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1
INTRODUCTION
EXPERIMENTAL INVESTIGATION
The pQzzolanic activity of any material containing
reactive silica can be determined by adding calcium oxide
to the pozzolan with water free from c~,rbon dioxide and
measuring the total alkalinity and calcium oxide content
after a specified reaction time[8]. Previous research has
indicated that rice husk ash can be classed as a pozzolan
on the basis of its reactivity measured in the above manner
and that it conforms to the requirements of an ASTM
C618 Class N pozzolan[9]. A typical chemical composition is shown in Table 1 together with the specific
gravity and Blaine fineness of the ash used in the
investigation. It can be seen from the table that the ash is
composed essentially of silica with small amounts of other
oxides.
?~2
2:30
2:00
Constituent
"~
Percentage
E
SiO,
AI,Oj
I:c,O3
CaO
MgO
Na:0
K20
Ignition loss
Blaine fineness
Specific gravity
Sod,urno l u m , n o t e ~
0%
/ x ~
1:30
92.995
0.592
0.152
0.432
O.415
0.037
2.190
2.932
12,500 cm-" .g
2,36
I% Sodium a l u m i n a t e
!0as
0:30
2W. Sodium a l u m l n o t e !
0100
90
80
70
Cement,
60
%
50
i
!
4:oo /
3:00 I /
~
E 2:30
o.~2
' Sodium
'
J~
c
~.
alummote
o
2T00
[ ~ ~ 2 %
Sodlumalummol"e
1:30
ifI O0
0:30
0
qO0
I
70
Cement,
80
90
60
%
50
0%
81-
olummate
Sodium
*/. Sodium a l u m , n o t e
/ I
-~
2%
Sodium o l u m m o t e
2
I
0100
o/
' c
o % Sodium a l u m , n o t e
33o -~>f-~
90
80
70
Lime,
60
50
I
/
0%
/1%
28124N
r\
16
12
Sodium o l u m ~ n a t e
Sodium oluminoi'e
/ / 2 . Sod,amo,omiote
~
' ~,
~ -
'
x x
8
4
0 iO0
90
80
70
Lime,
60
50
283
Table 2. Compresssive strength of cement-rice husk ash mortars continuously moist cured
Age at test
Mix description
Cement + RHA:Sand
7 days
28 days
90 days
. . . . . . . . . . . . . .
Water/Cement + RHA
Compressive strength (MPaI*
(1 +0):2.75
(0.9 +0.1 ):2.75
(0.8 + 0.2 ): 2.75
(0.7 +0.3):2.75
(0.6 + 0.4):2.75
(0.5 + 0.5): 2.75
0.60
0.63
0.72
0.77
0.78
0.80
14.48
11.03
10.69
10.00
8.27
5.86
15.17
15.17
13.79
14.48
14.00
6.55
16.92
16.38
15.47
16.25
15.90
8.23
Table 3. Compressive strength of lime-rice husk ash mortars cured at 55~C for 7 days
Age at test
Mix proportion
Lime+ RHA:Sand
Percentage*
sodium
aluminate
t0.5 + 0.5):2.75
0.5
1.00
2.50
5.00
7.50
(0.33 + 0.67): 2.75
0.33
0.67
1.67
3.33
5.(X)
10.25 + 0.75):2.75
0.25
0.50
1.25
2.50
3.75
(0.20+0.80):2.75
0.20
0.40
1.00
2.00
3.00
Water/Lime + RHA
Saturated
density
(kg/m 3)
1.114
1.130
1.227
1.379
1.442
1.504
1.176
1.177
1.219
1.304
1.372
1.467
I. 194
1.224
1.233
1.267
1.383
1.391
1.220
1.251
1.275
1.278
1.364
1.439
1826
1826
1810
1778
1762
1762
1810
1810
1826
1810
1762
1762
1826
1826
1794
1810
1778
1762
1826
1810
1778
1778
1794
1762
7 days
28 days
90 days
................
Compressive strength
(MPal't
0.41
0.74
0.99
1.94
1.94
1.96
1.07
1.81
2.12
1.81
4.34
6.51
1.45
1.46
1.72
2.58
3.64
4.53
0.45
0.55
1.09
1.27
1.32
1.34
0.65
0.84
1.09
2.14
2.06
2.28
1.34
1.86
2.20
2.70
4.64
6.90
1.65
1.62
1.75
2.63
3.81
4.85
0.57
0.61
1.14
1.43
1.37
1.65
0.83
1.31
1.21
2.64
2.33
2.70
1.43
1.94
2.27
2.72
4.80
7.09
1.68
1.61
1.79
2.54
3.83
5.01
0.61
0.64
1.09
1.50
1.5 I
1.56
2S4
I)~tl'id I ( .... I,. Ri~ ardo I" t'am~t aml Iqi,hwcmhl K I',~tl!
Table 4. (_ompressive strength of cement lime rice husk ash mortars moist cured for 3 da3.s
Age at test
7 days
Mix proportion
Cement + Lime
+ RHA.'Sand
2~ days
91) day~,
Percentage
sodium
aluminate
Water
Cement + Lime
+ RHA
Saturated
density
{kg,.'m3)
Compressi,..e strength
(MPal*
1.25
2.50
1.25
2.50
1.25
2.50
1.00
2.(X)
1.00
2.00
0.624
0.644
0.644
0.675
0.561
0.605
0.560
0.580
0.623
0.644
1970
1986
1970
1922
2034
2018
1970
1970
1986
2018
0.27
1.05
3.82
3.97
4.06
4.57
4.65
4.90
5.31
5.47
1.64
1.92
1.80
1.98
1.90
2.00
2.59
3.26
0.65
1.85
4.65
4.6~
5.49
5.63
6.18
6.04
6.69
6.72
Mix proportions
(Cement + Lime+ RHA}:
Sand
(0.10 + 0.30 + 0.60):2.75
(0.15+0.283+0.567):2.75
(0.50+ 0 +0.50):2.75
(0.60 + 0 + 0.40):2.75
Percentage
sodium
aluminate
Water
Cement +
Lime+RHA
Density
!kg/m 3)
Linear
shrinkage
(%)
1.25
1.25
1.00
1.00
0.604
0.580
0.619
0.604
1938
1970
1938
1922
0.036
0.041
0.043
0.040
Compressive
Moisture
strength* (MPa)
content
....................
in a % of
7 days
28 days
total absorption
..............
(%)
Cube Block Cube Block
27.23
22.67
31.52
38.84
1.79
2.27
3.38
3.51
1.94
2.33
3.45
3.49
3.77
3.94
5.43
5.72
3.85
3.87
5.08
5.32
285
ASTM requirements
Compressive strength
(1) Non load-bearing
individual unit
average of 3 units
(2) Load-bearing
grade N
individual unit
average of 3 units
grade S
individual unit
average of 3 units
Linear shrinkage ('~%)
0.03 or less
0.03-43.045
0.04543.065, max
3.45 MPa
4.14 MPa
5.50 MPa
6.90 M Pa
4.10 MPa
4,80 MPa
Moisture content (~) for job
site humidity conditions
InterHumid mediate Arid
45
40
35
40
35
30
35
30
25
"~'("
O.60r
05(
0.4C
g
.
gc
0 3C
5
0.20
J
0.10
Shrmkaqe
0
Expansion
-0.08
Number
of
'""
Id'
II
cycles
Fig. 5. Length change characteristics of cement .lime rice husk ash mortars subjected to cyclic
wetting and drying
4-
9~'~
?._._ --~
Cement/
I, m e / R H A
9""
_o~_~.- ._g___8---
3 --
L
I
q-'-'" ~
,':/*,, ..........
,
'---Y
..____ x+
. ~ * ~
~ ....
I---
60/40
Cement/RHA
..........
,5/28.3,56
Cement/hme/RHA
4
5
Number
6
of
I0
il
12
cycles
Fig. 6. Loss in weight of cement lime -.ricehusk ash mortars subjected to cyclic wetting and drying.
compressive strength, particularly for the mixes containing lime. The relatively high cost of sodium aluminate
however mitigates against the use of the material in
proportions higher than those considered in this investigation.
An economic assessment of the viability of block
manufacture based on the use of rice husk ash requires
further experimental investigation. This is currently being
carried out at the Asian Institute of Technology.
Sand
Cement
Lime
Rice husk ash
Sodium aluminate
Mix components
1.00
23.7
19.9
7.7
410.0
Relative
cost per
kg
4.776
1.733
Quantity
(kg)
4.583
23.700
5.128
6.560
4.583
1.00
0.666
0.016
4.776
41.072
45.848
39.971
Relative
cost
cost
Quantity
Ikg)
(0.60 + 0 + 0.40):2.75
Relative
(1.0 + 0 + 0):2.75
0.800
0.016
4.400
0.800
Quantity
(kg)
36.080
6.160
6.560
4.400
18.960
Relative
cost
(0.50 + 0 + 0.50):2.75
Table 7. Relative cost comparison of masonry units made with different mixes
4.033
0.146
0.439
0.879
0.018
Quantity
(kg)
30.377
4.033
3.460
8.736
6.768
7.300
Relative
cost
4.033
0.219
0.415
0.831
0.018
Quantity
(kg)
31.259
4.033
5.190
8.258
6.398
7.380
Relative
cost
(0.15+0.283 +0.567):2.75
t',
"x
2~