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2 Hazards identification
Classification of the substance or mixture
GHS06 Skull and crossbones
H310
H331
H314
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Label elements
Labelling according to EU guidelines:
Code letter and hazard designation of product:
T Toxic
C Corrosive
Hazard-determining components of labelling:
hydrofluoric acid
nitric acid
Risk phrases:
Toxic by inhalation, in contact with skin and if swallowed.
Causes severe burns.
Irritating to respiratory system.
Safety phrases:
Keep away from living quarters.
Keep container tightly closed and in a well-ventilated place.
When using do not eat or drink.
Do not breathe fumes/aerosol.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
This material and its container must be disposed of as hazardous waste.
Hazard description:
WHMIS-symbols:
D1A - Very toxic material causing immediate and serious toxic effects
D2B - Toxic material causing other toxic effects
E - Corrosive material
Classification system:
NFPA ratings (scale 0 - 4)
Health = 4
Fire = 0
Reactivity = 0
Void
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY 0
Health = 4
Fire = 0
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
*
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description: Mixture of the substances listed below with nonhazardous additions.
(Contd. on page 3)
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Dangerous components:
7697-37-2 nitric acid
H272;
H314
7664-39-3 hydrofluoric acid
H300; H310; H330;
H314
Additional information: For the wording of the listed risk phrases refer to section 16.
*
10-25%
2.5-10%
5 Firefighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant
foam.
Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Do not inhale explosion gases or combustion gases.
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Protection of hands:
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Protective gloves
Neoprene gloves
Acid resistant gloves
Only use chemical-protective gloves with CE-labelling of category III.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has
therefore to be checked prior to the application.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
Eye protection:
Tightly sealed goggles
Body protection: Protective work clothing
*
<2
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
Undetermined.
Undetermined.
Flash point:
Not applicable.
Ignition temperature:
Decomposition temperature:
Not determined.
Auto igniting:
Danger of explosion:
Explosion limits:
Lower:
Upper:
Not determined.
Not determined.
23 hPa
Density at 20C:
Relative density
Vapour density
1.25 g/cm
Not determined.
Not determined.
(Contd. on page 6)
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Evaporation rate
Not determined.
Fully miscible.
Viscosity:
Dynamic:
Kinematic:
Not determined.
Not determined.
Solvent content:
Organic solvents:
Other information
0.0 %
No further relevant information available.
11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
7697-37-2 nitric acid
Inhalative LC50/4 h 67 mg/l (rat)
7664-39-3 hydrofluoric acid
Oral
LD50
1276 mg/kg (rat)
Primary irritant effect:
on the skin: Strong caustic effect on skin and mucous membranes.
on the eye: Strong caustic effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Toxic
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation
of esophagus and stomach.
12 Ecological information
Toxicity
Acquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
(Contd. on page 7)
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13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system.
Uncleaned packagings:
Recommendation: Packaging can be reused or recycled after cleaning.
Recommended cleansing agent: Water, if necessary with cleansing agents.
14 Transport information
DOT regulations:
Hazard class:
8
Identification number:
UN2922
Packing group:
II
Proper shipping name (technical name): LIQUIDE CORROSIF TOXIQUE, N.S.A. (ACIDE
FLUORHYDRIQUE, ACIDE NITRIQUE)
Label
8+6.1
TDG (Transport dangerous goods):
TDG class:
Danger code (Kemler):
UN-Number:
Packaging group:
UN proper shipping name:
8 Corrosive substances
86
2922
II
2922 CORROSIVE LIQUID, TOXIC, N.O.S.
(HYDROFLUORIC ACID, NITRIC ACID)
(Contd. on page 8)
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IMDG Class:
UN Number:
Label
Packaging group:
EMS Number:
Marine pollutant:
Segregation groups
Propper shipping name:
8
2922
8+6.1
II
F-A,S-B
No
Acids
CORROSIVE LIQUID, TOXIC,
(HYDROFLUORIC ACID, NITRIC ACID)
N.O.S.
ICAO/IATA Class:
UN/ID Number:
Label
Packaging group:
Propper shipping name:
8
2922
8+6.1
II
CORROSIVE LIQUID, TOXIC,
(HYDROFLUORIC ACID, NITRIC ACID)
N.O.S.
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or
mixture
Section 313 (Specific toxic chemical listings):
7697-37-2 nitric acid
7664-39-3 hydrofluoric acid
TSCA (Toxic Substances Control Act):
All ingredients are listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
(Contd. on page 9)
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Cancerogenity categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
Product related hazard informations:
Hazard symbols:
T Toxic
C Corrosive
Hazard-determining components of labelling:
hydrofluoric acid
nitric acid
Risk phrases:
Toxic by inhalation, in contact with skin and if swallowed.
Causes severe burns.
Irritating to respiratory system.
Safety phrases:
Keep away from living quarters.
Keep container tightly closed and in a well-ventilated place.
When using do not eat or drink.
Do not breathe fumes/aerosol.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
This material and its container must be disposed of as hazardous waste.
National regulations:
Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
*
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
(Contd. on page 10)
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