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1.1 Biomes
The World is the BIOSPHERE
As in all of the living that occur on the earth and their interactions with all other non-living thing
things
It is very difficult to study the world, as there is much variation
Ecology divides the Biosphere up into chunks that are easier to study
Biomes
Biomes are the largest division of the biosphere
There are 8 land biomes (terrestrial) & many more aquatic biomes
Defined broadly by their BIOTIC (living) and ABIOTIC (non-living) factors
Factors that Affect Biome Conditions
Certain factors affect TEMPERATURE and PRECIPITATION, which are the main conditions of a
biome:
- Latitude
- Elevation
- Ocean currents
Latitude
Measured in degrees from the equator
Areas closest to the equator have a more constant temperature
Elevation
The higher you go, the less atmosphere you have on top of you
Thinner atmosphere holds less heat
Ocean Currents
CONVECTION cycles warm water from the equator up to the poles (bringing cool water back to the
equator)
Water is a heat sink (high specific heat) that can stabilize temperatures
Adaption to Biomes
Plants and animals will often evolve adaptations to better suit their biomes condition
3 main types:
- Structural
- Physiological
- Behavioural
Structural Adaptation
An outward physical change to an animal (or plant) that gives it better chance to survive
Ex. Opossum has a prehensile (can grab and curl) tail
Physiological Adaptation
Physiological adaptation is an adaptation that occurs within the animal (not surface)
Ex. Snake venom
Behavioural Adaptation
Adaptations to the behaviour of an animal
Ex. Squirrels storing nuts for the winter
Habitat
A division of the ecosystem
The place where the organism actually lives
Abiotic Interactions
Nutrients are chemicals that are required for growth and repair
Oxygen and sunlight are important for plant life
Soil is an integral nutrient store for plants
Species, Organisms, Populations and Communities
A species is a group of organisms that are so closely related they can reproduce
A population is all of one particular species in an area (ex. herd)
A community is all of the populations in one ecosystem
Biotic Interactions
Commensalism
An interaction between two species where one is helped, but the other is not affected
Ex. Remora shark attaching to whales or larger shark to feed off of messy eating
Mutualism
Both organisms benefit from the interaction
Ex. Bees pollinate plants while gaining the means to make honey
Parasitism
One organism is harmed and the other is helped
Ex. Cymothoa Exigua replacing fish tongue
Competition
Two or more organisms compete for the same resource (food, habitat, etc.)
Predation
Occurs when one animals eats another
Some animals have developed means to hide (camouflage) or look like things that are poisonous
(miming)
There must be a way for CARBON, NITROGEN & PHOSPHORUS to cycle around in the biosphere
If there wasnt, then everything would be trapped in dead matter & there would be nothing to build
anything with
Nitrogen Cycle
Nitrogen is an important part of DNA, RNA and protons
It is also the most abundant gas in the Earths atmosphere (78%)
Plants are unable to use atmospheric nitrogen. It must be made available by certain processes.
Nitrogen Fixation
Atmospheric nitrogen (N2) is converted into NITRATE (NO3) or ammonium (NH4+)
N2 + 3H2 = 2NH3
nitrogen + hydrogen = ammonia fertilizer
Uptake
Now that the nitrogen has been converted into useable Nitrate, plants can uptake it and incorporate it
into proteins
This is how nitrogen is introduced into the food chain
Returning Nitrogen to the atmosphere
In order to maintain balance in an ecosystem, some nitrate must be converted back into atmospheric
nitrogen
This is done by DENITRIFYING BACTERIA
Nitrogen can also be cycled into the atmosphere in volcanic ash & nitrous oxide
Phosphorus Cycle
Phosphorus is an important part of DNA, RNA and bones
***1 of 3 nutrients that isnt found in the atmosphere***
Phosphorus is stored as Phosphate ions in rocks
Can be released by the process of WEATHERING (environmental breakdown)
POPs
Persistent Organic Pollutants
Typically pesticides like DDT (dichloro diphenyl trichloroethane)
Kills bugs very well, but toxic to man animals (thins bird shells)
Heavy Metals
Any metal of high density is considered a heavy metal
Examples: Lead, Cadmium, Mercury, Copper, Selenium
Lead
Used to be used in gas to stop rough idling
Also large amount in e-wash
Effects nervous and reproductive systems in humans
3.1 Change in the Ecosystem
Adaptive Radiation
Adaptive Radiation is where many different species evolve from one ancestral species
This allows species to inhabit different niches, lessening competition
Natural Selection
Organisms with traits that are beneficial to survive will be more likely to pass their genes on to future
generations
Ecological Succession
After serious damage has been done to an ecosystem (by natural disaster), there must be a way for
the land to be reclaimed
There processes are called ECOLOGICAL SUCCESSION, there are 2 types: - Primary - Secondary
Primary Succession
Reclaiming land from rock (like after a volcanic eruption)
Step 1:
! Spores from lichen & other PIONEER SPECIES are blown in on the wind or, are carried in
on birds
! Pioneer species are organisms that are capable of living and growing in harsh conditions
Step 2:
! Pioneer species consume rock, breaking it down & releasing nutrients
! When the organism dies and rots, it adds to the growing layer of soil
Step 3:
! Plants and other organisms take hold, animals move in. Eventually a MATURE
COMMUNITY (a.k.a. CLIMAX COMPOUND) is achieved
Secondary Succession
Happens after a forest fire or other catastrophic event where the soil remains
Just like primary succession, but it starts at the point where the plants take hold and animals move
in
Natural Disasters
Flooding
Can cause soil erosions, and large amounts of property damage
Sometimes causes raw sewage to be released into populations causing disease
Tsunami
Caused by underwater earthquakes or mudslides
Massive damage from concussive force of the wave
Salt can cause problems in ecosystems
Drought
Below average precipitation
Can cause problems with farming and livestock
Major issue with changing climate
Insect Infestation
Introduced species of insect can cause serious harm to plants, in an ecosystem
As the plants are also habitat for many other creatures, the whole ecosystem suffers
Pine Beetle
Burrows into older, weaker pine trees
Younger pine trees produce resin that flushes them out
Blue Stain Fungus
Stressed trees (drought, overcrowding, etc.) produce less resin and are unable to fight off the
beetle
The beetle has developed a symbiotic relationship with the blue stain fungus that inhibits resin
production
Warmer winter temperature kills off less beetles
Sustainability
The use of resources in a manner that allows the resource to recover
Resource Use
Refers to the way in which humans acquire and use materials like gas, oil, wood
If we are talking about how land is used, we call it LAND USE
Problems with Human Expansion
Human-built roads and other pathways divide ecosystems into smaller fragments
This will affect wildlife and plant seed movement
Habitat Loss
Refers to the complete destruction of an ecosystem
The habitat can no longer support the plants and animals that are native to it
Deforestation
Where trees are cut down and not replaced
Can lead to soil degradation (no roots to hold nutrient rich soil in place) it will wash away/ erode
with rain
Effects of Agriculture
Loss of biodiversity in the region (only growing one or two crop plants)
Tractors and other farm machinery can cause SOIL COMPACTION which harms soil health
This compaction can increase the amount of run-off (rain water washing away nutrients) and
increase the amount of nitrogen and phosphorus
Excess grazing animals can also stress the land through compaction and loss of plant biomass
Aeration
Punching out plugs of earth can help allow air and nutrients to reach the root systems
Effects of Exploitation
Contamination
Toxins from manufacturing can leach into the environment, harming living things
Over Exploitation
The use of a resource till it is completely exhausted
Can cause extinction
Overexploitation and Food Webs
Certain species are critical to the success of an ecosystem (typically because they are food for
many things). These species are known as KEYSTONE SPECIES
Harming the health of a keystone species can have devastating effects on the ecosystems
Orcas
Orcas used to eat these sperm whales
Now that they werent around anymore they had to eat harbour seals, sea lions, fur seals, and sea
otters
The result of this was a lack of sea otters
Sea otter eat sea urchins, without them, the sea urchins grew out of control (and ate through much
of our kelp forests)
Kelp forests are very important marine ecosystems
In the end
Preying on sperm whales lead to a large decline in kelp forests
3.3 Introduced Species
Native and Foreign Species
A native species is a species that belongs in a given ecosystem
Foreign species are species that are not native to an ecosystem
These foreign species can be INTRODUCED (brought in) on purpose or accident
Some of these introduced species can be considered INVASIVE if they harm the native species r
take over their habitat
Competition
The invasive species competes with the native species for resources
Ex. The Africanized honey bee
Invasive species often have advantages over the native species as they lack in natural predators in
the new environment
Invasive species arent all bad they can be very useful (Asian carp)
Habitat Alteration
The invasive species alters the habitat, negatively affecting the native species
Ex. the Kudzu vine
Predation
The invasive species actively hunts and eats the native species.
Ex. the Cane toad
Disease or Parasitism
Invasive species either bring disease or is itself a parasite
Ex. Tongue eating louse
4.1 Atomic Theory and Bonding
What is an ELEMENT?
Anything you can see on the PERIODIC TABLE is an ELEMENT
An element is a PURE SUBSTANCE
Elements cannot be broken down by chemical means
The smallest piece of an Element
The smallest piece of an element that still has properties of that element is an ATOM
What is a COMPOUND?
A compound is two or more atoms CHEMICALLY BONDED TOGETHER IN A SPECIFIC MATTER
A compound s a PURE SUBSTANCE
The smallest piece of a compound
The smallest piece of a compound that still has properties of that compound is a MOLECULE
What are atoms made of?
Atoms are made up of 3 subatomic particles: PROTONS, NEUTRONS, ELECTRONS
PROTONS
Protons live in the nucleus
Have a mass of 1 Atomic Mass Unit (a.m.u.)
Has an electric charge of +1
NEUTRONS
Neutrons also live in the nucleus
Have a mass ever so slightly larger than a proton (still considered 1 amu)
Has an electric charge of 0
ELECTRONS
Electrons live in orbit around the nucleus
Have so little mass, they are considered to be massless (9.1x10-31kg)
Has an electric charge of -1
How to figure out how many of each there are in an atom?
The ATOMIC NUMBER (abbreviated z) is usually located on top of the atomic symbol
The atomic number is the number of protons in the element
The number of protons DEFINES THE ELEMENT (42 protons is Mo 41 is Nb)
Neutrons
The ROUNDED ATOMIC MASS is basically equal to protons and neutrons
# of Neutrons = rounded atomic mass - atomic number
Ex. Molybdenum
N = 96 - 42
N = 54 neutrons
Ion Formation
Remember that the number of protons defines the atoms
Ion Formation
Remember that the number of protons defines the atoms
When an atom gains or loses electrons, it will become charged. We call these things IONS
Ions form because atoms want to have a full outer (valence) shell of electrons
How to judge the charge?
Look at the upper right hand corner for the charge
If the ion is a positively charged ion, it is a CATION
If the ion is a negatively charged ion, it is a ANION
How do we figure out protons, neutrons and electrons for ions?
The # of protons and neutrons will be the same as if you are calculating them for an atom
You must consider the charge of the ion to get the electrons
+2+ - lose electrons
"-2 - add electrons
Bohr Models
Electrons live in orbits
Remember this pattern (you can count it off the period table): 2,8,8
Take your total number of electrons, and start filling shells till you have found them all a home
Nitrogen:
#p = 6
#n = 6
#e = 6
Carbon:
#p = 7
#n = 7
#e = 7
Oxygen:
Oxygen Ion:
Lewis Structures
Only show the outer (valence) electrons
Binding pairs of electrons are shown on a line
Oxygen Atom:
Oxygen Ion:
Step 3: Place remaining electrons around the atoms to fill up the valence shell
Remember the OCTET rule: Each atom wants 8 electrons (except H, which wants 2)
Ex.
The number of electrons has to equal the
total number of valence electrons (Step 1)
Ex.
Ex.
Bohr:
Lewis:
Ionic
LiCl
CaF2
Covalent
- Share electrons
- Bohr: balls
- Lewis: lines
- Has a charge
- Non-metal vs. metal
Diatomic molecule - Pair of atoms of the same element that are joined together by COVALENT
bonds.
Ex. Br2, N2, O2, C2 HOFBriINCl
4.2 Names and Formulas Compounds
Multivalent Metals
You have to use the charge of the anion to figure out the roman numeral
Roman numerals are used to show the charge: I, II, III, IV, V, VI, VII, VIII, IX, X
Ex. What is the name of FeCl3 = Iron (III) Chloride
Formula for Copper (II) Bromide = CuBr2
Osmium (IV) Nitride = Os3N4
What About Polyatomic Ions
You will occasionally see things that are not on the periodic table in a name (such as Carbonate or
Perchlorate)
In a formula, it will appear as a grouping atoms (KNO3 for instance)
They are treated as a single entity, and their endings are NOT changed
Brackets may have to be used to show that there is more than one of the polyatomic ion in
question
Ex. Ca(NO3)2 is different from CaNO32
What is the name of the following compounds?
Mg(NO3)2
=
Magnesium Nitrate
NH4Cl
=
Ammonium Chloride
What is the formula for:
Aluminum bicarbonate
Sodium acetate
Iron (III) sulfide
Rhenium (VII) phosphite
=
=
=
=
Al(HCO3)2
NaCH3COO
Fe(HS)3
Re3(PO3)7
Covalent Compounds
Covalent compounds are NON-METAL bonded to NON-METAL
The rules for these are slightly different
DO NOT EVER REDUCE THE SUBSCRIPT ON COVALENT COMPOUNDS
The Only Prefix Rule
If the 1st element in the only one (its a mono) we dont use the mono
Ex. CO = Carbon monoxide NOT monocarbon monoxide
Ex. N2H4 = Dinitrogen tetrahydride
Ex. Dihydrogen monoxide = H2O
Ex. Dicarbon hexahydride = C2H6
4.3 Chemical Equations
Balancing Equations (Making sure the world doesnt end)
Remember what an equation looks like: REACTANT PRODUCTS
Why will the world end?
The Law of Conservation of Mass States:
Matter cannot be created nor destroyed, only changed from one form to another
Ex. Magnesium metal reacts with Oxygen gas to form Magnesium oxide
Mg(s) + O2 (g) MgO(s)
2Mg + O2 = 2MgO
Phases
(s) = Solid
(aq) = Aqueous dissolved in solution
(l) = Liquid a pure liquid
(g) = Gas
We use coefficients to make sure we have equal number of atoms on each side of the equation
pH Indicators
There are solutions that will change colour in certain pH ranges (see p. 224)
You can use this to dial in the pH of an unknown substance
5.2 Salts
What is a salt?
A salt is an ionic compound (a metal and a non-metal), that is the non-water product of an acid/
base reaction
Ex. HBr + NaOH NaBr + H2O
acid + base salt + water
Metal Oxide
A metal oxide is a metal reacted with an oxide
When a metal oxide is dissolved in water, you create a base
Ex. MgO + H2O Mg(OH)2
Mg oxide + water base
Ex. Calcium oxide reacts with water
CaO + H2O Ca(OH)2
Non-metal Oxide
Non-metal bonded to an oxide
When a non-metal oxide (unofficial: nmo) is placed in water, you get an acid
Ex. SO2 + H2O H2SO3
nmo + water acid
Ex. Carbon dioxide reacts with water
CO2 + H2O H2CO3
Metals Reacting with Acids
Metals will react with acids to create a salt and hydrogen gas
Ex. H2SO4 + 2Na Na2SO4 + H2
Carbonates and Acid rain
H2SO4 and HNO3 are the main acid components of acid rain
These acids react with the carbonate ions found in limestone around many lakes to neutralize it,
protecting the ecosystem
Some lakes do not have limestone, so they will become acidic
5.3 Organic Compounds
Organic Compounds Must Contain Carbon
Almost all compounds that contain carbon are considered ORGANIC
Except:
Carbonates (anything with CO3-2)
Carbides (for now anything with a Carbon at the end of the formula)
Oxides of Carbon
Methods of Drawing Organic Compounds
Structural formula
Drawn out like a Lewis structure, except no lone pairs shown
Hydrocarbons
Hydrocarbons contain ONLY Carbon and Hydrogen
Many of them are fuels (methane, propane, butane, etc.)
Alcohols
Contain a covalently bonded OH group in the formula
All alcohols are poisonous
Commonly used as solvents
Acid Base
An acid (H in front) reacts with a base (OH in the back) to create a salt & water
Ex. Hydrobromic acid (HBr) reacts with sodium hydroxide
HBr + NaOH NaBr + H2O
acid + base salt + water
Combustion
A hydrocarbon reacts with oxygen to form Carbon dioxide and water
C10H8 + 12O2 " 10CO2 + 4H2O
If the hydrocarbon has a S or a N in it, SO2 and NO2 will be produced as well
Ex. 2C2H7N + 9O2 " 4CO2 + 7H2O + 2NO2
2C2H7S + 15O2 " 8CO2 + 10H2O + 2SO2
6.2 Factors Affecting Reaction
Collision Theory
A chemical reaction happens when particles collide with
! The correct orientation
! Enough energy to begin the reaction (Activation energy)
Temperature
Temperature is the average kinetic energy of all particles in a sample
If you increase the temperature, you increase the numbers of particles that have enough energy to
undergo a reaction
Increasing temperature also increases the number of collisions, but it is far less of an effect
Concentration
The concentration of a solution is now much SOLUTE is dissolved in a certain amount of
SOLVENT
If you have more SOLUTE, then there are more particles to undergo collisions, and thus the rate of
reaction will increase
Surface Area
Only effects heterogeneous (different phases) systems (and solid/solid**)
If you increase the surface area, you are increasing the amount of stuff in contact, allowing for
more collisions
Increasing surface area increases the reaction rate
Catalysts
A catalyst is something that is not consumed (or is consumed and regenerated) in a reaction and
increases the rate
Catalysts do this by lowering the amount of energy required for a successful collision
Sometimes an isotope is unstable, and will emit radiation to become more stable
There are 3 types: alpha, beta and gamma
7. 2 Half-Life
What is half-life?
Half-life is the amount of time it takes for half of a substance to decay (become something else)
An elements half-life is constant. (Ex. Carbon-14 has a half-life of 5730 years. This doesnt
change EVER)
As a result, you can use the amount of a substance that remains as a clock to tell how old
something is Carbon dating, potassium clock, etc.)
Decay Curves
Because everything decays in the same way, all decay curves will look the same
The difference is that the time scale on the bottom will differ
Velocity ()
The displacement of an object during a time interval divided by the time interval
Describes how fast an objects position is changing
!
Equation: =
Plate Interactions
When 2 plates come together, there are 3 things that can happen:
! They move away from each other (Divergent)
! They can come together (Convergent)
! They can slide past each other (Transform)
Divergent Plate Interactions
The 2 tectonic plates in question are moving apart from each other
The gap is known as a rift
Convergent Plate Interactions
There are 2 types of place: Oceanic and Continental
Oceanic plates are more dense than continental plates
Oceanic/ Continental Convergence
The more dense oceanic plate will slide underneath the continental plate
This cause a SUBDUCTION ZONE
A deep underwater valley, called a TRENCH forms where the plates made contact
You will see volcanoes slightly inland due to excess molten rock
Oceanic/ Oceanic Convergence
Cooling causes one plate to be denser than the other
One of the 2 plates will cool slightly faster and slip underneath the other one
You will find trenches at the boundary and volcanic chains nearby
Continental/ Continental Convergence
Neither plate is dense enough to sink so they push upwards making a large mountain range like
the Himalayas