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Edexcel GCE
Chemistry (8080, 9080)
6244/01
Summer 2005
Edexcel GCE
(i)
(ii)
(1)
(1)
QWC*
(2 marks)
(1)
(1)
H2O H2SO3
2H2O H3O+ + HSO3
H2O H+ + HSO3
(1)
Contains/produces H+/H3O+
If H2SO4 formed in equation, can score last mark
(iii) (Silicon dioxide) giant covalent/ giant atomic/ giant molecular/
macromolecular
(1)
(4 marks)
(1)
(1)
(i)
(ii)
(c)
(i)
(ii)
(1)
(3 marks)
(1 mark)
(1 mark)
(1)
(1)
(1 mark)
(3 marks)
2. (a)
(i)
(The first electron affinity) is the energy/ enthalpy/ heat change when
1 electron is added to each atom in 1 mole
- must not imply endothermic process e.g. energy required
(1)
of gaseous atoms
(1)
OR
energy change per mole (1)
(1)
(for) A(g) + e A (g)
(ii)
(2 marks)
(1)
(1)
(1)
(3 marks)
(1)
(1)
(2 marks)
(b) (i)
QWC*
(1)
(1)
Charge density of K+ is less than charge density for Ca2+ without explanation
is worth (1) out of these 1st two marks
+
(1)
(1)
(1)
(1)
(3 marks)
Total 13 marks
3. (a)
(b)
(1)
Grignard reagent/ named reagent with incorrect alkyl group scores (0) for
reagent but can score both condition marks.
If halogenoalkane given as reagent, can score 1st mark if Mg included under
conditions.
(1)
(i)
(ii)
(c)
(d)
Observation
effervescence/ bubbles/ fizzing
NOT gas evolved
2C2H5COOH + Na2CO3 2C2H5COONa + CO2 + H2O
Observation
steamy/ misty/ white fumes
NOT smoke
C2H5COOH + PCl5 C2H5COCl + POCl3 + HCl
Reagent
(any one of)
HCN
HCN or KCN
KCN
HCN
(ii)
(3 marks)
(1)
(1)
Condition
(to match)
and KCN
(buffered between) pH between 6 and 9
+ acid /H+ NOT excess
+ base / OH NOT excess
Type of reaction
Nucleophilic addition - both words needed
Condition
Reagent
(any one of)
(to match)
Hydrogen
Pt / Ni / Pd (catalyst) IGNORE ref to temp.
Sodium
(in) ethanol
Lithium aluminium hydride
dry ether/ ethoxyethane
Sodium borohydride
(in) aqueous/ water/ ethanol/ methanol
(1)
(2 marks)
(1)
(1)
(2 marks)
(1)
(1)
(2 marks)
(2)
(1)
(3 marks)
(2)
Type of reaction
Reduction
ACCEPT redox / hydrogenation (not addition)
ACCEPT nucleophilic addition if metal hydrides used
(1)
(3 marks)
(e)
(i)
H H O
C C N C CH3
O
O
(1)
H
C
CH3 (1)
O
ALLOW
If
(ii)
NHCH3
C O represented
(2 marks)
H H H H
+
H C C C C NH3Cl
OR
H H OH H
+ NH3 Cl
OR
H H H H
H C C C C NH3Cl
H H OH H
OR
H H H H
+
H C C C C NH3
H H OH H
OR
+
NH3
NOT
H H H H
H C C C C NH3 Cl
H H OH H
+
If show all bonds in NH3, + charge must be shown on N atom
H
ie
+
N H
H
(1 mark)
(f)
Optical
NOT stereo
(1)
CH2NH2
C
HO H
CH2CH3
H2NH2C
CH3CH2
OH
OR
CH2NH2
C
(2)
but NOT
(3 marks)
Total 21 marks
4. (a)
(i)
(ii)
Kp = p(CO2)
1.48 (atm)
(1 mark)
(i)
(ii)
Kp = p(Cl2) x p(NO)2
(p(NOCl))2
2NOCl
Start
1
-0.22
eq moles
0.78
2NO
0
+0.22
0.22
(1 mark)
Cl2
0
+0.11
0.11
(1)
(1)
0.09910
(1)
0.495
(1)
(1)
(1 mark)
(5 marks)
(1)
(1)
(2 marks)
(1)
(1)
(2 marks)
Total 12 marks
5. (a)
(b)
QWC*
(1)
(1)
(i)
(1)
(ii)
(2 marks)
(1)
(2 marks)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(3 marks)
(1)
(1)
max
(2)
(4 marks)
(1)
(1)
(1)
(3 marks)
Total 14 marks
TOTAL FOR PAPER: 75 MARKS