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?
n =
M
m
n =
84
1,6 ?
= 0,02 mol ? (rounded to 2 decimal places)
1.2 Each atom has three oxygen atoms, there is 0,02 mol of atoms
1 mol = 6,023 x 1023 particles
therefore 0,02 mol ? x 3 atoms? x 6,023 x 1023 particles? = 3,44 x 1022 oxygen
atoms?
SECTION B: SOLUTIONS AND HINTS
Learner Note: Emphasize the correct use of formulae and layout. Use the correct
unit
GAUTENG DEPARTMENT OF EDUCATION SENIOR SECONDARY INTERVENTION PROGRAMME
PHYSICAL SCIENCE Grade 11 SESSION 11 (LEARNER NOTES)
Page 3 of 8
Question 2
2.1 Empirical formula
the simplest ratio of atoms in a molecule??
Elements C H O
In 100g 39,9 g 6,7 g 53,4 g ?
Convert mass to
mol
n =
M
m
12
39,9
= 3,325 mol
1
6,7
= 6,7 mol
16
53,4
= 3,3375 mol ?
Divide by
smallest answer 3.325
3.325
= 1
3.325
6,7
= 2,01
3.325
3.3375
= 1
Ratio of
elements in the
empirical
formula
1 2 1 ?
Empirical formula CH2O ??
2.3 M (CH2O)
= 12 + 2(1) + 16
= 30 g.mol-1 ?
Molecular mass is double empirical formula mass therefore molecular formula is
C2H4O2 ??
Question 3
(It is important to balance chemical equations before doing the calculations. Th
e only
time where the balancing coefficients are used will be in the ratio step.)
3.1 2 ?SO2 (g) + O2 (g) ? 2 ?SO3 (g)
3.2 n =
M
m
n =
64
256
n = 4 mol SO2
n =
M
m
n =
32
80
n = 2,5 mol O2
Learner Note: If the steps are followed, the questions become relatively simple.
Remember we are working out what the ratio of the elements are in the molecule
therefore when you determine the number of mol the element mass is usedregardles
s
of whether the element is diatomic!
GAUTENG DEPARTMENT OF EDUCATION SENIOR SECONDARY INTERVENTION PROGRAMME
PHYSICAL SCIENCE Grade 11 SESSION 11 (LEARNER NOTES)
Page 4 of 8
3.3 A ratio of 2 mol SO2 is needed for 1 mol O2 according to reaction?. Therefor
e 2,5 mol
O2 needs 5 mol SO2 to react completely, the SO2 is therefore the limiting reagen
t?
3.4 4 mol SO2 reacts and 4 mol SO3 is produced?
n =
M
m
4 =
80
m
?
m = 320 g SO3 made ??
Question 4
4.1 M (CuSO4 . 5 H2O)
= 63,5 + 32 + 4(16) + 5 (1 + 1 + 16)
= 159,5 + 90
= 249,5 g.mol-1 ?
% water =
249,5
90
x 100 ?
= 36 % water ??
4.2 c =
MV
m
c =
40x0,25
10
c = 1 mol.dm-3
GAUTENG DEPARTMENT OF EDUCATION SENIOR SECONDARY INTERVENTION PROGRAMME
PHYSICAL SCIENCE Grade 11 SESSION 11 (LEARNER NOTES)
Page 5 of 8
The Mole
The mole is one of the base units of the SI and is the base unit of the amount o
f matter of
substance.
A mole of any substance always has the same number of atoms.
Definition: A mole of any substance is that amount of substance which contains a
s many
elementary particles as there are atoms in 12g of carbon-12.
The amount of matter or substance is not the same as the mass of the substance.
While one
mole of a substance contains the same number of particles, their masses are not
the same.
The formula used to calculate the number of moles in a substance:
In symbols n =
M
m
Avogadro s Number
One mole of any substance is approximately equal to 6,02x1023 elementary particl
es.
This very large number is known as Avogadro s number or Avogadro s constant and has
the
symbol NA or L.
Therefore: Number of particles = Avogadro s number x number of moles
In symbols Np = NA x n
Molar Volumes of Substances
Molar volume is the volume of one mole of a substance and can be measured in dm3
/mol.
One mole of any gas occupies a volume of approximately 22,4dm3 at Standard Tempe
rature
and Pressure (STP). Standard Temperature is 0oC (273K) and Standard Pressure is
101,3kPa.
Equal volumes of all gases at STP contain the same number of molecules.
Therefore: molar volume = volume of substance
Number of moles of substance
n = 22,4 dm3
V
Empirical formula
smallest ratio of atoms in a molecule
True Formula or molecular formula
actual ratio of atoms in a molecule eg. the Em
pirical
Formula of a substance is COH2 but its molecular formula is C2O2H4
Percentage Composition shows percentage of each element in a compound compared t
o
its molecular mass
SECTION C: ADDITIONAL CONTENT NOTES
GAUTENG DEPARTMENT OF EDUCATION SENIOR SECONDARY INTERVENTION PROGRAMME
PHYSICAL SCIENCE Grade 11 SESSION 11 (LEARNER NOTES)
Page 6 of 8
Learner Note: Revise steps for each type of calculation and follow the prescribe
d method. Attempt all questions and refer to notes when in doubt.
Question 1: 25 minutes
1.1 Calculate the relative formula mass of KClO3 (3)
1.2 Calculate how many times a molecule of methanol (CH3OH) is heavier than a mo
lecule of water (5)
1.3 Calculate the empirical formula of the substance with the following composit
ion
45,3 % O; 43 % Na; 11,3 % C (5)
1.4 How many potassium atoms are there in 2 g K2SO4 (5)
1.5 Fe + S ? FeS
Which of the two substances will be used up if 10 g Fe and 10 g S are mixed and
heated (7)
(25)
SECTION D: HOMEWORK
GAUTENG DEPARTMENT OF EDUCATION SENIOR SECONDARY INTERVENTION PROGRAMME
c.
? ?
2.3 a.
? ?
b. Lewis base ?
c. Lewis acid ?
Cl
He
F
F
O
H
H
N
H
H
H
H+
N
H
H
H