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CBSE Board
Class XII Chemistry Set 1
Board Paper - 2011
Time: 3 hours
Total Marks: 70
General instructions:
1. All questions are compulsory.
2. Marks for each question are indicated against it.
3. Question numbers 1 to 8 are very short- answer questions carrying 1 mark each.
Answer these in one word or about one sentence each.
4. Question numbers 9 to 18 are short-answer questions, carrying 2 marks each. Answer
these in about 30 words each.
5. Question numbers 19 to 27 are short answer questions, carrying 3 marks each. Answer
these in about 40 words each.
6. Question numbers 28 to 30 are long answer questions of carrying 5 marks each.
Answer these in about 70 words each.
7. Use Log Tables, if necessary. Use of calculators is not permitted.
Q. 1 'Crystalline solids are anisotropic in nature'. What does this statement mean?
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Q. 2 Express the relation between conductivity and molar conductivity of a solution held in
a cell.
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Q. 3 Define 'electrophoresis'.
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Ni s 2Ag aq
Ni2 aq 2Ag s , Eo 1.05V
1F 96500 C mol1
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The N - O bond is NO-2 is shorter than the N - O bond in NO3SF6 is kinetically an inert substance
OR
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[2]
[2]
[2]
Explain.
-form of glucose?
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Q. 19 Silver crystallizes in face-centred cubic unit cell. Each side of this unit cell has a
length of 400 pm. Calculate the radius of the silver atom. (Assume the atoms just touch
each other on the diagonal across the face of the unit cell. That is each face atom is touching
the four corner atoms.)
[3]
Q. 20 Nitrogen pentaoxide decomposes according to equation:
2N2O5 g
4NO2 g
O2 g
This first order reaction was allowed to proceed at 40 oC and the data below were
collected:
[N2O5] (M)
0.400
0.289
0.209
0.151
0.109
Time (min)
0.00
20.0
40.0
60.0
80.0
(a) Calculate the rate constant. Include units with your answer.
(b) What will be the concentration of N2O5 after 100 minutes?
(c) Calculate the initial rate of reaction.
Q. 21 Explain how the phenomenon of adsorption finds applications in each of the
following processes:
(i)
Production of high vacuum
(ii) Heterogeneous catalysis
(iii) Froth floatation process
OR
Define each of the following terms:
(i) Micelles
(ii) Peptization
(iii) Desorption
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C O2 H
MnO4
2 4
(ii)
KMnO4
heated
H S H
(iii) Cr2O2
2
7
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Q. 24 Write the name, stereochemistry and magnetic behaviour of the following: (At. Nos.
Mn = 25, Co = 27, Ni = 28)
(i) K4[Mn(CN)6]
(ii) [Co(NH3)5Cl] Cl2
(iii)
K2[Ni(CN)4]
Q. 25 Answer the following:
(i) Haloalkanes easily dissolve in organic solvents, why?
(ii) What is known as a racemic mixture? Give an example.
(iii) Of the two bromo derivatives, C6H5CH(CH3)Br and C6H5CH(C6H5)Br, which one is more
reactive in SN1 substitution reaction and why?
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Q. 26 (a) Explain why an alkylamine is more basic than ammonia.
(b) How would you convert:
(i) Aniline to nitrobenzene
(ii) Aniline to iodobenzene?
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Q. 28 (a) Difference between molarity and molality for a solution. How does a change in
temperature influence their values?
(b) Calculate the freezing point of an aqueous solution containing 10.50 g of MgBr2 in 200 g
of water. (Molar mass of MgBr2 = 184 g)
(Kf for water = 1.86 K kg mol-1)
OR
(a) Define the terms osmosis and osmotic pressure. Is the osmotic pressure of a solution a
colligative property? Explain.
(b) Calculate the boiling point of a solution prepared by adding 15.00 g of NaCl to 250.0 g of
water.(Kb for water = 0.512 K kg mol-1), Molar mass of NaCl = 58.44 g.
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Q. 30 (a)
(i)
(ii)
(b)
(i)
C H2SO4 conc.
(iii) Cl2 F2
excess
Or
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(a)
Account for the following:
(i)
The acidic strength decreases in the order:
HCl>H2S>PH3
(ii)Tendency to form pentahalides decreases down the group in group 15 of the
periodic table.
(b) Complete the following chemical equations:
(i)
P4 SO2Cl2
(ii)
XeF2 H2O
(iii) I2 HNO3
conc
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