Documente Academic
Documente Profesional
Documente Cultură
Abstract
Malaysia is the major producer of palm oil in the world. It produces 8.5 million tonnes per year (8:5 106 t y1 ) of palm
oil from 38:6 106 t y1 of fresh fruit bunches. Palm oil production generates large amounts of process residues such as bre
(5:4 106 t y1 ), shell (2:3 106 t y1 ), and empty fruit bunches (8:8 106 t y1 ). A large fraction of the bre and much of
the shell are used as fuel to generate process steam and electricity in the palm processing mill itself. However, much is wasted
by pile burning in the open air with attendant air pollution, dumped in areas adjacent to the mill, or utilized as manure in
the palm oil plantation. In this paper, an attempt has been made to convert these residues into solid fuel. The palm shell and
bre is densied into briquettes of diameter 40, 50 and 60 mm under moderate pressure of 5 13:5 MPa in a hydraulic press.
Experiments are carried out to determine density, durability, impact and compressive strength of the briquettes. The heating
value, burning characteristics, ash and moisture content are other objects of the study. A relationship between press pressure
and the briquette density has been established. The produced briquettes have densities between 1100 and 1200 kg m3 . The
briquettes properties are quite good with good resistance to mechanical disintegration, and will withstand wetting. The gross
caloric value is about 16:4 MJ kg1 (maf), and the ash content is about 6% and the equilibrium moisture content is about
12%. Further work is required to acquire complete understanding of the densication process before good quality and durable
briquettes could be made free from cracks. ? 2002 Elsevier Science Ltd. All rights reserved.
Keywords: Briquettes; Palm oil residues; Palm shell; Palm bre; Densication; Mechanical properties
1. Introduction
Malaysia grows signicant quantities of rice, sugar
cane, palm, coconut and rubber. Palm oil mills produce
crude palm oil and palm kernels as their main products. It also produces signicant quantities of residues
such as bre (from the masocap), shell (from around
the kernel) and empty fruit bunches (EFB). Fibre
and shell are the main thermal energy sources from the
palm oil mills. In 1992 bre and shell generated about
650 GW h to meet the electrical energy demand of
265 palm oil mills through combined heat and power
production. This amounted to 23% of the electrical
production of the country. The biowaste readily available from the palm oil industry is renewable energy
resource. In general, the fresh fruit bunch contains
(by weight) about 21% palm oil, 6 7% palm kernel,
14 15% bre, 6 7% shell and 23% FFB. One
method of upgrading loose residue material to improve
their handling and or combustion properties is by
0961-9534/02/$ - see front matter ? 2002 Elsevier Science Ltd. All rights reserved.
PII: S 0 9 6 1 - 9 5 3 4 ( 0 2 ) 0 0 0 2 2 - 3
506
densication into pellets or briquettes of higher density than original bulk density of the material. It has
been noted that, there is marked improvement in combustion characteristics of densied biomass residue
(DBR) compared to loose biowaste. DBRs have been
reported to have superior and comparable combustion
characteristics to wood-based fuels [1,2]. The properties of importance for any biofuels are its physical and
chemical properties which include density, moisture
content, heating value, ash content, etc. Also important are its mechanical properties such as impact, compressive strength, as well as handling and storage [3].
2. Methodology
2.1. Raw material procurement
The bre and shell residues are collected from a
nearby palm oil mill in the ratio of 60:40 which is
the usual practice in mills to re the boilers fresh,
and theiras received state. The proximate analysis
of solid oil palm residues are as follows:
Fibre
Shell
EFB
72.8
18.8
8.4
76.3
20.5
3.2
75.7
17
7.3
Fibre
Shell
EFB
Hydrogen
Carbon
Sulphur
Nitrogen
Oxygen
Ash
6
47.2
0.3
1.4
36.7
8.4
6.3
52.4
0.2
0.6
37.3
3.2
6.3
48.8
0.2
0.7
36.7
2.3
temperature of 32 C.
2.2. Briquetting process
The moulds are made in diKerent ratios on weight
basis to obtain an optimum mix. Die moulds then subjected to high pressure in a press. The cylindrical briquettes were made of diameters 40, 50 and 60 mm
as shown in Fig. 1. The pressure applied is from 5
13:5 MPa against a back-up piston. The diameter to
length ratio of briquettes was kept constant at 0.75.
The optimum die charges were generally proportional
to the cross-sectional area and ranged from 113 g for
40 mm die to 380 g for 60 mm.
3. Results and discussion
3.1. Pressuredensity relationships
The relationship between pressure and density has
been studied by many research workers. Wheeler [4]
proposed a relationship between pressure and density
for straw in the form of a simple power-law at high
densities. Ooi Chin [5] have worked on pellets and
found a diKerent exponential relationship between die
pressure and density of the form
D = anP + b;
(1)
507
14
13
Pressure (MPa)
12
11
10
9
50mm diameter
60mm diameter
4
1100
1120
1140
1160
1180
1200
1220
1240
1260
1280
1300
Density ( kg/m3)
Fig. 2. Pressure versus relaxed density for three diKerent sizes of the briquettes.
where a; b are empirical constants which vary for different types of feed stocks viz saw dust, rice, husk,
coconut bre, etc. Osobor [6] and Faborode [7] have
also proposed relationships between pressure and density. In the present analysis, after the briquette is removed from the die after 1 week drying at room temperature, the measured length was used to calculate
the relaxed density of the briquette. Fig. 2 shows the
graph between relax density and die pressure for the
three sizes of the mould diameter. There is an exponential increase in pressure with increase in relax density. The relationship is in the form
P = aebD ;
(2)
a = 0:0389;
b = 0:0045;
50 mm diameter;
a = 0:0871;
b = 0:0036;
60 mm diameter;
a = 0:189;
b = 0:0033:
508
Table 1
Burning rate, airfuel ratio and ash content of DBR and coal
Specimen
Mass
(g)
Burning
time (min)
Consumption
(kg s1 )
Burning rate
in (W)
A=F ratio
% ash
DPR
Coal
91.7
136
50
109
3:05 105
2:08 105
3:1 104
3:1 104
500
683
10.2
14.9
5.8
6.8
The crack analysis is made after keeping the briquettes for 4 days at atmosphere conditions. The
cracks fall into two categories: surface (S) and deep
(D) cracks. The crack length is measured in the axial
direction (x) and the depth of the crack in the radial
direction (r). Table 2 shows the crack analysis for
diKerent specimen diameters.
The crack length in the axial direction increases
with diameter of briquettes. The briquettes withstood
the impact when allowed to fall freely from a height
of 12 m. Also the briquettes when immersed in
water for a period of 30 360 s do not show signs
of disintegration which indicate that they do not require shielding from driving rain during transport and
storage.
509
Table 2
Crack analysis for densied biomass residue (DBR)
d = 40 mm
d = 50 mm
d = 60 mm
Specimen
x (mm)
r (mm)
Category
x (mm)
r (mm)
Category
x (mm)
r (mm)
Category
51.2
77.7
54.7
56.9
59.6
S
S
S
S
D
S
D
S
S
28.6
9.8
28.7
6.7
43.2
9.9
27.2
11.2
11.8
9.8
76.9
52.3
D
S
S
S
D
S
D
S
D
S
63.2
10.8
22.3
7.1
28.5
6.9
17.2
11.2
39.6
7.2
32.7
13.9
57.6
11.2
34.6
11.4
46.7
11.4
46.7
D
S
D
S
S
S
S
S
64.2
65.2
65.5
67
References
[1] Bhattacharya SC, Shrestha RM. Biotechnology and
economics, RFRIC Asian Institute of Technology (AIT),
Bangkok, 1990, ISBN 974-888201-441.
[2] Bhattacharya SC, Shrestha RM. A survey of uncarbonised
briquettes and bicoal markets in Thailand. RERIC
International Journal 1989;11:1727.
[3] Carre J, Huber J, Lacrose J. Critical analysis of dry process
improvement of materials for energy producing purposes.
Final report ADE=958=83-BDF=1, center de Recherche
Agronomique.
[4] ODogherty HJ, Wheeler JA. Compression of straw to high
densities in close cylindrical dies. Journal of Agricultural
Engineering 1984;29:6171.
78.9
80.9
80.9