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====================================Ans5:C
the correct answer is C as eventually reactants will get used up and the rate will decrease.
Explanation:
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====================================Ans6:D
At higher temperature The activation energy remains the same, but more
particles have this required activation energy, and therefore the reaction
proceeds at a faster rate.
-10>-20
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====================================Ans7:B
the answer for your question is B because it doesnot involve any breaking of
bonds its only two reactive free radicals joining together in a termination
step.
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====================================Ans8:D the dense
gas have heavier Mr
.multiplied the percentage of each gas by it's molar mass
overall Mr of "D" is higher. you can calculate it like this:
[82.3%(2)+15.2%(4)+2.3%(16) ]/100=2.62
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====================================Ans9:A
a change in the number of moles of N2 must be accompanied by a change in the number of moles
of H2 and NH3.
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====================================Ans10:D
45.98) =61.79
45.98/61.79 X 100=74.41
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====================================Ans11:
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====================================Ans12:D
Without the argon, strontium oxide would form in the air.as argon provide
inert environment without it it ll ignite in air
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====================================Ans13:A
Of the four metals given, only barium will react with water and has an insoluble sulfate.
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====================================Ans14:B
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====================================Ans15:C
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====================================Ans16:C
1.change in oxidation number of sulfur=6-6 =0
0,2,8= ans C
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====================================Ans17:D
MgOH is basic, so the ammonium chloride neutralizes it, since it's acidic.
Mg(OH)2 is a base and it will react with an acid
It will not react with NaCl as it is a salt not an acid
It reacts with NH4Cl because it acts as an acid because NH4+ ion donates a
proton (Bronsted Lowry acid)
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====================================Ans18:C
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====================================Ans19:D
Si,P,Cl
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====================================Ans20:B
already.
In this case, the hydrogen becomes attached to the CH2 group, because the
CH2 group has more hydrogens than the CH group.
Notice that only the hydrogens directly attached to the carbon atoms at
either end of the double bond count. The ones in the CH3 group are totally
irrelevant.
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====================================Ans22:C
a C=C double bond is not oxidised by H+/Cr2O7 2cis-3-Hexen-1-ol has a primary hydroxl group therefore product is carboxylic
acid
CH3CH2CH=CHCH2CO2H
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====================================Ans23:B
1.CH3CHCl CH3
2.
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====================================Ans24:A
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====================================Ans25:B
Butan-2-ol is a good example of this, with no less than three different
alkenes being formed when it is dehydrated.
Dehydration of butan-2-ol leads to a mixture containing:
1.but-1-ene
2.cis-but-2-ene (also known as (Z)-but-2-ene)
3.trans-but-2-ene (also known as (E)-but-2-ene)
The dehydration of butan-2-ol
In the second stage, the positive ion then sheds a water molecule and
produces a carbocation.
The complication arises in the next step. When the carbocation loses a
hydrogen ion, where is it going to come from?
But-1-ene is formed.
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====================================Ans27:C
Concentrated phosphoric(V) acid, H3PO4, can be used instead.
The dehydration of ethanol
Ethanol can be dehydrated to give ethene by heating it with an excess of
concentrated sulphuric acid or Concentrated phosphoric(V) acid, H3PO4at
about 170C.
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====================================Ans28:B
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====================================Ans29:D
the two carboxylic acids would react with sodium hydroxide to give salts. However
the two esters would be hydrolysed, giving an alcohol and a sodium salt of a
carboxylic acid in each case.
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====================================Ans30:A
Addition Polymerization of alkene involves breaking its pi-bond, forming a
new sigma bond.
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====================================Ans31:A
Ar is neutral therefore # of electron = 18
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====================================Ans32:C
key word
BOTH
things present in the equilibrium. The only thing that changes an equilibrium
constant is a change of temperature.
3.An increase in temperature will not change the activation energy of the reaction
1n 3 correct so A
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====================================Ans35:A
coordinate covalent bond
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====================================Ans38:A
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====================================Ans39:A
Several methods exist for the preparation of alcohols in the laboratory.
hydrolysis of a bromoalkane with NaOH(aq)
Primary alkyl halides react with aqueous NaOH or KOH mainly to primary
alcohols in nucleophilic aliphatic substitution. (Secondary and especially
tertiary alkyl halides will give the elimination (alkene) product instead.
reduction of a ketone with NaBH4
Aldehydes or ketones are reduced with sodium borohydride or lithium
aluminium hydride (after an acidic workup).
Alkenes engage in an acid catalysed hydration reaction using concentrated
sulfuric acid as a catalyst which gives usually secondary or tertiary alcohols.
The hydroboration-oxidation and reduction of alkenes are more reliable in
organic synthesis.
Grignard reagents react with carbonyl groups to secondary and tertiary
alcohols
Noyori asymmetric hydrogenation is the asymmetric reduction of -ketoesters
The formation of a secondary alcohol via reduction and hydration is shown:
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====================================Ans40: D
Hydrogen cyanide adds to the carbonyl groups of aldehydes and most
ketones to form compounds called cyanohydrins. (Ketones in which the
carbonyl group is highly hindered do not undergo this reaction.)
A chirality center is a tetrahedral carbon atom that is bonded to four different
groups.
1.the product of butanal: the first carbon atom will have a hydroxyl group, a