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Instructions :
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i. The question paper has four parts. All the four parts are compulsory
ii. PART A carries 10 marks , each question carries one marks.
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iii) write balanced chemical equations and draw diagrams wherever necessary
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PART-A
I ANSWER ALL THE QUESTIONS. EACH QUESTION CARRIES ONE MARK 1X10=10
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
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15. How does Acetyl chloride react with Anisol in presence of anhydrous aluminum chloride
catalyst. Write the chemical equation of the reaction.
16. What are the effects of the electron withdrawing and electron donating groups on acidity of
carboxylic acids
17. What are antacids? Give an example.
18. What are food preservatives ? Give one example
PART C
5X3=
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III ANSWER ANY FIVE OF THE FOLLOWING EACH QUESTION CARRIES THREE MARKS
15
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PART-D
IV ANSWER ANY THREE OF THE FOLLOWING . EACH QUESTION CARRIES FIVE MARKS
3X5= 15
(3)
(2)
b. write two differences between ideal and non ideal solutions of two liquids
(2)
29. a). calculate the standard free energy change for the following reaction occurring in the galvanic
cell at 298K
3Mg(s) + 2Al3+ (aq) 3Mg2+(aq) +2 Al (s)
(4)
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30. a. Derive the integrated rate equation for the rate constant of a first order reaction (4)
b. what is pseudo first order reaction ?
(1)
H2 S oxidation
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SO2 +
g.
(2)
(2)
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V ANSWER ANY FOUR OF THE FOLLOWING . EACH QUESTION CARRIES FIVE MARKS
4X5=20
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(3)
(2)
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33. a. How is phenol manufactured by cumene process. Give the chemical equations of the reaction
involved .
(3)
b. How do you prepare ethanol by using the Grignard Reagent?
34. a. How is Benzol chloride converted into benzaldehyde ? Name the reaction
(2)
(3)
b. Write the chemical equation for the reaction between dilute NaOH and acetalhyde, mention the
name of the product formed .
(2)
35. a. Explain how is Hinbergs reagent is used to distinguish the primary, secondary and tertiary
amines
b. Write the chemical reactions involved in the conversion of aniline into phenol
36. a. What are carbohydrates ?and how are they classified ?
(2)
(3)
(2)
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(2)
Scheme of Valuation
VALUE POINT
MARK
S
Q.N
O
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Two
Invertase
A=XeF6 or Xenonhexaflouride
A mixture containing two enantiomers in equal proportions will have zero optical
rotation.
Acetaldoxime
10
Uracil
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1
1
1
PART -B
Formula d=zM
-------a3 NA substitution with correct answer(10.5 x 103 kgm-3)
OR
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10.5 g cm-3
1
12
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13
protection)
Lanthanides
Actinides
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14
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Lower
complexes
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15
16
17
18
Ex: Table salt, sugar, vegetable oils, OR any other suitable example
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PART-C
4NO + 6H2O
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500k,9bar
2NO2
2NO + O2
3
1
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20
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1
1
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Statement
(i)
2KClO3 Mno2 2KCl + 3O2
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(i)
1
1
(ii)
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Availability of d- orbitals
1
1
1
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Diamagnetic
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dsp2 Hybridisation
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(i)
(ii)
(iii)
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(a) Up to a = 4 /3 OR r=
1
1
1
1
1
1
PART -D
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Substitution:
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Vmix =0
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M2 = 58 g mol-1
[ NO UNIT DEDUCT ONE MARK]
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0.88 x 90
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1
1
(a) RP
Rate = - d[R] = k[R] OR
dt
d[R] = - kdt
[R]
Integrating euation
Ln[R] = -kt+I --------------------(1)
To calculate I :
T=o, R=[R]0
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ln[R]o =-kxo+I
OR
ln[R]0=I
substitutionequation (1)
ln [R] = -kt + ln [R]0
Rearranging
Ln[R] = - kt
OR
[R]0
K= 1/t. ln [R]0
OR
[R]
K= 2.303 log10 [R]0
t
[R]
(b) Order of reaction is one and molecularity is two or more than two
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FeCl3 + 3H2O
Hydrolysis
AS2 S3 +3H2O
Fe(OH)3 + 3HCl.
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PART-V
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Step-1
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(a)
+ Br -
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Step-2
(CH3)3 COH
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+OH - fast
(b) Alkylhalide reacts with anyl halide gives alkylarenes when treated with
sodium indry ether
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(a) Explanation
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OR
Step wise reaction carries
(b) HCHO+ CH3 Mg Br CH3CH2OBr
Methanal
CH3CH2OMgBr + HOH CH3CH2OH+Mg(OH)Br
Ethanol
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(a)
H2
Pd-BaSO4
Benzoyl
chloride
Rosenmund reduction
Benzaldehyde
Ethanal
3-Hydroxybutanal
CH3-CH=CH-CHO
But-2 enal
(ALDOL)
2
(a) Hinsbergd reagent reacts with 1 amine gives a product which is soluble in
alkali
(b) Hinsbergs reagent reacts with 2 amine gives a product which is insoluble
in alkali
Hinsbergs reagemt doesnot react with 3 amine
C6H5NH2 + NaNO2+2HCl 273-278 k C6H5N2+Cl- + NaCl + 2H2O
C6H5N2+Cl- + H2OC6H5OH + N2 + HCl
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1
1
1
1
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1
1
1
1
1