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1.1 Steel
Steel has had a major influence on our lives, the cars we drive, the buildings we work in, the homes
in which we live and countless other facets in between. Steel is used in our electricity-power-line
towers, natural-gas pipelines, machine tools, military weapons-the list is endless. Steel has also
earned a place in our homes in protecting our families, making our lives convenient, its benefits are
undoubtedly clear.
Steel is by far the most important, multi-functional and most adaptable of materials. The
development of mankind would have been impossible but for steel. The backbone of developed
economies was laid on the strength and inherent uses of steel.
The various uses of steel which in turn is a measure of adaptability of steel can be judged from the
following characteristics of steel :
- Hot and cold formable
- Weldable
- Suitable machinability
- Hard, tough and wear resistant
- Corrosion resistant
- Heat resistant and resistance to deformation at high temperatures.
Steel compared to other materials of its type has low production costs. The energy required for
extracting iron from ore is about 25 % of what is needed for extracting aluminum. Steel is
environment friendly as it can be recycled. 5.6 % of element iron is present in earth's crust,
representing a secure raw material base . Steel production is 20 times higher as compared to
production of all non-ferrous metals put together.
The steel industry has developed new technologies and has strived hard to make the world's strongest
and most versatile material even better. There are altogether about 2000 grades of steel developed of
which 1500 grades are high grade steels. There is still immense potential for developing new grades
of steel with varying properties .The large number of grades gives steel the characteristic of a basic
production material Steel has enjoyed an important position in our lives and will continue to do so in
the years to come. However, the degree to which it maintains its dominant position will depend on if
steel can exploit its potential by developing new higher grades and adaptable grades . This can be
achieved by refining the structure and applying alloying techniques and thus furthering its utility
value. We will have to find out ways to use steel and be ready to face a stiff competition from
Aluminium in the future.
1.1.1.b Disadvantages:
1. Tendency toward austenite retention
2. Cost
3. Special handling
4. Temper brittleness in certain grades.
7. Improved toughness
2.
3. Better hardenability
5. Greater strength
6.
Improved machinability
1.1.4 Raw materials & Fluxes :1. Hot metal Chemical composition : 4.3% C, 0.7% Si, <0.3% Mn, 0.2% P, 0.05 0.07% S.
2. Scrap Chemical composition : 0.2% C, 0.2% Si, 0.5% Mn, 0.5% P, 0.025% S, 99.0% Fe t ,
0.45% FeO.
3. IronOre Chemical composition : 0.08% P, 0.02% S, 94.8% Fe2O3, 1.3% SiO2,1.6% Al2O3,
2% LOI (max.), 0.2% Others. Grain size 10 50.
4. DRI (Direct Reduced Iron) Chemical composition : 0.2% C, 0.6% P, 0.02% S, 90.1% Fe t
or 81.1% Fe net + 11.6% FeO.
5. Calcined lime Chemical composition : 87.0% CaO, 3.3% MgO, 3 5% SiO2, <1.5%
Al2O3, 2.5 5% LOI, 1.95% Others. Grain size 10 50.
6. Calcined dolomite Chemical composition : 53% CaO, 35% MgO, 3.5% SiO2, 1.1% Al2O3,
4% LOI, 4.9% Others. Grain size 10 50.
1.1.5 The grades of steel produced by primary steel making can be given as:
1. Drawing Quality (D.Q.):-This type of steel contains 0.08% of carbon, 0.03% of silicon, 0.017%
of sulphur and the alloying elements less than 0.13%.
3. Alloy Steel:-The carbon and sulphur percentage is same as above but the silicon is increased to
0.13% and the alloying elements increased to 1.75%.
Crushed cooled
It is the function of the sintering plant to process fine grain raw material into coarse grained
iron ore sinter for charging the blast furnace.
To begin with, meticulously prepared mixtures are created consisting of fine ore,
concentrates, extras and undersizes arising from screening lumpy burden components at the
blast furnace. Ferriferous fine grain discharges from the production chain of the entire steel
works are also put into the mixtures. By igniting suitable fuel, iron ore sinter is produced by
down draft process. Normally, coke breeze from screening lump coke at the blast furnace is
used as fuel.
2. Batteries: A set of ovens that process coal into coke. Coke ovens are
constructed in batteries of 69 ovens(20-22 tonne capacity each) that are 5
meter tall, 15 meter long, and less than two feet wide. Coke batteries, because
of the exhaust fumes emitted when coke is pushed from the ovens, often are
the dirtiest area of a steel mill complex. Oven is heatedwith the mixture of CO
gas and BF gas(9:1 ratio).During carbonization, coking coals undergo
transformation into plastic state at around 350o-400o C swell and then
resolidify at around 500o-550o C to give semi-coke and then coke. In coke
ovens, after coal is charged inside the oven, plastic layers are formed adjacent
to the heating walls, and with the progress of time, the plastic layers move
towards the centre of oven from either side and ultimately meet each other at
the centre. During coke making, two opposite reactions take place, viz.
condensation and pyrolysis. The quality and quantity of plastic layer is of
extreme importance and it determines the inherent strength of coke matrix.
3. Coke sorting plant(CSP): This plant sort out cokes on the basis of their
sizes. That is, 25-80 mm sized cokes are sent to Blast Furnace, less than 25
mm sized coke is sent to sintering plant, and nut cokes are directly sold.
4. Bi Product Plant(BPP): With addition to steel, SAIL produces bi products
which is produced my exhaust gases of coke ovens. Main bi products which
they make are tar(Napthene), fertilizers(ammonium sulphate) and Benzene.
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ii.
Fluxes :
The major function of the fluxes, limestone and/or LD Slag is to combine with the ash in the
coke and the gangue in the ores to make a fluid slag that can be drained readily from the
furnace hearth.
The ratio of basic oxides to acid oxides must be controlled carefully to preserve the sulfurholding power of the slag, as well as its fluidity and melting point. In instances where the
acids in the coke ash and ore gangue are not sufficient to make enough slag volume to provide
control of the process, silica gravel or quartzite may be added with the charge.
iii.
Coke :
from falling into the hearth and provides a lattice through which the reducing gasses generated at the
tuyeres can pass. Size of coke charged in Blast Furnace is +25 to 80mm.
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As a result of chemical equilibrium limitations, all of the carbon monoxide produced in the
blast furnace cannot be consumed in the reduction of the burden. Consequently, the gas issuing from
the top of the furnace contains sufficient carbon monoxide to have a calorific value of 800 900 Kcal
/ Nm3 of gas.
This gas is typically used to preheat the blast air and to generate power for running the turboblowers; thus, much of the energy is returned to the blast furnace operation. The excess gas is often
used in other portions of the plant. As a consequence of economic and technical supremacy the blast
furnace process continues to become more and more efficient.
i.
The void fraction of a mixture of particles is less than that of either size.
The void fraction decreases only slightly for a ratio of 0.5.
So upper size limit should be about 2 times the lower one.
Physical strength
Maximum breakdown i.e. disintegration of iron ore occurs between 400 6000 C. So a
high driving rate decreases this phenomenon.
ii.
iii.
2.3.4 Progressive steps by which the two-bell top permits charging of materials
a) Bell type with movable throat armour (MTA)
The trajectory of falling material can be varied by varying the throat dia by means of a set of
variable armoured plates (Called MTA) so that desired burden distribution is achieved.
Adjustments are totally circumferential, but there is a limit to how much adjustment can be
attained.The two-bell system requires less height than other systems and it is a comparatively
simple device. The MTA is hydraulically operated & controlled through PLC. The system is
depicted in the figures below.
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b) Bell-Less Top
In case of BLT, there are no bells, as the nomenclature states. This top charging unit was
developed to solve the problem of gas sealing under a high-pressure operation, to provide flexibility
for the most advantageous distribution of burden, and to reduce maintenance time and frequency for
the equipment. When the furnace stockline has descended to the desired level, the lower seal valve
opens and allows the charge to flow onto the distribution chute. The distribution chute rotates around
the vertical axis of the furnace and changes to predetermined angles with respect to the horizontal
plane.
The skips dump the materials to a receiving hopper which is separated from the BLT by upper
material gate and upper gas seal valve. After opening of upper material gate & upper seal valve,
material is discharged into BLT material bin placed over lower material gate & lower gas seal valve.
Then the UMG & USV closed to seal the furnace from the atmosphere & receiving hopper is ready to
receive material from the skips.To dump the material into the furnace, lower seal valve opens and
then lower material gate opened. The material is dumped through a rotating chute which can dump
material at any position of the furnace and can complete the dumping in variable number of rotation
so that desired burden distribution is achieved. This system has the flexibility of charging the
materials in distinctive rings, in spiraling rings of smaller diameter, or of point/spot area filling. The
whole BLT system is hydraulically operated & PLC controlled. Besides achieving perfect burden
distribution, BLT ensures very good gas sealing at the furnace top so that furnace can be operated at
high top pressure.
CONE
PRE-HEATING ZONE
150 3000 C
THROA
T
S
T
A
C
K
O
R
S
H
A
F
T
UPPER REDUCTION
ZONE
300 9000 C
BREAK UP
OF CaCO3
LOWER REDUCTION
ZONE
900 12000 C
FUSION ZONE
SLAG
BIGINS TO
FORM
PIG IRON
BIGINS
MELTING
MOISTUR
E
REMOVA
L
REDUCTIO
N OF IRON
BELLY
BOS
H
COKE
BURNS
1200 16000 C
TUYER
E
TUYERE ZONE,
16000 C
SLAG
FORMATION
ENDS
SLAG, 14200 C
TAP
HOLE
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Fe + 3/2 CO2 ;
H = +12,866 kJ/kmol
Fe + 4/3 CO2 ;
H = +3940 kJ/kmol
FeO + CO
Fe + CO2
H = 16,108 kJ/kmol
Fe + 3/2 H2O ;
H = +48,953 kJ/kmol
Fe + 4/3 H2O ;
H = +51,0421 kJ/kmol
FeO + H2
Fe + H2O
H = +25,104 kJ/kmol
FeO + CO
Fe + CO2
H = 16,108 kJ/kmol
CO2 + C
2CO
H = +172,590 kJ/kmol
FeO + C
Fe + CO
H = +156,482 kJ/kmol
FeO + H2
Fe + H2O
H = +25,104 kJ/kmol
H2O + C
CO + H2
H = +131,378 kJ/kmol
FeO + C
Fe + CO
H = +156,482 kJ/kmol
FeO + H2
Fe + H2O
H = +25,104 kJ/kmol
H2O + C
CO + H2
H = +131,378 kJ/kmol
FeO + C
Fe + CO
H = +156,482 kJ/kmol
Liquid Slag
BF Gas
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As the hot metal leaves the taphole it is discharged into the trough which is a long, narrow basin. At
the far end of the trough there is a dam to hold back the hot metal until the depth of metal in the
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trough is sufficient to contact the bottom of a refractory skimmer block. The skimmer holds back the
slag and diverts it into the slag runners.
The hot metal flows over the dam and down the iron runner where, by a series of gates, it is directed
in sequence to the train of ladles positioned under stationary spouts along the runner. A tilting spout
is positioned between two hot metal tracks. The spout is first tilted to fill the ladle on one track and
then tilted to back to fill the ladle on the other track. While the second ladle is being filled, the first
one can be replaced with an empty so that the cast can be continued uninterrupted while several
ladles are filled.
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2.5.2.1 CONTINUOUS CASTING:The main function of Continuous Casting Shop is to produce steel slabs directly from the
molten steel coming from SMS-II and sending them to Hot Strip Mill (HSM) for hot rolling.
Argon purging
Steel from the electric or basic oxygen furnace is tapped into a ladle and taken to the continuous
casting machine. The ladle is raised onto a turret that rotates the ladle into the casting position
above the tundish. Liquid steel flows out of the ladle into the tundish, and then into a watercooled copper mold. Solidification begins in the mold, and continues through the First Zone and
Strand Guide. In this configuration, the strand is straightened, torch-cut, then discharged for
intermediate storage or hot charged for finished rolling.
Depending on the product end-use, various shapes are cast. In recent years, the
melting/casting/rolling processes have been linked while casting a shape that substantially
conforms to the finished product. The Near-Net-Shape cast section has most commonly been
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applied to Beams and Flat Rolled products, and results in a highly efficient operation. The
complete process chain from liquid metal to finished rolling can be achieved within two hours.
2.
Steel chemistry
3.
Product size
4.
5.
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( g) TundishPriheating Station
( h ) Submerged Entry Nozzle (SEN)
Priheating Device
(c) Tundish
A tundish, located above the mold to feed liquid steel to the mold at a regulated rate
2)
A primary cooling zone or water-cooled copper mold through which the steel is fed from the
tundish, to generate a solidified outer shell sufficiently strong enough to maintain the strand
shape as it passes into the secondary cooling zone
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3)
A secondary cooling zone in association with a containment section positioned below the
mold, through which the still mostly-liquid strand passes and is sprayed with water or water
and air to further solidify the strand
4)
5)
A severing unit (cutting torch or mechanical shears) to cut the solidified strand into pieces for
removal and further processing
6)
To minimize cracking, the casting surface should be maintained in the austenitic range, or in
general above 16000F.
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f) Tundish
The shape of the tundish is typically rectangular, but delta and "T" shapes are also
common. Nozzles are located along its bottom to distribute liquid steel to the molds.
The tundish also serves several other key functions:
Enhances oxide inclusion separation
Provides a continuous flow of liquid steel to the mold during ladle exchanges
Maintains a steady metal height above the nozzles to the molds, thereby keeping steel flow
constant and hence casting speed constant as well (for an open-pouring metering system).
Provides more stable stream patterns to the mold(s)
No. of burners per station 5, Calorific value 2100 Kcal/m3
g) Mold
The main function of the mold is to establish a solid shell sufficient in strength to
contain its liquid core upon entry into the secondary spray cooling zone. Key product
elements are shape, shell thickness, uniform shell temperature distribution, defect-free
internal and surface quality with minimal porosity, and few non-metallic inclusions.
The mold is basically an open-ended box structure, containing a water-cooled inner
lining fabricated from a high purity copper alloy. Mold water transfers heat from the
solidifying shell. The working surface of the copper face is often plated with
chromium or nickel to provide a harder working surface, and to avoid copper pickup
on the surface of the cast strand, which can facilitate surface cracks on the product.
Mold heat transfer is both critical and complex. Mathematical and computer modeling
are typically utilized in developing a greater understanding of mold thermal
conditions, and to aid in proper design and operating practices. Heat transfer is
generally considered as a series of thermal resistances as follows:
Heat transfer through the solidifying shell
Heat transfer from the steel shell surface to the copper mold outer surface
Heat transfer through the copper mold
Heat transfer from the copper mold inner surface to the mold cooling water
Length of mold 1000 m
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From the meniscus to the point where the shell begin to form, in this region liquid
metal is separated from the mold by a thin layer of lubricating oil
3.
The ragion over which the shell has insufficient strength to pull away from the
mold, but due to the condition of the casting surface, intermittent contect exists
4.
The zone over which a definite gas exists, reduced heat transfer takes place by
radition& conduction across the gas in the gap
h) Mold Oscillator
Mold oscillation is necessary to minimize friction and sticking of the solidifying shell,
and avoid shell tearing, and liquid steel breakouts, which can wreak havoc on
equipment and machine downtime due to clean up and repairs. Friction between the
shell and mold is reduced through the use of mold lubricants such as oils or powdered
fluxes. Oscillation is achieved either hydraulically or via motor-driven cams or levers
which support and reciprocate (or oscillate) the mold.
Mold oscillating cycles vary in frequency, stroke and pattern. However, a common
approach is to employ what is called "negative strip", a stroke pattern in which the
downward stroke of the cycle enables the mold to move down faster than the section
withdrawal speed. This enables compressive stresses to develop in the shell that
increase its strength by sealing surface fissures and porosity.
Types of mold :2. The solid block mold
3. Plant mold
4. Tubular mold
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i) Mold Powder:
Used for the lubrication in the mold
Composition of mold powder : Fly ash 40 50%, Glass 10 23%, Calcium Fluoride
12 17%, Sodium Borate 1 8%, Sodium Carbonate 5 6%, Lime 3 6%, Iron
Oxide 3 4%,
j) Secondary Cooling
Typically, the secondary cooling system is comprised of a series of zones, each
responsibleresponsible for a segment of controlled cooling of the solidifying strand as
it progresses through the machine. The sprayed medium is either water or a
combination of air and water.
Uniform spray cooling
Constant surface temperature
Multibank spray cooling
Radiant cooling
k) Nozzles
Most frequently spray nozzle used on billet casting machine gives a full cone pattern
(round/square) although just under the mold one or two nozzle producing a V-pattern
are after employed; the length of the spray chamber may vary from as little as 0.5 m to
4 m. The spray chamber in a slab caster typically has a length in excess of 10 m.
l) Strand Containment
The containment region is an integral part of the secondary cooling area. A series of
retaining rolls contain the strand, extending across opposite strand faces. Edge roll
containment may also be required. The focus of this area is to provide strand guidance
and containment until the solidifying shell is self-supporting.
In order to avoid compromises in product quality, careful consideration must be made
to minimize stresses associated with the roller arrangement and strand unbending.
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Thus, roll layout, including spacing and roll diameters are carefully selected to
minimize
between-roll
bulging
and
liquid/solid
interface
strains.
Strand support requires maintaining strand shape, as the strand itself is a solidifying
shell containing a liquid core, that possesses bulging ferrostatic forces from head
pressure related to machine height. The area of greatest concern is high up in the
machine. Here, the bulging force is relatively small, but the shell is thinner and at its
weakest. To compensate for this inherent weakness and avoid shell rupturing and
resulting liquid steel breakouts, the roll diameter is small with tight spacing. Just
below the mold all four faces are typically supported, with only the broad faces
supported at regions lower in the machine.
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Ingot rolling
Rolling
Shearing
Piling
HSM is the customer of SMSII and Slabbing mill. In the furnaces of the hot-rolling mill, the slabs
produced in the continuous casting line are heated to a temperature of approximately 1,250C, before
being rolled into hot-rolled wide strip. The finished material leaves the train (see diagram) at a
maximum speed of 20 m/s.
Fig. 15: Hot Strip Mill
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01.)
Slab
02.)
roller
Deburring
table 09)
Roughing
device 10.)
Crop
train
shear 17.) Coil weighting machine
03.) Reheating furnace No. 5, walking 11.) High-pressure water 18.) Walking beam conveyer
beam
furnace descaling
19.)
Finishing
13.)
Runout
14.)
table/strip sampling
21.)
Outer
coil
coils
07.)
High-pressure
water
of coils
Annealing
Skin Pass
Mill
eye
binding
06.) Waste gas heat recovery furnaces 3, 4, 15.) Transverse transport of coil
5
conveyer
V-plate
Grains elongated,
permanent strain, hard
& brittle
Heated then soaked,
makes it soft
H2SO4
Pickling
Line
Unrolled
Rolled
Surface hardening
Tandem
Mill
SHEARING
SLITTING
Temp.
Control
Finishing
HCl
5 stands(0.15mm)
Hydraulic
automation gauge
control
Computerized mill
control
Emulsion spray
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Chapter 4:
5. SMS2 should be further modernized along with CCP in such a way that HRM is
included in the process thus producing Sheets and plates as final product.
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REFRENCES
1. William Callister (2003). MATERIAL SCIENCE AND METALLURY.
DELHI: WILEY.
2. DOCUMENTS AND SPECIFICATIONS PROVIDED BY THE INDIVIDUAL
SHOPS.
3. INTERNAL DOCUMENTS PROVIDED BY THE COMPANY
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