Documente Academic
Documente Profesional
Documente Cultură
TM
AQUATREAT BIOCIDES
Effective against a broad spectrum of microorganisms
Introduction
Product Chemistry
AQUATREAT biocides are based on dithiocarbamate chemistry. AQUATREAT SDM (Figure 1) and
AQUATREAT KM (Figure 2) are single component
biocides based on the sodium and potassium salts
of dimethyldithiocarbamate. AQUATREAT DNM-9,
AQUATREAT DNM-30 and AQUATREAT DNM360 are dual component biocides based on a blend
of sodium dimethyldithiocarbamate and disodium
ethylene-bis-dithiocarbamate (Figure 3).
AQUATREAT SDM
Performance Features
EPA registered for a wide range
of applications
Meet FDA requirements for use in paper
and sugar applications
Cost-effective
Effective against a broad spectrum
of microorganisms including bacteria,
fungi and algae:
- Aerobic and anaerobic bacteria
- Sulfate reducing bacteria (SRB)
- Yeasts and molds
- Legionella
Compatibility and strong performance
in a wide range of environments/conditions
- Broad pH and temperature stability
- Organic loading
- Dissolved and suspended solids
Not persistent in discharge waters
Favorable handling and toxicity compared
with competitive materials
AQUATREAT BIOCIDES
AQUATREAT KM
AQUATREAT
DNM-9, DNM-30, DNM-360
Page
Product
Cooling
Towers
Air
Washers
Pulp &
Paper
Mills
Cane
Sugar
Mills
Beet
Sugar
Mills
Drilling
Fluids
Petroleum
Recovery
Sapstain
Control
AQUATREAT SDM
AQUATREAT KM
AQUATREAT DNM-9
AQUATREAT DNM-30
AQUATREAT DNM-360
Hydrocarbon
Fluids
1600
Toxicology
1400
Biocide
Classification
under 21 CFR 191.12
AQUATREAT DNM-30
Isothiazolin
Gluteraldehyde
DBNPA
Non-irritant
Corrosive
Severe Irritant
Severe Irritant
mg/kg
1200
1000
800
600
400
200
0
AQUATREAT
DNM-30
Isothiazolin
Gluteraldehyde
3000
2500
2000
mg/kg
1500
1000
Biocide
Classification
under 21 CFR 191.11
AQUATREAT DNM-30
Isothiazolin
Gluteraldehyde
DBNPA
Non-irritant
Severe Irritant
Severe Irritant
Severe Irritant
AQUATREAT
DNM-30
Isothiazolin
Gluteraldehyde
AQUATREAT Biocides
AQUATREAT BIOCIDES
Cooling Water Applications
Cooling Towers
and Air Washers
AQUATREAT biocides are particularly effective
in controlling problematic organisms in both open
recirculating and closed cooling water systems.
In open recirculating systems, AQUATREAT
biocides are effective against algae and bacteria
commonly found in bulk water and in biofilms.
In closed-loop systems, it is particularly important
to control sulfate reducing bacteria (SRB), denitrifying bacteria, and other anaerobic bacteria. Due to
their functionality and compatibility in reducing
environments, AQUATREAT biocides are often the
biocides of choice in closed-loop cooling systems.
In air washers, AQUATREAT biocides offer the user
broad functionality and a low order of toxicity relative to other commonly used materials.
Algae Control Using
AQUATREAT DNM-30
Algae are organisms that use light energy and
carbon dioxide from the air to produce organic
biomass. They represent a broad range of unicellular and filamentous organisms. Most system operators also refer to the cyanobacteria (blue-green
algae) as members of the algal group although
they are most closely related to bacteria.
Photo 2: Algae
Algae cause a number of direct and indirect problems in water treatment systems. Directly, many
algae grow in dense fibrous mats that plug distribution piping, accelerate corrosion and overall reduce
system performance. These mats also provide areas
for the growth of corrosion causing anaerobic bacteria. Another important effect of algal growth is
the continuous removal of carbon dioxide during
the daylight hours. This can alter water chemistry
and complicate normal scale control treatment
programs.
Indirectly, the consequence of algal growth can
be even more severe and detrimental. Algae convert inorganic carbon (CO2) into organic biomass.
As this biomass dies, it contributes nutrients that
fuel the growth of other bacteria. These bacteria
can foul heat exchanger surfaces and contribute
to corrosion, e.g., sulfate-reducing bacteria.
Laboratory Studies
Laboratory studies are often used to obtain preliminary efficacy data and establish baseline dose
response information. It is important that a biocide
demonstrates a broad range of activity. AQUATREAT DNM-30 has been tested against a number
of pure and field obtained enrichment cultures from
a variety of sources as shown in Table 4. These data
show that AQUATREAT DNM-30 is effective at low
use concentrations against a wide variety of filamentous and unicellular algae.
Algae
Type
Source
MIC*
Ulothrix spp.
5-10
Heterocapsa pygmaea
Slime-forming algae
2.5-5
Euglena gracilis
Unicellular flagellate
ATCC* 12894
5-10
Chlorella pyrenoidosa
ATCC 7516
15-20
Scenedesmus obliquus
ATCC 11457
20-25
20-25
Oscillatoria prolifera
Unknown
2.5-5
Oscillatoria spp.
Carolina Biological
15-20
20-25
35-40
1-5
* The Minimum Inhibitory Concentration (MIC) tests were conducted in the medium specified by the source supplier (American
Type Culture Collection, Rockville, MD; Carolina Biological Co., (CBC) ) or in Alga Gro Medium (CBC) for pure cultures or in
Alga Gro Medium reconstituted in filter sterilized cooling tower basin water for cooling tower enrichments.
Field Studies
AQUATREAT dithiocarbamates have been used and
evaluated in a number of cooling water systems for
their efficacy against planktonic and mat forming
algae. The Figures 6 and 7 (following page) document their ability to control algal mat formation
using alternating slug and maintenance dosages.
System Conditions
Bulk water capacity - 35,000 gallons
Bulk water temperature - 80-100F
Bulk water pH - 8.0 - 8.6
Total dissolved solids - 1,000 - 2,000 ppm
AQUATREAT BIOCIDES
150
Maintenance Dose
100
Slug
Dosage
60
NaOCl
80
Dithiocarbamate
mg Chlorophyll/cm2
mg Chlorophyll/cm2
200
NaOCl
100
250
Dithiocarbamate
40
20
50
0
0
20
40
Days
60
80
Week
Organism
Source
Enrichment Medium
MIC (PPM)
Escherichia coli
ATCC 29990
API-H (mod)
55-60
Escherichia coli
UM 0315
API-H (mod)
60-65
Pseudomonas fluorescens
ATCC 13525
API-H (mod)
85-90
Pseudomonas putida
ATCC 12633
API-H (mod)
60-65
Enterobacter aerogenes
UM 0298
API-H (mod)
35-40
Salmonella typhirmurium
ATCC 14028
API-H (mod)
55-60
NRRL B4278
API-H (mod)
15-20
UM 0115
API-H (mod)
5-10
ATCC 15291
1-5
1.00E+07
0 ppm
CFU/ml
1.00E+06
25 ppm
91.8%
1.00E+05
50 ppm
97.3%
1.00E+04
1.00E+03
1.00E+08
Control (pH5)
DNM-30 (pH5)
Control (pH7)
DNM-30 (pH7)
Control (pH9)
DNM-30 (pH9)
1.00E+07
CFU/ml
1.00E+06
1.00E+05
1.00E+04
1.00E+03
1.00E+02
0
10
15
20
Time (H)
25
30
AQUATREAT BIOCIDES
Cooling Water Applications
When present inside the amoeba, its control is much
more difficult. The conditions presented in Figure
10 show how the functionality of AQUATREAT
DNM-30 for control of unassociated Legionella compares with that of other available biocides. Figure 11
shows the efficacy of AQUATREAT DNM-30 for
amoeba-associated bacteria. This study shows that
DNM-30 has the capacity to penetrate amoeba and
kill intracellular Legionella.
400
350
MIC (ppm Active)
300
250
200
150
100
50
0
SMB
DBNPA
DN-30
DNM-30 Isothiazolin
Quat
SRB Data
The sulfate reducers are a group of anaerobic bacteria that produce hydrogen sulfide from the reduction of sulfate and other sulfur species during their
growth process. While difficult to detect, SRB are
ubiquitous in most industrial water systems where
anaerobic conditions exist. SRB cause severe corrosion and odor problems in both open recirculating
and closed cooling water systems. The economic
implications of SRB in industrial water systems are
significant due to the intensity of under-deposit and
pitting corrosion that they often cause. AQUATREAT DNM-30 has been found to be especially
effective in the control of SRB in both open recirculating and closed cooling water systems.
Figure 12 shows data from a laboratory study
in which AQUATREAT DNM-30 was used to treat
cooling tower sludge. A sludge-in-water sample
was treated with an initial dose of 120 ppm of
AQUATREAT DNM-30 and the number of viable
SRB was determined versus time using an MPN
technique. The data show that the initial dose produced a reduction from 105 to 104 SRB/gram of
sludge. A subsequent 120 ppm dose of AQUATREAT DNM-30 effectively reduced the population
to less than 101 SRB/gram of sludge.
10000
1.00E+07
Legionella CFU/ml
1.00E+06
CFU/ml
1000
100
10
Control
1.00E+05
1.00E+04
Dithiocarbamate
at 120 ppm
(as product)
1.00E+03
1.00E+02
1.00E+01
20
60
ppm DNM-30 (active)
100
20
40
60
100
80
Hours
120
140
160
1.00E+07
1.00E+06
Control
CFU/cm2
Figure 13 shows a field study in which AQUATREAT DNM-30 was evaluated for efficacy against
planktonic SRB in a closed, chilled-water loop.
The number of SRB was counted for five weeks
prior to the addition of AQUATREAT DNM-30.
During week five, a 120 ppm dose of AQUATREAT
DNM-30 was added to the system. The number of
SRB was counted for an additional five weeks after
the biocide addition. The data show that a single
dosage of AQUATREAT DNM-30 effectively lowered the total SRB from 105 SRB/ml to less than
101 SRB/ml.
Control
1.00E+05
100 ppm
DNM-30
1.00E+04
100 ppm
DNM-30
1.00E+03
Total SRB
Total Anaerobes
1.00E+06
MPN SRB/ml
6
8
Time (Weeks)
10
12
CFU/ml or MPN/ml
1.00E+05
1.00E+05
Denitrifiers(0ppm)
1.00E+04
Heterotrophs (176ppm)
1.00E+03
Denitrifiers(176ppm)
1.00E+02
0
10
15
Time (H)
20
25
30
AQUATREAT BIOCIDES
Cooling Water Applications
tively uninjured, while cells exhibiting an orange to
red fluorescence are injured or dead. Using this
technique, two chilled water
samples from closed-loop
systems were treated with
AQUATREAT DNM-30.
The sample labeled Chilled
Water #1 consisted of primary chilled water from a
commercial bank operating
24 hours per day. The
sample labeled Chilled
Water #2 was obtained from
a central plant that supplied chilled water to
10 surrounding buildings. The chilled water from
this system had not been drained for approximately
20 years and contained dozens of primary and
secondary loops. The data in Figure 16 show that
AQUATREAT DNM-30 has good efficacy in both of
these challenging systems after a 12-hour exposure.
50
45
% Cellular Damage
40
35
30
Benefits of
AQUATREAT Biocides
in Cooling Water
Applications
25
20
15
10
5
0
0 ppm
120
ppm
Chilled Water #1
0 ppm
120
ppm
Chilled Water #2
Summary of
Cooling Tower Data
AQUATREAT DNM-30 is a very effective biocide
for problematic microorganisms in both open recirculating and closed cooling water systems. AQUATREAT DNM-30 has proven especially effective for
the control of anaerobic microorganisms such as
SRB and denitrifying bacteria. Additionally, AQUATREAT DNM-30 is effective in closed-loop systems
because of its stability in reduced or non-oxidizing
environments.
10
Pulp
and Paper
Applications
In paper manufacture, large volumes of water are
used in grinding and conveying pulp. The same
water is also used as a medium for forming the
paper web. This water is recycled throughout the
papermaking process and is often a significant
source of microbial contamination. The result of
contamination can lead to significant problems such
as imperfections or loss of paper, mill downtime
and equipment failure. One problem compounding
microbial control issues is the use of recycled fiber,
which contains a much higher microbial load. An
effective biocide must have good microbial control
across a range of pH and temperature conditions
and exhibit functionality in applications using both
virgin and recycled fiber. AQUATREAT biocides
have proven effective in such systems and are widely used to control slime yeasts and fungi associated
with paper mill applications.
Case Study I
AQUATREAT DNM-30 has proven cost-effective
for control of microorganisms associated with fouling in pulp and paper applications. Pulp is digested
at relatively high temperatures, and these temperatures are maintained throughout the papermaking
process. Therefore, a primary group of microorganisms that must be controlled is thermophilic (grow
optimally at temperatures above 45C) bacteria.
A study was conducted with samples from a paper
mill that was experiencing serious microbial problems. The microbial problems included significant
pH reductions in the primary buffer and in the
machine stock chest. Excessive slime formation
on the wet end was also observed. To solve the
problem, several biocides were evaluated in both
the virgin and recycle fiber at process temperature.
The results are shown in Figures 17-22.
Note for Figures 17-22: Measurements taken after 8 hours
of exposure to biocide. Benzalkonium chloride (Quat) was
treated at 50 ppm, AQUATREAT DMN-30 was treated
at 50 ppm, methylene-bis-thiocyanate (MBT) was treated
at 20 ppm, dibromonitrilopropionamide (DBNPA) was
treated at 50 ppm, and isothiazolone was treated at 25 ppm.
1.00E+04
CFU/g
1.00E+03
1.00E+02
1.00E+01
1.00E+00
Control
DNM 30
Quat
MBT
DBNPA
Isothiazolone
CFU/g
1.00E+06
1.00E+05
1.00E+04
1.00E+03
Quat
MBT
DBNPA
Isothiazolone
11
AQUATREAT BIOCIDES
1.00E+08
1.00E+08
1.00E+07
1.00E+07
1.00E+06
1.00E+06
CFU/g
CFU/g
1.00E+05
1.00E+04
1.00E+04
1.00E+03
Control DNM-30
Quat
MBT
DBNPA
Isothiazolone
CFU/g
Control DNM-30
Quat
MBT
DBNPA
Isothiazolone
The data in Figures 17-22 demonstrate that AQUATREAT DNM-30 is a cost-effective biocide in both
virgin and recycle fiber. AQUATREAT DNM-30
was particularly effective against thermophilic
anaerobic bacteria including those causing the
pH reduction in the system.
1.00E+04
1.00E+03
1.00E+02
Control DNM-30
Quat
MBT
DBNPA
Isothiazolone
1.00E+08
1.00E+07
CFU/g
1.00E+03
1.00E+05
1.00E+06
1.00E+05
1.00E+04
Control DNM-30
Quat
MBT
DBNPA
12
1.00E+05
Isothiazolone
Case History II
A 650-ton-per-day mill producing clay-coated recycled paperboard was in the process of closing its
water system (increasing the use of recycled water
and reducing effluent volume). Excess machine
whitewater was clarified with a disc saveall. The
clarified water from the saveall was used as shower
water on the paper machines. The microbial load
of the water system had been evaluated on a weekly
basis from the start of the recycled water program.
Chlorine was applied to the influent water, paper
machine stock system and saveall influent.
Chlorine residuals were tested on each shift. Shortly
after switching to recycled water, total bacterial
counts increased 1,000 times and deposit problems
began to occur on the paper machine. The deposits
were especially prevalent on felt transfer rolls and
suction boxes. Deposits periodically broke free and
caused sheet breaks. The deposits were analyzed
and found to be over 90% microbiological, principally slime. Deposits were also found downstream
on the showers that had been converted to recycled
water. It was determined that the most cost-effective program would be to treat only the recycled
shower water. A biocide evaluation was performed
comparing a variety of biocides. AQUATREAT
DNM-30 was found to have the highest bacterial kill
activity in the system and was determined to be the
most cost-effective biocide.
1.00E+06
CFU/ml
1.00E+05
1.00E+04
0
10
15
Time (H)
20
25
30
1.00E+06
Control
1.00E+05
CFU/ml
Summary of
Pulp and Paper Data
1.00E+04
10
15
Time (H)
20
25
30
Benefits of
AQUATREAT Biocides
in Pulp and Paper
Applications
Effective over a wide pH range
Effective on slime-forming
bacteria, fungi, and yeasts
Meet FDA criteria for use on machines
making paper or board for use in food
packaging (21 CFR 176.300)
Non-irritating to personnel
13
AQUATREAT BIOCIDES
Sugar Applications
Laboratory Studies
Laboratory studies demonstrate the functionality of
AQUATREAT DNM-30 for use in the treatment of a
beet sugar system. In these studies, fresh samples
of raw recirculating juice were incubated across time
at 55C. During incubation, aliquots were taken and
analyzed for total sugar, total lactic acid and pH.
Figures 26-28 show a comparison of AQUATREAT
DNM-30 with a competitive biocide for their relative ability to maintain total sugar
200
160
(g/L)
Competitive
Product A*
80
Control
40
0
20
Hours
40
60
7
6
pH
5
4
Competitive
Product A*
3
0
20
Hours
Control
40
60
Concentration (g/L)
0.5
Control
0.4
0.3
Competitive
Product A*
0.2
0.1
0.0
20
Hours
40
60
14
Field Studies
Beet Sugar Field Study I
A beet sugar production factory in California employs a 5,000-ton tower diffuser system. The normal
chemical treatment before this trial was a shock
dose of formaldehyde. No formaldehyde was
added in the seven days prior to this trial. Six samples were selected for monitoring. These samples
included:
250
200
Concentration (mg/L)
150
Bottom
100
Middle
50
Top
0
0
20
40
Hours
60
80
1.00E+04
Concentration (CFU/ml)
45C
Top of diffuser
Raw Juice
1.00E+03
Press Water
1.00E+02
1.00E+01
1.00E+00
72C
Circulating Juice
66C
20
40
Hours
60
80
300
104
65C
Top
CFU/ml
66C
102
70C
Concentration (mg/L)
250
103
Raw Juice
200
150
Bottom
Middle
Circulating Juice
100
101
50
Press Water
100
0
20
40
Hours
60
80
20
40
Hours
60
80
15
AQUATREAT BIOCIDES
Sugar Applications
1.00E+08
8
ClO2
Concentration CFU/g
1.00E+07
DNM-30
(20 ppm)
ClO2
7.5
84
Percent Sugar
82
7
Total Bacteria
80
5
4
78
Leuconostoc
3
0
6
Hours
% Sugar
10
76
12
7
1.00E+06
6.5
6
1.00E+05
5.5
1.00E+04
1.00E+02
Mesophiles
Thermophiles
pH
1.00E+03
4.5
4
Days
16
Benefits of
AQUATREAT Biocides
in Sugar Applications
EPA registered
Meet FDA criteria under 176.320
Effective against difficult to treat
thermophilic, spore-forming bacteria
Reduces sugar loss and
organic acid formation
Cost-effective at typical use levels
1.00E+06
Controls
CPU/ml or MPN SRB/ml
1.00E+05
1.00E+04
Heterotrophs
1.00E+03
60 ppm DNM-30
120 ppm DNM-30
20
40
60
Sulfate-reducer
Source
Enrichment System
MIC (PPM)
Desulfovibrio spp.
ATCC 7757
Med-42
20-25
Desulfovibrio spp.
Postgate E
65-70
Desulfovibrio spp.
API-sulfate
15-20
Desulfovibrio spp.
API-sulfate
55-60
Desulfobacter spp.
ATCC 43913
Med 1648
45-50
Desulfomonile spp.
ATCC 49306
Med 1690
20-25
Desulfococcus spp.
ATCC 33890
Med 1250
120-130
17
AQUATREAT BIOCIDES
Oil Field Applications
In Figures 36 and 37, the activity of AQUATREAT
DNM-30 is compared with a cocodiamine product
in two additional injection waters. The control
of aerobic heterotrophic bacteria was monitored
across time. The data again show excellent activity
of AQUATREAT DNM-30 relative to the competitive biocide.
and 40, AQUATREAT DNM-30 maintains its efficacy for both heterotrophic bacteria and SRB in seawater brine solutions.
1.00E+06
No Sulfite
100 ppm Sulfite
1.00E+05
1.00E+04
1.00E+07
1.00E+03
1.00E+06
Control
1.00E+02
CFU/ml
1.00E+05
1.00E+01
1.00E+04
CDA (30)
1.00E+00
1.00E+03
1.00E+02
1.00E+01
6
8
Time in Hours
12
24
DNM-30 (120)
0
10
20
30
40
50
Time (h)
60
70
80
CFU/ml
Control
1.00E+05
CFU/ml
Control 6.8%
1.00E+06
1.00E+06
1.00E+04
1.00E+05
1.00E+04
1.00E+02
1.00E+02
1.00E+01
DNM-30 (120)
10
20
30
40
50
Time (h)
60
70
DNM-30 in 6.8%
5
15
Time (h)
20
25
1.00E+07
1.00E+06
Control in 3.4%
1.00E+05
Control
in 6.8%
1.00E+04
1.00E+03
DNM-30 in 3.4%
1.00E+02
DNM-30 in 6.8%
1.00E+01
0
Efficacy in Brines
Biocides are frequently used in oilfield systems
that contain brines and must maintain their activity
under these conditions. As can be seen in Figures 39
18
10
80
SRB/ml
DNM-30 in 3.4%
1.00E+03
CDA (30)
1.00E+03
1.00E+01
Control 3.4%
1.00E+07
1.00E+07
12
24
Time (h)
Treatment
Compound
Amount
Pounds/bbl
Blank mud
pH
14
6.1
8.3
8.3
10.1
13.7
8.2
28.0
8.1
37.0
8.0
45.0
7.9
AQUATREAT DNM-30
pH
.25 as is
6.8
8.2
7.3
10.4
7.9
8.5
9.8
8.3
12.0
8.2
17.1
8.2
AQUATREAT KM
pH
.25 as is
6.9
8.3
7.5
10.3
7.9
8.4
10.1
8.4
13.1
8.3
19.2
8.2
Paraformaldehyde (dry)
pH
.25 as is
5.0
8.3
6.2
10.1
8.7
8.2
9.1
8.1
10.1
8.0
14.0
8.0
Aldehyde-type (25%)
pH
1.0 as is
6.4
8.3
7.4
10.1
10.5
8.1
11.5
8.0
12.9
8.0
21.0
8.0
19
AQUATREAT BIOCIDES
Oil Field Applications
Days
Int.
12
15
19
600 rpm
12
10
11
10
11
12
13
12
11
300 rpm
AV, cps
5.5
5.5
6.5
5.5
4.5
10 Sec. Gel
10 Min. Gel
pH
8.5
8.5
8.2
7.7
7.6
7.0
6.6
6.5
6.3
5.7
API F.L.
10.5
10.5
13.0
44.0
55.0
55.0
56.5
58.5
59.1
60.0
Fann Data
PV, cps
YP, #/100 ft
Days
Int.
13
600 rpm
12
12
12
11
11
10
11
10
11
300 rpm
AV, cps
5.5
5.5
5.5
5.5
10 Sec. Gel
10 Min. Gel
8.5
8.5
8.5
8.6
8.5
8.6
8.5
8.2
8.1
9.0
9.0
9.0
9.0
9.0
9.4
9.6
9.8
15.2
Fann Data
PV, cps
YP, #/100 ft
pH
API F.L
Days
Int.
13
16
13
12
11
11
10
10
10
10
10
10
Fann Data
600 rpm
300 rpm
AV, cps
6.5
5.5
5.5
PV, cps
10 Sec. Gel
10 Min. Gel
pH
8.5
8.5
8.6
8.7
8.5
8.6
8.5
8.5
8.2
8.3
API F.L.
9.5
10.0
10.0
10.5
11.0
10.8
11.0
12.0
14.0
16.0
20
* Base mud was prepared by adding to tap water 7.5 pound per barrel of bentonite clay while stirring, followed by 3.5 pounds per barrel of attapulgite
clay. After the clays were hydrated, 3.0 pounds per barrel of cornstarch were added. Two pounds per barrel of topsoil were added to each mud.
1.00E+08
1.00E+07
1.00E+06
1.00E+05
CFU/ml
Fuel Storage
AQUATREAT biocides are approved for use
in No. 2 oil, intermediate fuel, and No. 6 oil.
AQUATREAT biocides are highly effective
fungicides and bacteriocides for such fuels.
In Figures 41-43, AQUATREAT DNM-30 is compared with a commonly used biocide in diesel fuel.
It can be seen in these data that AQUATREAT
DNM-30 was superior in controlling yeast, mold
and bacteria using a standard ASTM protocol.
1.00E+04
Competitive Product B*
1.00E+03
1.00E+02
DNM-30
1.00E+01
1.00E+00
0
100
200
Time (h)
300
400
* 2,2-(1-methyltrimethylenedioxy)bis-(4-methyl-1,3,2-dioxaboriane)=67.4%
* 2,2-oxybis (4,4,6-trimethyl-1,3,2-dioxaborinane)=27.4%
1.00E+08
1.00E+07
1.00E+06
1.00E+05
CFU/ml
Competitive Product B*
1.00E+04
1.00E+03
DNM-30
1.00E+02
1.00E+01
1.00E+00
Control
100
200
Time (h)
300
400
* 2,2-(1-methyltrimethylenedioxy)bis-(4-methyl-1,3,2-dioxaboriane)=67.4%
* 2,2-oxybis (4,4,6-trimethyl-1,3,2-dioxaborinane)=27.4%
Benefits of
AQUATREAT Biocides
in Oil Applications
Control
Competitive Product B*
Non-corrosive
1.00E+06
CFU/ml
1.00E+05
1.00E+04
1.00E+03
1.00E+02
1.00E+01
1.00E+00
DNM-30
100
200
Time (h)
300
400
* 2,2-(1-methyltrimethylenedioxy)bis-(4-methyl-1,3,2-dioxaboriane)=67.4%
* 2,2-oxybis (4,4,6-trimethyl-1,3,2-dioxaborinane)=27.4%
21
AQUATREAT BIOCIDES
This pesticide is toxic to fish. Do not apply (or use) in estuarine oil
fields where drilling fluids (muds) are discharged in the surface water.
Do not contaminate water by cleaning of equipment or disposal of
wastes. Do not discharge effluent containing this product into lakes,
streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge
Elimination System (NPDES) permit and the permitting authority has
been notified in writing prior to discharge. Do not discharge effluent
containing this product to sewer systems without previously notifying
the local sewage treatment plant authority. For guidance, contact
your State Water Board or Regional Office of the EPA.
First Aid
IF IN EYES
- Hold eye open and rinse slowly and gently with water
for 15-20 minutes.
- Remove contact lenses, if present, after the first 5 minutes,
then continue rinsing eye.
- Call a poison control center or doctor for treatment advice.
IF ON SKIN OR CLOTHING
- Rinse skin immediately with plenty of water for 15-20 minutes.
IF SWALLOWED
3. CONTAINER DISPOSAL:
(a) Reseal container and offer for reconditioning, or
IF INHALED
- Move person to fresh air.
(b) Metal Containers: Triple rinse (or equivalent). Then offer for
recycling or reconditioning, or puncture and dispose of in a sanitary
landfill or by other approved state and local procedures.
(c) Plastic containers: Triple rinse (or equivalent). Then offer for
recycling or reconditioning, or puncture and dispose of in a sanitary
landfill, or incineration, or if allowed by state and local authorities,
by burning. If burned, stay out of smoke.
22
TM
North America
South America
United States
Alco Chemical
909 Mueller Drive, P.O.Box 5401
Chattanooga, TN 37406-0401
Toll-free 800-251-1080
Phone: 423-629-1405
Fax: 423-698-8723
Argentina
National Starch & Chemical S.A.
Specialty Polymers & Adhesives Group
N. Avellaneda 1357
1642 San Isidro
Phone: 54-11-4743-2066
Fax: 54-11-4742-2971
Canada
Nacan Products Limited
Specialty Polymers & Adhesives Group
50 Marie-Victorin Blvd.
Boucherville, Quebec J4B 1V5
Phone 450-655-2220
Fax 450-655-6136
Brazil
National Starch & Chemical
Rua Cenno Sbrighi, 27
0503-010 - Sao Paolo - SP
Phone: 55-11-3618-3655
Fax: 55-11-3611-1473
Mexico
National Starch & Chemical S.A. de C.V.
Specialty Polymers & Adhesives Group
Blvd. Miguel de Cervantes Saavedra No. 71
Col. Granada
C.P. 11520 Mexico, D.F.
Phone: 52-5-262-7350
Fax: 52-5-531-0417
Venezuela
National Starch & Chemical C.A.
Specialty Polymers & Adhesives Group
Avenida Francisco de Miranda
Centro Plaza, Torre C
Piso 15 Oficina 15F
Caracas
Phone: 58-2-2840035
Fax: 58-2-2861827
Europe
Asia-Pacific
Switzerland
Alco Chemical Europe
Specialty Polymers & Adhesives Group
Industriestrasse 16
CH-6203
Sempach Station
Phone: 41-41-469-6700
Fax: 41-41-469-6710
China
National Starch & Chemical Ltd.
Specialty Polymers & Adhesives Group
Guang Zhou Office
Rm 2702, Tower 2, Dong-jun Plaza
836 Dong Feng Dong Road
Guangzhou 510080 P.R.C.
Phone: 86-20-8761-5092
Fax: 86-20-8760-5440
Africa
South Africa
Arkem (Pty.) Ltd.
P.O. Box 12673
200 Lansdowne Road
Jacobs, Natal
Durban 4052
Phone: 27 31 468 8722
Fax: 27 31 468 8556
Thailand
National Starch & Chemical Ltd.
Specialty Polymers & Adhesives Group
Bangna Towers C, 11th Floor,
2/3 Mu 14, Bangna Trad (Km6)
Bangplee, Samutprakarn 10540
Phone: 66-2-312-0530
Fax: 66-2-312-0276
Taiwan
National Starch & Chemical Ltd.
No. 1, Kung Yeh I Road
Ping Cheng Industrial Park
Ping Cheng City, Taoyuan Hsien
Phone: 886-3-469-6550
Fax: 886-3-419-1080
Korea
National Starch & Chemical Ltd.
18th floor, Sam Boo Bldg.
676 Yeoksam-dong
Kangnam-ku, Seoul 135-080
Phone: 82-2-527-6000
Fax: 82-2-527-6025/6
Australia
National Starch & Chemical Pty., Ltd.
7-9 Stanton Road
Seven Hills, Sydney NSW 2147
Phone: 61-2-9624-6022
Fax: 61-2-9624-1468
Japan (Osaka)
Nippon-NSC, Ltd.
Specialty Polymers & Adhesives Group
Sanbazuru Building
1-6-5 Semba Nishi
Minoo, Osaka 562
Phone: 81-727-30-8895
Fax: 81-727-27-2193
The information given and the recommendations made herein are based on our research and are believed to be accurate but no guaranty of their accuracy is made. In every case, we urge and
recommend that purchasers, before using any product in full scale production, make their own tests to determine to their own satisfaction whether the product is of acceptable quality and is
suitable for their particular purposes under their own operating conditions. THE PRODUCTS DISCUSSED HEREIN ARE SOLD WITHOUT ANY WARRANTY AS TO MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED. No representative of ours has any authority to waive or change the foregoing provisions but,
subject to such provisions, our engineers are available to assist purchasers in adapting our products to their needs and to the circumstances prevailing in their business. Nothing contained
herein shall be construed to imply the non-existence of any relevant patents or to constitute a permission, inducement or recommendation to practice any invention covered by any patent.
5301-01-0807-10M