SULIT

4541/1
Chemistry
Paper 1
October
2007
1 hrs

4541/1

BAHAGIAN SEKOLAH
KEMENTERIAN PELAJARAN MALAYSIA
______________________________________________
PEPERIKSAAN SELARAS DIAGNOSTIK TINGKATAN 4 2007

FORM 4 CHEMISTRY
Paper 1
Satu jam lima belas minit

JANGAN BUKA KERTAS SOALAN INI HINGGA DIBERITAHU

1.
2.
3.
4.
5.
6.
7.

Kertas soalan ini mengandungi 50 soalan.

Jawab semua soalan
Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan
Bagi setiap soalan hitamkan satu ruangan sahaja
Sekiranya anda hendak menukar jawapan, padamkan tanda yang telah
dibuat. Kemudian hitamkan jawapan yang baru.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala.
Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh
diprogramkan.

Kertas soalan ini mengandungi 17 halaman bercetak

The following figure shows the symbol of atom X

16

X
8
Which of the following is the electron arrangement for an ion for X?
A
B
C
D
2

Which of the following elements would form an ionic compound with chlorine?
A
B
C
D

lead (II) bromide

silver bromide
lead (II) iodide
iron (II) bromide

Which of the following elements burns in air to form an oxide and when the oxide
dissolves in water, it turns blue litmus to red?
A
B
C
D

Potassium
Hydrogen
Oxygen
Helium

When a molten substance is electrolysed, a brown vapour is produced at the anode

and a grey solid which is attracted by a magnet is produced at the cathode. The
substance could be
A
B
C
D

2.6
2.8
2.8.6
2.8.8

Sodium
Potassium
Carbon
Hydrogen

Among the following salts, which is soluble in water?

A
B
C
D

Barium sulphate
Lead(II) chloride
Zinc carbonate
Lead(II) nitrate

Which of the following voltaic cells has the highest voltage?

A
Cu

B
Zn

C
Zn

Mg

Mg

Fe

D
Ag

Cu

The table below shows the relative atomic mass for atoms of elements Q and S.
Element
Q

Relative atomic mass

20

40

Which of the following statements are correct?

I
II
III
IV

1 mol of atom S has twice the number of atoms in 1 mol of atom Q

One atom of S is 2 times heavier than one atom of Q
2 g of Q contains the same the number of moles of atoms as in 8 g of S
40 g of S contains the same number of atoms as in 20 g of Q

A
B
C
D

II and III only

I, II and III only
II and IV only
I, II, III and IV

The figure below shows the set-up of apparatus for the titration of potassium
hydroxide solution with sulphuric acid.

Sulphuric acid 0.1 mol dm 3

20 cm3 of potassium
hydroxide solution
0.1 mol dm 3
And phenolthalein as an
indicator
What is the total volume of the mixture in the conical flask at the end point of the
titration ?
A
10 cm3
B
20 cm3
C
30 cm3
D
40 cm3

The electron arrangement of atom E is 2.8.7 and atom G has four valence
electrons. What is the formula of the compound formed between E and G ?
A
B
C
D

10

A green solid is heated up strongly and the residue is black in colour. The solid is
A
B
C
D

11

GE2
GE4
G2E
G4E

Sodium carbonate
Lead(II) nitrate
Iron(II) carbonate
Copper(II) carbonate

The chemical formula for magnesium chloride is as follows:

MgCl2
Which of the following information can be obtained from the formula?
I
The mol ratio of magnesium to chlorine is 1: 2
II
The compound is made up of magnesium ions and chloride ions
III
The relative formula mass of the compound is the total mass of two
magnesium atoms and 1 chlorine atom
IV
One formula unit of this compound contains two ions only
A
B
C
D
12

I and II only
I and III only
II and III only
II, III and IV only

The table below shows the proton number of elements M and N.

Element
M
N

Proton number
3
17

Which is true of the compound formed between elements M and N?

Compound formula
Type of bond
A
MN
Ionic bond
B
MN
Covalent bond
C
M2N3
Ionic bond
D
M3N2
Covalent bond
13

The diagram shows a simple voltaic cell. The beaker contains glacial ethanoic

acid.
V
Zn

Fe
glacial ethanoic acid

Which of the following substances will cause the flow of electrons when added
into the beaker?
A
B
C
D
14

Alcohol
Chloroform
Sodium carbonate solution
Tetrachloromethane

Sulphuric acid used as an electrolyte in car battery has concentration of 0.5 mol
dm 3. How many moles of sulphuric acid is there in 100 cm3?
A
0.025
B
0.05
C
0.1
D
0.5

15 The table below shows the results of qualitative analysis of a salt.

Qualitative analysis

Observation

Sodium hydroxide solution is

added slowly until in excess.

White precipitate formed

dissolves in excess sodium
hydroxide solution.

Ammonia solution is mixed

slowly until in excess.

White precipitate formed does

not dissolve in excess
ammonia solution.

Among the following ions, which may be present in the salt?

A
B
C
D

16

Zn2+
Pb2+
Cu2+
Mg2+

What is the number of atoms contained in 24 g of oxygen gas?

6

Given the relative atomic mass, O = 16, Avogadro Number = 6.02 X 1023
1.5 X 1023
3.0 X 1023
4.52 X 1023
9.03 X 1023

A
B
C
D

17

The electron arrangements of atoms of elements Y and Z are 2.8.4 and 2.6
respectively. Which of the following statements about formation of compound of
P and Q is true?

18

Each atom of Z receives an electron from an atom of Y

Each atom of Y receives four electrons from an atom of Z

Each atom of Y combines with two atoms of Z by sharing of electrons

Each atom of Y combines with one atom of Z by transfer of electrons

The diagram shows a voltaic cell.

V
F
Metal N
Metal M
Dilute hydrochloric acid
Which of the following metal pair will result in the flow of electrons from metal
M to metal N?

A
B
C
D

Metal M
Zinc
Copper
Copper
Tin

Metal N
Aluminium
Zinc
Silver
Iron

19

The table below shows the observation of the reaction between calcium carbonate
and thanoic acid in two different solvents.
Beaker
X
Y

Reaction

Observation

calcium carbonate + ethanoic acid in

distilled water.
calcium carbonate +
ethanoic acid in benzene

Effervescence occurs
No visible change

Which of the following statements are true about the observation in beaker X and
beaker Y?

20

I
II
III
IV

Water ionizes ethanoic acid in beaker X

Benzene ionizes ethanoic acid in beaker
Water reacts with calcium carbonate in beaker X.
Ethanoic acid remains as molecule in beaker Y.

A
B
C
D

I and II only
I and IV only
II and III only
III and IV only

The equation below shows the action of heat on copper(II) carbonate, CuCO3.
CuCO3 CuO + CO2
How many moles of CuCO3 are needed to produce 6.0 g of copper(II) oxide,
CuO?
[Relative atomic mass : C = 12, O = 16, Cu = 64]
A
B
C
D

0.035
0.050
0.075
0.080

21

22

23

Which of the following is correct for relative molecular mass?

A

Mass of an atom
1/12 x mass of one carbon-12 atom

Mass of one molecule

1/12 x mass of one carbon-12 molecule

Mass of one molecule

1/12 x mass of one carbon-12 atom

Mass of an atom
1/12 x mass of one carbon-12 molecule

How many electrons are shared in the bonding of an oxygen molecule

A

The diagram shows an electrolytic cell.

Carbon

Carbon

Methylbenzene

Which of the following statements best explain why the bulb does not
light up?

24

A
Methylbenzene is not soluble in water.
B
Methylbenzene has strong covalent bonds.
C
Methylbenzene has no free mobile ions.
D
Methylbenzene has low melting point.
Which of the following solution has the lowest pH value?
9

A
B
C
D

0.1 mol dm 3 ethanoic acid

0.1 mol dm 3 potassium hydroxide
0.1 mol dm 3 ammonia solution
0.1 mol dm 3 nitric acid

The formula for a carbonate ion is CO32- and for nitrate ion is NO3-. If the formula
of the carbonate salt of X is XCO3, what is the formula of the nitrate salt of X?

25

A
B
C
D

26

XNO3
X2NO3
X(NO3)2
X(NO3)3

The diagram shows the set up of the apparatus for an experiment to study the
reaction between chlorine gas and substance X.
Chlorine gas

Substance X

When the reaction is completed, a white solid is observed. Name the substance
produced.
A
B
C
D

27

Copper(II) chloride
Iron(II) chloride
Lithium chloride
Lithium oxide

The diagram shows the electron arrangement of a compound formed between two
M atoms

10

Which of the following statements is true about the compound?

A
Consists of ions
B
Conduct electricity in molten state
C
The compound has a low melting point
D
Dissolves in water
28

Which of the following products are formed at the anode and cathode when
aqueous potassium sulphate solution is electrolysed using platinum electrodes ?

CathodeAnode
A
PotassiumSulphur dioxideB
HydrogenOxygenD
HydrogenSulphur dioxide

29

PotassiumOxygenC

Two different acids have pH values 1 and 4 respectively. The difference in the pH
values is due to the

A
different degree of ionisation
B
different concentrations
C
different acidic properties
different electrical conductivities

30

Below is the diagram of set up of apparatus to verify the presence of an anion.

11

Dropper

Solution Y
+
Dilute sulphuric acid
+
Iron(II) sulphate
solution

Concentrated
sulphuric acid

What anion can be identified from this confirmatory test?

A
B
C
D
31

Which of the following elements are in Group 18 in the Periodic Table of

Elements?
A
B
C
D

32

Helium and krypton

Hydrogen and oxygen
Oxygen and krypton
Helium, hydrogen and oxygen

0.32 g of metal X combines with 0.36 g of non-metal Y. What is the empirical

formula for this compound?
Given the relative atomic mass X=64 and Y=35.5
A
B
C
D

33

Nitrate ion
Sulphate ion
Chloride ion
Carbonate ion

XY
X2Y
XY2
XY3

The diagram shows the electron arrangement of an ion X 2+

2+

12

Which of the following is true about an ion X 2+ ?

A
B

Atom X receives electrons

The number of electrons for atom X is 8
C
Electron arrangement of atom X is 2.8
D
X is placed in the Period 3 in the Periodic Table

34

The table shows the electron arrangement for elements X, Y dan Z .

ElementElectron arrangementX
Y
Z
2.8.2
2.8.18.6
2.8.8.3
What is the charge for ion of element X, Y dan Z?
A
B
C
D

X
+2
-2
+2
+2

Y
-2
+2
-2
-2

Z
+6
-3
+3
-3

35

Which of the following is an electrolyte?

A
B
C
D

Glacial ethanoic acid

Ammonia in chloroform
Aqueous solution of magnesium sulphate
Hydrogen chloride in methylbenzene

36

Which of the following is observed if copper (II) sulphate solution is

electrolysed using carbon electrodes?

A
B
C
D

Anode dissolves
Copper is deposited at anode
Oxygen is liberated at cathode
The colour intensity of the solution decreases

37

The reaction between hydrochloric acid and copper ( II ) oxide is an example of

A

displacement reaction

13

B
neutralization reaction
C
decomposition reaction
precipitation reaction

38

Which of the folllowing statements are true about alkali?

A
B
C
D

Weak alkali is an alkali that has higher degree of ionisation

Strong alkali has a low pH value
Alkalis are bases that are soluble in water
Alkalis are not corrosive

39 Plaster of Paris which is used to make plaster casts for supporting broken bones is
made up of
A

calcium sulphate
B
calcium silicate
C
calcium phosphate
D
calcium carbonate

40

Which of the following compound is wrongly matched to its colour?

CompoundColour ACopper(II) nitrate ReddishBCopper(II) sulphateBlueCCopper(II)

carbonateGreenDCopper(II) oxideBlack
41

Aluminium oxide has both acidic and basic properties, therefore it is

A
B
C
D

42

a base oxide
an acid oxide
a metalloid oxide
an amphoteric oxide

Which of the following statements are true about covalent compound?

I
Dissolves in water
II
Formed from reaction between metal and non metal elements
III
Formed from electron sharing between atom
IV
Do not conduct electricity
A
B
C
D

I and II only
III and IV only
I, II and III only
I, II, III and IV

14

43

You are required to electroplate an iron fork with nickel. Which of the following
cathode and electrolyte are used in the electroplating process?
CathodeElectrolyteA
Nickel plateNickel (II) carbonateB
Nickel plateIron
(II) sulphateC
Iron forkIron (II) sulphateD
Iron forkNickel (II) nitrate

44

What is the colour of aqueous ammonia when added with a few drops of methyl
orange solution?
A
remain colourless
B
orange
C
yellow
pink

45

Which pair of solutions when combined will produce an insoluble salt?

A
B
C
D

46

Nitric acid and potassium carbonate

Barium chloride and sodium sulphate
Sulphuric acid and sodium hydroxide
Hydrochloric acid and magnesium nitrate

A night club owner wants to use colourful electric lamps to attract

customers.

Which of the following substances A, B, C or D in the Periodic Table is suitable

to be used in the lamps?
ADBC
47

Which of the following substances have good electrical conductivity in the molten
and in the aqueous form ?
I
II
III

Copper solid
Sodium chloride
Copper ( II ) chloride

15

IV

Chlorine gas

A
B
C

I and II only
II and III only
I, III and IV only
I, II, III and IV

D
48

49

When aqueous solution of silver nitrate is electrolysed using silver electrodes,

which of the following will happen?
I
II
III
IV

Hydrogen gas is liberated at anode.

Silver ions are formed at anode.
Silver atoms are formed at cathode.
Silver ions release electrons at cathode.

A
B
C
D

I and III only

II and III only
II, III and IV only
I, II, III, and IV

The diagram shows the crystalline structure of salt, NaCl.

Which of the following is not a characteristic of the crystal of sodium chloride ?

A It has sharp corners
B
It has flat surfaces
C It has an acute angle between the two adjacent surfaces
D It has straight edges between two adjacent surfaces

16

50

Pb2+ ion can be differentiated from Al3+ ion by using the following reagents except
A
B
C
D

sodium hydroxide
hydrochloric acid
potassium iodide
sodium sulphate
END OF QUESTION PAPER

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