Suppose you are hiking down the Grand Canyon. At the
top, the temperature early in the morning is a cool 3C. By late afternoon, the temperature at the bottom of the canyon has warmed to a sweltering 34C. What is the difference between the higher and lower temperatures in (a) Fahrenheit degrees and (b) kelvins? Dermatologists often remove small precancerous skin lesions by freezing them quickly with liquid nitrogen, which has a temperature of 77 K. What is this temperature on the (a) Celsius and (b) Fahrenheit scales?
3.
On the Rankine temperature scale, which is sometimes
used in engineering applications, the ice point is at 491.67 degrees R and the steam point is at 671.67 degrees R. Determine a relationship (analogous to Equation 12.1) between the Rankine and Fahrenheit temperature scales.
4.
A steel aircraft carrier is 370 m long when moving through
the icy North Atlantic at a temperature of 2.0C. By how much does the carrier lengthen when it is traveling in the warm Mediterranean Sea at a temperature of 21C?
5.
When the temperature of a coin is raised by 75 C, the
coins diameter increases by 2.3 x10 -5 m. If the original diameter of the coin is 1.8 x 10-2 m, find the coefficient of linear expansion.
6.
A steel ruler is calibrated to read true at 20.0 C. A
draftsman uses the ruler at 40.0 C to draw a line on a 40.0 C copper plate. As indicated on the warm ruler, the length of the line is 0.50 m. To what temperature should the plate be cooled, such that the length of the line truly becomes 0.50 m?
7.
8.
9.
A copper kettle contains water at 24 C. When the water is
heated to its boiling point of 100.0 C, the volume of the kettle expands by 1.2 x10 -5 m3. Determine the volume of the kettle at 24 C. Suppose that the steel gas tank in your car is completely filled when the temperature is 17 C. How many gallons will spill out of the twenty-gallon tank when the temperature rises to 35 C? The bulk modulus of water is B = 2.2 x 10 9 N/m 2. What change in pressure P (in atmospheres) is required to keep water from expanding when it is heated from 15 to 25 C?
10. Two identical thermometers made of Pyrex glass contain,
respectively, identical volumes of mercury and methyl alcohol. If the expansion of the glass is taken into account, how many times greater is the distance between the degree marks on the methyl alcohol thermometer than the distance on the mercury thermometer? 11. Ideally, when a thermometer is used to measure the temperature of an object, the temperature of the object itself should not change. However, if a significant amount of heat flows from the object to the thermometer, the temperature will change. A thermometer has a mass of 31.0 g, a specific heat capacity of c = 815 J/(kgC), and a temperature of 12.0C. It is immersed in 119 g of water, and the final temperature of the water and thermometer is 41.5C. What was the temperature of the water before the insertion of the thermometer?
12. A rock of mass 0.20 kg falls from rest from a height of 15
m into a pail containing 0.35 kg of water. The rock and water have the same initial temperature. The specific heat capacity of the rock is 1840 J/(kgC). Ignore the heat absorbed by the pail itself, and determine the rise in the temperature of the rock and water. 13. How much heat must be added to 0.45 kg of aluminum to change it from a solid at 130 C to a liquid at 660 C (its melting point)? The latent heat of fusion for aluminum is 4.0 x105 J/kg. 14. Find the mass of water that vaporizes when 2.10 kg of mercury at 205 C is added to 0.110 kg of water at 80.0 C. 15. A 42-kg block of ice at 0 C is sliding on a horizontal surface. The initial speed of the ice is 7.3 m/s and the final speed is 3.5 m/s. Assume that the part of the block that melts has a very small mass and that all the heat generated by kinetic friction goes into the block of ice. Determine the mass of ice that melts into water at 0C. 16. An unknown material has a normal melting/freezing point of -25.0 C, and the liquid phase has a specific heat capacity of 160 J/(kgC). One-tenth of a kilogram of the solid at -25.0 C is put into a 0.150-kg aluminum calorimeter cup that contains 0.100 kg of glycerin. The temperature of the cup and the glycerin is initially 27.0 C. All the unknown material melts, and the final temperature at equilibrium is 20.0 C. The calorimeter neither loses energy to nor gains energy from the external environment. What is the latent heat of fusion of the unknown material? 17. It is claimed that if a lead bullet goes fast enough, it can melt completely when it comes to a halt suddenly, and all its kinetic energy is converted into heat via friction. Find the minimum speed of a lead bullet (initial temperature is 30.0 C) for such an event to happen. 18. A woman has been outdoors where the temperature is 10 C. She walks into a 25 C house, and her glasses steam up. Using the vapor pressure curve for water that accompanies Problem 75, find the smallest possible value for the relative humidity of the room. 19. Liquid nitrogen boils at a chilly -195.8 C when the pressure is one atmosphere. A silver coin of mass 1.5 x10 -2 kg and temperature 25 C is dropped into the boiling liquid. What mass of nitrogen boils off as the coin cools to -195.8 C? 20. A lead object and a quartz object each have the same initial volume. The volume of each increases by the same amount, because the temperature increases. If the temperature of the lead object increases by 4.0 C, by how much does the temperature of the quartz object increase? 21. Ice at -10.0 C and steam at 130 C are brought together at atmospheric pressure in a perfectly insulated container. After thermal equilibrium is reached, the liquid phase at 50.0 C is present. Ignoring the container and the equilibrium vapor pressure of the liquid at 50.0 C, find the ratio of the mass of steam to the mass of ice. The specific heat capacity of steam is 2020 J/(kgC). 22. Multiple-Concept Example 11 uses the same physics principles as those employed in this problem. A block of material has a mass of 130 kg and a volume of 4.6 x10 -2
m3. The material has a specific heat capacity and
coefficient of volume expansion, respectively, of 750 J/(kg C) and 6.4 x10-5 (C)-1. How much heat must be added to the block in order to increase its volume by 1.2 x10 -5 m3? 23. A gas is enclosed within a chamber that is fitted with a frictionless piston. The piston is then pushed in, thereby compressing the gas. Which statement below regarding this process is consistent with the first law of thermodynamics? a. b. c. d.
The internal energy of the gas will increase.
The internal energy of the gas will decrease. The internal energy of the gas will not change. The internal energy of the gas may increase, decrease, or remain the same, depending on the amount of heat that the gas gains or loses.
24. Is it possible for the temperature of a substance to rise
without heat flowing into the substance? a. b. c.
Yes, provided that the volume of the substance does not
change. Yes, provided that the substance expands and does positive work. Yes, provided that work is done on the substance and it contracts.
25. The first law of thermodynamics states that the change U
in the internal energy of a system is given by U Q W, where Q is the heat and W is the work. Both Q and W can be positive or negative numbers. Q is a positive number if ________, and W is a positive number if ________. a. b. c. d.
the system loses heat; work is done by the system
the system loses heat; work is done on the system the system gains heat; work is done by the system the system gains heat; work is done on the system
26. A system does 164 J of work on its environment and gains
77 J of heat in the process. Find the change in the internal energy of (a) the system and (b) the environment. 27. In exercising, a weight lifter loses 0.150 kg of water through evaporation, the heat required to evaporate the water coming from the weight lifters body. The work done in lifting weights is 1.40 x105 J. (a) Assuming that the latent heat of vaporization of perspiration is 2.42 x10 6 J/ kg, find the change in the internal energy of the weight lifter. (b) Determine the minimum number of nutritional Calories of food (1 nutritional Calorie = 4186 J) that must be consumed to replace the loss of internal energy. 28. When a .22-caliber rifle is fired, the expanding gas from the burning gunpowder creates a pressure behind the bullet. This pressure causes the force that pushes the bullet through the barrel. The barrel has a length of 0.61 m and an opening whose radius is 2.8 x10 -3 m. A bullet (mass = 2.6 x10-3 kg) has a speed of 370 m/s after passing through this barrel. Ignore friction and determine the average pressure of the expanding gas. 29. (a) Using the data presented in the accompanying pressure volume graph, estimate the magnitude of the work done when the system changes from A to B to C along the path shown. (b) Determine whether the work is done by the system or on the system and, hence, whether the work is positive or negative. 30. Refer to Multiple-Concept Example 3 to see how the concepts pertinent to this problem are used. The pressure of a gas remains constant while the temperature, volume, and internal energy of the gas increase by 53.0 C, 1.40 x10 -3 m3, and 939 J, respectively. The mass of the gas is 24.0 g, and its specific heat capacity is 1080 J/(kgC). Determine the pressure.