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Metallurgical Research of Development Institute, P.O. Box :87, Helwan, Cairo, Egypt
2 Faculty
ABSTRACT: Experimental design technique is applied to optimize shaking table and dry high intensity magnetic
separation processes on recovery of cassiterite from Igla Placer ore of Eastern Desert of Egypt. It could
investigate the effects of individual operating parameters and their interactions for both shaking table and dry
high intensity magnetic separation processes. Applying the optimum conditions for both separation techniques
showed that in case of shaking table separation concentrate containing 13.2% SnO2 and recovery of 86.2% by
weight SnO2 was obtained from a feed containing about 0.048 % SnO2. Cleaning of this concentrate by using dry
high intensity magnetic separation a final concentrate with 90.67% SnO2 and operational recovery of 96.7% SnO2
by weight was obtained.
Keywords: Cassiterite, shaking table, dry high intensity magnetic separation, Box-Behnken design, statistical experimental design
1. INTRODUCTION
Cassiterite (SnO2) is known as tinstone, stannic
oxide, tin (IV) oxide. It has many different industrial
applications such as ceramics, coating cans, pigments
[1], sensors of combustible gases [2], high voltage
varistors [3-4], and as electrode. It has a high specific
gravity
(6.8 - 7.1) and a Mohs scale hardness
of 6 to 7. There are two types of cassiterite, alluvial
placer and lode cassiterite. Alluvial placer cassiterite is
the major source of tin concentrate [5]. Tin placers
contain recoverable amounts of other heavy minerals
such as columbite-tantalite, wolframite, ilmenite, and
monazite [6-10]. About 70% of total world tin
production is produced from placer deposits [11].
About 35 countries mine tin throughout the world.
China, Indonesia, Peru, Bolivia and Brazil accounted
for about 95% of the world tin production [12].
Gravity technique is more recommended for
recovery of cassiterite due to the large difference in
specific gravity between cassiterite (6.8-7.1) and the
gangue silicate minerals (2.6) [13-16]. Cassiterite
could be upgraded by washing, tabling, and magnetic
or electrostatic separation. The final product is
virtually pure cassiterite. On the other hand lode
cassiterite deposit is reduced to the necessary size by
conventional crushing and grinding. The prepared
feed is concentrated by gravity methods that involve
screening, classification, jigging, and tabling. The
concentrate is usually a lower grade than placer
concentrate owing to associated sulfide minerals [5].
The unit operation to prepare primary cassiterite
concentrate in Malaysia and Thailand is the sluice
box used on alluvial deposits known as palongs. The
concentrate contains about 15 to 30 % tin and the
recovery efficiency can be up to 80 % [13]. At Iscor's
Uis Mine in South West Africa, a very low-grade tin
Volume 11 - Issue 22
Stroke length
cm
Feed rate
gm/min
Recovery
% by weight
Belt speed
rpm
Feed rate
gm/min
Grade
% by weight
Recovery
% by weight
Sum
of
squares
DF
Mean square
F Value
Prope > F
Where:
is the predicted response, s are studied
and
are the regression
variables;
parameters. Software package, Design-Expert 6.0.5,
Stat-Ease, Inc., Minneapolis, USA, was used for
regression analysis of experimental data and to plot
M. A. Youssef, M.K. Abd El-Rahman, N.H. Helal, M. M. El- Rabiei, S. R. Elsaidy / The Journal of ORE DRESSING 2009
2
2.5
3
50
75
100
15
20
25
Table 3. Factorial design for shaking table and dry magnetic separation
Shaking Table Separation
Dry Magnetic Separation
Run
1
4
3
400
20
7.37
81.4
75
75
750
90.6
2
5
2.5
400
20
6.87
84
80
75
500
62.5
3
4
2
100
20
10.6
76.8
80
100
750
58.7
4
4
2.5
100
25
8.94
82
75
100
1000
77.1
5
4
3
100
20
5.7
80
75
75
750
90.6
6
4
3
250
25
7.95
83
75
50
500
81.3
7
5
2.5
100
20
6.2
81.9
70
50
750
74.6
8
4
3
250
15
7.46
79.8
70
75
1000
73.2
9
3
3
250
20
5.79
79.2
75
75
750
90.6
10
4
2.5
400
25
12.47
83.4
75
75
750
90.6
11
3
2.5
400
20
9
82.6
80
50
750
61.3
12
4
2.5
100
15
8.5
81
75
50
1000
79
13
5
2
250
20
4
74.5
80
75
1000
64.2
14
3
2.5
100
20
8.2
81.4
75
75
750
90.6
15
3
2.5
250
15
7.95
80.8
70
100
750
78.6
16
4
2.5
250
20
13.2
84.9
70
75
500
72.4
17
4
2.5
250
20
13.2
84.9
75
100
500
78.2
18
4
2.5
250
20
13.19
84.9
19
5
2.5
250
15
4.5
76.4
20
3
2
250
20
8.8
80.4
21
5
3
250
20
3.4
77.5
22
4
2.5
400
15
9.4
79.4
23
4
2.5
250
20
13.21
84.9
24
4
2
400
20
11.5
77.9
25
4
2
250
25
11.9
80
26
3
2.5
250
25
10
82
27
4
2.5
250
20
13.2
84.9
28
4
2
250
15
9.4
78.4
29
5
2.5
250
25
8.7
88.6
96.7
96.4
95.6
91.2
96.7
94.6
87.6
88.1
96.7
96.7
95.7
92.3
96.1
96.7
85.8
89.3
91.7
Volume 11 - Issue 22
0.048
SiO2
58.6
Al2 O3
12.01
MgO
CaO
Na2O
8.26
4.90
4.05
K2O
1.79
TiO2
0.53
Fe2O3
6.16
ZrSO4
Cl
P 2O5
0.01
0.20
0.11
SO3
0.046
L .O. I
3.00
18
0.10
Cum. Wt% passing
SnO2 % ( 0.0005)
8
6
4
80
0.08
SnO2 Distribution %
60
0.06
40
0.04
20
0.02
SnO2 %
10
SnO2 Distribution %
12
100
16
14
2
0
0.00
10
100
1000
10000
Size, micron
Figure 4. The relation between the size (micron) of the original sample and cumulative weight %, SnO2 %, and
distribution percentage of the SnO2
Table 5. Size analysis and distribution of the
undersize fraction of sieve 11.3 mm
Weight SnO2 % Distribution
Size, mm
%
(0.0005)
%
-11.3 + 0.9
81.52
0.061
80.80
-0.9 + 0.4
7.39
0.060
7.17
-0.4 + 0.125
6.60
0.064
6.83
-11.3 to 0.125 95.51
0.0611
94.8
-0.125 + 0.08
1.88
0.060
1.82
-0.08
2.61
0.080
3.37
Total
100.00
0.062
100.00
Distribution
%
42.08
57.92
100
M. A. Youssef, M.K. Abd El-Rahman, N.H. Helal, M. M. El- Rabiei, S. R. Elsaidy / The Journal of ORE DRESSING 2009
Recovery = _7.43 _ 2.48 * + 77.38 * + 7.76 * _ 0.68 * _1.8 * 2 _ 17.42 * 2 _ 6.63* 2 _ 0.045* 2 + 2.1* +
(2)
1.5* + 0.55* + 1.0* + 0.16* + 1.0*
Recovery = -585.05 +16.94* + 0.33* + 0.014* - 0.11* 2 - 4.44* 2 - 2.36* 2 + 3.40 * + 1.80* + 7.20*
(3)
Table 7. ANOVA for response surface 2FI model analysis of variance
Shaking Table Separation
Source
Model
231.41
14
16.53
1.02
1
1.02
13.87
1
13.87
2.61
1
2.61
44.85
1
44.85
2
21.11
1
21.11
2
122.98
1
122.98
2
14.43
1
14.43
2
8.09
1
8.09
4.41
1
4.41
0.20
1
0.20
30.25
1
30.25
0.022
1
0.022
0.64
1
0.64
2.25
1
2.25
Residual
44.01
14
3.14
Lack of Fit
44.01
10
4.40
0.00
4
0.00
Pure Error
Cor Total
275.42
28
Dry High Intensity Magnetic Separation
Model
225.81
9
25.09
136.13
1
136.13
4.35
1
4.35
2.31
1
2.31
2
31.84
1
31.84
2
32.42
1
32.42
2
9.16
1
9.16
0.72
1
0.72
0.20
1
0.20
0.81
1
0.81
Residual
1.74
7
0.25
Lack of Fit
1.74
3
0.58
Pure Error
0.00
4
0.00
Cor Total
227.55
16
5.26
0.32
4.41
0.83
14.27
6.72
39.12
4.59
2.57
1.40
0.064
9.62
7.158E-003
0.20
0.72
0.0019
0.5778
0.0543
0.3773
0.0020
0.0213
< 0.0001
0.0502
0.1310
0.2559
0.8033
0.0078
0.9338
0.6587
0.4117
100.79
546.84
17.48
9.28
127.92
130.25
36.80
2.90
0.81
3.25
< 0.0001
< 0.0001
0.0041
0.0187
< 0.0001
< 0.0001
0.0005
0.1322
0.3971
0.1142
Volume 11 - Issue 22
Table 8. ANOVA for response surface quadratic model for the shaking table separation and dry high intensity
magnetic separation
Shaking Table Separation
Dry Magnetic Separation
The statistical parameters
(Grade %)
(Recovery %
(Grade %)
(Recovery %
The standard deviation
0.85
1.77
2.24
0.50
R-squared
0.9575
0.8402
0.9820
0.9923
Adequate precision
15.631
7.879
18.017
28.811
84.9646
82.8047
80.6448
R e co ve ry %
78.4849
76.325
3.00
5.00
2.75
4.50
2.50
4.00
2.25
3.50
2.00 3.00
M. A. Youssef, M.K. Abd El-Rahman, N.H. Helal, M. M. El- Rabiei, S. R. Elsaidy / The Journal of ORE DRESSING 2009
Desirability
3.00
0.295
0.417
85.9647
0.417
0.540
0.540
84.4923
Recovery %
83.0198
2.75
80.075
25.00
400.00
81.5474
Predicti 0.91
2.50
22.50
325.00
20.00
2.25
0.786
250.00
17.50
175.00
0.540
15.00 100.00
0.540
0.663
0.417
2.00
3.00
3.50
4.00
4.50
5.00
(a)
97.212
Desirability
100.00
0.381
94.0903
0.381
87.8468
0.536
87.50
84.725
100.00
80.00
87.50
77.50
75.00
75.00
62.50
Recovery %
90.9685
0.536
0.690
0.690
Predicti 1.00
75.00
62.50
72.50
50.00 70.00
50.00
70.00
72.50
75.00
77.50
80.00
(b)
Figure 7. Optimum parameters for shaking table and
dry high ntensity magnetic separation
98.2563
95.1641
Recovery %
92.0719
88.9797
85.8875
100.00
80.00
87.50
77.50
75.00
75.00
62.50
72.50
50.00
70.00
(degree)
(degree)
Stroke
Belt speed
73
2.50
length (cm)
(rpm)
Feed rate
Feed rate
742
307.6
(gm/min)
(gm/min)
Water flow
24.22
rate (l/min)
Volume 11 - Issue 22
Table 10. Shaking table and dry high ntensity magnetic separation cassiterite concentrates at optimum
parameters
Shaking Table Separation
Fraction
Weight %
SnO2 %
Recovery %
Concentrate
tail
Total
Fraction
Non magnetic
0.314
99.686
100
13.2
0.0066
0.048
86.2
13.8
100
Cleaning of Shaking Table Concentrate using Dry High Intensity Magnetic Separation
Weight %
SnO2 %
Recovery %
Operational
Overall
Operational
14.5
0.046
90.67
96.7
Magnetic
Total
85.5
100
0.268
0.314
0.51
13.2
3.3
100
Overall
83.36
2.84
86.20
4. CONCLUSIONS
Recovery of cassiterite from Igla Placer ore of
Eastern Desert of Egypt using shaking table gravity
separation and high intensity dry magnetic separation
M. A. Youssef, M.K. Abd El-Rahman, N.H. Helal, M. M. El- Rabiei, S. R. Elsaidy / The Journal of ORE DRESSING 2009
[2]
Joseph
Watson,
The
stannic
oxide
semiconductor gas sensor in The Electrical
engineering Handbook 3d Edition; Sensors
Nanoscience Biomedical Engineering and
Instruments ed R.C Dorf CRC Press Taylor
and Francis, (2006).
[3]
Wang, Chun-Ming; Wang, Jin-Feng; Su, WenBin, Microstructural morphology and electrical
properties of copper- and niobium-doped tin
dioxide polycrystalline varistors, Journal of the
American Ceramic Society 89 (2006) 2502.
[4]
[5]
[6]
[7]
[8]
[9]