Documente Academic
Documente Profesional
Documente Cultură
Sustainable
Mediului
Development
i Antreprenoriatul
Entrepreneurship
Dezvoltrii
Vol.Durabile
1, No. 3 (2012)
Vol. 1, Nr. 3 (2012)
1. Introduction
1. Introducere
21
Environmental
Engineering
and
Ingineria
Sustainable
Mediului
Development
i Antreprenoriatul
Entrepreneurship
Dezvoltrii
Vol.Durabile
1, No. 3 (2012)
Vol. 1, Nr. 3 (2012)
Phone: +40 264/593833;
Fax:
+40
264/590818
e-mail: andrada@chem.ubbcluj.ro
Ci Ct
100
Ci
Ci Ct
m
(1)
(2)
1000
3. Rezultate i discuii
3.1.
Establishing
optimum
biosorbent
quantity
In order to esablish the optimum biosorbent
quantity, 100 mL MB aqueous solution of 100 mg/L
was used.
Experiments were conducted in batch
conditions with magnetic stirring at 200 rpm, pH
5.12 and room temperature (T = 22C) using
different amounts of fir tree sawdust, 1, 2, 3, 4
and 5 g respectively, with a grain size of 0.4 - 0.6
mm.
Experiments have shown that equilibrium
100
1g
90
5g
80
4
mbiosorbent (g)
C (mg MB/L)
70
60
50
40
30
20
10
96.5
0
0
50
100
150
200
250
97
97.5
98
98.5
99
99.5
max (%)
t (min)
200
50 m g/L
g/L
200 m
6.45
200
180
4.18
160
150
120
C (mg MB/L)
C (mg MB/L)
140
100
80
60
100
3.28
2.18
75
40
1.77
0
0
0
50
100
150
200
250
t (min)
3.5
3
>0.6
Q (mg MB/g)
d (mm)
2.5
0.4-0.6
2
1.5
1
0.5
0.2-0.4
>0.6m m
0.4-0.6m m
0
97.9
98
98.1
98.2
98.3
98.4
98.5
50
100
150
200
250
t (min)
max (%)
100
99.5
max (%)
99
98.5
98
97.5
97
96.5
96
150
200
300
400
500
600
v (rpm)
Figure 7. Influence of stirring rate over the maximum biosorption process efficiency.
4. Conclusions
4. Concluzii
In this paper we studied methylene blue (MB) azodye biosorbtion from aqueous solution using
Romanian fir tree sawdust (Abies Alba) collected
from Mrgu village, Cluj County. Such material,
industrial waste from wood processing industry is a
convenient alternative depollution technique for
wastewaters containing dyes.
In order to establish the optimum working
condition the influence of the following parameters
on the biosorbtion process efficiency was
considered: initial concentration of MB, the amount
of biosorbent, biosorbent grain size and influence
of stirring speed.
Rezultate
obinute
indic
faptul
c
rumeguul de brad considerat are o capacitate
mare de reinere a MB din soluii apoase, valoarea
maxim fiind 6.45 mg/g la valori ale randamentului
de pn la 99.88%.
n urma comparrii rezultatelor obinute s-a
ajuns la concluzia c variata optim de operare
este: cantitate de biosorbent 3 g (la 100 mL soluie
apoas), granulaie 0.4-0.6 mm i o vitez de
agitare de 200 rpm, n regim discontinuu.
References
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Sanda
Andrada
Micneanu
a
absolvit
Facultatea de Chimie i Inginerie Chimic a
Universitii Babe-Bolyai Cluj-Napoca n anul
1994, obinnd titlul de inginer chimist,
specializarea Tehnologia Substanelor Anorganice,
iar n anul 1995 a obinut diploma de Studii
Aprofundate, specializarea Cataliz i Biocataliz.
Titlul de Doctor n tiine, specializarea Chimie, cu
lucrarea intitulat, Simularea la nivel atomic a
materialelor oxidice cu proprieti catalitice, l-a
obinut la Facultatea de tiine Militare, Tehnologie
i Management a Universitii Cranfield din Marea
Britanie, n anul 2002.
Cariera sa profesional ncepe n anul 1995
la Catedra de Chimie Tehnologic a Facultii de
Chimie i Iniginerie Chimic, Universitatea BabeBolyai Cluj-Napoca ca i preparator. La aceast
catedra parcurge pe rnd treptele ierarhiei
didactice pn n anul 2008 cnd obine titlul de
confereniar universitar.
De-a lungul carierei didactice, a fost/este
titular a cursurilor (nivel licen i master): Bazele
tehnologiei mediului, Procese catalitice/Cataliz
eterogen, Analiza i sinteza sistemelor chimice,
Evaluarea factorilor de risc n protecia mediului i
Materiale naturale utilizate n procese de
depoluare.
Activitatea sa de cercetare este strns
legat de problematica polurii mediului nc de la
conceperea proiectului de diplom (ndeprtarea
SO2 din aer prin oxidare catalitic), dezvoltndu-se
n cadrul colectivului de cercetare pe msura
trecerii anilor. n cadrul colectivului de Chimie
Aplicat n Protecia Mediului din care face parte,
sunt abordate probleme legate de dezvoltarea
unor tehnologii (catalitice, necatalitice) de
eliminare a substanelor toxice din medii poluate, i
utilizarea i caracterizarea materialelor naturale la
depoluarea mediului.
Activitatea didactic i tiinific este
concretizat prin publicarea unor cri i capitole
(3), manuale de laborator (1), susinere de cursuri
invitate
n
programe
Socrates/Erasmus,
participarea la numeroase proiecte de cercetare
(20), publicarea de articole (55), recenzor pentru
reviste de specialitate (eg. Desalination, Chemical
Engineering Journal) i stagii de cercetare
(Universitatea
Henry
Poincar,
Frana,
Universitatea Exeter, Universitatea Cranfield,
Marea Britanie).