration [17], combined with
attempts to burn biomass-based or biomass-derived fuels (e.g. gas-to-liquid process
(GTL), biomass-to-liquid (BTL), etc.), should make combustion more environmentally
friendly and sustainable.
1.2
Fundamentals of ignition
auto-ignition or
induced ignition
A key parameter for auto-ignition is the (auto-) ignition temperature. A typical value is
632C for methane in air and 556 C for methane in oxygen [15].
For induced ignition, the minimum ignition energy (MIE) is important. For gases, it is on the
order of ~1 mJ, whereas for dusts, it is typically ~ 1J (methane: 0.29 mJ; hydrogen: 0.03 mJ)
[15]. MIE is a function of temperature, pressure and stoichiometry.
For liquids, one can make a distinction between flashpoint and fire point.
Explosive substances are a category for themselves. They are instable compounds that
react easily.
Hypergolic mixtures ignite spontaneously upon contact of the respective fuel and oxidizer.
For each combustible fuel/air mixture, there is an upper and a lower flammability limit
(explosion limit). In between, in the so-called flammability range (explosion range ), the
combustion reaction can be started.
For instance, the flammability range of methane stretches from 5-15%. For hydrogen, is goes
from 4-74.2% in air and from 4-94% in oxygen, all at ambient pressure (the higher the
pressure, the wider the flammability range becomes) [15].
Another important concept is quenching. By quenching, the deactivation of radicals can be
understood. It can occur in the gas-phase (homogeneous quenching, eq. 2) on the surface of
e.g. a vessel wall (heterogeneous quenching, eq. 3).
H. + OH. + M H2O + M
H. + H. H2
(eq. 2)
(eq. 3)
Heterogeneous quenching can be observed on a miners lamp, where the flame cannot
penetrate a fine wire mesh. This phenomenon is also exploited by flame arrestors in the
petrochemical energy, where the MESG (maximum experimental safe gap) defines the
maximum gap, measured in mm, between two metal plates in a specified experimental setup that will prevent the passage of flame from one side to the other (which of course
depends on pressure, temperature and gas composition).
M in eq. 2 is a third body.
A lot about ignition can be learnt from the pT explosion diagram, which is shown for the
H2/O2 system below.
Fig. 2
At point 1 (~800K, ~ 5 mbar), there is no ignition, but only a slow reaction. Radicals that are
formed can diffuse the the vessel walls, where they are quenched. According to Ficks law of
diffusion, the flux of radicals J, expressed in mol/(m*s), is given by equation 4:
J= D*c/ t
(eq. 4)
(eq. 5)
Hence at low pressures, diffusion wins over the radical chain branching mechanism
necessary for ignition.
When the pressure is increased, up to point 2 in Fig. 2, the 1st explosion limit is surpassed.
As diffusion losses cannot keep pace with the formation of new radicals in the gas phase,
spontaneous ignition occurs. This regime is characterized by a competition of chain
branching in the gas phase and quenching of the radicals at the vessel wall. Therefore, the
vessel wall plays a significant role in this regime.
When the pressure is further increased to over 100 mbar (800 K), see point 3, spontaneous
ignition ceases, as the 2nd explosion limit is passed.
In this new regime, the competition of chain branching and chain termination reactions in the
gas phase determines ignition.
At low pressures, the following reaction is favoured (equation 6):
H. +O2 OH. +O.
(eq. 6)
(eq. 7)
At even higher pressures, see point 4 in Fig. 2, the 3rd explosion limit is reached.
Here, thermal ignition occurs. This regime is characterized by a competition between heat
formation (~x) and heat losses (~ x).
The pT explosion diagram of hydrogen/oxygen shows that ignition is a complex, non-linear
phenomenon. For hydrocarbons, one also encounters cool flame regions. For details, the
reader is referred to the pertinent literature [6].
Further important terms related to ignition are
Ignition delay
The time span between ignition and the spotting of actual combustion is termed ignition
delay. Since a radical pool needs to be formed before the bulk of a combustible fuel/air
mixture starts burning with a noticeable increase in pressure and temperature, a certain time
elapses. There exist several definitions for the ignition delay time, e.g. 5% of fuel consumed
or 10% of maximum pressure increase reached [6].
Ignitability
As it is known from the phenomenon of engine knock, some fuels are more prone to ignition
than others. This behaviour can be described by the octane number for gasoline fuels, the
cetane number for diesel fuels and the methane number for gas engines [6].
Flashover
If a fire occurs in a confined space, e.g. in a domestic building, the combustion gases will be
partly combustible and accumulate at the ceiling of the room. Due to the lack of oxygen at
the location of the fire, pyrolysis yields these combustible gases which, suddenly, can ignite
(typically around 500C) [18].
Backdraft
This phenomenon is similar to a flashover. When hot combustion gases, which are partly
combustible, have accumulated in a closed room, the opening of a door or window leads to
fresh oxygen delivery into that room, resulting in an explosion-like start of combustion [18].
Flashover and backdraft are potential dangers for fire fighters.
Loss of containment and fires
When liquid or gaseous hydrocarbons are accidentally released in, for instance, a
petrochemical installation, they can ignite at an ignition source, leading to pool fires or jet
fires. A very severe fire hazard in the gas-processing industries is a so-called BLEVE [19].
BLEVE stands for boiling liquid expanding vapour explosion. It can occur when a vessel that
contains liquefied gas is ruptured under the action of an external fire.
Fire protection
An important aspect of fire protection is to make combustible materials resistant to flames.
The concept is often to retard ignition and combustion.
Fire protection [20] is not discussed here, as this would go beyond the scope of this book.
Prevention of ignitions
Undesired ignitions of combustible gas/air [21] or dust/air mixtures [22] can lead to severe
explosions in industry. The European Union has created the ATEX directive1 [23] to
increase workplace safety in this respect by setting minimum standards.
1
ATEX 95 equipment directive 94/9/EC: Equipment and protective systems intended for use in
potentially explosive atmospheres; ATEX 137 workplace directive 99/92/EC: Minimum requirements
for improving the safety and health protection of workers potentially at risk from explosive
atmospheres.
No
1
2
3
4
5
6
7
8
9
Ignition source
Hot surfaces
Flames, hot gases
Mechanically generated sparks
Electrical machinery
Leaking currents, cathodic corrosion protection
Static electricity2
Flash of lighte ning
Electromagnetic fields (9kHz-300 GHz)
Electromagnetic radiation (300-3*106 GHz, 0.1-1000 m)
10
11
12
13
Ionising radiation
Ultrasound
Adiabatic compression, shock waves, gas flows
Chemical reactions
Table 2 Ignition sources.
1.3
Technical combustion systems are in widespread use. They cover various applications,
some of which are
Stationary combustors (heat and energy generation from gaseous, liquid or solid fuels
derived from fossil sources, waste or biomass).
Engines
Low-tech stoves for domestic use
Engines, for instance span from microcombustors (catalytic combustion processes with
powers of a few mW) [24] up to 80 MW for ship diesel applications [25]. Large combustion
power plants can exceed a power output of 1000 MW [26]. All these combustors need to
have a reliable ignition source. Technically, this is solved by the installation of a so-called
ignition system.
Ignition systems [27] have the task to reliably start combustion either infrequently (e.g. in a
power plant) or repetitively (e.g. in engines with induced ignition).
Internal combustion engines can be grouped into those relying on
induced ignition
auto-ignition
Propagating brush discharges are a rare and hence often overlooked type of undesired ignition
hazards.
10
Exhaust gas recirculation (EGR), the recycling of a part of the exhaust gases back
into the combustion chamber, e.g. to use the heat, dilute the fuel/air mixture for better
mixing and lower combustion peak temperatures for lower thermal NO x emissions or
CO2 enrichment [31].
Fig. 3
Electric spark plug with platinum electrode for use in automotive engines. Modified from [39].
11
Early patents on spark plugs were filed by Nikola Tesla (US 609250,/1998), Frederick
Richard Simms (GB 24859/1898), Robert Bosch (GB 26907/1898) and Sir Oliver Lodge (GB
2162/1903). Today, over 300 patent applications relating to spark plugs are published every
year [40]. An electric spark plug generates a plasma [41] in the combustion chamber which is
characterized by high pressures and temperatures. Free electrons and radicals from that
plasma can ignite the fuel/air mixture.
1.5 Alternative ignition systems
Despite their advantages, electric spark plugs are no ideal ignition sources. For instance,
wear of the electrodes necessitates frequent maintenance and replacement especially in
high-pressure applications such as gas engines [35].
Also, with spark plugs it is only possible to ignite the fuel/air mixture at the side of a
combustion chamber, although the ideal location would be in the middle. This is not feasible,
as the spark plug would then prevent proper fuel distribution by interfering with air turbulence
and would lead to excessive radical quenching and pollutant formation.
Therefore, attempts are made to develop alterative ignition systems. Table 3 provides an
overview of selected alternative ignition systems.
Standard
ignition process
Electric
spark
ignition
using a coil
in practical use
This concludes the brief section about some important concepts of combustion and ignition.
For details on combustion and ignition, the reader is referred to the references given above
and to the pertinent literature, e.g. [36], [37], [38].
12
The selection was made according to the following principles: Technology that
[2]
[3]
[4]
Charles E. Baukal, Jr., The John Zink Combustion Handbook, CRC, ISBN: 9780849323379 (2001).
[5]
[6]
[7]
Tyler Volk, CO2 Rising: The World's Greatest Environmental Challenge, The MIT
Press, ISBN: 978-0262220835 (2008).
[8]
[9]
Adrian M. Cunliffe, Paul T. Williams, De-novo formation of dioxins and furans and the
memory effect in waste incineration flue gases, Waste Management 29(2), 739-748
(2009).
[10]
Thomas P. Wampler, Applied Pyrolysis Handbook, CRC, 2nd edition, ISBN: 9781574446418 (2006).
[11]
Christopher Higman, Maarten van der Burgt, Gasification, Second Edition, Gulf
Professional Publishing; 2nd edition, ISBN: 978-0750685283 (2008).
[12]
[13]
13
Manufacturing
[14]
John F. Coleman, Managing Major Fires, Fire Engineering Books, ISBN13: 9780912212968 (2001).
[15]
Bernard Von Elbe, Guenther Lewis, Combustion, Flames and Explosions of Gases,
Cambridge At the University Press (1938).
[16]
[17]
[18]
J.E. Floyd, K.B. McGrattan, Extending the mixture fraction concept to address underventilated fires, Fire Safety Journal 44(3), 291-300 (2009).
[19]
Tasneem Abbasi, S.A. Abbasi, The boiling liquid expanding vapour explosion
(BLEVE) is fifty and lives on!, Journal of Loss Prevention in the Process Industries
21(4),485-487(2008).
[20]
NFPA, Fire Protection Handbook, National Fire Protection Association (NFPA), 20th
edition, ASIN: B001AR4LMA (2008).
[21]
ISO 13702:1999, Petroleum and natural gas industries -- Control and mitigation of
fires and explosions on offshore production installations -- Requirements and
guidelines, ISO TC 67/SC 6/WG 1 (1999).
[22]
Rolf Eckhoff, Dust Explosions in the Process Industries, Gulf Professional Publishing,
3rd edition, ISBN: 978-0750676021 (2003).
[23]
http://ec.europa.eu/enterprise/atex/index_en.htm (2009).
[24]
K.C. Jiang, H. Yang, P.D. Prewett, Design and analysis of a micro reciprocating
engine for the timemultiplexed deep etching process, Microelectromechanical
Systems Conference, 87 90 (2001).
[25]
http://www.wartsila.com/Wartsila/global/docs/en/ship_power/media_publications/tech
nical_papers/sulzer/low_speed_engines_continuing_progress.pdf (2005).
[26]
Platts UDI World Electric Power Plants Data Base, http://www.platts.com/ (2009).
[27]
Robert Bosch GmbH, Ignition Systems for Gasoline Engines: Bosch Technical
Instruction, ISBN: 978-0837610481 (2003).
[28]
[29]
http://www.oldengine.org/members/diesel/Marine/othmarin.htm (2009).
[30]
14
[31]
Erjiang Hu, Zuohua Huang, Bing Liu, Jianjun Zheng, Xiaolei Gu, Bin Huang,
Experimental investigation on performance and emissions of a spark-ignition engine
fuelled with natural gashydrogen blends combined with EGR, International Journal of
Hydrogen Energy 34(1), 528-539 (2009).
[32]
Norbert Peters, Turbulent Combustion, Cambridge University Press, ISBN: 9780521660822 (2000).
[33]
Robert Bosch GmbH, Spark Plugs: Engine Management for Spark-Ignition Engines :
Edition 98/99 : Technical Instruction, Bentley Publishers, ISBN: 978-0837604787
(1999).
[34]
Claire Soares, Gas Turbines: A Handbook of Air, Land and Sea Applications,
Butterworth-Heinemann, ISBN: 978-0750679695 (2007).
[35]
[36]
[37]
[38]
[39]
http://www.ngksparkplugs.com/products/spark_plugs/laser_platinum.asp?mode=nml#
(2009).
[40]
[41]
Claire Tendero, Christelle Tixier, Pascal Tristant, Jean Desmaison, Philippe Leprince,
Atmospheric pressure plasmas: A review, Spectrochimica Acta Part B: Atomic
Spectroscopy 61(1), 2-30 (2006).
15