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11/3/10
Epithermal Au-Ag
! Products of large-scale hydrothermal convective
systems driven by magmatic heat in the upper 1-6
km of the Earths crust.
! The term epithermal was coined by Lindgren
(1922, 1933).
! Subdivision into:
! 1. high-sulfidation (alunite-kaolinite or acid sulfate),
! 2. low-sulfidation (adularia-sericite),
! [3. hot spring deposits]
Epithermal Ores
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Low-sulfidation Deposits
Epithermal Ores
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Midas, Nevada
Epithermal Ores
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250C
300C
Neutral chloride
LS waters
2 km
400C
2 km
Magmatic heat
source (plus
volatiles?)
C
200
! Meteoric
convection
! Peripheral
bicarbonate
waters
! Steam-heated acid
sulfate waters
Magma
Epithermal Ores
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crater lake
acid chloride
waters / brines
200C
300C
400C
300C
Magmatic heat
and volatile
source
Acid alteration
in upflow &
lateral outflow
zones
2 km
Volcanism may
disrupt or
destroy
hydrothermal
system
2 km
Magma
Epithermal Ores
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! Low
sulfidation
deposits
Baguio
Pueblo Viejo
Porgera
Ladolam
Pascua-Lama
! High
sulfidation
deposits
Round Mountain
El Indio
Comstock Lode
McDonald
Hishikari
Pachuca-Real
Waihi
Kelian
Pierina
200
400
600
800
Au (t)
Epithermal Ores
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Epithermal Ores
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Selected
styles and
geometries of
epithermal
deposits
Epithermal Ores
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Ore Deposition
Low sulfidation
! Boiling is the principle mechanism
! Mixing occurs during collapse of the
system
High sulfidation
! Unequivocal evidence for mixing at some
deposits
! Boiling is a viable mechanism for deposits
where gold is transported as a bisulfide
complex
Depositional Mechanisms
! Boiling leading to loss of H2S
! Au(HS)2- + H+ + 0.5H2 <> Au + 2H2S
Epithermal Ores
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10
Epithermal Ores
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11
Epithermal Ores
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12
Epithermal Ores
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Midas
Bladed
Calcite
Temperature
stability of
hydrothermal
minerals
Alunite:
KAl3(SO4)2(OH)6
Jarosite:
KFe3(SO4)2(OH)6
13
Epithermal Ores
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Frequency and
abundance of
ore and gangue
minerals in Aurich epithermal
deposits
14
Epithermal Ores
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Solubility of Au,
Ag, Zn as a
function of S
and Cl
concentrations
at pH and redox
of LS mineral
assemblages. Clpoor solutions
typical of Aurich LS
ore deposits
transport Au as
bisulfide
complexes, but
cannot transport
much chloridecomplexed base
metals.
15
Epithermal Ores
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Low-Sulfidation Systems
16
Epithermal Ores
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High-Sulfidation Systems
17