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Introduction
Secondary steel making is the term applied to the processes for treatment of liquid steel between the primary steel
making unit and the casting. These processes involve in refining operation to provide metallurgical benefits which
include better alloy recovery, homogenous molten bath composition, accurate control of temperature for casting,
better de-oxidation, excellent de-sulphurisation, low levels of hydrogen oxygen & nitrogen contents, achievement of
low inclusion rating through promoting inclusion separation coupled with inclusion modification and so on. It is the
increasing demand of high quality steel that prompted development of secondary steel making technology. Also,
secondary steel making enhance the productivity of primary steel making units and improves the overall economics.
Stirring systems
These systems involve in stirring the molten steel bath for obtaining homogenous temperature, composition,
inclusion floatation and promotion of slag-metal refining reaction. Stirring systems are further classified as Ladle
Stirring and Vessel Stirring.
Ladle stirring
Here, stirring is carried out either by gas or by electro-magnetic methods. Gas Stirring process is a method where
stirring is done through injection of inert gas into the steel bath. Stirring results from the expansion of gas due to
heating and decrease in pressure as the gas rises. One of the methods is injection of inert gas through deeply
inserted refractory lance from the top in to the molten steel bath. These lances may be of T, Y or straight bore type.
Initially, nitrogen was used as medium for purging that resulted in increased nitrogen pick up in steels. This led to
application of argon gas for stirring to produce steels with low nitrogen. Gas stirring by purging argon through the
porous plug located at the bottom of the ladle has evolved as the most effective method of gas stirring. From the
simple argon purging from porous plug, further developments took place in the form of using snorkel over the steel
bath by sealed argon bubbling and provision of composition adjustment through the process known as CAS method.
Here, the slag remains undisturbed and limits the detrimental effects of primary furnace slag contamination like poor
recovery of aluminium, increased phosphorous reversion etc. The best advantages of gas stirring method can be
accrued through mixing a basic reducing slag with steel in the inert environment to simultaneously achieve deoxidation & de-suphurisation. Also, the argon stirring helps in reducing the hydrogen content and improves the
cleanliness of the steel by floatation of oxide inclusions. Electro-Magnetic Stirring process is a stirring method
involving induction stirring through electro-magnetic coils positioned close to the ladle. Here, the supply of turbulent
currents through the coils diametrically at 1/3rd and 2/3rd of the ladle depth below the surface of the molten steel
induces stirring action. This method provides lower stirring energy than the gas stirring system with better stirring
energy distribution with controlled stirring action. The stirring system is reported to be an excellent process for
floatation and separation of non-metallic inclusions.
Vessel stirring
One of the most popular secondary steel making process for stainless steel production is through Argon Oxygen Decarburization (AOD) unit. It is a low cost stainless steel production method that can absorb large amounts of scrap
and high carbon ferrochrome. The initial carbon content of the melt is about 3% and the process possesses the
capability to achieve carbon levels of maximum 0.015%.The steel melted in Electric Arc Furnace is transferred to
AOD where oxygen and argon are injected into the molten bath through the tuyeres located at the lower side wall of
the converter. Chromium oxidation increases as the carbon content is reduced. In this process, to ensure rapid decarburization but low chromium losses while conserving argon, a low ratio of argon : oxygen is injected initially. As
the carbon content of the bath decreases, the ratio is increased. After de-carburization, FeSi is used as reductant to
recover chromium lost to the slag. Basic slag is produced through addition of sufficient amount of lime for decreasing
the activity of silica and followed by vigorous stirring that enables to offset the detrimental effect of chromium on bath
oxygen content for production of low oxide inclusions coupled with high degree of de-sulphurization of the stainless
steel. Further developments took place through application of top and bottom blowing leading to improved production
rates.
CAS- OB Process
This is a development to the earlier CAS method of gas stirring wherein there is provision for oxygen lancing and
feeding aluminium through the snorkel to enable chemical heating of steel for increasing temperature.
AC Plasma method
This is a heating system employing three plasma torches using argon as the carrier gas. The advantage of this
method is avoiding carbon pick up which is evident in arc heating systems. It is expected that this technology would
come out in a big way for production of ultra low carbon steels.
Circulation degassers
In this process, a vacuum chamber is positioned above the ladle possessing a snorkel or snorkels which are dipped
into the molten steel bath. There are two types of Circulation Degassers namely Dortmund Hrder (DH) and
Ruhrstahl Heraeus (RH) units. DH unit has a single snorkel and operates by repeatedly sucking the metal into the
vacuum chamber and then releasing it back into the ladle. RH unit has two snorkels dipped into the ladle. Similar to
the DH degasser, the snorkels are covered with a sheet metal cone at the start of the operation to act as slag
breaker preventing slag from entering the vacuum chamber. Metal is circulated into the chamber by injecting argon
gas into the bottom of one leg. This induces an up flow; and down flow occurs in the other leg creating a circulating
movement. Here, the slag remains undisturbed leading to poor de-sulphurisation. New developments in DH and RH
degassing units took place in the form of increased vessel size, stirring energy for faster & efficient operation
coupled with changes in design & refractories to limit temperature losses about 12C to 15C through fast and
repeated use. RH-OB is a process which incorporates an oxygen injection facility near to the bottom of the vacuum
chamber to enable production of low carbon steels. Also, temperature recovery is achieved through use of aluminium
in combination with oxygen and normal degassing practice is carried out for production of clean steels. Considering
suppression of slag-metal mixing in circulation degassers with no de-sulphurisation, new techniques have been
developed which involve injecting refining slag into the up leg of RH vessel and is reported to achieve desulphurisation to the tune of 80%.
Tank degassers
Here, the ladle is placed in a vacuum tank and stirred with an inert gas while the tank is evacuated. Alternatively, the
ladle may have a sealing arrangement on its periphery for a lid to be fitted which forms the vacuum chamber.
stirring is continued in all the operational steps and the adjustment of flow rate is done for varied operations carried
out during processing. The heating rate is about 3C 4 C/min and during heating, argon flow rate is kept on the
lower side. In this system, under vacuum, carbon-oxygen reaction and carbon-Al2O3 reaction under the high
temperature arc are of great help in achieving low oxygen content without any solid reaction product. Hydrogen
levels as low as 1.5 ppm are achieved caused by intense mass transfer by argon and low partial pressure of
hydrogen because of dilution of liberated carbon monoxide. The greatest advantage of this process is the high
degree of de-sulphurisation as high as 80% for production of steels with sulphur levels as low as 0.005%. VAD is
now a widely used method of producing clean steels in the world.
caster caused by high aluminum in steels. Conclusions The growth of secondary steel making led to the
development of new steel products which enhanced the competitive position of steel. Continuous developments in
the area of secondary steel making are taking place for improving the productivity, quality of the steel products and
improving the overall economics of steel production in the world.