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GPA publications necessarily address problems of a general nature and may be used by anyone desiring to do so.
Every effort has been made by GPA to assure accuracy and reliability of the information contained in its
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regarding apparatus, equipment, or method so covered.
FOREWARD
GPA 2261 provides the gas processing industry a method for determining the chemical composition of natural gas
and similar gaseous mixtures using a Gas Chromatograph (GC).
The precision statements contained in this standard are based on the statistical analysis of round-robin laboratory
data obtained by Section B.
This standard was developed by the cooperative efforts of many individuals from industry under the sponsorship of
GPA Section B, Analysis and Test Methods.
Throughout this publication, the latest appropriate GPA Standards are referenced
Analysis for Natural Gas and Similar Gaseous Mixtures by Gas Chromatography
1. SCOPE
2. SUMMARY OF METHOD
Lower
Region
Round
Robin
Higher
Region
0.01 - 0.1
0.01 - 0.1
0.01 - 40
0.01 - 0.1
0.01 - 0.1
0.01 - 0.25
0.01 - 0.25
0.01 - 0.12
0.01 - 0.12
0.01 - 0.1
0.01 - 0.1
0.1 - 30
0.1 - 30
40 - 100
0.1 - 10
0.1 - 10
0.25 - 4
0.25 - 4
0.12 - 1.5
0.12 - 1.5
0.1 - 1.5
0.1 - 1.5
> 30
> 30
N/A
> 10
> 10
>4
>4
> 1.5
> 1.5
> 1.5
> 1.5
3. APPARATUS
3.1 Chromatograph - Any Gas Chromatograph may
be used as long as the specifications for repeatability and
reproducibility stated in Section 10 within the round-robin
test component ranges listed in Table 1 are met or
exceeded. The equipment described in this section has
been proven to meet the above requirements; however
other configurations including portable and online may be
acceptable.
5. SAMPLE INTRODUCTION
6. CALIBRATION PROCEDURE
6.1 Calibration
6.1.1 Response factors for the components of interest
are determined in accordance with the calculations
discussed in Section 8. This can be accomplished by
3
8. CALCULATIONS
Component
Nitrogen
Methane
Carbon Dioxide
Ethane
Propane
Isobutane
n-Butane
Isopentane
n-Pentane
Hexanes Plus
Response Factor
0.0006465
0.0008398
0.0004514
0.0004821
0.0003843
0.0003275
0.0003193
0.0002849
0.0002641
0.0002403
Component
Nitrogen
Methane
Carbon Dioxide
Ethane
Propane
Isobutane
n-Butane
Isopentane
n-Pentane
Hexanes Plus
Area
Resp. Factor
1050
0.0006465
95153
0.0008398
1255
0.0004514
21470
0.0004821
13623
0.0003843
2253
0.0003275
4324
0.0003193
1398
0.0002849
1321
0.0002641
2080
0.0002403
Unnorm.
Mole %
0.68
79.91
0.57
10.35
5.24
0.74
1.38
0.40
0.35
0.50
100.12
Wt. %
0.91
61.27
1.20
14.88
11.04
2.06
3.84
1.38
1.21
2.21
100.00
Mu = Pu x K where:
Mu - Mol% of component in unknown
Pu- Peak area of each component in unknown
sample
K - Response factor as determined in 8.2
Mole %
2.03
89.75
0.53
3.08
1.90
0.97
0.97
0.30
0.29
0.18
100.00
Mole Wt.
Lbs./Mole
28.013
0.1905
16.043
12.8039
44.01
0.2509
30.07
3.1092
44.097
2.3063
58.123
0.4301
58.123
0.8021
72.15
0.2886
72.15
0.2525
92.489
0.4624
20.8966
Component
Nitrogen
Methane
Carbon Dioxide
Ethane
Propane
Isobutane
n-Butane
Isopentane
n-Pentane
Hexanes Plus
Mole %
0.68
79.81
0.57
10.34
5.23
0.74
1.38
0.40
0.35
0.50
Norm.
Mole %
0.68
79.81
0.57
10.34
5.23
0.74
1.38
0.40
0.35
0.50
100.00
Component
Nitrogen
Methane
Carbon Dioxide
Ethane
Hydrogen Sulfide
Propane
Isobutane
n-Butane
Isopentane
n-Pentane
Hexanes Plus
Area
Resp. Factor
1050
0.0006465
95153
0.0008398
1255
0.0004514
21470
0.0004821
13623
2253
4324
1398
1321
2080
0.0003843
0.0003275
0.0003193
0.0002849
0.0002641
0.0002403
Unnorm.
Norm. Mole
Mole %
%
0.68
0.68
79.91
79.77
0.57
0.57
10.35
10.33
0.05
0.05
5.24
5.23
0.74
0.74
1.38
1.38
0.40
0.40
0.35
0.35
0.50
0.50
100.12
100.00
10. PRECISION
Example 1
Mol %
Repeatability
1/4
Nitrogen
0.04
0.16
Methane
71.6
0.03
0.25
CO2
0.14
0.01
0.06
Ethane
4.9
0.02
0.05
Propane
2.3
0.01
0.04
Iso-butane
0.26
0.01
0.01
N-butane
0.6
0.01
0.03
Iso-pentane
0.12
0.01
0.01
N-pentane
0.14
0.01
0.01
Hexanes Plus
0.1
0.01
0.02
Example 2
Repeatability Reproducibility
Reproducibility
1/2
Mol %
Repeatability
Reproducibility
Nitrogen
7.7
0.06
0.44
Methane
86.4
0.03
0.14
CO2
7.9
0.01
0.24
Ethane
9.7
0.03
0.07
Propane
4.3
0.01
0.05
Iso-butane
0.01
0.02
Nitrogen
.02 15
0.039x
0.158x
N-butane
1.9
0.02
0.05
Methane
50 100
0.0079x1/3
91000x-3
Iso-pentane
0.45
0.01
0.02
CO2
.02 15
0.0042x1/3
0.12x1/3
N-pentane
0.42
0.01
0.02
Ethane
.02 15
0.0124x1/3
0.0315x1/3
0.01
0.03
.02 15
0.026x1/2
0.35
Propane
0.0084x1/8
Hexanes Plus
Iso-butane
.02 8
0.01x1/5
0.018x1/2
N-butane
.02 8
0.0117x2/5
0.033x1/2
1/4
1/4
Iso-pentane
.02 4
0.009x
0.025x
N-pentane
.02 4
0.01x1/5
0.026x1/3
Hexanes Plus
.02 2
0.0135x1/4
0.051x1/2
Where:
Example 3
Nitrogen
Methane
CO2
Ethane
Propane
Iso-butane
N-butane
Iso-pentane
N-pentane
Hexanes
Plus
Mol %
UB
Reproducibility
PE
7.70
86.40
7.90
9.70
4.30
1.00
1.90
0.45
0.42
0.077
0.86
0.079
0.097
0.043
0.010
0.019
0.0045
0.0042
0.44
0.14
0.24
0.067
0.054
0.018
0.045
0.020
0.020
0.45
0.88
0.25
0.12
0.07
0.02
0.05
0.02
0.02
0.35
0.0035
0.030
0.03
11. DEFINITIONS
APENDIX A - Calibrations
Where
K = Response factor
Pi = Partial pressure of pure component in mm of
mercury to nearest 0.5 mm
Po = Barometric pressure in mm of mercury to
nearest 0.5 mm
A = Peak area of pure component in arbitrary
units
A-1 Linearity
Section 4, Appendix C and GPA 2198 discuss Linearity
and list procedures to determine the linear range and
calibration requirements of GC systems. When it is
anticipated that the range of concentrations of components
in the unknown samples will not fall in the linear
calibrated range of the instrument, it is necessary to make
corrections for this. Two means of accomplishing this are
through multi-level calibration (calibration curve) or
secondary analysis.
Table A-1
Component
Oxygen
Nitrogen
Methane
Carbon
Monoxide
Carbon Dioxide
Ethane
Propane
Isobutane
n-Butane
Isopentane
n-Pentane
Partial
Pressure mm
of Hg (Pi)
100
100
500
100
Barometric
Pressure mm of
Hg (Po)
750
750
750
750
Pi/Po * 100
100 (650)*
200 (450)*
100 (200)*
100 (100)*
100 (100)*
50 (50)*
50 (50)*
750
750
750
750
750
750
750
13.33
26.67
13.33
13.33
13.33
6.67
6.67
13.33
13.33
66.67
13.33
Fnorm= 100- Cn
100
Where
Fnorm = Normalization Factor
Cn = Concentration of component n
K= (Pi) (100)
(Po) (A)
9
10
In this example,
Peak Area
100000
80000
60000
40000
20000
0
0
20
40
60
80
100
120
Mole% Methane
120000
Peak Area
100000
80000
60000
40000
20000
0
0
20
40
60
80
100
120
Mole% Methane
11
12
13