One Part Polyurethane

MATERIAL SAFETY DATA SHEET

Pentens

1. Product and Company Identification

Product Name

One Part Polyurethane

Synonyms
Chemical Formula
Product Codes

PENTENS PU-300/PU-101

Supplier Information

8F, No. 2, Lane 348, Sec. 2 ,Chung-Shang Rd., Chung-Ho City ,Taipei
Hsien, Taiwan

Emergency phone
numbers

886-2-22400220 ext116

2. Composition / Information on Ingredients

Ingredient

CAS Number

Percent (by weight)

101-68-8

Trade Secret

Diphenyimethane
Diisocyanate

20447-40-5

Trade Secret

Di-n0butyl pthlatc

84-74-2

Trade Secret

4,4 DiphenylmethaneDusocyanate

3. Harzards Identification
Emergency overview

--

Human health hazards Toxic by inhalation and ingestion. Irritation to eyes, respiratory
systems and skin. May cause sensitization by inhalation. Hazards
polymerization may occur. Possible evolution of carbon dioxide gas
may rupture closed containers.
Environmental Effects No environmental hazards are known.
Physical and Chemical Fire produces toxic and corrosive fumes.
Hazards
Specific Harzars

--

4. First-Aid Measures
a. Effects and symptoms
Inhalation

May lead to mucous membrane irritation, tightness of chest, respiratory

tract irritation, coughing, headache, shortness of breath. May lead to
allergic sensitive in some individuals resulting in asthma-like symptoms
upon exposure below TLV. Sensitized ersons should be removed from
any further exposure. Persons with asthma-type conditions or other
chronic respiratory diseases should be excluded from working with the
chemical.

Ingestion

Skin Contact

Localized irritation and discoloration may occur. Occasionally contact

dermatitis is produced as a manifestation of a specific skin allergy.

Eye Contact

Liquid can cause eye irritation, tearing, reddening and swelling.

Permanent cornea injury is unlikely. In addition, vapors in excess of
0.02ppm may cause irritation.

Ingestion

Ingestion is unlikely, the acute oral LD 50 is greater than 15g/kg.

Ingestion can cause irritation and corrosive action in the month, stomach
and digeslive tract.

b. Effects and
symptoms
Inhalation

Move to uncontaminated area, administer oxygen if necessary.

Asmathic-like symptoms, if manifested, may developed immediately, or
be delayed for up to several hours. Obtain medical attention.
Treatment is symptomatic.

Ingestion

Skin Contact

Wash area thoroughly with soap and water.

reuse.

Eye Contact

Flush with water for at least 15 minutes holding lids open with fingers
consult a physician.

Ingestion

Do not induce vomiting. Drink water to reduce corrosity.

physician Treatment is symptomatic.

Launder clothing before

Consult a

5. Fire-Fighting Measures
Extinguishing Media

Large quantity water, foam, dry chemical, Carbon Dioxide.

Special Firefighting
Procedures

Wear self-contained breathing apparatus and full protective clothing.

Fire fighting equipment must be thoroughly cleaned and decontaminated
after use.

Unusual Fire And

Explosion Hazards

Reaction with water may foam.

Avoid water contamination in closed containers or confined areas.

6. Accidental Release Measures

Personal Precaution

Wear appropriate protective clothing and recommended respiratory

equipment.

Environmental

Do not allow to enter sewerage systems or open watercourses.

Precautions
Methods for Cleaning

Spilled should be covered with loose, ahsorbent, non-biodegradable

Up

material. Deactivation solution (90% water, 8% concentrated

ammonia, 2% detergent) over spilt area; allow to react 10 minutes or
longer. Collect materials in open containers and treat with additional
deactivating solution ; allow to stand uncovered for 24-48 hours. Wash
area with deactivating solution. Respiratory, eye and skin protection
should be worn during spill, clean-up and ventilation maintained.

7. Handling and Storage

Handling

Avoid contact with eyes, skin and clothing. Avoid breathing vapor or

mist. Use adequate ventilation.

handing.
Storage

Wash hand and face thoroughly after

Do not stare drums uncovered out of doors. Do not reseal container

unless it is certain that no moisture contamination has occurred.

8. Exposure Controls/ Personal Protection

Engineering Measure

Local exhaust required to keep airborne concentration below the TLV.

Explosion protected electrical equipment. Follow guidelines in the
ACGTH publication <Industrial Ventilation> Exhaust air may need to
be cleaned by scrubbers or filters to reduce environmental
contamination.

Respiratory protection Because of the low vapor pressure, ventilation is sufficient to keep vapors
below the TLV at room temperature. Exception is when the material is
sprayed or heated. If airborne concentrations exceed or are expected to
exceed the TLV, use MSHA/NIOSH approved positive pressure supplied
air respirator with a full face piece or an air supplied hood. For
emergencies, use a positive pressure self-contained breathing apparatus.
Air purifying (cartridge type) respirators are not approved for
protection against isocyanates.
Hands

Productive gloves/rubber gloves

Eyes

Chemical resistant goggles.

Skin and body

Impermeable coveralls and boots as necessary to Prevent eye and skin

contact. Safety shower, eyewash station in work area.

Other protective
measures

Clean protective clothing should be worn daily, Shower after work is

recommended.

9. Physical and Chemical Properties

Physical State and
appearance

Amber Liquid

Odor

Aromatic

Intensity

Slight

Boiling Point (F)

625

Melting Point

Nil

Specific Gravity (at

25C)

1.23

Solubility in Water

Reachts with water

Vapor pressure (mm Hg 10 -5

at 25C)
Vapor Density (AIR=1) 8.5

10. Stability and Reactivity

Stability

Stable under normal conditions

Incompatibility (Materials to
avoid)

Water, amines, strong bases, alcohol, surface active materials.

Hazardous Decomposition
Product

Carbon dioxide, carbon monoxide, nitrogen oxide,

Combustion products ammonia, trace amount of hydrogen
cyanide, acetaldehyde, CH, Toluene & irritating fumes.

11. Toxicological Information

Acute toxicity

LD 50, Oral : 15g/kg ( Rats )

LC 50, inhalation : 370mg/m3 (Rats-4hrs)

Carcinogenicity

No data available.

12. Ecological Information

Product and wastes

Do not allow to escape into waters, waste water or soil.

Possible Environmental
Effects ,Behavior and Fate

No date available on any potential adverse effect on

environment.

13. Disposal Considerations

Product and wstes disposal

Incinerate or dispose of in accordance with existing federal,

state and local environment control regulation.

Contain disposal

1. Containers should be neuralized with liquid

Decontaminant, decontaminated containers must remain
open for at least 48 hours to allow carbon dioxide gas
evolved to escape. Drums may then be disposed off in a
licensed facility.

14. Transport Information

Land Road / Railway
ADR/RID Class

Not classified

Inland waterways
ADNR CLASS

Sea
IMDG Class

Air
IATA-DGR Class

15. SPECIAL PRECAUTIONS

Special comments

Prevent skin and eye contact. Observe TLV limitations.

Avoid breathing vapors and aerosols. Workers should
shower and change to fresh clothing after each shift.
A sensitized individual should not be Exposed to the
product which caused the sensitization. Stored in
tightly sealed containers to protect From atmospheric
moisture. Stored in cool area. Individuals with
existing respiratory disease such as chronic bronchitis,
emphysema or asthma should not be exposed to
isocyanates. These individuals should be identified
through baseline and annual evaluation and removed
from further exposure. Medical examination should
include medical history, vital capacity and forced
expiratory volume at one second.

Literature Reference

1. NIOSH/OSHA .Occupational Health Guidelines for

Chemical Harzards,1981
2. Material Safety Data Sheet (of the raw material
manufacture)

ALL OF THE MSDS DATA ARE FOR REFERENCE ONLY. THE USER SHOULD
JUDGE THE USABILITY THEMSELVES.
COPYRIGHT 2003 UFON NANO-CHEMICAL CORP.
http://www.pentens.com