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Department of Geological Sciences, Northwestern University, 1850 Campus Drive, Evanston, IL 60208-2150, USA
School of Earth and Environmental Sciences, Seoul National University, San 56-1, Sillim 9-dong, Gwanak-gu, Seoul 151-747, Korea
Received 18 January 2006; received in revised form 10 May 2006; accepted 22 May 2006
Abstract
The Red (Hong) River straddles southwestern China and northern Vietnam and drains the eastern Indo-Asian collision zone. We
collected bed sediments from its tributaries and main channel and report the petrographic point counts of framework grains and
major oxide compositions as well as organic and inorganic carbon contents. The Q:F:Rf ratios and Q:F:(LLc) ratios of the bedload indicate quartz-poor, mineralogically immature sediments of recycled orogen provenance. The weathering indices based on
major oxides the chemical index of alteration (CIA) and the weathering index of Parker are also consistent with the recycled
sedimentary nature of the bed sediments. Using geographic information system (GIS) we calculated for each sample basin such
parameters as temperature, precipitation, potential evapotranspiration, runoff, basin length, area, relief, and areal exposure of
igneous, metamorphic and sedimentary rocks. Statistically meaningful correlations are obtained between the two weathering
indices, between CIA and sedimentary to metamorphic rock fragments ratio, S / (S + M), and between CIA and sedimentary rock
cover, but otherwise correlations are poor. The bed sediments preserve signatures of their provenance, but the effect of weathering
is not clearly seen. Subtle differences in the bed sediments are observed between the Red and the Himalayan rivers (Indus, Ganges,
and Brahmaputra) as well as between sub-basins within the Red River system and are attributed mainly to differences in lithology.
2006 Elsevier B.V. All rights reserved.
Keywords: Tibet; Da; Lo; Climate; GIS; Chemical index of alteration
1. Introduction
The collision of India and Asia and the resulting buildup of the Himalayas and the Tibetan Plateau (HTP) are the
most significant tectonic events in the Cenozoic. The
southern periphery of the HTP is an especially important
source of terrigenous sediments on Earth today as
evidenced by the large suspended sediment load carried
Corresponding author. School of Earth and Environmental Sciences,
Seoul National University, San 56-1, Sillim 9-dong, Gwanak-gu, Seoul
151-747, Korea. Tel.: +82 2 880 9167; fax: +82 2 871 3269.
E-mail address: yhuh@snu.ac.kr (Y. Huh).
0037-0738/$ - see front matter 2006 Elsevier B.V. All rights reserved.
doi:10.1016/j.sedgeo.2006.05.029
156
157
Fig. 1. (a) Simplified geologic map of the Red River drainage basin modified from Wakita et al. (2004). RRSZ: Red River Ailao Shan Shear Zone.
(b) Sample location map showing major tributaries of the Red River system.
158
Fig. 2. Average monthly precipitation, potential evapotranspiration, and temperature in the drainage basins of the Red River main channel (MC) and
its two largest tributaries, the Da and Lo.
Table 1
Petrography of bed sediments (63500 m) of the Red River
River Name
Date
mm/dd/
yy
63
263 m GazziDickinson method
500 m (wt.%)
L
Tot
(wt.%)
Q F Lv Lc Lch Ls Lm
% in sample
Rf
Al Op Hm Q
% in sample
Al Op Hm
09/07/01
01/07/03
09/07/01
01/07/03
12/29/02
12/29/02
08/18/01
12/28/02
66.6
59.6
89.9
65.6
97.6
96.3
96.9
94.7
31.6
37.4
9.0
33.9
0.9
1.1
2.1
1.7
64
67
65
62
69
64
70
67
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
2
1
4
2
2
0
2
1
21
8
16
18
9
6
7
15
13
17
14
16
19
25
18
15
100
100
100
100
100
100
100
100
4
5
2
6
2
8
6
5
2
2
4
7
1
3
2
5
2
1
3
8
5
10
5
4
57
51
57
53
57
40
57
51
0
2
0
2
1
6
1
1
0
1
0
0
1
1
0
0
0
2
0
0
0
3
0
1
2
1
3
0
4
1
3
1
27
22
20
29
23
8
17
19
13
17
20
15
12
35
19
25
100 8
100 4
100 5
100 8
100 6
100 16
100 7
100 8
2
2
3
8
2
6
2
2
0
0
2
4
2
8
1
3
01/12/03
09/05/01
01/06/03
12/30/02
12/31/02
12/31/02
01/02/03
94.4
78.4
82.1
81.2
78.9
99.5
95.5
2.6
19.2
13.1
16.5
17.4
0.3
3.5
78 1 0
63 3 0
73 0 0
62 11 0
54 1 0
68 13 0
65 3 0
2
3
0
1
0
2
0
4
1
1
0
0
1
0
12
18
21
9
5
5
11
4
12
4
16
39
11
20
100
100
100
100
100
100
100
1
5
2
2
8
1
7
1
3
1
8
6
3
6
1
5
1
13
5
7
11
58 1 1
53 1 0
49 4 3
53 13 2
35 2 1
52 14 2
63 2 2
2
1
1
0
0
2
0
4
8
0
1
1
4
1
7
0
3
1
1
2
1
20
23
34
16
19
9
14
7
13
6
15
42
14
16
100 6 2
100 4 3
100 1 0
100 11 11
100 11 5
100 5 3
100 11 6
2
4
1
12
3
4
10
Lo
Lo @ Ha Jiang
Gam @ Chiem Hoa
Chay @ Bao Yen
Chay @ Doan Hung, bl. res.
Lo @ Doan Hung, bl. Chay
RD111
RD210
RD207
RD209
RD213
08/24/01
01/01/02
12/31/02
01/01/03
01/02/03
96.7
95.2
80.8
97.9
69.8
2.2
4.6
14.9
0.04
27.3
70 11 0
64 2 0
57 10 0
77 16 0
55 6 0
0
0
0
0
0
1
4
0
0
3
5 14
8 22
2 30
2 4
29 7
100
100
100
100
100
7
4
3
1
2
2
3
5
1
1
18
8
11
4
3
65 12 4
59 3 2
55 11 4
70 17 7
51 7 2
0
0
0
0
0
0
1
1
0
0
1
5
1
0
2
1 16 100 10 3
9 22 100 8 4
5 23 100 8 12
1 6 100 2 1
36 2 100 4 3
15
6
9
4
2
Bank Sediment
Chay @ Doan Hung, bl. res.
88
100 2
29
79
8 0
0
2
0
1
2
5
3
2
Tot
Pl V Ca Ch S
RD121
RD218
RD120
RD217
RD203
RD204
RD103
RD202
1
6
1
2
1
4
3
1
Standard method
5 4
7 100
Da
Babian Jiang
Babian Jiang
Amo Jiang
Amo Jiang
Da @ Lai Chau
Namna @ Lai Chau
Da @ Muong La, ab. res.
Da @ Muong La, ab. res.
Sample
ID
32
Res = reservoir; ab. = above; bl. = below; nr. = near; LB = left bank.The sample ID in bold indicates the furthest downstream sample for the three tributary systems.
Q = total quartz; F = total feldspar; L = Lv + Lc + Lch + Ls + Lm; Lv = volcanic; Lc = total carbonate grains; Lch = chert; Ls = sedimentary; Lm = metamorphic.
Al = alterites; Op = opaque minerals; Hm = heavy minerals; Rf = total rock fragments; Pl = plutonic; V = volcanic; Ca = carbonate; Ch = chert; S = sedimentary; M = metamorphic.
159
160
from the finer silt and clay size fractions. The <63 m size
fraction was sequentially filtered with a pre-weighed
Whatman filter paper and 2 m Millipore filter paper
to determine the silt (263 m) content. The recovered
sand- and silt-size fractions together amounted to >96 wt.%
of the total initial sample, and the clay fraction was negligible (Table 1). Thin sections were prepared from the
sand-size fraction and subjected to both standard and
GazziDickinson petrographic analyses (Potter et al.,
2001; Garzanti et al., 2005), counting 200 framework
grains per sample (Table 1). Aliquots of the <500 m bulk
samples were ground using agate mortar and pestle and
analyzed for chemical composition after lithium borate
fusion at XRAL laboratories in Ontario, Canada. The 10
traditional major element oxides (Si, Al, Fe, Mn, Mg, Ca,
Na, K, Ti, P) were analyzed by ICP-AES (Table 2).
Aliquots of the <500 m ground sample were used to
obtain inorganic carbon (IC) and total carbon (TC)
concentrations by standard coulometric techniques (Huffman, 1977). We calculated the organic carbon (OC) content
by difference.
For Geographic Information System (GIS)-based
analyses, we calculated climatic, hydrologic, geomorphologic, and geologic parameters for individual drainage
basins for each of our samples using the Spatial Analyst
extension of ArcGIS (Table 3). The climatic parameters
were calculated for the months that the samples were
collected. Data for air temperature, precipitation, and
potential evapotranspiration have a spatial resolution of
30 arc sec (Leemans and Cramer, 1991). Runoff data set
was acquired from the UNEP/GRDC Composite Runoff
Fields v 1.0, which is the interpolated runoff at 30-minuteresolution from measurements at hydrological stations
(Fekete et al., 2002). Basin length spans the distance
from the mouth of the river to the furthest point on the
basin perimeter, determined using the Measure tool in
Table 2
Major oxide and carbon content (in weight %) of the bulk (<500 m) bed sediments and the weathering indices
Sample ID
SiO2
Al2O3
Fe2O3
MnO
MgO
CaO
Na2O
K2 O
TiO2
P2O5
LOI
SUM
IC
OC
CIAa
WIP b
Da
RD121
RD218
RD120
RD217
RD203
RD204
RD103
RD202
80.60
79.20
83.94
71.24
81.92
69.83
85.95
80.43
7.70
7.26
6.59
10.37
6.40
10.67
6.74
7.35
3.09
2.97
4.45
4.54
2.92
5.52
3.51
4.23
0.05
0.06
0.06
0.08
0.04
0.09
0.05
0.06
0.81
0.81
1.66
1.88
0.84
1.79
1.01
0.99
0.61
0.95
0.95
1.18
0.55
1.36
0.74
0.71
0.48
0.31
0.41
0.64
0.46
0.87
0.62
0.60
1.42
1.38
1.41
1.89
1.38
3.04
1.81
1.82
0.47
0.55
0.66
0.64
0.37
0.87
0.58
0.67
0.07
0.07
0.07
0.09
0.06
0.11
0.08
0.07
3.20
3.60
3.60
5.45
2.10
3.10
2.75
1.89
98.5
97.2
103.8
98.0
97.0
97.3
103.8
98.8
0.12
0.20
0.16
0.45
0.11
0.24
0.07
0.13
0.17
0.40
0.14
0.23
0.04
<0.01
0.12
<0.01
76
77
72
77
73
67
65
70
19
17
21
27
18
39
25
24
5.24
7.56
9.21
10.45
11.53
8.91
11.26
2.63
4.72
4.16
6.93
5.24
3.45
4.78
0.04
0.10
0.38
0.11
0.10
0.06
0.07
0.86
1.69
0.68
1.87
1.62
1.39
1.95
2.53
3.20
1.20
3.59
2.52
2.47
2.41
0.11
0.91
0.91
1.32
0.43
1.34
1.30
0.99
1.80
2.55
2.33
2.63
2.60
2.84
0.52
0.72
0.67
0.71
0.83
0.47
0.65
0.07
0.12
0.08
0.10
0.20
0.08
0.10
3.90
5.00
3.23
4.11
6.99
2.50
4.26
100.3
102.8
98.0
97.4
98.1
99.7
97.4
0.53
0.82
0.21
0.62
0.52
0.49
0.43
0.04
0.14
<0.01
0.12
0.87
0.03
0.25
73
69
66
62
75
61
64
13
28
33
40
31
39
43
Lo
RD111
RD210
RD207
RD209
RD213
RD209Bk
UCC c
Ass d
10.85
7.55
9.42
5.14
9.69
9.02
15.40
3.62
4.20
4.64
10.89
0.89
3.77
16.38
5.04
1.13
0.12
0.09
0.25
0.03
0.09
0.53
0.10
1.64
0.95
1.88
0.26
0.92
1.65
2.48
0.45
5.77
1.66
3.00
0.25
1.96
1.17
3.59
1.31
0.96
0.43
0.86
0.69
0.56
0.56
3.27
0.42
2.79
1.72
2.69
2.39
2.42
1.50
2.80
0.91
0.45
0.97
0.77
0.09
0.43
8.41
0.64
0.25
0.10
0.09
0.09
0.02
0.09
0.27
0.15
0.02
2.50
3.25
3.36
0.55
4.67
<0.01
100.5
98.5
97.2
95.9
98.1
96.7
0.22
0.27
0.24
0.02
0.23
0.04
0.10
0.15
0.14
0.05
0.44
<0.01
45
68
55
56
65
71
49
22
41
28
31
24
71.09
77.18
63.95
85.60
73.47
57.22
66.60
91.50
LOI = loss on ignition; IC = inorganic carbon; OC = organic carbon. See Table 1 for sample names.
The sample ID in bold indicates the furthest downstream sample for the three tributary systems.
a
Chemical Index of Alteration. See text for definition.
b
Weathering Index of Parker. See text for definition.
c
Upper continental crust. Rudnick and Gao (2003).
d
Average Phanerozoic sandstone. Condie (1993).
161
Table 3
GIS parameters for the Red River sub-basins
Sample
ID
Climatic
Geomorphologic
CCWIa
Lithologic
Air T
PRC
PET
Runoff
Basin length
Area
Relief
mm/y
mm/y
mm/y
km
103 km2
19.0
8.9
19.8
9.8
10.8
12.1
21.2
11.9
2184
176
2308
198
227
210
2402
218
1041
719
1086
730
739
723
1174
736
1390
322
1256
266
303
247
1551
317
233
233
144
144
515
54
664
664
5.60
5.60
3.66
3.66
26.36
6.54
43.47
43.47
1027
1027
1328
1328
1068
1180
1154
1154
0
0
5
5
5
18
8
8
2
2
4
4
1
5
3
3
98
98
91
91
94
78
89
89
315
73
136
29
146
11
892
182
114
2062
178
164
185
169
171
685
993
697
695
655
694
696
336
969
77
184
239
223
231
54
313
52
545
25
704
789
0.89
19.87
2.40
33.20
4.01
43.80
47.53
677
857
760
962
962
1015
982
11
1
9
5
2
11
13
0
14
39
23
19
20
19
89
86
53
72
79
70
69
27
354
5
104
6
155
185
Lo
RD111
RD210
RD207
RD209
RD213
1807
195
182
183
189
1172
597
666
676
626
1233
337
375
376
333
193
186
147
234
365
7.13
15.06
4.30
6.30
36.30
653
716
1103
962
788
7
1
7
14
4
2
5
33
39
20
91
95
60
46
76
364
88
50
91
154
Da
RD121
RD218
RD120
RD217
RD203
RD204
RD103
RD202
20.2
11.5
12.2
13.3
11.9
Ig
Met
Sed
% area
m/y
Climatic parameters are for the months sampled. T = air temperature; PRC = precipitation; PET = potential evapotranspiration.
CCWIa = Cumulative Chemical Weathering Index = Runoff Basin length / Relief (Grantham and Velbel, 1988).
The sample ID in bold indicates the furthest downstream sample for the three tributary systems.
4.1. Petrography
The bed sediments are mostly sand-sized (median
94 wt.%), and the silt size fraction is significant
( 25 wt.%) in only 4 samples (RD121, 218, 217, 213).
The framework grains of all 21 samples are angular to
sub-angular, suggesting that they have not been in the
sedimentary mill for long periods of time. The framework
grains were point counted once according to the standard
method to obtain Q:F:Rf ratios which can be interpreted in
terms of the mineralogical maturity (Fig. 3a). They were
counted a second time according to the GazziDickinson
method to obtain Q:F:L ratios which yield information on
tectonic provenance (Fig. 4a). The main difference
between the two methods is in the assignment of grains
within larger fragments to the category of the larger
fragment for the standard method and to the category of
the individual grain for the GazziDickinson method
(Ingersoll et al., 1984). Quartz and rock fragments are
found in subequal proportions, and feldspars are minor;
average of the three lowermost samples of the Da, Red
162
Fig. 3. (a) QFRf discrimination diagram with the compositional classification of Pettijohn et al. (1987) for the Red River system. (b) Ternary diagram
showing relative abundance of volcanic, sedimentary and plutonic + metamorphic rock fragments.
MC, and Lo is Q:F:Rf = 46:3:51. On the QFRf discrimination diagram, the samples occupy the lithic arenite
field (Pettijohn et al., 1987, p.158) with one exception
(Fig. 3a) and on the QFL diagram, the recycled orogen
field (Dickinson et al., 1983) (Fig. 4a). The ratio of stable
to unstable framework grains, Q / (Q + Rf ), is intermediate
and ranges from 0.29 to 0.52. An exceptional sample from
the Lo drainage (RD209) has a high Q / (Q + Rf ) ratio of
Fig. 4. (a) QFL diagram with tectonic discrimination according to Dickinson et al. (1983) for the Red River system. Filled or highlighted samples
indicate the lowermost samples of the three sub-basins. (b) QFL diagram with 90% confidence interval about the mean (Weltje, 2002) for the Red,
Brahmaputra and Indus Rivers (Garzanti et al., 2004, 2005).
163
Fig. 5. (a) Compositional maturity (Herron, 1988) and (b) tectonic setting
discrimination (Roser and Korsch, 1988) diagrams. Average sandstone
and UCC values are also plotted for reference. Filled or highlighted
samples indicate the lowermost samples of the three sub-basins.
164
undergone sorting during transportation in river channels, the weathering indices could reflect variation in
parent rock composition rather than the degree of
weathering. However, as one of the conditions of a
useful weathering index is that it should permit
comparison of material developed from different parent
rock types (Price and Velbel, 2003), we adopt two of
them for river bed sediments. The most commonly used
is the chemical index of alteration (CIA) (Nesbitt and
Young, 1982).
CIA 100xAl2 O3 =Al2 O3 K2 O Na2 O CaO*;
where the major oxide concentrations are in molar units.
The CaO is from silicates and is calculated by subtracting from total CaO the fractions from apatite and
carbonate (See Section 4.3) (Table 2). The CIA ranges
between 45 (RD111 of the Lo) and 77 (RD121, 217, and
218 of the Da). The latter three high-CIA samples also
have high silt-size fractions (>30%)(Table 1). The Da
samples have a median CIA of 72, in the range of secondary minerals (Nesbitt and Young, 1982) and are interpreted to contain more weathered material than the Lo
samples (median CIA 56) at 5% significance level
(Fig. 6). The Red main channel samples have moderate
values (median CIA: 66).
Another weathering index that we considered is the
Weathering Index of Parker (WIP). It includes only the
highly mobile alkali and alkaline earth elements and not
Al2O3 (Parker, 1970) and for this reason is deemed to be
Fig. 6. Extent of chemical weathering quantified using (a) the Chemical Index of Alteration (CIA) and (b) the Weathering Index of Parker (WIP). The
horizontal lines of the box and whiskers indicate the percentage of the samples below that line. Outliers (<5% or >95%) are marked with open circles.
Higher CIA values and lower WIP values are in theory more intensely weathered samples.
165
166
167
168