1st lecture (Sandlers book, 4th & 6th chapter): Close system, Open system, Mass, Energy and

Entropy Balance, Intensive and Extensive properties, mathematical preliminaries.

2nd lecture (Y. V. C. Raos book, 2nd chapter): Fundamental relations in entropy and energy
representation, postulates I and II in thermodynamics, Euler relations, Gibbs Duhem relation.
3rd lecture (Y. V. C. Raos book, 4th chapter): Legendre transform, partial Legendre transform.
4th lecture (Y. V. C. Raos book, 4th chapter): Thermodynamic potential, derivation of
Helmholtz free energy, enthalpy, example of how to obtain enthalpy from fundamental
relation in energy representation by partial Legendre transform.
5th lecture (Sandlers book, 6th chapter, section 6.2): Derivation of Gibbs free energy. Maxwell
relation.
6th lecture (Sandlers book, 6th chapter, section 6.2): Application of Maxwell relations, Joul
Thompson coefficient, specific heat at constant pressure and volume, the difference between
them, variation of specific heat at constant pressure with pressure.
7th lecture (Sandlers book, 6th chapter, section 6.4): Equations of state: ideal gas law, van der
Waals equation of state, Redlich Kwong and Redlich Kwong Suave equation of state,
compressibility factor, Virial equation of state. Change in enthalpy and entropy between two
states.
8th lecture (Sandlers book, 6th chapter, section 6.6): van der Waals equation of state written in
terms of reduced temperature and pressure, idea of corresponding states, compressibility
factor as a function of reduced temperature and reduced pressure, discussion on figure 6.6-2.
9th lecture: Quiz -1
10th lecture (Sandlers book, 6th chapter, section 6.6): Calculation of change in enthalpy and
entropy between two states by making use of corresponding states, discussion on figure 6.6-4
and 6.6-5.
11th lecture (Sandlers book, 6th chapter, section 6.6 and 6.7): Solving of problems related to
enthalpy and entropy departure function. Discussion about iterative scheme for solving these
problems. Derivation of enthalpy and entropy departure functions in volume explicit form.
12th lecture: (Sandlers book, 7th chapter, section 7.1, 7.2 and 7.3): Discussion about
conditions for equilibrium and stability under different constraints. Derivation of vapourliquid equilibrium using vdw equation.
13th lecture: Quiz -2
14th lecture: (Sandlers book, 7th chapter, section 7.4): Discussion on metastability in regard to
phase equilibria. Introduction of the idea of Fugacity. Interpretation of phase equilibrium in
terms of fugacity.
15th lecture: (Sandlers book, 7th chapter, section 7.4): Discussion on how to calculate fugacity
of vapour and liquid phases. Discussion on Poynting correction factor. Simplification of
Poynting correction factor subjected to assumptions and simplifications.
16th lecture: (Sandlers book, 7th chapter, section 7.4): Discussion on calculation of fugacity of
solid. Solving of problems related to calculation of fugacity.

17th lecture: (Sandlers book, 7th chapter, section 7.7): Derivation of variation of equilibrium
saturation pressure as a function of temperature (Clausius equation and Clausius Clapeyron
equation). Calculation of Triple point.
18th lecture: (Sandlers book, 8th chapter, section 8.1): Thermodynamic property of mixtures,
partial molar property, chemical potential.
19th lecture: (Sandlers book, 8th chapter, section 8.2 & 8.6): Generalized Gibbs-Duhem
equation. Experimental determination of partial molar volume and enthalpy.
20th lecture: (Sandlers book, 8th and 9th chapter): Reading assignment on criteria for phase
equilibrium in multi-component system (section 8.7). Introduction to ideal gas
mixtures(section 9.1)
21st lecture: (Sandlers book, 9th chapter, section 9.2 & 9.3): Fugacity of a species in a
mixture. Introduction to ideal mixtures.
22nd lecture: (Sandlers book, 9th chapter, section 9.3): Excess Gibbs free energy, excess
partial molar Gibbs free energy, Activity coefficient, Gibbs Duhem Equation in terms of
activity coefficient
23rd lecture: (Sandlers book, 9th chapter, section 9.5 & 9.6): Models of activity coefficient:
one constant Margules equation, Regular solution theory and derivation of van Laar equation,
Redlich Kister equation, two constants Margules equation.
24th lecture: (Sandlers book, 9th chapter, section 9.5 & 9.6): Regular solution theory,
solubility parameter, Wilson equation, Non-random two liquid equation.
25th lecture: (Sandlers book, 9th chapter, 9.4; 10th chapter, section 10.1): Lewis-Randall rule,
derivation of Raoults law and modified Raoults law, introduction to vapour-liquid
equilibrium, bubble point and dew point curve, calculation of vapour-liquid equilibrium
diagram at constant temperature.
26th lecture: (Sandlers book, 10th chapter, section 10.1): Calculation of vapour-liquid
equilibrium diagram at constant pressure, Dew point and bubble point calculation,
Introduction to Flash calculation
27th lecture: (Sandlers book, 10th chapter, section 10.1): Details of flash calculation, Single
stage process for separation of species in a mixture by evaporation.
28th lecture: (Sandlers book, 10th chapter, section 10.1): Multiple stage separation of species
in a mixture. Introduction to distillation.
29th lecture: (Sandlers book, 10th chapter, section 10.2, 11.5): Azeotrope mixture.
Introduction to Osmotic equilibrium.
30th lecture: (Sandlers book, 11th chapter, section 11.5): Estimation of osmotic pressure,
estimation of molecular weight of a solute. Derivation of Gibbs phase rule for osmotic
equilibrium.
31st lecture: (Sandlers book, 11th chapter, section 11.2): Liquid-liquid equilibrium. Stability
criterion.

32nd lecture: (Sandlers book, 11th chapter, section 11.2): Liquid-liquid equilibrium involving
solution at infinite dilution.
33rd lecture: (Sandlers book, 11th chapter, section 11.3): Vapor-liquid-liquid equilibrium.