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(Eq. 1)
where q is expressed in joules. Note that for an exothermic reaction, the heat lost during a chemical
reaction is exactly the same as the heat absorbed by the universe, hence the minus sign in the equation.
For chemical changes that take place inside a calorimeter, the system is considered to be isolated from
the rest of the universe so theoretically, all the energy released by the chemical reaction stays in the
calorimeter. For reactions that take place in solution, the heat of reaction changes the temperature both
of the solution and the calorimeter.
The heat of the reaction is then expressed as
qreaction = - (qproduct solution + qcalorimeter)
(Eq. 2)
(Eq. 3)
where s is the solution specific heat in J/g C, m is the solution mass and T is the temperature
change. Some of the heat given off by the reaction also raises the calorimeter temperature as given by:
qcalorimeter = C T
(Eq. 4)
where C is the calorimeter constant in J/C. The constant C must be determined experimentally for
each individual calorimeter apparatus.
Combining equations (2), (3) and (4) expresses the heat of reaction as:
qreaction = - (s m T + C T)
(Eq. 5)
(Eq. 6)
Specific heat and density values for all salt solutions that can be produced in this experiment are listed
in Table 1. Each solution mass will be calculated from the total measured solution volume and the
tabulated solution density. The reaction T is determined from a temperature vs. time graph of the
system where T is measured before and after mixing the reactants. The calorimeter constant in this
experiment is determined from the temperature change that occurs when cold and warm water are
mixed in the calorimeter in the absence of a chemical reaction.
For an acid-base neutralization reaction, the enthalpy of the reaction is called the enthalpy of
neutralization, which is the measured heat of reaction per mole of water formed. This is calculated
using the equation
Hneutralization = qneutralization /mole water formed
(Eq. 7)
The moles of water produced will be calculated from your acid solution volume, its concentration and
the reaction stoichiometry. You will compare your experimental reaction H value with the calculated
reaction H value that you determine from the data in Table 3.
When describing solution concentrations, normality (N, expressed in equivalents per liter) is
sometimes used instead of molarity. This is because some acids such as sulfuric acid donate more than
one mole of protons per mole of acid and some bases such as Ba(OH)2 accept more than one mole of
protons per mole of base. The normality of an acid or base solution is the solution molarity times the
number of protons per mole the acid can donate or the base can react with. A 1.00 M H2SO4 solution is
2.00 N since sulfuric acid is diprotic.
For your experiment you will carry out just one of the reactions listed in Table 1 on the next page.
Your instructor will tell you which one to do. In each case, a 2.00 N acid solution will react
completely with a 2.00 N base solution to give water and the indicated salt. The concentration of each
salt formed will be 1.00 N, not 2.00 N, since the final solution volume is double the initial volume.
Make sure to name your system in your report.
Remember that in each case, moles of water produced equals moles of base used. Also in each case,
0.200 N base equals 0.200 M base. Calculate the moles of base from the molarity of your assigned
base and the volume of base used (always 50.00 mL).
Assigned Reaction Systems: For your experiment, you will be assigned to carry out just one of the
reactions listed in Table 1:
Table 1: Equations for Neutralization Reactions
System No
Neutralization Reaction
10
11
12
Solution
1
2
3
4
5
6
7
8
9
10
11
12
H2O
Na2SO4
Na3PO4
NaCl
NaNO3
KNO3
KCl
K2SO4
K3PO4
NH4NO3
NH4Cl
(NH4)2SO4
(NH4)3PO4
Salt
Salt
Concentration Concentration
(M)
(N)
0.500
1.00
0.333
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.500
1.00
0.333
1.00
1.00
1.00
1.00
1.00
0.500
1.00
0.333
1.00
3
Solution
Specific Heat
(J/g C)
4.184
3.77
3.81
3.89
3.81
3.80
3.87
3.75
3.78
3.86
3.95
3.81
3.86
Solution
Density
(g/mL)
1.00
1.12
1.11
1.04
1.06
1.07
1.05
1.14
1.13
1.04
1.02
1.09
1.08
EXPERIMENTAL
You should not necessarily do the experiments in the order 1, 2, 3. The supply of special thermometers
is limited and there will be a wait for access to the reactant bottles if everyone wants them at the same
time. Its better for half the class to start with Trial 2 which requires acid and base reagents and one
thermometer rather than for everyone to start with Trial 1, which requires two special thermometers
but no reagents.
Trial 1: Calorimeter Constant
Two special 0.01 C thermometers are required for this part, one to monitor the room temperature cup
of water and one for the cup of hot water. Weigh a coffee cup calorimeter (2 nested coffee cups) to
0.001 g. Remove the calorimeter from the balance and pour about 50 mL of room temperature
distilled water from the lab carboy into it. Reweigh the calorimeter containing water to find the mass
of the water. Repeat this process weighing about 50 mL more distilled water into a clean, dry 100 mL
beaker.
Hang a 0.01 C thermometer from a ring stand and clamp with a paper clip so that its bulb is
completely immersed in the calorimeter water without touching the sides or the bottom of the cup.
Heat the water in the beaker on a hotplate with occasional stirring. Measure its temperature with an
ordinary 0.1C thermometer until it reaches about 40C. Place the beaker containing the hot water on
an insulating board or book and suspend a 0.01 C thermometer in it as you did for the calorimeter.
For a 4.5 minute period, use the hanging thermometers to stir and record temperature-time data for the
two containers of water at half minute intervals. Measure both temperatures to 0.01C. At the fiveminute mark, while stirring the water in the calorimeter, rapidly pour the beaker of hot water into the
cold water. Continue to stir occasionally and record temperature-time data for ten more minutes at half
minute intervals.
Trials 2 and 3: Neutralization Reaction
Only one special 0.01 C thermometer is required for this part. Since the acid and base reactant
solutions will have been stored close together for several hours in the same room, you can assume that
the temperature of one is the same as that of the other. You will be assigned one of the chemical
systems listed in Table 1. The acid concentrations are: [HCl] = 2.00M = 2.00N; [HNO3] = 2.00M =
2.00N; [H2SO4] = 1.00M = 2.00N; [H3PO4] = 0.667M = 2.00N. The NaOH, KOH and NH4OH base
concentrations are all 2.00M = 2.00N.
Pipet 50.00 mL of your assigned acid into a clean, dry calorimeter. Pipet 50.00 mL your assigned
0.200 N base solution into a clean, dry 100 mL beaker. Suspend a 0.01 C thermometer from a ring
stand so the thermometer bulb is fully immersed in the acid solution. Since the acid and base solutions
are stored together in the laboratory for several hours before the experiment, you can assume they are
at the same temperature. For a 4.5 minute period, stir occasionally and record temperature-time data
for the acid solution at half-minute intervals.
At the five minute mark, while stirring the acid in the calorimeter, rapidly pour the NaOH solution into
the acid. After the solutions are well mixed, stir occasionally and record temperature-time data for ten
more minutes.
Do a second neutralization reaction, Trial 3 with the same acid-base pair you used in Trial 2.
Time of mixing
38
Temperature (C)
36
34
32
y = mwarmx + bwarm
30
28
y = mmixx + bmix
26
24
22
y = mcoolx + bcool
20
0
10
11
12
13
14
15
Time (min)
To find the initial temperature for each trial, extrapolate the straight line temperature vs. time plot
before mixing the solutions to the vertical line representing the five minute mixing moment. To find
the final temperature after mixing, extrapolate the straight line plot after mixing back to the five
minute mixing line.
Trial 1: Calorimeter Constant
For Trial 1, use Equation 3 twice, once to calculate heat lost by the warm water and once to calculate
heat gained by the cool water. Heat gained by the cold water equals the original mass of cold water
times the specific heat of water times its temperature change. Heat lost by the hot water equals the
original mass of hot water times the specific heat of water times its temperature change. The two heat
quantities will have opposite signs. You might expect them to have the same magnitude but they will
not. Some heat will be lost to the plastic cup calorimeter. This difference in heat, not temperature,
between the two qsolution quantities is the heat absorbed by the calorimeter. To find the calorimeter
constant in J/C, divide the heat absorbed by the calorimeter by the temperature change (T) of the
cool water.
Hf (kJ/mol)
H2O
HCl
HClO4
HNO3
H2SO4
H3PO4
NaOH
KOH
NH4OH (or NH3)
NaCl
KCl
NH4Cl
NaClO4
NaNO3
KNO3
NH4NO3
Na2SO4
K2SO4
(NH4)2SO4
Na3PO4
K3PO4
(NH4)3PO4
-285.8
-167.4
-129.3
-207.5
-909.2
-1277.4
-469.4
-479.9
-362.3
-407.1
-418.8
-299.6
-369.4
-446.4
-459.8
-339.7
-1387.0
-1408.8
-1174.4
-1987.4
-2032.9
-1674.9
Reagent Disposal:
Since they contain no heavy metals and are essentially pH neutral, all the salt solutions produced in
this experiment may be poured directly down sink drains without harming the environment. Unused
acid and base solutions, however, violate the pH limits of must municipal sewage systems and must be
disposed of as hazardous waste, preferably by pouring them into the heavy metal waste container
provided in the laboratory hood.
6
Time (min)
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
11.5
12.0
12.5
13.0
13.5
14.0
14.5
15.0
Mix Solutions
Instructors Initials______________
Trial 3
Solution
Temperatures
Acid Solution
Time (min)
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0 (Mix)
5.5
6.0
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
11.5
12.0
12.5
13.0
13.5
14.0
14.5
15.0
Salt Solution
Solution
Temperatures
Acid Solution
Salt Solution
Instructors Initials_____________
Plot temperature vs. time for your three trials and attach the graphs to this report.
2.
Use the information provided on p. 5 to calculate the calorimeter constant of your apparatus.
Show your setup here.
(2 points)
2.
(6 points)
(3 points)
3.
(3 points)
4.
(3 points)
5.
6.
(1 points)
Time (min)
6.0
7.0
8.0
9.0
10.0
11.0
12.0
13.0
14.0
15.0
Temperature (C)
23.25
23.27
23.28
23.30
23.30
23.35
23.44
23.47
28.35
Temperature (C)
28.50
28.55
28.48
28.32
28.25
28.20
28.05
27.96
27.80
27.75
The density of the product mixture was 1.02 g/mL and its heat capacity was 4.02 J/gC. The
calorimeter constant was 52.8 J/C.
1.
Write the balanced equation for the reaction between aqueous HCl and NaOH.
(1 point)
2.
Using Excel or Graphical Analysis, plot Temperature vs. Time. There will be two straight
lines, one before mixing and one after. The former line will allow you to find the initial temperature
and the latter line will give the final temperature.) Find the initial temperature of the acid and base
solutions and the final temperature of the mixture. Determine T for the reaction.
(4 points)
3.
4.
Calculate the enthalpy of neutralization per mole of water produced in the experiment.
(2 points)
12
(3 points)