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02/01/2010
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component
CAS-No.
Concentration
25068-38-6
77.0 - 80.0%
Ethyl acetate
141-78-6
20.0 - 23.0%
3. HAZARDS IDENTIFICATION
Emergency Overview
Appearance
Form
liquid
Colour
Pale yellow
Odour
Solvent odor
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Hazard Summary
WARNING!
Flammable.
Material can cause the following:
irritation of nose, throat, and lungs
Skin irritation
Eye irritation
central nervous system (CNS) effects
liver effects
Kidney effects
Inhalation may cause dizziness, headache and incoordination.
May cause sensitization by skin contact.
Eye contact
Inhalation
Skin contact
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5. FIRE-FIGHTING MEASURES
Flash point
Ignition temperature
Lower explosion limit
Upper explosion limit
Suitable extinguishing media:Use the following extinguishing media when fighting fires involving this
material:
Water spray
Foam
Carbon dioxide (CO2)
Dry chemical
Specific hazards during fire fighting: Vapors can travel to a source of ignition and flash back. Heated
material can form flammable or explosive vapors with air. Closed containers may rupture via pressure
build-up when exposed to fire or extreme heat. During a fire, irritating and highly toxic gases and/or
fumes may be generated during combustion or decomposition.
Special protective equipment for fire-fighters: In the event of fire, wear self-contained breathing
apparatus.
Further information: EXPLOSION HAZARD. Fight advanced fires from a protected location.
Cool closed containers exposed to fire with water spray.
Remain upwind.
Avoid breathing smoke.
Contain run-off.
LAMAL CR-1-80
Storage
Storage conditions: Avoid temperature extremes during storage; ambient temperature preferred.
Store away from excessive heat (e.g. steampipes, radiators), from sources of ignition and from reactive
materials. Material can burn; limit indoor storage to approved areas equipped with automatic sprinklers.
Store out of direct sunlight in a cool place. Keep containers tightly closed in a cool, well-ventilated place.
Avoid all ignition sources. Ground all metal containers during storage and handling.
Other data: STIR WELL BEFORE USE.
Further information:
CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Since emptied containers retain product
residue follow all MSDS and label warnings even after container is emptied.
Improper disposal or re-use of this container may be dangerous and illegal. Refer to applicable local,
state and federal regulations.
Bisphenol-A, Epichlorohydrin
Polymer
Component
Ethyl acetate
Regulation
Regulation
Type of listing
TWA
Type of listing
TWA
STEL
TWA
REL
PEL
TWA
Value
10 mg/m3
Value
150 ppm
300 ppm
400 ppm
1,400 mg/m3 400 ppm
1,400 mg/m3 400 ppm
1,400 mg/m3 400 ppm
Eye protection: Use chemical splash goggles (ANSI Z87.1 or approved equivalent). Eye protection
worn must be compatible with respiratory protection system employed.
Hand protection: Chemical-resistant gloves should be worn whenever this material is handled. The
glove(s) listed below may provide protection against permeation. (Gloves of other chemically resistant
materials may not provide adequate protection): 4H Glove (Trademark of Safety 4 A/S of Denmark)
butyl-rubber Gloves should be removed and replaced immediately if there is any indication of
degradation or chemical breakthrough. Rinse and remove gloves immediately after use. Wash hands
with soap and water.
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Skin and body protection: Use chemically resistant apron or other impervious clothing to avoid
prolonged or repeated skin contact. Where splashing is possible, full chemically resistant protective
clothing (e.g. acid suit) and boots are required.
Respiratory protection: A respiratory protection program meeting OSHA 1910.134 and ANSI Z88.2
requirements or equivalent must be followed whenever workplace conditions warrant a respirator's use.
None required if airborne concentrations are maintained below the exposure limit listed in Exposure
Limit Information. Up to 1000 ppm organic vapor: Wear a properly fitted NIOSH approved (or
equivalent) full-facepiece, air-purifying respirator, OR full facepiece, airline respirator in the pressure
demand mode. Above 1000 ppm organic vapor or Unknown: Wear a properly fitted NIOSH approved (or
equivalent) self-contained breathing apparatus in the pressure demand mode, OR full-facepiece, airline
respirator in the pressure demand mode with emergency escape provision.
Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower.
Engineering measures: Use explosion-proof local exhaust ventilation with a minimum capture
velocity of 100 ft/min (0.5 m/sec) at the point of vapor evolution. Refer to the current edition of Industrial
Ventilation: A Manual of Recommended Practice published by the American Conference of
Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of
exhaust systems.
liquid
Pale yellow
Solvent odor
Not Applicable
77 C ( 170.60 F) Ethyl acetate
-84.00 C ( -119.20 F) Ethyl acetate
-4 C ( 24.80 F) Tag closed cup
426 C (798.80 F) Ethyl acetate
1.10 %(V)Xylene
11.50 %(V)Ethyl acetate
97.3333 mmHg at 20 C (68.00 F) solvent
3.7Xylene
insoluble
1.11
no data availableno data available
6.20 Ethyl acetate
22 - 26 %
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
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Materials to avoid
Hazardous
There are no known hazardous decomposition products for this material.,
decomposition products
polymerisation
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Toxicity to fish
Toxicity to algae
EC50 Algae 96 h
2,000 mg/l
Toxicity to aquatic
invertebrates
Disposal
Waste Classification: 40 CFR 261.20 - .24 - Characteristic Waste D001, 100 lbs.
When a decision is made to discard this material as supplied, it is classified as a RCRA hazardous waste
with the characteristic of ignitability.
For disposal, incinerate this material at a facility that complies with local, state, and federal regulations.
(See 40 CFR 268)
Contaminated packaging: Empty containers should be taken to an approved waste handling site for
recycling or disposal.
DOT
Proper shipping name
UN-Number
Class
Packing group
Marine pollutant
Resin solution
UN 1866
3
II
bisphenol-A-(epichlorhydrin) polymer
IMO/IMDG
Proper shipping name
UN-Number
Class
Packing group
Marine pollutant
RESIN SOLUTION
UN 1866
3
II
bisphenol-A-(epichlorhydrin) polymer
Transportation classifications may vary by container volume and may be influenced by regional or
country variations in regulations
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SARA TITLE III: Section 311/312 Categorizations (40CFR370): Acute Health Hazard
Chronic Health Hazard
Fire Hazard
141-78-6
5,000 lbs RQ
US. Toxic Substances Control Act (TSCA): All components of this product are in compliance with
the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical
Substance Inventory.
Pennsylvania
Any material listed as "Not Hazardous" in the CAS REG NO. column of SECTION 2,
Composition/Information On Ingredients, of this MSDS is a trade secret under the provisions of the
Pennsylvania Worker and Community Right-to-Know Act.
Health
Fire
Reactivity
1*
3
HMIS: * = Chronic Effects (See Hazards Identification)
HMIS
Legend
ACGIH
BAc
Butyl acetate
OSHA
PEL
STEL
TLV
TWA
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and
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may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text.
Version: 2.3
Print Date: 09/05/2013
Layout 000101105168
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